CN104530354A - Environment-friendly high-flame-retardant yacht-interlayer buoyancy perfusion composite material and preparation method thereof - Google Patents
Environment-friendly high-flame-retardant yacht-interlayer buoyancy perfusion composite material and preparation method thereof Download PDFInfo
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- CN104530354A CN104530354A CN201410603090.3A CN201410603090A CN104530354A CN 104530354 A CN104530354 A CN 104530354A CN 201410603090 A CN201410603090 A CN 201410603090A CN 104530354 A CN104530354 A CN 104530354A
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- yacht
- interlayer
- buoyancy
- matrix material
- polyester polyol
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4018—Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4202—Two or more polyesters of different physical or chemical nature
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses an environmentally-friendly high-flame-retardant yacht-interlayer buoyancy perfusion composite material and a preparation method thereof. The composite material is composed of polyester polyol 1, polyester polyol 2, polyester polyol 3, polyether polyol, polyurethane silicone oil, a catalyst 1, a catalyst 2, tris(1-chloro-2-propyl)phosphate, water and isocyanate. The environment-friendly high-flame-retardant yacht-interlayer buoyancy perfusion composite material has high flame retardant property and is uninflammable when coming across fire, so the safety of the yacht and passengers is ensured; and meanwhile, raw materials used for the composite material are environment-friendly, so the composite material does not release substances poisonous and harmful to the human body and has no harm to human health.
Description
Technical field
The present invention relates to a kind of matrix material and preparation method thereof, particularly a kind of environmental protection high flame retardant yacht interlayer buoyancy perfusion matrix material and preparation method thereof.
Background technology
Yacht manufacturers of the prior art is constantly innovating the quality and the weather resistance that promote yacht materials, as introduced in the application of yacht structure by the matrix material of excellent property.Be typically provided with sandwich structure in the structure design of yacht, actual often take in interlayer, to pour into some matrix materials to alleviate the weight of hull when manufacturing, increase its stiffness and increase the buoyancy of hull, certain insulation and insulation effect can also be played simultaneously.But often flame retardant properties is not good for some yacht interlayer perfusion matrix material of the prior art, the easy initiation fire when running into fault or accident, thus has certain potential safety hazard.And the raw material sources of some perfusion matrix material not environmentally, often can volatilize some poisonous and hazardous materials, thus have harm to HUMAN HEALTH.
Summary of the invention
The object of the invention is to overcome defect of the prior art, provide a kind of environmental protection high flame retardant yacht interlayer buoyancy to pour into matrix material and preparation method thereof, described matrix material has very high flame retardant properties, and environment-protecting asepsis is to human body fanout free region.
The present invention is achieved by the following technical programs.
A kind of environmental protection high flame retardant yacht interlayer buoyancy perfusion matrix material, described matrix material is made up of the component of following quality proportioning: combined polyether Ju Zhi ︰ isocyanic ester=1.3 ︰ 1;
The formation of described combined polyether polyester is as follows according to the mass fraction:
Polyester polyol 1 35-45 part
Polyester polyol 2 55-60 part
Polyester polyol 3 25-35 part
Polyether glycol 15-25 part
Urethane silicone oil 2.5-3.6 part
Catalyzer 1 1.8-2.5 part
Catalyzer 2 1.0-1.5 part
Tricresyl phosphate (the chloro-2-propyl group of 1-) ester 35-45 part
Water 3.0-3.6 part.
Above-mentioned a kind of environmental protection high flame retardant yacht interlayer buoyancy perfusion matrix material, wherein, described isocyanic ester is isocyanic ester PAPL, is purchased from Dow Chemical.
Above-mentioned a kind of environmental protection high flame retardant yacht interlayer buoyancy perfusion matrix material, wherein, described polyester polyol 1 is polyester polyol CT400, is purchased from Jiangsu Fu Sheng novel material company limited.
Above-mentioned a kind of environmental protection high flame retardant yacht interlayer buoyancy perfusion matrix material, wherein, described polyester polyol 2 is polyester polyol 4450, is purchased from Yadong, Shijiazhuang Chemical Co., Ltd..
Above-mentioned a kind of environmental protection high flame retardant yacht interlayer buoyancy perfusion matrix material, wherein, described polyester polyol 3 is polyester polyol 1200, is purchased from Guangzhou Hairma Chemicals Ltd..
