CN104530950A - Environment-friendly high-flame-retardant automotive internal thermal insulation spray paint and preparation method thereof - Google Patents
Environment-friendly high-flame-retardant automotive internal thermal insulation spray paint and preparation method thereof Download PDFInfo
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- CN104530950A CN104530950A CN201410603115.XA CN201410603115A CN104530950A CN 104530950 A CN104530950 A CN 104530950A CN 201410603115 A CN201410603115 A CN 201410603115A CN 104530950 A CN104530950 A CN 104530950A
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- polyester polyol
- spray material
- flame retardant
- environmental protection
- high flame
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/06—Polyurethanes from polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4018—Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4202—Two or more polyesters of different physical or chemical nature
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/08—Polyurethanes from polyethers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Fireproofing Substances (AREA)
Abstract
The invention discloses an environment-friendly high-flame-retardant automotive internal thermal insulation spray paint and a preparation method thereof. The spray paint is composed of polyester polyol 1, polyester polyol 2, polyester polyol 3, polyether polyol, polyurethane silicone oil, a catalyst 1, a catalyst 2, tris(2-chloroethyl)phosphate, water and isocyanate. The spray paint has high flame retardant property, and is not prone to combustion when meets fire, such that automotive safety and passenger life safety are ensured. All the raw materials for the spray paint are environment-friendly raw materials, such that the spray paint does not release substances harmful or toxic to human bodies. Therefore, the spray paint is not harmful to human health.
Description
Technical field
The present invention relates to a kind of spray material and preparation method thereof, particularly a kind of environmental protection high flame retardant automobile inside holding spray material and preparation method thereof.
Background technology
Automobile inside holding spray material effectively can completely cut off solar radiant heat, and indoor/outdoor temperature-difference difference usually can be made to reach 6 degrees Celsius.The usual flame retardant properties of automobile inside holding spray material of the prior art is not good, the easy initiation fire when running into fault or accident, thus has certain potential safety hazard.And the raw material sources of some heat insulating sprayed material of the prior art not environmentally, often can volatilize some poisonous and hazardous materials, thus have harm to HUMAN HEALTH.
Summary of the invention
The object of the invention is to overcome defect of the prior art, provide a kind of environmental protection high flame retardant automobile inside holding spray material and preparation method thereof, described spray material has very high flame retardant properties, and environment-protecting asepsis is to human body fanout free region.
The present invention is achieved by the following technical programs.
A kind of environmental protection high flame retardant automobile inside holding spray material, described spray material is made up of the component of following quality proportioning: combined polyether Ju Zhi ︰ isocyanic ester=1.1 ︰ 1;
The formation of described combined polyether polyester is as follows according to the mass fraction:
Polyester polyol 1 50-55 part
Polyester polyol 2 28-32 part
Polyester polyol 3 20-40 part
Polyether glycol 10-15 part
Urethane silicone oil 2.5-3.6 part
Catalyzer 1 1.5-2.2 part
Catalyzer 2 1.5-1.8 part
Tricresyl phosphate (2-chloroethyl) ester 28-35 part
Water 3-4 part.
Above-mentioned a kind of environmental protection high flame retardant automobile inside holding spray material, wherein, described isocyanic ester is isocyanic ester M100, is purchased from Wanhua Chemical Group Co., Ltd..
Above-mentioned a kind of environmental protection high flame retardant automobile inside holding spray material, wherein, described polyester polyol 1 is polyester polyol 3325, is purchased from Changzhou Kanghong Decoration Material Co., Ltd..
Above-mentioned a kind of environmental protection high flame retardant automobile inside holding spray material, wherein, described polyester polyol 2 is polyester polyol 3360, is purchased from Changzhou Kanghong Decoration Material Co., Ltd..
Above-mentioned a kind of environmental protection high flame retardant automobile inside holding spray material, wherein, described polyester polyol 3 is polyester polyol 400, is purchased from the photochemical factory in south, Zhangjiagang.
Above-mentioned a kind of environmental protection high flame retardant automobile inside holding spray material, wherein, described polyether glycol is polyether glycol 4110, is purchased from Dongchang, Zhengjiang City petroleum chemical plant.
Above-mentioned a kind of environmental protection high flame retardant automobile inside holding spray material, wherein, described urethane silicone oil is urethane silicone oil AK-158, is purchased from Nanjing Dymatic Shichuang Chemical Co., Ltd..
Above-mentioned a kind of environmental protection high flame retardant automobile inside holding spray material, wherein, described catalyzer 1 is catalyzer HP-2, is purchased from Zhen Yu Chemical Co., Ltd. of Liyang City.
Above-mentioned a kind of environmental protection high flame retardant automobile inside holding spray material, wherein, described catalyzer 2 is catalyst A 33, is purchased from Zhen Yu Chemical Co., Ltd. of Liyang City.
