CN104530688A - Environmental-friendly high-flame retardancy composite material for life raft and preparation method of composite material - Google Patents
Environmental-friendly high-flame retardancy composite material for life raft and preparation method of composite material Download PDFInfo
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- CN104530688A CN104530688A CN201410603075.9A CN201410603075A CN104530688A CN 104530688 A CN104530688 A CN 104530688A CN 201410603075 A CN201410603075 A CN 201410603075A CN 104530688 A CN104530688 A CN 104530688A
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Abstract
The invention discloses an environmental-friendly high-flame retardancy composite material for a life raft and a preparation method of the composite material. The composite material consists of vegetable oil polyether glycol, polyether glycol, diethanolamine, a polyurethane silicon oil, a catalyst, phosphoric acid tris(1-chlorine-2-propyl) ester, water and isocyanate. The flame retardancy of the composite material is high, and the composite material is not easy to burn when meeting with fire, so that the safety of the life raft and the personal safety of riding staff are guaranteed; and besides, the raw materials used by the composite material are all environmental-friendly raw materials, so that the composite material cannot give off substances which are toxic and harmful to human bodies, and the composite material is not harmful to the health of the human bodies.
Description
Technical field
The present invention relates to a kind of matrix material and preparation method thereof, particularly a kind of environmental protection high flame retardant liferaft matrix material and preparation method thereof.
Background technology
Liferaft is that boats and ships are equipped with in emergency circumstances region out of danger or from the lifesaving appliance of ship in distress emergency escape and equipment, during shipwreck can the wrecked personnel of confession riding, also can be used as flood fighting and to take precautions against natural calamities equipment special.Liferaft of the prior art is made of plastics usually, but usually to there is flame retardant properties not good for plastics, the easy initiation fire when running into fault or accident, thus has certain potential safety hazard.And the raw material sources of some plastics of the prior art not environmentally, often can volatilize some poisonous and hazardous materials, thus have harm to HUMAN HEALTH.
Summary of the invention
The object of the invention is to overcome defect of the prior art, provide a kind of environmental protection high flame retardant liferaft matrix material and preparation method thereof, described matrix material has very high flame retardant properties, and environment-protecting asepsis is to human body fanout free region.
The present invention is achieved by the following technical programs.
A kind of environmental protection high flame retardant liferaft matrix material, described matrix material is made up of the component of following quality proportioning: combination Ju Mi ︰ isocyanic ester=1.2 ︰ 1;
The formation of described combined polyether is as follows according to the mass fraction:
Plant oil polyether glycol 60-80 part
Polyether glycol 35-45 part
Diethanolamine 5-9 part
Urethane silicone oil 2.5-3.8 part
Catalyzer 2-3 part
Tricresyl phosphate (the chloro-2-propyl group of 1-) ester 35-42 part
Water 3.0-3.3 part.
Above-mentioned a kind of environmental protection high flame retardant liferaft matrix material, wherein, described isocyanic ester is isocyanic ester MR200, is purchased from Mitsui Chemicals, Inc..
Above-mentioned a kind of environmental protection high flame retardant liferaft matrix material, wherein, described plant oil polyether glycol is plant oil polyether glycol JTM-4110, is purchased from Jin Tian Chemical Co., Ltd. of Laizhou City.
Above-mentioned a kind of environmental protection high flame retardant liferaft matrix material, wherein, described polyether glycol is polyether glycol 4110, is purchased from Shanghai Gaoqiao Chemical Co., Ltd..
Above-mentioned a kind of environmental protection high flame retardant liferaft matrix material, wherein, described urethane silicone oil is urethane silicone oil 508, is purchased from great river, Jiangdu chemical industry Industrial Co., Ltd..
Above-mentioned a kind of environmental protection high flame retardant liferaft matrix material, wherein, described catalyzer is catalyst A PM9, is purchased from Jintan Ai Wensi fine materials company limited.