Above-mentioned a kind of environmental protection high flame retardant yacht interlayer buoyancy perfusion matrix material, wherein, described polyether glycol is polyether glycol 4110, is purchased from Dongchang, Zhengjiang City petroleum chemical plant.
Above-mentioned a kind of environmental protection high flame retardant yacht interlayer buoyancy perfusion matrix material, wherein, described urethane silicone oil is urethane silicone oil AK-8806, is purchased from Nanjing Dymatic Shichuang Chemical Co., Ltd..
Above-mentioned a kind of environmental protection high flame retardant yacht interlayer buoyancy perfusion matrix material, wherein, described catalyzer 1 is catalyzer D31, is purchased from Changzhou De Ye Chemical Co., Ltd..
Above-mentioned a kind of environmental protection high flame retardant yacht interlayer buoyancy perfusion matrix material, wherein, described catalyzer 2 is catalyst A 33, is purchased from Changzhou De Ye Chemical Co., Ltd..
The preparation method of above-mentioned a kind of environmental protection high flame retardant yacht interlayer buoyancy perfusion matrix material, preparation process is as follows: first prepare combined polyether polyester: by polyester polyol 1, polyester polyol 2, polyester polyol 3, polyether glycol, urethane silicone oil, catalyzer 1, catalyzer 2, tricresyl phosphate (the chloro-2-propyl group of 1-) ester and water add in reactor and carry out hybrid reaction, stirring velocity 80-120r/min, churning time 6-8h combined polyether polyester, and then combined polyether polyester is mixed with the mass ratio of isocyanic ester by 1.3 ︰ 1, matrix material of the present invention can be obtained.
The flame retardant properties of environmental protection high flame retardant yacht interlayer buoyancy perfusion matrix material of the present invention is high, meets fiery nonflammable, thus has ensured the security of yacht and the personnel safety of passenger.Simultaneously because the use raw material of described matrix material is environmental protection raw material, thus also can not discharge the poisonous and hazardous material of human body.
Embodiment
Below by way of specific embodiment, the specific embodiment of the present invention is described in further detail.
Embodiment 1
A kind of preparation method of environmental protection high flame retardant yacht interlayer buoyancy perfusion matrix material, preparation process is as follows: first prepare combined polyether polyester: by the polyester polyol CT400 of 35 parts, the polyester polyol 4450 of 55 parts, the polyester polyol 1200 of 25 parts, the polyether glycol 4110 of 15 parts, the urethane silicone oil AK-8806 of 2.5 parts, the catalyzer D31 of 1.8 parts, the catalyst A 33 of 1.0 parts, tricresyl phosphate (the chloro-2-propyl group of the 1-) ester of 35 parts and the water of 3.0 parts add in reactor and carry out hybrid reaction, stirring velocity 80r/min, churning time 6h combined polyether polyester, and then combined polyether polyester is mixed by the mass ratio of 1.3 ︰ 1 with isocyanic ester PAPL, matrix material of the present invention can be obtained.
Embodiment 2
A kind of preparation method of environmental protection high flame retardant yacht interlayer buoyancy perfusion matrix material, preparation process is as follows: first prepare combined polyether polyester: by the polyester polyol CT400 of 38 parts, the polyester polyol 4450 of 57 parts, the polyester polyol 1200 of 28 parts, the polyether glycol 4110 of 17 parts, the urethane silicone oil AK-8806 of 2.8 parts, the catalyzer D31 of 2.0 parts, the catalyst A 33 of 1.2 parts, tricresyl phosphate (the chloro-2-propyl group of the 1-) ester of 38 parts and the water of 3.2 parts add in reactor and carry out hybrid reaction, stirring velocity 100r/min, churning time 7h combined polyether polyester, and then combined polyether polyester is mixed by the mass ratio of 1.3 ︰ 1 with isocyanic ester PAPL, matrix material of the present invention can be obtained.
Embodiment 3
A kind of preparation method of environmental protection high flame retardant yacht interlayer buoyancy perfusion matrix material, preparation process is as follows: first prepare combined polyether polyester: by the polyester polyol CT400 of 43 parts, the polyester polyol 4450 of 59 parts, the polyester polyol 1200 of 32 parts, the polyether glycol 4110 of 23 parts, the urethane silicone oil AK-8806 of 3.4 parts, the catalyzer D31 of 2.3 parts, the catalyst A 33 of 1.4 parts, tricresyl phosphate (the chloro-2-propyl group of the 1-) ester of 42 parts and the water of 3.4 parts add in reactor and carry out hybrid reaction, stirring velocity 110r/min, churning time 8h combined polyether polyester, and then combined polyether polyester is mixed by the mass ratio of 1.3 ︰ 1 with isocyanic ester PAPL, matrix material of the present invention can be obtained.
