CN104403071A - Environmentally-friendly high-flame-retardant heat-insulation composite material used for vessel bulkhead - Google Patents
Environmentally-friendly high-flame-retardant heat-insulation composite material used for vessel bulkhead Download PDFInfo
- Publication number
- CN104403071A CN104403071A CN201410639658.7A CN201410639658A CN104403071A CN 104403071 A CN104403071 A CN 104403071A CN 201410639658 A CN201410639658 A CN 201410639658A CN 104403071 A CN104403071 A CN 104403071A
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- CN
- China
- Prior art keywords
- polyester polyol
- composite material
- parts
- flame retardant
- environmental protection
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4202—Two or more polyesters of different physical or chemical nature
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6633—Compounds of group C08G18/42
- C08G18/6637—Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/6648—Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3225 or C08G18/3271 and/or polyamines of C08G18/38
- C08G18/6655—Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3225 or C08G18/3271 and/or polyamines of C08G18/38 with compounds of group C08G18/3271
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/50—Phosphorus bound to carbon only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses an environmentally-friendly high-flame-retardant heat-insulation composite material used for a vessel bulkhead, the composite material comprises a combined material and isocyanate, the mass ratio of the combined material: isocyanate is 1.3: 1, the composite material has high flame retardant properties, and is not easy to burn when meeting a fire, thus ensuring the safety of the whole vessel, the composite material has the advantages of deformation resistance, even if the composite material is used for a long term, the composite material may not deform, and raw materials used in the composite material are environmentally friendly, so that no substances toxic and harmful to the human body may be released.
Description
Technical field
The present invention relates to a kind of matrix material, particularly a kind of environmental protection high flame retardant naval vessels bulkhead heat-preserving complex material.
Background technology
on naval vessels bulkheadbe typically provided with heat-preserving complex material, heat-preserving complex material of the prior art is mainly made up of materials such as flammable textiles, fiber interior lining panel, polyurethane foam thing, leatheroid and hot melt adhesive glue.
naval vesselsin transportation, due to reason all pole fire hazardous such as electrical short-circuit, motor fault, traffic accidents, cause any property loss and loss of life and personal injury.And flammable lagging material often increases the weight of the degree of fire in accident.And a lot of raw material sources not environmentally, often can volatilize some hazardous and noxious substances, people exists
naval vesselsinteriorly can suck these hazardous and noxious substances, larger harm can be caused to HUMAN HEALTH for a long time in the past.Therefore, right
naval vesselsthe flame retardant resistance of interior material and the research of the feature of environmental protection have major and immediate significance.
Summary of the invention
The object of the invention is to overcome defect of the prior art, a kind of environmental protection high flame retardant is provided
naval vessels bulkhead heat-preserving complex material, described matrix material has very high flame retardant resistance, and environment-protecting asepsis is to human body fanout free region.
The present invention is achieved by the following technical programs.
A kind of environmental protection high flame retardant
naval vessels bulkhead heat-preserving complex material, described matrix material is made up of the component of following quality proportioning: combination material ︰ isocyanic ester=1.3 ︰ 1;
The formation of described combination material is as follows according to the mass fraction:
Polyester polyol 1 35-55 part
Polyester polyol 2 25-35 part
Polyester polyol 3 10-20 part
Polyester polyol 4 40-45 part
Urethane silicone oil 3.5-4.5 part
Trolamine 7-9 part
Diethanolamine 3-6 part
Catalyzer HP-54 1.8-2.8 part
Catalyzer HP-80 1.5-1.8 part
Water 3-3.6 part
Fire retardant TCEP 45-50 part.
Above-mentioned environmental protection high flame retardant
naval vessels bulkhead heat-preserving complex material, wherein, described urethane silicone oil is urethane silicone oil AK8860, is purchased from Nanjing Dymatic Shichuang Chemical Co., Ltd..
Above-mentioned environmental protection high flame retardant
naval vessels bulkhead heat-preserving complex material, wherein, described fire retardant TCEP, is purchased from Qingdao Lian Mei Chemical Co., Ltd..
Above-mentioned environmental protection high flame retardant
naval vessels bulkhead heat-preserving complex material, wherein, described isocyanic ester is isocyanic ester MR200, is purchased from Mitsui chemical company
Flame retardant properties of the present invention is high, meets fiery nonflammable, thus has ensured the security of whole naval vessels.Matrix material of the present invention has not dimensional instability, even if life-time service also can not deform, in addition because the use raw material of described matrix material is environmental protection raw material, thus also can not discharge the poisonous and hazardous material of human body.
Embodiment
Below by way of specific embodiment, the specific embodiment of the present invention is described in further detail.
Polyester polyol 1 is polyester polyol 10200, is purchased from Changzhou Kanghong Decoration Material Co., Ltd. or sea, Guangzhou agate.
Polyester polyol 2 is polyester polyol 10300, is purchased from Changzhou Kanghong Decoration Material Co., Ltd. or sea, Guangzhou agate.