The preparation method of above-mentioned a kind of environmental protection high flame retardant automobile inside holding spray material, preparation process is as follows: first prepare combined polyether polyester: by polyester polyol 1, polyester polyol 2, polyester polyol 3, polyether glycol, urethane silicone oil, catalyzer 1, catalyzer 2, tricresyl phosphate (2-chloroethyl) ester and water add in reactor and carry out hybrid reaction, stirring velocity 80-120r/min, churning time 6-8h combined polyether polyester, and then combined polyether polyester is mixed with the mass ratio of isocyanic ester by 1.1 ︰ 1, spray material of the present invention can be obtained.
The flame retardant properties of environmental protection high flame retardant automobile inside holding spray material of the present invention is high, meets fiery nonflammable, thus has ensured the security of whole vehicle and the personnel safety of passenger.Simultaneously because the use raw material of described spray material is environmental protection raw material, thus also can not discharge the poisonous and hazardous material of human body.
Embodiment
Below by way of specific embodiment, the specific embodiment of the present invention is described in further detail.
Embodiment 1
A kind of preparation method of environmental protection high flame retardant automobile inside holding spray material, preparation process is as follows: first prepare combined polyether polyester: by the polyester polyol 3325 of 50 parts, the polyester polyol 3360 of 28 parts, the polyester polyol 400 of 20 parts, the polyether glycol 4110 of 10 parts, the urethane silicone oil AK-158 of 2.5 parts, the catalyzer HP-2 of 1.5 parts, the catalyst A 33 of 1.5 parts, tricresyl phosphate (2-chloroethyl) ester of 28 parts and the water of 3 parts add in reactor and carry out hybrid reaction, stirring velocity 80r/min, churning time 6h combined polyether polyester, and then combined polyether polyester is mixed by the mass ratio of 1.1 ︰ 1 with isocyanic ester M100, spray material of the present invention can be obtained.
Embodiment 2
A kind of preparation method of environmental protection high flame retardant automobile inside holding spray material, preparation process is as follows: first prepare combined polyether polyester: by the polyester polyol 3325 of 52 parts, the polyester polyol 3360 of 30 parts, the polyester polyol 400 of 25 parts, the polyether glycol 4110 of 12 parts, the urethane silicone oil AK-158 of 2.8 parts, the catalyzer HP-2 of 1.7 parts, the catalyst A 33 of 1.6 parts, tricresyl phosphate (2-chloroethyl) ester of 30 parts and the water of 3.3 parts add in reactor and carry out hybrid reaction, stirring velocity 100r/min, churning time 7h combined polyether polyester, and then combined polyether polyester is mixed by the mass ratio of 1.1 ︰ 1 with isocyanic ester M100, spray material of the present invention can be obtained.
Embodiment 3
A kind of preparation method of environmental protection high flame retardant automobile inside holding spray material, preparation process is as follows: first prepare combined polyether polyester: by the polyester polyol 3325 of 54 parts, the polyester polyol 3360 of 31 parts, the polyester polyol 400 of 35 parts, the polyether glycol 4110 of 14 parts, the urethane silicone oil AK-158 of 3.4 parts, the catalyzer HP-2 of 2.0 parts, the catalyst A 33 of 1.7 parts, tricresyl phosphate (2-chloroethyl) ester of 33 parts and the water of 3.8 parts add in reactor and carry out hybrid reaction, stirring velocity 110r/min, churning time 8h combined polyether polyester, and then combined polyether polyester is mixed by the mass ratio of 1.1 ︰ 1 with isocyanic ester M100, spray material of the present invention can be obtained.
Embodiment 4
A kind of preparation method of environmental protection high flame retardant automobile inside holding spray material, preparation process is as follows: first prepare combined polyether polyester: by the polyester polyol 3325 of 55 parts, the polyester polyol 3360 of 32 parts, the polyester polyol 400 of 40 parts, the polyether glycol 4110 of 15 parts, the urethane silicone oil AK-158 of 3.6 parts, the catalyzer HP-2 of 2.2 parts, the catalyst A 33 of 1.8 parts, tricresyl phosphate (2-chloroethyl) ester of 35 parts and the water of 4 parts add in reactor and carry out hybrid reaction, stirring velocity 120r/min, churning time 8h combined polyether polyester, and then combined polyether polyester is mixed by the mass ratio of 1.1 ︰ 1 with isocyanic ester M100, spray material of the present invention can be obtained.
Be below the flame retardant properties test result of environmental protection high flame retardant automobile inside holding spray material of the present invention:
Inspecting standard requires: the combustionvelocity of fire retardant material should be not more than 100mm/min, if there is following situations, identifies test-results on request respectively, and assay is divided into A, B, C, D, E 5 grades:
A-(0 mm/min): sample is exposed to 15s in flame, extinguish burning things which may cause a fire disaster sample still unburn, or sample can burn, but flame extinguishes before reaching the first measurement graticule, can count without burning extent.
B: during from tester, flame is self-extinguish in 60s, and burning extent is not more than 50mm, then think and meet standard-required.
C-combustionvelocity measured value (mm/min)
During from tester, flame is measured between graticule at two and is extinguished, and when not meeting the 2nd article of situation, then by criterion calculation combustionvelocity.
