CN104356331A - Environment-friendly high-flame-retardant composite material for doors/windows of furniture - Google Patents
Environment-friendly high-flame-retardant composite material for doors/windows of furniture Download PDFInfo
- Publication number
- CN104356331A CN104356331A CN201410639434.6A CN201410639434A CN104356331A CN 104356331 A CN104356331 A CN 104356331A CN 201410639434 A CN201410639434 A CN 201410639434A CN 104356331 A CN104356331 A CN 104356331A
- Authority
- CN
- China
- Prior art keywords
- polyester polyol
- matrix material
- isocyanic ester
- composite material
- flame retardant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4202—Two or more polyesters of different physical or chemical nature
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses an environment-friendly high-flame-retardant composite material for doors/windows of furniture. The composite material is prepared from the following ingredients, namely combined materials and isocyanate which are in the proportioning ratio (by mass) of 1.9: 1, wherein isocyanate consists of isocyanate 1 and isocyanate 2, and the mass ratio of isocyanate 1 to isocyanate 2 is 1: 1. The composite material is high in flame retardance and is not prone to combustion when the composite material is exposed to fire, so that the safety of a whole vehicle and the personnel safety of passengers are guaranteed. The composite material disclosed by the invention has a difficultly-deforming property and cannot deform even if in long-term use; in addition, raw materials used by the composite material are all environment-friendly raw materials, so that substances which are toxic and harmful to human bodies cannot be released.
Description
Technical field
The present invention relates to a kind of matrix material and preparation method thereof, particularly a kind of environmental protection high flame retardant furniture door and window matrix material.
Background technology
Along with the development of society, the raising of people's living standard, furniture door and window adopts the material compositions such as fiber interior lining panel, polyurethane foam thing, leatheroid and hot melt adhesive glue mostly.In routine use process, due to reason all pole fire hazardous such as electrical short-circuit, motor fault, traffic accidents, cause any property loss and loss of life and personal injury.And flammable ornament often increases the weight of the degree of fire in accident.And a lot of raw material sources not environmentally, often can volatilize some hazardous and noxious substances, people can suck these hazardous and noxious substances when living, and can cause larger harm for a long time to HUMAN HEALTH in the past.
Summary of the invention
The object of the invention is to overcome defect of the prior art, a kind of environmental protection high flame retardant is provided
furnituredoor and window matrix material, described matrix material has very high flame retardant resistance, and environment-protecting asepsis is to human body fanout free region.
The present invention is achieved by the following technical programs.
A kind of environmental protection high flame retardant
furnituredoor and window matrix material, described matrix material is made up of the component of following quality proportioning: combination material ︰ isocyanic ester=1.9 ︰ 1;
Isocyanic ester is made up of isocyanic ester 1 and isocyanic ester 2, isocyanic ester 1: isocyanic ester 2 is 1:1, counts in mass ratio;
The formation of described combination material is as follows according to the mass fraction:
Polyester polyol 1 50-55 part
Polyester polyol 2 45-48 part
Polyester polyol 3 55-58 part
Polyester polyol 4 20-30 part
Urethane silicone oil 3.5-3.9 part
Catalyst for trimerization 1.2-2 part
Catalyzer HP-2 2-3.5 part
Water 3.6-3.8 part
Fire retardant TCEP 35-45 part.
Above-mentioned environmental protection high flame retardant
furnituredoor and window matrix material, wherein, described polyester polyol 1 is polyester polyol 8410, is purchased from Jiangsu Fu Shengxi Materials Co., Ltd.
Above-mentioned environmental protection high flame retardant
furnituredoor and window matrix material, wherein, described polyester polyol 2 is polyester polyol 6320, is purchased from Jiangsu Fu Shengxi Materials Co., Ltd.
Above-mentioned environmental protection high flame retardant
furnituredoor and window matrix material, wherein, described polyester polyol 3 is polyester polyol 8186, is purchased from Jiangsu Fu Shengxi Materials Co., Ltd.
Above-mentioned environmental protection high flame retardant
furnituredoor and window matrix material, wherein, described polyester polyol 4 is polyether glycol 6200, is purchased from Jiangsu Fu Shengxi Materials Co., Ltd.
Above-mentioned environmental protection high flame retardant
furnituredoor and window matrix material, wherein, described urethane silicone oil is urethane silicone oil 8807, is purchased from Nanjing Dymatic Shichuang Chemical Co., Ltd..
Flame retardant properties of the present invention is high, meets fiery nonflammable, thus has ensured the security of whole vehicle and the personnel safety of passenger.Matrix material of the present invention has not dimensional instability, even if life-time service also can not deform, in addition because the use raw material of described matrix material is environmental protection raw material, thus also can not discharge the poisonous and hazardous material of human body.