Embodiment 4
A kind of preparation method of environmental protection high flame retardant yacht interlayer buoyancy perfusion matrix material, preparation process is as follows: first prepare combined polyether polyester: by the polyester polyol CT400 of 45 parts, the polyester polyol 4450 of 60 parts, the polyester polyol 1200 of 35 parts, the polyether glycol 4110 of 25 parts, the urethane silicone oil AK-8806 of 3.6 parts, the catalyzer D31 of 2.5 parts, the catalyst A 33 of 1.5 parts, tricresyl phosphate (the chloro-2-propyl group of the 1-) ester of 45 parts and the water of 3.6 parts add in reactor and carry out hybrid reaction, stirring velocity 120r/min, churning time 8h combined polyether polyester, and then combined polyether polyester is mixed by the mass ratio of 1.3 ︰ 1 with isocyanic ester PAPL, matrix material of the present invention can be obtained.
Be below the flame retardant properties test result of environmental protection high flame retardant yacht interlayer buoyancy of the present invention perfusion matrix material:
Inspecting standard requires: the combustionvelocity of fire retardant material should be not more than 100mm/min, if there is following situations, identifies test-results on request respectively, and assay is divided into A, B, C, D, E 5 grades:
A-(0mm/min): sample is exposed to 15s in flame, extinguish burning things which may cause a fire disaster sample still unburn, or sample can burn, but flame extinguishes before reaching the first measurement graticule, can count without burning extent.
B: during from tester, flame is self-extinguish in 60s, and burning extent is not more than 50mm, then think and meet standard-required.
C-combustionvelocity measured value (mm/min)
During from tester, flame is measured between graticule at two and is extinguished, and when not meeting the 2nd article of situation, then by criterion calculation combustionvelocity.
D-combustionvelocity measured value (mm/min)
During from tester, flame arrives the second graticule, or from timing, the long-time smoulder of sample, then can when tester termination test during 20min, and record combustion time and burning extent and by criterion calculation combustionvelocity.
E: sample has burnt and arrived the first graticule in flame ignition 15s, then think that sample can not meet the requirement of combustionvelocity.
Assay: A(0mm/min).
Here description of the invention and application is illustrative, not wants by scope restriction of the present invention in the above-described embodiments, and therefore, the present invention is not by the restriction of the present embodiment, and the technical scheme that any employing equivalence replacement obtains is all in the scope of protection of the invention.
Claims (10)
1. an environmental protection high flame retardant yacht interlayer buoyancy perfusion matrix material, it is characterized in that, described matrix material is made up of the component of following quality proportioning: combined polyether gathers ester ︰ isocyanic ester=1.3 ︰ 1;
The formation of described combined polyether polyester is as follows according to the mass fraction:
Polyester polyol 1 35-45 part
Polyester polyol 2 55-60 part
Polyester polyol 3 25-35 part
Polyether glycol 15-25 part
Urethane silicone oil 2.5-3.6 part
Catalyzer 1 1.8-2.5 part
Catalyzer 2 1.0-1.5 part
Tricresyl phosphate (the chloro-2-propyl group of 1-) ester 35-45 part
Water 3.0-3.6 part.
2. a kind of environmental protection high flame retardant yacht interlayer buoyancy perfusion matrix material as claimed in claim 1, it is characterized in that, described isocyanic ester is isocyanic ester PAPL.
3. a kind of environmental protection high flame retardant yacht interlayer buoyancy perfusion matrix material as claimed in claim 1, it is characterized in that, described polyester polyol 1 is polyester polyol CT400.
4. a kind of environmental protection high flame retardant yacht interlayer buoyancy perfusion matrix material as claimed in claim 1, it is characterized in that, described polyester polyol 2 is polyester polyol 4450.
5. a kind of environmental protection high flame retardant yacht interlayer buoyancy perfusion matrix material as claimed in claim 1, it is characterized in that, described polyester polyol 3 is polyester polyol 1200.