The preparation method of above-mentioned a kind of environmental protection high flame retardant liferaft matrix material, preparation process is as follows: first prepare combined polyether: plant oil polyether glycol, polyether glycol, diethanolamine, urethane silicone oil, catalyzer, tricresyl phosphate (the chloro-2-propyl group of 1-) ester and water are added in reactor and carry out hybrid reaction, stirring velocity 80-120r/min, churning time 6-8h combined polyether, and then combined polyether is mixed with the mass ratio of isocyanic ester by 1.2 ︰ 1, matrix material of the present invention can be obtained.
The flame retardant properties of environmental protection high flame retardant liferaft matrix material of the present invention is high, meets fiery nonflammable, thus has ensured the security of liferaft and the personnel safety of passenger.Simultaneously because the use raw material of matrix material of the present invention is environmental protection raw material, thus can not discharge the poisonous and hazardous material of human body, to HUMAN HEALTH without harm.
Embodiment
Below by way of specific embodiment, the specific embodiment of the present invention is described in further detail.
Embodiment 1
A kind of preparation method of environmental protection high flame retardant liferaft matrix material, preparation process is as follows: first prepare combined polyether: by the plant oil polyether glycol JTM-4110 of 60 parts, the polyether glycol 4110 of 35 parts, the diethanolamine of 5 parts, the urethane silicone oil 508 of 2.5 parts, the catalyst A PM9 of 2 parts, tricresyl phosphate (the chloro-2-propyl group of the 1-) ester of 35 parts and the water of 3 parts add in reactor and carry out hybrid reaction, stirring velocity 80r/min, churning time 6h combined polyether, and then combined polyether is mixed by the mass ratio of 1.2 ︰ 1 with isocyanic ester MR200, matrix material of the present invention can be obtained.
Embodiment 2
A kind of preparation method of environmental protection high flame retardant liferaft matrix material, preparation process is as follows: first prepare combined polyether: by the plant oil polyether glycol JTM-4110 of 65 parts, the polyether glycol 4110 of 37 parts, the diethanolamine of 6 parts, the urethane silicone oil 508 of 2.8 parts, the catalyst A PM9 of 2.5 parts, tricresyl phosphate (the chloro-2-propyl group of the 1-) ester of 38 parts and the water of 3.1 parts add in reactor and carry out hybrid reaction, stirring velocity 90r/min, churning time 7h combined polyether, and then combined polyether is mixed by the mass ratio of 1.2 ︰ 1 with isocyanic ester MR200, matrix material of the present invention can be obtained.
Embodiment 3
A kind of preparation method of environmental protection high flame retardant liferaft matrix material, preparation process is as follows: first prepare combined polyether: by the plant oil polyether glycol JTM-4110 of 75 parts, the polyether glycol 4110 of 42 parts, the diethanolamine of 8 parts, the urethane silicone oil 508 of 3.6 parts, the catalyst A PM9 of 2.8 parts, tricresyl phosphate (the chloro-2-propyl group of the 1-) ester of 40 parts and the water of 3.2 parts add in reactor and carry out hybrid reaction, stirring velocity 110r/min, churning time 7.5h combined polyether, and then combined polyether is mixed by the mass ratio of 1.2 ︰ 1 with isocyanic ester MR200, matrix material of the present invention can be obtained.
Embodiment 4
A kind of preparation method of environmental protection high flame retardant liferaft matrix material, preparation process is as follows: first prepare combined polyether: by the plant oil polyether glycol JTM-4110 of 80 parts, the polyether glycol 4110 of 45 parts, the diethanolamine of 9 parts, the urethane silicone oil 508 of 3.8 parts, the catalyst A PM9 of 3 parts, tricresyl phosphate (the chloro-2-propyl group of the 1-) ester of 42 parts and the water of 3.3 parts add in reactor and carry out hybrid reaction, stirring velocity 120r/min, churning time 8h combined polyether, and then combined polyether is mixed by the mass ratio of 1.2 ︰ 1 with isocyanic ester MR200, matrix material of the present invention can be obtained.
