CN104530367A - Environment protective and high flame-resistant composite material for car door inner panel and preparation method thereof - Google Patents
Environment protective and high flame-resistant composite material for car door inner panel and preparation method thereof Download PDFInfo
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- CN104530367A CN104530367A CN201410602998.2A CN201410602998A CN104530367A CN 104530367 A CN104530367 A CN 104530367A CN 201410602998 A CN201410602998 A CN 201410602998A CN 104530367 A CN104530367 A CN 104530367A
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- matrix material
- high flame
- flame retardant
- environmental protection
- guard plate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6666—Compounds of group C08G18/48 or C08G18/52
- C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/6681—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38
- C08G18/6688—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38 with compounds of group C08G18/3271
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3271—Hydroxyamines
- C08G18/3278—Hydroxyamines containing at least three hydroxy groups
- C08G18/3281—Hydroxyamines containing at least three hydroxy groups containing three hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4018—Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4804—Two or more polyethers of different physical or chemical nature
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4891—Polyethers modified with higher fatty oils or their acids or by resin acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Vehicle Interior And Exterior Ornaments, Soundproofing, And Insulation (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention discloses an environment protective and high flame-resistant composite material for a car door inner panel and a preparation method thereof. The composite material consists of polyether polyols, polyester polyols, vegetable oil based polyether polyols, triethanolamine, polyurethane silicone oil, catalyst, tris(1-chloro-2-propyl)phosphate, water and isocyanate. The composite material has a high flame-resistant property, is not easy to burn in a fire and thus protects the safety of vehicles and passengers. At the same time, the composite material does not release toxic and harmful substances to humans and has no harm to human health due to the use of environmentally friendly raw materials.
Description
Technical field
The present invention relates to a kind of matrix material and preparation method thereof, particularly a kind of environmental protection high flame retardant inner guard plate of automobile door matrix material and preparation method thereof.
Background technology
Along with making rapid progress of automotive industry, people are also improving constantly the pursuit of automotive trim.Inner guard board of automobile door is as the weight integral part of automotive trim, and its comfortableness, security and the feature of environmental protection also more and more become the target that people pursue.Inner guard plate of automobile door many employings plastics of the prior art, but usually to there is flame retardant properties not good for plastics, the easy initiation fire when meeting with an accidet, thus cause serious life property damage.And the raw material sources of some plastics of the prior art not environmentally, often can volatilize some hazardous and noxious substances, people can suck these hazardous and noxious substances in car, can cause larger harm for a long time to HUMAN HEALTH in the past.
Summary of the invention
The object of the invention is to overcome defect of the prior art, provide a kind of environmental protection high flame retardant inner guard plate of automobile door matrix material and preparation method thereof, described matrix material has very high flame retardant properties, and environment-protecting asepsis is to human body fanout free region.
The present invention is achieved by the following technical programs.
A kind of environmental protection high flame retardant inner guard plate of automobile door matrix material, described matrix material is made up of the component of following quality proportioning: combined polyether Ju Zhi ︰ isocyanic ester=1.2 ︰ 1;
The formation of described combined polyether polyester is as follows according to the mass fraction:
Polyether glycol 63-75 part
Polyester polyol 38-50 part
Plant oil polyether glycol 25-35 part
Trolamine 4.9-5.8 part
Urethane silicone oil 3.2-3.8 part
Catalyzer 1.9-2.6 part
Tricresyl phosphate (the chloro-2-propyl group of 1-) ester 35-46 part
Water 5.6-6.2 part.
Above-mentioned a kind of environmental protection high flame retardant inner guard plate of automobile door matrix material, wherein, described isocyanic ester is isocyanic ester MR100, is purchased from Mitsui Chemicals, Inc..
Above-mentioned a kind of environmental protection high flame retardant inner guard plate of automobile door matrix material, wherein, described polyether glycol is polyether glycol 4110, is purchased from Shanghai Gaoqiao Chemical Co., Ltd..
Above-mentioned a kind of environmental protection high flame retardant inner guard plate of automobile door matrix material, wherein, described polyester polyol is polyester polyol 400, is purchased from the photochemical factory in south, Zhangjiagang.
Above-mentioned a kind of environmental protection high flame retardant inner guard plate of automobile door matrix material, wherein, described plant oil polyether glycol is plant oil polyether glycol JTM-4110, is purchased from Jin Tian Chemical Co., Ltd. of Laizhou City.
Above-mentioned a kind of environmental protection high flame retardant inner guard plate of automobile door matrix material, wherein, described urethane silicone oil is urethane silicone oil 508, is purchased from great river, Jiangdu chemical industry Industrial Co., Ltd..
Above-mentioned a kind of environmental protection high flame retardant inner guard plate of automobile door matrix material, wherein, described catalyzer is catalyst A FM20, is purchased from Jintan Ai Wensi fine materials company limited.