6. a kind of environmental protection high flame retardant yacht interlayer buoyancy perfusion matrix material as claimed in claim 1, it is characterized in that, described polyether glycol is polyether glycol 4110.
7. a kind of environmental protection high flame retardant yacht interlayer buoyancy perfusion matrix material as claimed in claim 1, it is characterized in that, described urethane silicone oil is urethane silicone oil AK-8806.
8. a kind of environmental protection high flame retardant yacht interlayer buoyancy perfusion matrix material as claimed in claim 1, it is characterized in that, described catalyzer 1 is catalyzer D31.
9. a kind of environmental protection high flame retardant yacht interlayer buoyancy perfusion matrix material as claimed in claim 1, it is characterized in that, described catalyzer 2 is catalyst A 33.
10. the preparation method of a kind of environmental protection high flame retardant yacht interlayer buoyancy perfusion matrix material as claimed in claim 1, it is characterized in that, preparation process is as follows: first prepare combined polyether polyester: by polyester polyol 1, polyester polyol 2, polyester polyol 3, polyether glycol, urethane silicone oil, catalyzer 1, catalyzer 2, tricresyl phosphate (the chloro-2-propyl group of 1-) ester and water add in reactor and carry out hybrid reaction, stirring velocity 80-120r/min, churning time 6-8h combined polyether polyester, and then combined polyether polyester is mixed with the mass ratio of isocyanic ester by 1.3 ︰ 1, matrix material of the present invention can be obtained.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410603090.3A CN104530354A (en) | 2014-10-31 | 2014-10-31 | Environment-friendly high-flame-retardant yacht-interlayer buoyancy perfusion composite material and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410603090.3A CN104530354A (en) | 2014-10-31 | 2014-10-31 | Environment-friendly high-flame-retardant yacht-interlayer buoyancy perfusion composite material and preparation method thereof |
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| CN104530354A true CN104530354A (en) | 2015-04-22 |
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| CN201410603090.3A Pending CN104530354A (en) | 2014-10-31 | 2014-10-31 | Environment-friendly high-flame-retardant yacht-interlayer buoyancy perfusion composite material and preparation method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105237717A (en) * | 2015-09-18 | 2016-01-13 | 扬中市天正合成材料研究中心 | Environmental-protection and high-flame retardation cruises bulkhead acid and alkali resistance storage PU foam material and preparation method thereof |
| CN106008887A (en) * | 2016-07-07 | 2016-10-12 | 扬中市天正合成材料研究中心 | High-toughness elastomer environment-friendly high-flame-retardancy foaming material and preparation method thereof |
| CN106146793A (en) * | 2016-07-07 | 2016-11-23 | 扬中市天正合成材料研究中心 | A kind of hard suitcase environmental protection high flame-retardant foamed material and preparation method thereof |
| CN106188460A (en) * | 2016-07-07 | 2016-12-07 | 扬中市天正合成材料研究中心 | A kind of sanitary ware environmental protection high flame-retardant foamed material and preparation method thereof |
| CN107266642A (en) * | 2017-06-29 | 2017-10-20 | 扬中市天正合成材料研究中心 | A kind of bumper environmental protection flame retardant polyurethane foam material and preparation method |
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2014
- 2014-10-31 CN CN201410603090.3A patent/CN104530354A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105237717A (en) * | 2015-09-18 | 2016-01-13 | 扬中市天正合成材料研究中心 | Environmental-protection and high-flame retardation cruises bulkhead acid and alkali resistance storage PU foam material and preparation method thereof |
| CN106008887A (en) * | 2016-07-07 | 2016-10-12 | 扬中市天正合成材料研究中心 | High-toughness elastomer environment-friendly high-flame-retardancy foaming material and preparation method thereof |
| CN106146793A (en) * | 2016-07-07 | 2016-11-23 | 扬中市天正合成材料研究中心 | A kind of hard suitcase environmental protection high flame-retardant foamed material and preparation method thereof |
| CN106188460A (en) * | 2016-07-07 | 2016-12-07 | 扬中市天正合成材料研究中心 | A kind of sanitary ware environmental protection high flame-retardant foamed material and preparation method thereof |
| CN107266642A (en) * | 2017-06-29 | 2017-10-20 | 扬中市天正合成材料研究中心 | A kind of bumper environmental protection flame retardant polyurethane foam material and preparation method |
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Application publication date: 20150422 |
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