CN104356339A - Environment-friendly high-flame-retardancy high/low-temperature thermal-insulation composite material for storerooms - Google Patents
Environment-friendly high-flame-retardancy high/low-temperature thermal-insulation composite material for storerooms Download PDFInfo
- Publication number
- CN104356339A CN104356339A CN201410639433.1A CN201410639433A CN104356339A CN 104356339 A CN104356339 A CN 104356339A CN 201410639433 A CN201410639433 A CN 201410639433A CN 104356339 A CN104356339 A CN 104356339A
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- China
- Prior art keywords
- polyester polyol
- parts
- flame retardant
- environmental protection
- low temperature
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3271—Hydroxyamines
- C08G18/3275—Hydroxyamines containing two hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4018—Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4202—Two or more polyesters of different physical or chemical nature
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6603—Compounds of groups C08G18/42, C08G18/48, or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/6614—Compounds of groups C08G18/42, C08G18/48, or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3225 or C08G18/3271 and/or polyamines of C08G18/38
- C08G18/6622—Compounds of groups C08G18/42, C08G18/48, or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3225 or C08G18/3271 and/or polyamines of C08G18/38 with compounds of group C08G18/3271
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
- C08K5/5317—Phosphonic compounds, e.g. R—P(:O)(OR')2
- C08K5/5333—Esters of phosphonic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyurethanes Or Polyureas (AREA)
- Fireproofing Substances (AREA)
Abstract
The invention discloses an environment-friendly high-flame-retardancy high/low-temperature thermal-insulation composite material for storerooms, which is composed of a composite material and isocyanate in a mass ratio of 1.38:1. The composite material has high flame retardancy, can not be easily combusted when meeting fire, can not be deformed even after long-term usage, and can not release toxic or harmful substances for the human body since all the raw materials used by the composite material are environment-friendly raw materials.
Description
Technical field
The present invention relates to a kind of matrix material and preparation method thereof, particularly one
environmental protection high flame retardant high/low temperature storage room heat-preserving complex material.
Background technology
In order to be incubated, can be provided with heat-preserving complex material in storage room, heat-preserving complex material of the prior art is mainly made up of materials such as flammable textiles, fiber interior lining panel, polyurethane foam thing, leatheroid and hot melt adhesive glue.In use procedure, due to reason all pole fire hazardous such as electrical short-circuit, motor fault, traffic accidents, cause any property loss and loss of life and personal injury.And flammable material often increases the weight of the degree of fire in accident.And a lot of raw material sources not environmentally, often can volatilize some hazardous and noxious substances, can cause larger harm for a long time to HUMAN HEALTH in the past.
Summary of the invention
The object of the invention is to overcome defect of the prior art, a kind of environmental protection high flame retardant is provided
high/low temperature storage room heat-preserving complex material, described matrix material has very high flame retardant resistance, and environment-protecting asepsis is to human body fanout free region.
The present invention is achieved by the following technical programs.
A kind of environmental protection high flame retardant
high/low temperature storage room heat-preserving complex material, described matrix material is made up of the component of following quality proportioning: combination material ︰ isocyanic ester=1.38 ︰ 1;
The formation of described combination material is as follows according to the mass fraction:
Polyester polyol 1 55-65 part
Polyester polyol 2 15-18 part
Polyester polyol 3 25-38 part
Polyether glycol 15-25 part
Urethane silicone oil 3-4.5 part
Diethanolamine 6-9 part
Catalyzer HP-42 1.9-2.9 part
Catalyzer HP-50 1-1.5 part
Water 3-4.2 part
Fire retardant DMMP 35-41 part.
Above-mentioned environmental protection high flame retardant high/low temperature storage room heat-preserving complex material, wherein, described polyester polyol 1 is polyester polyol 8190, is purchased from Jiangsu Fu Sheng novel material company limited.
Above-mentioned environmental protection high flame retardant high/low temperature storage room heat-preserving complex material, wherein, described polyester polyol 2 is polyester polyol 2056, is purchased from Jiangsu Fu Sheng novel material company limited.
Above-mentioned environmental protection high flame retardant high/low temperature storage room heat-preserving complex material, wherein, described polyester polyol 3 is polyester polyol 6300, is purchased from Jiangsu Fu Sheng novel material company limited.
Flame retardant properties of the present invention is high, meets fiery nonflammable, thus has ensured the personnel safety of security and passenger.Matrix material of the present invention has not dimensional instability, even if life-time service also can not deform, in addition because the use raw material of described matrix material is environmental protection raw material, thus also can not discharge the poisonous and hazardous material of human body.