Be below the flame retardant properties test result of environmental protection high flame retardant liferaft matrix material of the present invention:
Inspecting standard requires: the combustionvelocity of fire retardant material should be not more than 100mm/min, if there is following situations, identifies test-results on request respectively, and assay is divided into A, B, C, D, E 5 grades:
A-(0 mm/min): sample is exposed to 15s in flame, extinguish burning things which may cause a fire disaster sample still unburn, or sample can burn, but flame extinguishes before reaching the first measurement graticule, can count without burning extent.
B: during from tester, flame is self-extinguish in 60s, and burning extent is not more than 50mm, then think and meet standard-required.
C-combustionvelocity measured value (mm/min)
During from tester, flame is measured between graticule at two and is extinguished, and when not meeting the 2nd article of situation, then by criterion calculation combustionvelocity.
D-combustionvelocity measured value (mm/min)
During from tester, flame arrives the second graticule, or from timing, the long-time smoulder of sample, then can when tester termination test during 20min, and record combustion time and burning extent and by criterion calculation combustionvelocity.
E: sample has burnt and arrived the first graticule in flame ignition 15s, then think that sample can not meet the requirement of combustionvelocity.
Assay: A(0 mm/min).
Here description of the invention and application is illustrative, not wants by scope restriction of the present invention in the above-described embodiments, and therefore, the present invention is not by the restriction of the present embodiment, and the technical scheme that any employing equivalence replacement obtains is all in the scope of protection of the invention.
Claims (7)
1. an environmental protection high flame retardant liferaft matrix material, is characterized in that, described matrix material is made up of the component of following quality proportioning: poly-ether ︰ isocyanic ester=1.2 ︰ 1 of combination;
The formation of described combined polyether is as follows according to the mass fraction:
Plant oil polyether glycol 60-80 part
Polyether glycol 35-45 part
Diethanolamine 5-9 part
Urethane silicone oil 2.5-3.8 part
Catalyzer 2-3 part
Tricresyl phosphate (the chloro-2-propyl group of 1-) ester 35-42 part
Water 3.0-3.3 part.
2. a kind of environmental protection high flame retardant liferaft matrix material as claimed in claim 1, it is characterized in that, described isocyanic ester is isocyanic ester MR200.
3. a kind of environmental protection high flame retardant liferaft matrix material as claimed in claim 1, it is characterized in that, described plant oil polyether glycol is plant oil polyether glycol JTM-4110.
4. a kind of environmental protection high flame retardant liferaft matrix material as claimed in claim 1, it is characterized in that, described polyether glycol is polyether glycol 4110.
5. a kind of environmental protection high flame retardant liferaft matrix material as claimed in claim 1, it is characterized in that, described urethane silicone oil is urethane silicone oil 508.
6. a kind of environmental protection high flame retardant liferaft matrix material as claimed in claim 1, it is characterized in that, described catalyzer is catalyst A PM9.
7. the preparation method of a kind of environmental protection high flame retardant liferaft matrix material as claimed in claim 1, it is characterized in that, preparation process is as follows: first prepare combined polyether: by plant oil polyether glycol, polyether glycol, diethanolamine, urethane silicone oil, catalyzer, tricresyl phosphate (the chloro-2-propyl group of 1-) ester and water add in reactor and carry out hybrid reaction, stirring velocity 80-120r/min, churning time 6-8h combined polyether, and then combined polyether is mixed with the mass ratio of isocyanic ester by 1.2 ︰ 1, matrix material of the present invention can be obtained.