The preparation method of above-mentioned a kind of environmental protection high flame retardant inner guard plate of automobile door matrix material, preparation process is as follows: first prepare combined polyether polyester: by polyether glycol, polyester polyol, plant oil polyether glycol, trolamine, urethane silicone oil, catalyzer, tricresyl phosphate (the chloro-2-propyl group of 1-) ester and water add in reactor and carry out hybrid reaction, stirring velocity 80-120r/min, churning time 6-8h combined polyether polyester, and then combined polyether polyester is mixed with the mass ratio of isocyanic ester by 1.2 ︰ 1, matrix material of the present invention can be obtained.
The flame retardant properties of environmental protection high flame retardant inner guard plate of automobile door matrix material of the present invention is high, meets fiery nonflammable, thus has ensured the security of vehicle and the personnel safety of passenger.Simultaneously because the use raw material of matrix material of the present invention is environmental protection raw material, thus can not discharge the poisonous and hazardous material of human body, to HUMAN HEALTH without harm.
Embodiment
Below by way of specific embodiment, the specific embodiment of the present invention is described in further detail.
Embodiment 1
A kind of preparation method of environmental protection high flame retardant inner guard plate of automobile door matrix material, preparation process is as follows: first prepare combined polyether polyester: by the polyether glycol 4110 of 63 parts, the polyester polyol 400 of 38 parts, the plant oil polyether glycol JTM-4110 of 25 parts, the trolamine of 4.9 parts, the urethane silicone oil 508 of 3.2 parts, the catalyst A FM20 of 1.9 parts, tricresyl phosphate (the chloro-2-propyl group of the 1-) ester of 35 parts and the water of 5.6 parts add in reactor and carry out hybrid reaction, stirring velocity 80r/min, churning time 6h combined polyether polyester, and then combined polyether polyester is mixed with the mass ratio of isocyanic ester by 1.2 ︰ 1, matrix material of the present invention can be obtained.
Embodiment 2
A kind of preparation method of environmental protection high flame retardant inner guard plate of automobile door matrix material, preparation process is as follows: first prepare combined polyether polyester: by the polyether glycol 4110 of 65 parts, the polyester polyol 400 of 40 parts, the plant oil polyether glycol JTM-4110 of 27 parts, the trolamine of 5.1 parts, the urethane silicone oil 508 of 3.3 parts, the catalyst A FM20 of 2.0 parts, tricresyl phosphate (the chloro-2-propyl group of the 1-) ester of 38 parts and the water of 5.8 parts add in reactor and carry out hybrid reaction, stirring velocity 90r/min, churning time 6.5h combined polyether polyester, and then combined polyether polyester is mixed with the mass ratio of isocyanic ester by 1.2 ︰ 1, matrix material of the present invention can be obtained.
Embodiment 3
A kind of preparation method of environmental protection high flame retardant inner guard plate of automobile door matrix material, preparation process is as follows: first prepare combined polyether polyester: by the polyether glycol 4110 of 70 parts, the polyester polyol 400 of 46 parts, the plant oil polyether glycol JTM-4110 of 30 parts, the trolamine of 5.5 parts, the urethane silicone oil 508 of 3.6 parts, the catalyst A FM20 of 2.4 parts, tricresyl phosphate (the chloro-2-propyl group of the 1-) ester of 44 parts and the water of 6.0 parts add in reactor and carry out hybrid reaction, stirring velocity 100r/min, churning time 7h combined polyether polyester, and then combined polyether polyester is mixed with the mass ratio of isocyanic ester by 1.2 ︰ 1, matrix material of the present invention can be obtained.
Embodiment 4
A kind of preparation method of environmental protection high flame retardant inner guard plate of automobile door matrix material, preparation process is as follows: first prepare combined polyether polyester: by the polyether glycol 4110 of 75 parts, the polyester polyol 400 of 50 parts, the plant oil polyether glycol JTM-4110 of 35 parts, the trolamine of 5.8 parts, the urethane silicone oil 508 of 3.8 parts, the catalyst A FM20 of 2.6 parts, tricresyl phosphate (the chloro-2-propyl group of the 1-) ester of 46 parts and the water of 6.2 parts add in reactor and carry out hybrid reaction, stirring velocity 120r/min, churning time 8h combined polyether polyester, and then combined polyether polyester is mixed with the mass ratio of isocyanic ester by 1.2 ︰ 1, matrix material of the present invention can be obtained.
Be below the flame retardant properties test result of environmental protection high flame retardant inner guard plate of automobile door matrix material of the present invention:
Test basis: GB 8410-2006 " combustioncharacteristics of automotive interior material "
Detection site: component testing laboratory of national car Quality Supervision and Inspection Center.
Inspecting standard requires: the combustionvelocity of fire retardant material should be not more than 100mm/min, if there is following situations, identifies test-results on request respectively, and assay is divided into A, B, C, D, E 5 grades:
A-(0 mm/min): sample is exposed to 15s in flame, extinguish burning things which may cause a fire disaster sample still unburn, or sample can burn, but flame extinguishes before reaching the first measurement graticule, can count without burning extent.
B: during from tester, flame is self-extinguish in 60s, and burning extent is not more than 50mm, then think and meet standard-required.
C-combustionvelocity measured value (mm/min)
During from tester, flame is measured between graticule at two and is extinguished, and when not meeting the 2nd article of situation, then by criterion calculation combustionvelocity.