Polyester polyol 3 is polyester polyol 10100, is purchased from Changzhou Kanghong Decoration Material Co., Ltd. or sea, Guangzhou agate.
Polyester polyol 4 is polyester polyol 3360, is purchased from Changzhou Kanghong Decoration Material Co., Ltd. or sea, Guangzhou agate.
Catalyzer HP-54 and catalyzer HP-80 is all purchased from Zhen Yu Chemical Co., Ltd. of Liyang City.
Embodiment 1
A kind of environmental protection high flame retardant
naval vessels bulkhead heat-preserving complex material, described matrix material is made up of the component of following quality proportioning: combination material ︰ isocyanic ester=1.3 ︰ 1;
The formation of described combination material is as follows according to the mass fraction:
Polyester polyol 1 35 parts
Polyester polyol 2 25 parts
Polyester polyol 3 10 parts
Polyester polyol 4 40 parts
Urethane silicone oil 3.5 parts
Trolamine 7 parts
Diethanolamine 3 parts
Catalyzer HP-54 1.8 parts
Catalyzer HP-80 1.5 parts
3 parts, water
Fire retardant TCEP 45 parts.
Add in reactor and carry out hybrid reaction, stirring velocity 80r/min, churning time 6h, can obtain combining material; Again combination material is mixed with isocyanic ester, matrix material of the present invention can be obtained.
Embodiment 2
A kind of environmental protection high flame retardant
naval vessels bulkhead heat-preserving complex material, described matrix material is made up of the component of following quality proportioning: combination material ︰ isocyanic ester=1.3 ︰ 1;
The formation of described combination material is as follows according to the mass fraction:
Polyester polyol 1 40 parts
Polyester polyol 2 30 parts
Polyester polyol 3 15 parts
Polyester polyol 4 40 parts
Urethane silicone oil 3.5 parts
Trolamine 7 parts
Diethanolamine 3 parts
Catalyzer HP-54 2 parts
Catalyzer HP-80 1.5 parts
3 parts, water
Fire retardant TCEP 45 parts.
Add in reactor and carry out hybrid reaction, stirring velocity 90r/min, churning time 7h, can obtain combining material; Again combination material is mixed with isocyanic ester, matrix material of the present invention can be obtained.
Embodiment 3
A kind of environmental protection high flame retardant
naval vessels bulkhead heat-preserving complex material, described matrix material is made up of the component of following quality proportioning: combination material ︰ isocyanic ester=1.3 ︰ 1;
The formation of described combination material is as follows according to the mass fraction:
Polyester polyol 1 50 parts
Polyester polyol 2 30 parts
Polyester polyol 3 18 parts
Polyester polyol 442 parts
Urethane silicone oil 4 parts
Trolamine 8 parts
Diethanolamine 5 parts
Catalyzer HP-54 2 parts
Catalyzer HP-80 1.5 parts
3.2 parts, water
Fire retardant TCEP 45 parts.
Add in reactor and carry out hybrid reaction, stirring velocity 110r/min, churning time 8h, can obtain combining material; Again combination material is mixed with isocyanic ester, matrix material of the present invention can be obtained.
Embodiment 4
A kind of environmental protection high flame retardant
naval vessels bulkhead heat-preserving complex material, described matrix material is made up of the component of following quality proportioning: combination material ︰ isocyanic ester=1.3 ︰ 1;
The formation of described combination material is as follows according to the mass fraction:
Polyester polyol 1 55 parts
Polyester polyol 2 35 parts
Polyester polyol 3 20 parts
Polyester polyol 4 45 parts
Urethane silicone oil 4.5 parts
Trolamine 9 parts
Diethanolamine 6 parts
Catalyzer HP-54 2.8 parts
Catalyzer HP-80 1.8 parts
3.6 parts, water
Fire retardant TCEP 50 parts.
Add in reactor and carry out hybrid reaction, stirring velocity 120r/min, churning time 8h, can obtain combining material; Again combination material is mixed with isocyanic ester, matrix material of the present invention can be obtained.
Be below flame retardant properties test result of the present invention:
Test basis: GB 8410-2006 " combustioncharacteristics of automotive interior material "
Detection site: component testing laboratory of national car Quality Supervision and Inspection Center.
Inspecting standard requires: the combustionvelocity of fire retardant material should be not more than 100mm/min, if there is following situations, identifies test-results on request respectively, and assay is divided into A, B, C, D, E 5 grades:
A-(0 mm/min): sample is exposed to 15s in flame, extinguish burning things which may cause a fire disaster sample still unburn, or sample can burn, but flame extinguishes before reaching the first measurement graticule, can count without burning extent.
B: during from tester, flame is self-extinguish in 60s, and burning extent is not more than 50mm, then think and meet standard-required.
C-combustionvelocity measured value (mm/min)
During from tester, flame is measured between graticule at two and is extinguished, and when not meeting the 2nd article of situation, then by criterion calculation combustionvelocity.