Embodiment
Below by way of specific embodiment, the specific embodiment of the present invention is described in further detail.
Isocyanic ester is stirred by isocyanic ester 1 and isocyanic ester 2 and is formed, isocyanic ester 1: isocyanic ester 2 is 1:1, counts in mass ratio;
Catalyzer HP-2, is purchased from Zhen Yu Chemical Co., Ltd. of Liyang City.
Catalyst for trimerization is purchased from Jintan Ai Wensi.
Fire retardant TCEP is purchased from Qingdao Lian Mei Chemical Co., Ltd..
Isocyanic ester 1 is magnificent for isocyanic ester M200 is purchased from Yantai ten thousand;
Isocyanic ester 2 is purchased from LG-DOW for isocyanic ester 5005.
Embodiment 1
By following component reaction preparation preparation combination material, by mass parts
Polyester polyol 1 50 parts
Polyester polyol 2 45 parts
Polyester polyol 3 55 parts
Polyester polyol 4 20 parts
Urethane silicone oil 3.5 parts
Catalyst for trimerization 1.2 parts
Catalyzer HP-2 2 parts
3.6 parts, water
Fire retardant TCEP 35 parts.
Add in reactor and carry out hybrid reaction, stirring velocity 890r/min, churning time 2h, can obtain combining material; Again combination material is mixed with the mass ratio of isocyanic ester by 1.9 ︰ 1, matrix material of the present invention can be obtained.
Embodiment 2
By following component reaction preparation preparation combination material, by mass parts
Polyester polyol 1 52 parts
Polyester polyol 2 46 parts
Polyester polyol 3 556 parts
Polyester polyol 4 25 parts
Urethane silicone oil 3.5 parts
Catalyst for trimerization 1.5 parts
Catalyzer HP-2 2.5 parts
3.6 parts, water
Fire retardant TCEP 35 parts.
Add in reactor and carry out hybrid reaction, stirring velocity 90r/min, churning time 7h, can obtain combining material; Again combination material is mixed with the mass ratio of isocyanic ester by 1.9 ︰ 1, matrix material of the present invention can be obtained.
Embodiment 3
By following component reaction preparation preparation combination material, by mass parts
Polyester polyol 1 53 parts
Polyester polyol 2 47 parts
Polyester polyol 3 55 parts
Polyester polyol 4 22 parts
Urethane silicone oil 3.5 parts
Catalyst for trimerization 2 parts
Catalyzer HP-2 2.5 parts
3.6 parts, water
Fire retardant TCEP 40 parts.
Add in reactor and carry out hybrid reaction, stirring velocity 110r/min, churning time 8h, can obtain combining material; Again combination material is mixed with the mass ratio of isocyanic ester by 1.9 ︰ 1, matrix material of the present invention can be obtained.
Embodiment 4
By following component reaction preparation preparation combination material, by mass parts
Polyester polyol 1 55 parts
Polyester polyol 2 48 parts
Polyester polyol 3 58 parts
Polyester polyol 4 30 parts
Urethane silicone oil 3.9 parts
Catalyst for trimerization 2 parts
Catalyzer HP-2 3.5 parts
3.8 parts, water
Fire retardant TCEP 45 parts.
Add in reactor and carry out hybrid reaction, stirring velocity 120r/min, churning time 8h, can obtain combining material; Again combination material is mixed by the mass ratio of 1.8 ︰ 1 with isocyanic ester MR300, matrix material of the present invention can be obtained.
Be below flame retardant properties test result of the present invention:
Test basis: GB 8410-2006 " combustioncharacteristics of automotive interior material "
Detection site: component testing laboratory of national car Quality Supervision and Inspection Center.
Inspecting standard requires: the combustionvelocity of fire retardant material should be not more than 100mm/min, if there is following situations, identifies test-results on request respectively, and assay is divided into A, B, C, D, E 5 grades:
A-(0 mm/min): sample is exposed to 15s in flame, extinguish burning things which may cause a fire disaster sample still unburn, or sample can burn, but flame extinguishes before reaching the first measurement graticule, can count without burning extent.
B: during from tester, flame is self-extinguish in 60s, and burning extent is not more than 50mm, then think and meet standard-required.
C-combustionvelocity measured value (mm/min)
During from tester, flame is measured between graticule at two and is extinguished, and when not meeting the 2nd article of situation, then by criterion calculation combustionvelocity.
D-combustionvelocity measured value (mm/min)
During from tester, flame arrives the second graticule, or from timing, the long-time smoulder of sample, then can when tester termination test during 20min, and record combustion time and burning extent and by criterion calculation combustionvelocity.