D-combustionvelocity measured value (mm/min)
During from tester, flame arrives the second graticule, or from timing, the long-time smoulder of sample, then can when tester termination test during 20min, and record combustion time and burning extent and by criterion calculation combustionvelocity.
E: sample has burnt and arrived the first graticule in flame ignition 15s, then think that sample can not meet the requirement of combustionvelocity.
Assay: A(0 mm/min), meet the flame retardant properties requirement of GB 8410-2006 " combustioncharacteristics of automotive interior material ".
Here description of the invention and application is illustrative, not wants by scope restriction of the present invention in the above-described embodiments, and therefore, the present invention is not by the restriction of the present embodiment, and the technical scheme that any employing equivalence replacement obtains is all in the scope of protection of the invention.
Claims (8)
1. an environmental protection high flame retardant inner guard plate of automobile door matrix material, is characterized in that, described matrix material is made up of the component of following quality proportioning: combined polyether gathers ester ︰ isocyanic ester=1.2 ︰ 1;
The formation of described combined polyether polyester is as follows according to the mass fraction:
Polyether glycol 63-75 part
Polyester polyol 38-50 part
Plant oil polyether glycol 25-35 part
Trolamine 4.9-5.8 part
Urethane silicone oil 3.2-3.8 part
Catalyzer 1.9-2.6 part
Tricresyl phosphate (the chloro-2-propyl group of 1-) ester 35-46 part
Water 5.6-6.2 part.
2. a kind of environmental protection high flame retardant inner guard plate of automobile door matrix material as claimed in claim 1, it is characterized in that, described isocyanic ester is isocyanic ester MR100.
3. a kind of environmental protection high flame retardant inner guard plate of automobile door matrix material as claimed in claim 1, it is characterized in that, described polyether glycol is polyether glycol 4110.
4. a kind of environmental protection high flame retardant inner guard plate of automobile door matrix material as claimed in claim 1, it is characterized in that, described polyester polyol is polyester polyol 400.
5. a kind of environmental protection high flame retardant inner guard plate of automobile door matrix material as claimed in claim 1, it is characterized in that, described plant oil polyether glycol is plant oil polyether glycol JTM-4110.
6. a kind of environmental protection high flame retardant inner guard plate of automobile door matrix material as claimed in claim 1, it is characterized in that, described urethane silicone oil is urethane silicone oil 508.
7. a kind of environmental protection high flame retardant inner guard plate of automobile door matrix material as claimed in claim 1, it is characterized in that, described catalyzer is catalyst A FM20.
8. the preparation method of a kind of environmental protection high flame retardant inner guard plate of automobile door matrix material as claimed in claim 1, it is characterized in that, preparation process is as follows: first prepare combined polyether polyester: by polyether glycol, polyester polyol, plant oil polyether glycol, trolamine, urethane silicone oil, catalyzer, tricresyl phosphate (the chloro-2-propyl group of 1-) ester and water add in reactor and carry out hybrid reaction, stirring velocity 80-120r/min, churning time 6-8h combined polyether polyester, and then combined polyether polyester is mixed with the mass ratio of isocyanic ester by 1.2 ︰ 1, matrix material of the present invention can be obtained.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410602998.2A CN104530367A (en) | 2014-10-31 | 2014-10-31 | Environment protective and high flame-resistant composite material for car door inner panel and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410602998.2A CN104530367A (en) | 2014-10-31 | 2014-10-31 | Environment protective and high flame-resistant composite material for car door inner panel and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN104530367A true CN104530367A (en) | 2015-04-22 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410602998.2A Pending CN104530367A (en) | 2014-10-31 | 2014-10-31 | Environment protective and high flame-resistant composite material for car door inner panel and preparation method thereof |
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| CN (1) | CN104530367A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105237702A (en) * | 2015-09-18 | 2016-01-13 | 扬中市天正合成材料研究中心 | Environmental-protection and high-flame retardation storage cabinet sheet composite material and preparation method thereof |
| CN106117495A (en) * | 2016-07-07 | 2016-11-16 | 扬中市天正合成材料研究中心 | A kind of concrete boat Inner wall of ship body polyurethane environmental protection high flame-retardant foamed material and preparation method |
| CN106146781A (en) * | 2016-07-07 | 2016-11-23 | 扬中市天正合成材料研究中心 | A kind of elastomer environmental protection high flame-retardant foamed material and preparation method thereof |
-
2014
- 2014-10-31 CN CN201410602998.2A patent/CN104530367A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105237702A (en) * | 2015-09-18 | 2016-01-13 | 扬中市天正合成材料研究中心 | Environmental-protection and high-flame retardation storage cabinet sheet composite material and preparation method thereof |
| CN106117495A (en) * | 2016-07-07 | 2016-11-16 | 扬中市天正合成材料研究中心 | A kind of concrete boat Inner wall of ship body polyurethane environmental protection high flame-retardant foamed material and preparation method |
| CN106146781A (en) * | 2016-07-07 | 2016-11-23 | 扬中市天正合成材料研究中心 | A kind of elastomer environmental protection high flame-retardant foamed material and preparation method thereof |
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Application publication date: 20150422 |