Embodiment
Do detailed further below by way of specific embodiment to the specific embodiment of the present invention
Described polyether glycol is polyether glycol 4113, is purchased from Jiangsu Fu Sheng novel material company limited or Shanghai is comforted good.
Urethane silicone oil is urethane silicone oil 8005, is purchased from Nanjing Dymatic Shichuang Chemical Co., Ltd.;
Catalyzer HP-42 and catalyzer HP-50 is purchased from Zhen Yu Chemical Co., Ltd. of Liyang City;
Fire retardant DMMP is purchased from Qingdao Lian Mei Chemical Co., Ltd.;
Isocyanic ester is that isocyanic ester M100 is purchased from Yantai ten thousand China.
Embodiment 1
A kind of environmental protection high flame retardant
high/low temperature storage room heat-preserving complex material, described matrix material is made up of the component of following quality proportioning: combination material ︰ isocyanic ester=1.38 ︰ 1;
The formation of described combination material is as follows according to the mass fraction:
Polyester polyol 1 55 parts
Polyester polyol 2 15 parts
Polyester polyol 3 25 parts
Polyether glycol 15 parts
Urethane silicone oil 3 parts
Diethanolamine 6 parts
Catalyzer HP-42 1.9 parts
Catalyzer HP-50 1 part
3 parts, water
Fire retardant DMMP 35 parts.
Add in reactor and carry out hybrid reaction, stirring velocity 80r/min, churning time 6h, can obtain combining material; Again by combination material with isocyanic ester by mixing, matrix material of the present invention can be obtained.
Embodiment 2
A kind of environmental protection high flame retardant
high/low temperature storage room heat-preserving complex material, described matrix material is made up of the component of following quality proportioning: combination material ︰ isocyanic ester=1.38 ︰ 1;
The formation of described combination material is as follows according to the mass fraction:
Polyester polyol 1 58 parts
Polyester polyol 2 16 parts
Polyester polyol 3 30 parts
Polyether glycol 17 parts
Urethane silicone oil 3.5 parts
Diethanolamine 6 parts
Catalyzer HP-42 2 parts
Catalyzer HP-50 1 part
3 parts, water
Fire retardant DMMP 37 parts.
Add in reactor and carry out hybrid reaction, stirring velocity 90r/min, churning time 7h, can obtain combining material; Again combination material is mixed with isocyanic ester, matrix material of the present invention can be obtained.
Embodiment 3
A kind of environmental protection high flame retardant
high/low temperature storage room heat-preserving complex material, described matrix material is made up of the component of following quality proportioning: combination material ︰ isocyanic ester=1.38 ︰ 1;
The formation of described combination material is as follows according to the mass fraction:
Polyester polyol 1 55 parts
Polyester polyol 2 20 parts
Polyester polyol 3 225 parts
Polyether glycol 20 parts
Urethane silicone oil 3 parts
Diethanolamine 8 parts
Catalyzer HP-42 2.5 parts
Catalyzer HP-50 1 part
3 parts, water
Fire retardant DMMP 35 parts.
Add in reactor and carry out hybrid reaction, stirring velocity 110r/min, churning time 8h, can obtain combining material; Again combination material is mixed with isocyanic ester, matrix material of the present invention can be obtained.
Embodiment 4
A kind of environmental protection high flame retardant
high/low temperature storage room heat-preserving complex material, described matrix material is made up of the component of following quality proportioning: combination material ︰ isocyanic ester=1.38 ︰ 1;
The formation of described combination material is as follows according to the mass fraction:
Polyester polyol 1 65 parts
Polyester polyol 2 18 parts
Polyester polyol 3 38 parts
Polyether glycol 25 parts
Urethane silicone oil 4.5 parts
Diethanolamine 9 parts
Catalyzer HP-42 2.9 parts
Catalyzer HP-50 1.5 parts
4.2 parts, water
Fire retardant DMMP 41 parts.
Add in reactor and carry out hybrid reaction, stirring velocity 120r/min, churning time 8h, can obtain combining material; Again combination material is mixed with isocyanic ester, matrix material of the present invention can be obtained.
Be below flame retardant properties test result of the present invention:
Test basis: GB 8410-2006 " combustioncharacteristics of automotive interior material "
Detection site: component testing laboratory of national car Quality Supervision and Inspection Center.
Inspecting standard requires: the combustionvelocity of fire retardant material should be not more than 100mm/min, if there is following situations, identifies test-results on request respectively, and assay is divided into A, B, C, D, E 5 grades:
A-(0 mm/min): sample is exposed to 15s in flame, extinguish burning things which may cause a fire disaster sample still unburn, or sample can burn, but flame extinguishes before reaching the first measurement graticule, can count without burning extent.