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| CN201410603075.9A CN104530688A (en) | 2014-10-31 | 2014-10-31 | Environmental-friendly high-flame retardancy composite material for life raft and preparation method of composite material |
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| CN201410603075.9A CN104530688A (en) | 2014-10-31 | 2014-10-31 | Environmental-friendly high-flame retardancy composite material for life raft and preparation method of composite material |
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| CN105237715A (en) * | 2015-09-18 | 2016-01-13 | 扬中市天正合成材料研究中心 | Environmental-protection and high-flame retardation yacht shell composite material and preparation method thereof |
| CN106008886A (en) * | 2016-07-07 | 2016-10-12 | 扬中市天正合成材料研究中心 | Environment-friendly high-fire-resistance rigid foam polyurethane door and window inner container filling foaming material and preparation method |
| CN106008874A (en) * | 2016-07-07 | 2016-10-12 | 扬中市天正合成材料研究中心 | Environment-friendly and highly-flame-retardant foam material for goods shelf and preparation method of foam material |
| CN106046297A (en) * | 2016-07-07 | 2016-10-26 | 扬中市天正合成材料研究中心 | Environment-friendly highly-flame-retardant polyurethane foam material for automobile fuel tanks and preparation method of environment-friendly highly-flame-retardant polyurethane foam material |
| CN106046306A (en) * | 2016-07-07 | 2016-10-26 | 扬中市天正合成材料研究中心 | Environmentally friendly high-flame-retardant polyurethane foaming material for tank body of oil tank truck and preparation method of environmentally friendly high-flame-retardant polyurethane foaming material |
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| CN106084165A (en) * | 2016-07-07 | 2016-11-09 | 扬中市天正合成材料研究中心 | A kind of packaging environmental protection high flame-retardant foamed material and preparation method thereof |
| CN106117484A (en) * | 2016-07-07 | 2016-11-16 | 扬中市天正合成材料研究中心 | A kind of agricultural bailer environmental protection high flame-retardant foamed material and preparation method thereof |
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-
2014
- 2014-10-31 CN CN201410603075.9A patent/CN104530688A/en active Pending
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105237715A (en) * | 2015-09-18 | 2016-01-13 | 扬中市天正合成材料研究中心 | Environmental-protection and high-flame retardation yacht shell composite material and preparation method thereof |
| CN106008886A (en) * | 2016-07-07 | 2016-10-12 | 扬中市天正合成材料研究中心 | Environment-friendly high-fire-resistance rigid foam polyurethane door and window inner container filling foaming material and preparation method |
| CN106008874A (en) * | 2016-07-07 | 2016-10-12 | 扬中市天正合成材料研究中心 | Environment-friendly and highly-flame-retardant foam material for goods shelf and preparation method of foam material |
| CN106046297A (en) * | 2016-07-07 | 2016-10-26 | 扬中市天正合成材料研究中心 | Environment-friendly highly-flame-retardant polyurethane foam material for automobile fuel tanks and preparation method of environment-friendly highly-flame-retardant polyurethane foam material |
| CN106046306A (en) * | 2016-07-07 | 2016-10-26 | 扬中市天正合成材料研究中心 | Environmentally friendly high-flame-retardant polyurethane foaming material for tank body of oil tank truck and preparation method of environmentally friendly high-flame-retardant polyurethane foaming material |
| CN106084170A (en) * | 2016-07-07 | 2016-11-09 | 扬中市天正合成材料研究中心 | A kind of freight lappet environmental protection high flame-retardant foamed material and preparation method thereof |
| CN106084169A (en) * | 2016-07-07 | 2016-11-09 | 扬中市天正合成材料研究中心 | A kind of greening bark moulding environmental protection high flame-retardant foamed material and preparation method thereof |
| CN106084165A (en) * | 2016-07-07 | 2016-11-09 | 扬中市天正合成材料研究中心 | A kind of packaging environmental protection high flame-retardant foamed material and preparation method thereof |
| CN106117484A (en) * | 2016-07-07 | 2016-11-16 | 扬中市天正合成材料研究中心 | A kind of agricultural bailer environmental protection high flame-retardant foamed material and preparation method thereof |
| CN106146781A (en) * | 2016-07-07 | 2016-11-23 | 扬中市天正合成材料研究中心 | A kind of elastomer environmental protection high flame-retardant foamed material and preparation method thereof |
| CN106188459A (en) * | 2016-07-07 | 2016-12-07 | 扬中市天正合成材料研究中心 | A kind of auto lamp bowl polyester foamed material of environmental protection high fire-retardance and preparation method thereof |
| CN106432669A (en) * | 2016-07-07 | 2017-02-22 | 扬中市天正合成材料研究中心 | Environment-friendly high-inflaming-resisting high-density foam material for water tank of tractor and preparation method of environment-friendly high-inflaming-resisting high-density foam material |
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Application publication date: 20150422 |
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