D-combustionvelocity measured value (mm/min)
During from tester, flame arrives the second graticule, or from timing, the long-time smoulder of sample, then can when tester termination test during 20min, and record combustion time and burning extent and by criterion calculation combustionvelocity.
E: sample has burnt and arrived the first graticule in flame ignition 15s, then think that sample can not meet the requirement of combustionvelocity.
Assay: assay: A(0 mm/min).
Here description of the invention and application is illustrative, not wants by scope restriction of the present invention in the above-described embodiments, and therefore, the present invention is not by the restriction of the present embodiment, and the technical scheme that any employing equivalence replacement obtains is all in the scope of protection of the invention.
Claims (10)
1. an environmental protection high flame retardant automobile inside holding spray material, it is characterized in that, described spray material is made up of the component of following quality proportioning: combined polyether gathers ester ︰ isocyanic ester=1.1 ︰ 1;
The formation of described combined polyether polyester is as follows according to the mass fraction:
Polyester polyol 1 50-55 part
Polyester polyol 2 28-32 part
Polyester polyol 3 20-40 part
Polyether glycol 10-15 part
Urethane silicone oil 2.5-3.6 part
Catalyzer 1 1.5-2.2 part
Catalyzer 2 1.5-1.8 part
Tricresyl phosphate (2-chloroethyl) ester 28-35 part
Water 3-4 part.
2. a kind of environmental protection high flame retardant automobile inside holding spray material as claimed in claim 1, it is characterized in that, described isocyanic ester is isocyanic ester M100.
3. a kind of environmental protection high flame retardant automobile inside holding spray material as claimed in claim 1, it is characterized in that, described polyester polyol 1 is polyester polyol 3325.
4. a kind of environmental protection high flame retardant automobile inside holding spray material as claimed in claim 1, it is characterized in that, described polyester polyol 2 is polyester polyol 3360.
5. a kind of environmental protection high flame retardant automobile inside holding spray material as claimed in claim 1, it is characterized in that, described polyester polyol 3 is polyester polyol 400.
6. a kind of environmental protection high flame retardant automobile inside holding spray material as claimed in claim 1, it is characterized in that, described polyether glycol is polyether glycol 4110.
7. a kind of environmental protection high flame retardant automobile inside holding spray material as claimed in claim 1, it is characterized in that, described urethane silicone oil is urethane silicone oil AK-158.
8. a kind of environmental protection high flame retardant automobile inside holding spray material as claimed in claim 1, it is characterized in that, described catalyzer 1 is catalyzer HP-2.
9. a kind of environmental protection high flame retardant automobile inside holding spray material as claimed in claim 1, it is characterized in that, described catalyzer 2 is catalyst A 33.
10. the preparation method of a kind of environmental protection high flame retardant automobile inside holding spray material as claimed in claim 1, it is characterized in that, preparation process is as follows: first prepare combined polyether polyester: by polyester polyol 1, polyester polyol 2, polyester polyol 3, polyether glycol, urethane silicone oil, catalyzer 1, catalyzer 2, tricresyl phosphate (2-chloroethyl) ester and water add in reactor and carry out hybrid reaction, stirring velocity 80-120r/min, churning time 6-8h combined polyether polyester, and then combined polyether polyester is mixed with the mass ratio of isocyanic ester by 1.1 ︰ 1, spray material of the present invention can be obtained.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410603115.XA CN104530950A (en) | 2014-10-31 | 2014-10-31 | Environment-friendly high-flame-retardant automotive internal thermal insulation spray paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410603115.XA CN104530950A (en) | 2014-10-31 | 2014-10-31 | Environment-friendly high-flame-retardant automotive internal thermal insulation spray paint and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN104530950A true CN104530950A (en) | 2015-04-22 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201410603115.XA Pending CN104530950A (en) | 2014-10-31 | 2014-10-31 | Environment-friendly high-flame-retardant automotive internal thermal insulation spray paint and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106008878A (en) * | 2016-07-07 | 2016-10-12 | 扬中市天正合成材料研究中心 | Environment-friendly high-flame-retardance foaming material for agricultural pesticide bucket and preparing method of environment-friendly high-flame-retardance foaming material |
| CN106084167A (en) * | 2016-07-07 | 2016-11-09 | 扬中市天正合成材料研究中心 | A kind of semi-rigid elastomer environmental protection high flame-retardant foamed material and preparation method thereof |
-
2014
- 2014-10-31 CN CN201410603115.XA patent/CN104530950A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106008878A (en) * | 2016-07-07 | 2016-10-12 | 扬中市天正合成材料研究中心 | Environment-friendly high-flame-retardance foaming material for agricultural pesticide bucket and preparing method of environment-friendly high-flame-retardance foaming material |
| CN106084167A (en) * | 2016-07-07 | 2016-11-09 | 扬中市天正合成材料研究中心 | A kind of semi-rigid elastomer environmental protection high flame-retardant foamed material and preparation method thereof |
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| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20150422 |
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| WD01 | Invention patent application deemed withdrawn after publication |