B: during from tester, flame is self-extinguish in 60s, and burning extent is not more than 50mm, then think and meet standard-required.
C-combustionvelocity measured value (mm/min)
During from tester, flame is measured between graticule at two and is extinguished, and when not meeting the 2nd article of situation, then by criterion calculation combustionvelocity.
D-combustionvelocity measured value (mm/min)
During from tester, flame arrives the second graticule, or from timing, the long-time smoulder of sample, then can when tester termination test during 20min, and record combustion time and burning extent and by criterion calculation combustionvelocity.
E: sample has burnt and arrived the first graticule in flame ignition 15s, then think that sample can not meet the requirement of combustionvelocity.
Assay: A(0 mm/min), meet the flame retardant properties requirement of GB 8410-2006 " combustioncharacteristics of automotive interior material ".
Density: 60-90kg density/m
3
Here description of the invention and application is illustrative, not wants by scope restriction of the present invention in the above-described embodiments, and therefore, the present invention is not by the restriction of the present embodiment, and the technical scheme that any employing equivalence replacement obtains is all in the scope of protection of the invention.
Claims (4)
1. an environmental protection high flame retardant
high/low temperature storage room heat-preserving complex material, it is characterized in that, described matrix material is made up of the component of following quality proportioning: combination material ︰ isocyanic ester=1.38 ︰ 1;
The formation of described combination material is as follows according to the mass fraction:
Polyester polyol 1 55-65 part
Polyester polyol 2 15-18 part
Polyester polyol 3 25-38 part
Polyether glycol 15-25 part
Urethane silicone oil 3-4.5 part
Diethanolamine 6-9 part
Catalyzer HP-42 1.9-2.9 part
Catalyzer HP-50 1-1.5 part
Water 3-4.2 part
Fire retardant DMMP 35-41 part.
2. environmental protection high flame retardant high/low temperature storage room heat-preserving complex material as claimed in claim 1, it is characterized in that, described polyester polyol 1 is polyester polyol 8190, is purchased from Jiangsu Fu Sheng novel material company limited.
3. environmental protection high flame retardant high/low temperature storage room heat-preserving complex material as claimed in claim 1, it is characterized in that, described polyester polyol 2 is polyester polyol 2056, is purchased from Jiangsu Fu Sheng novel material company limited.
4. environmental protection high flame retardant high/low temperature storage room heat-preserving complex material as claimed in claim 1, it is characterized in that, described polyester polyol 3 is polyester polyol 6300, is purchased from Jiangsu Fu Sheng novel material company limited.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410639433.1A CN104356339A (en) | 2014-11-13 | 2014-11-13 | Environment-friendly high-flame-retardancy high/low-temperature thermal-insulation composite material for storerooms |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410639433.1A CN104356339A (en) | 2014-11-13 | 2014-11-13 | Environment-friendly high-flame-retardancy high/low-temperature thermal-insulation composite material for storerooms |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104356339A true CN104356339A (en) | 2015-02-18 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410639433.1A Pending CN104356339A (en) | 2014-11-13 | 2014-11-13 | Environment-friendly high-flame-retardancy high/low-temperature thermal-insulation composite material for storerooms |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105237715A (en) * | 2015-09-18 | 2016-01-13 | 扬中市天正合成材料研究中心 | Environmental-protection and high-flame retardation yacht shell composite material and preparation method thereof |
| CN106146793A (en) * | 2016-07-07 | 2016-11-23 | 扬中市天正合成材料研究中心 | A kind of hard suitcase environmental protection high flame-retardant foamed material and preparation method thereof |
| CN108250386A (en) * | 2018-01-11 | 2018-07-06 | 江苏向阳科技有限公司 | A kind of flame retardant polyurethane foam material and preparation method and application |
-
2014
- 2014-11-13 CN CN201410639433.1A patent/CN104356339A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105237715A (en) * | 2015-09-18 | 2016-01-13 | 扬中市天正合成材料研究中心 | Environmental-protection and high-flame retardation yacht shell composite material and preparation method thereof |
| CN106146793A (en) * | 2016-07-07 | 2016-11-23 | 扬中市天正合成材料研究中心 | A kind of hard suitcase environmental protection high flame-retardant foamed material and preparation method thereof |
| CN108250386A (en) * | 2018-01-11 | 2018-07-06 | 江苏向阳科技有限公司 | A kind of flame retardant polyurethane foam material and preparation method and application |
| CN108250386B (en) * | 2018-01-11 | 2021-05-14 | 江苏向阳科技有限公司 | Flame-retardant polyurethane foam material and preparation method and application thereof |
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| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20150218 |
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| WD01 | Invention patent application deemed withdrawn after publication |