E: sample has burnt and arrived the first graticule in flame ignition 15s, then think that sample can not meet the requirement of combustionvelocity.
Assay: A(0 mm/min), meet the flame retardant properties requirement of GB 8410-2006 " combustioncharacteristics of automotive interior material ".
Density: 420-490kg density/m
3
Here description of the invention and application is illustrative, not wants by scope restriction of the present invention in the above-described embodiments, and therefore, the present invention is not by the restriction of the present embodiment, and the technical scheme that any employing equivalence replacement obtains is all in the scope of protection of the invention.
Claims (6)
1. an environmental protection high flame retardant
furnituredoor and window matrix material, is characterized in that, described matrix material is made up of the component of following quality proportioning: combination material ︰ isocyanic ester=1.9 ︰ 1;
Isocyanic ester is made up of isocyanic ester 1 and isocyanic ester 2, isocyanic ester 1: isocyanic ester 2 is 1:1, counts in mass ratio;
The formation of described combination material is as follows according to the mass fraction:
Polyester polyol 1 50-55 part
Polyester polyol 2 45-48 part
Polyester polyol 3 55-58 part
Polyester polyol 4 20-30 part
Urethane silicone oil 3.5-3.9 part
Catalyst for trimerization 1.2-2 part
Catalyzer HP-2 2-3.5 part
Water 3.6-3.8 part
Fire retardant TCEP 35-45 part.
2. environmental protection high flame retardant as claimed in claim 1
furnituredoor and window matrix material, is characterized in that, described polyester polyol 1 is polyester polyol 8410, is purchased from Jiangsu Fu Shengxi Materials Co., Ltd.
3. environmental protection high flame retardant as claimed in claim 1
furnituredoor and window matrix material, is characterized in that, described polyester polyol 2 is polyester polyol 6320, is purchased from Jiangsu Fu Shengxi Materials Co., Ltd.
4. environmental protection high flame retardant as claimed in claim 1
furnituredoor and window matrix material, is characterized in that, described polyester polyol 3 is polyester polyol 8186, is purchased from Jiangsu Fu Shengxi Materials Co., Ltd.
5. environmental protection high flame retardant as claimed in claim 1
furnituredoor and window matrix material, is characterized in that, described polyester polyol 4 is polyether glycol 6200, is purchased from Jiangsu Fu Shengxi Materials Co., Ltd.
6. environmental protection high flame retardant as claimed in claim 1
furnituredoor and window matrix material, is characterized in that, described urethane silicone oil is urethane silicone oil 8807, is purchased from Nanjing Dymatic Shichuang Chemical Co., Ltd..
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410639434.6A CN104356331A (en) | 2014-11-13 | 2014-11-13 | Environment-friendly high-flame-retardant composite material for doors/windows of furniture |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410639434.6A CN104356331A (en) | 2014-11-13 | 2014-11-13 | Environment-friendly high-flame-retardant composite material for doors/windows of furniture |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104356331A true CN104356331A (en) | 2015-02-18 |
Family
ID=52523654
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410639434.6A Pending CN104356331A (en) | 2014-11-13 | 2014-11-13 | Environment-friendly high-flame-retardant composite material for doors/windows of furniture |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104356331A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105237704A (en) * | 2015-09-18 | 2016-01-13 | 扬中市天正合成材料研究中心 | Environmental-protection and high-flame retardation PU foam material for high-speed train bar counters, and preparation method thereof |
| CN106084168A (en) * | 2016-07-07 | 2016-11-09 | 扬中市天正合成材料研究中心 | A kind of petroleum pipeline environmental protection high flame-retardant foamed material and preparation method thereof |
| CN106146794A (en) * | 2016-07-07 | 2016-11-23 | 扬中市天正合成材料研究中心 | A kind of automobile-used ceiling environmental protection high flame-retardant foamed material and preparation method thereof |
-
2014
- 2014-11-13 CN CN201410639434.6A patent/CN104356331A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105237704A (en) * | 2015-09-18 | 2016-01-13 | 扬中市天正合成材料研究中心 | Environmental-protection and high-flame retardation PU foam material for high-speed train bar counters, and preparation method thereof |
| CN106084168A (en) * | 2016-07-07 | 2016-11-09 | 扬中市天正合成材料研究中心 | A kind of petroleum pipeline environmental protection high flame-retardant foamed material and preparation method thereof |
| CN106146794A (en) * | 2016-07-07 | 2016-11-23 | 扬中市天正合成材料研究中心 | A kind of automobile-used ceiling environmental protection high flame-retardant foamed material and preparation method thereof |
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Legal Events
| Date | Code | Title | Description |
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| C06 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20150218 |