D-combustionvelocity measured value (mm/min)
During from tester, flame arrives the second graticule, or from timing, the long-time smoulder of sample, then can when tester termination test during 20min, and record combustion time and burning extent and by criterion calculation combustionvelocity.
E: sample has burnt and arrived the first graticule in flame ignition 15s, then think that sample can not meet the requirement of combustionvelocity.
Assay: A(0 mm/min), meet the flame retardant properties requirement of GB 8410-2006 " combustioncharacteristics of automotive interior material ".
Density: 80-140kg density/m
3
Here description of the invention and application is illustrative, not wants by scope restriction of the present invention in the above-described embodiments, and therefore, the present invention is not by the restriction of the present embodiment, and the technical scheme that any employing equivalence replacement obtains is all in the scope of protection of the invention.
Claims (4)
1. an environmental protection high flame retardant naval vessels bulkhead heat-preserving complex material, it is characterized in that, described matrix material is made up of the component of following quality proportioning: combination material ︰ isocyanic ester=1.3 ︰ 1;
The formation of described combination material is as follows according to the mass fraction:
Polyester polyol 1 35-55 part
Polyester polyol 2 25-35 part
Polyester polyol 3 10-20 part
Polyester polyol 4 40-45 part
Urethane silicone oil 3.5-4.5 part
Trolamine 7-9 part
Diethanolamine 3-6 part
Catalyzer HP-54 1.8-2.8 part
Catalyzer HP-80 1.5-1.8 part
Water 3-3.6 part
Fire retardant TCEP 45-50 part.
2. environmental protection high flame retardant naval vessels bulkhead heat-preserving complex material as claimed in claim 1, it is characterized in that, described urethane silicone oil is urethane silicone oil AK8860, is purchased from Nanjing Dymatic Shichuang Chemical Co., Ltd..
3. environmental protection high flame retardant naval vessels bulkhead heat-preserving complex material as claimed in claim 1, is characterized in that described fire retardant TCEP is purchased from Qingdao Lian Mei Chemical Co., Ltd..
4. environmental protection high flame retardant naval vessels bulkhead heat-preserving complex material as claimed in claim 1, it is characterized in that, described isocyanic ester is isocyanic ester MR200, is purchased from Mitsui chemical company.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410639658.7A CN104403071A (en) | 2014-11-13 | 2014-11-13 | Environmentally-friendly high-flame-retardant heat-insulation composite material used for vessel bulkhead |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410639658.7A CN104403071A (en) | 2014-11-13 | 2014-11-13 | Environmentally-friendly high-flame-retardant heat-insulation composite material used for vessel bulkhead |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104403071A true CN104403071A (en) | 2015-03-11 |
Family
ID=52640745
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410639658.7A Pending CN104403071A (en) | 2014-11-13 | 2014-11-13 | Environmentally-friendly high-flame-retardant heat-insulation composite material used for vessel bulkhead |
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| Country | Link |
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| CN (1) | CN104403071A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105237717A (en) * | 2015-09-18 | 2016-01-13 | 扬中市天正合成材料研究中心 | Environmental-protection and high-flame retardation cruises bulkhead acid and alkali resistance storage PU foam material and preparation method thereof |
| CN105237704A (en) * | 2015-09-18 | 2016-01-13 | 扬中市天正合成材料研究中心 | Environmental-protection and high-flame retardation PU foam material for high-speed train bar counters, and preparation method thereof |
| CN106146794A (en) * | 2016-07-07 | 2016-11-23 | 扬中市天正合成材料研究中心 | A kind of automobile-used ceiling environmental protection high flame-retardant foamed material and preparation method thereof |
| CN108948307A (en) * | 2018-06-25 | 2018-12-07 | 扬中市天正合成材料研究中心 | A kind of car door guard plate environmental protection flame retardant PU foamed material and preparation method thereof |
-
2014
- 2014-11-13 CN CN201410639658.7A patent/CN104403071A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105237717A (en) * | 2015-09-18 | 2016-01-13 | 扬中市天正合成材料研究中心 | Environmental-protection and high-flame retardation cruises bulkhead acid and alkali resistance storage PU foam material and preparation method thereof |
| CN105237704A (en) * | 2015-09-18 | 2016-01-13 | 扬中市天正合成材料研究中心 | Environmental-protection and high-flame retardation PU foam material for high-speed train bar counters, and preparation method thereof |
| CN106146794A (en) * | 2016-07-07 | 2016-11-23 | 扬中市天正合成材料研究中心 | A kind of automobile-used ceiling environmental protection high flame-retardant foamed material and preparation method thereof |
| CN108948307A (en) * | 2018-06-25 | 2018-12-07 | 扬中市天正合成材料研究中心 | A kind of car door guard plate environmental protection flame retardant PU foamed material and preparation method thereof |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20150311 |