CN107266643A - A kind of driver's cabin kuppe environmental protection flame retardant polyurethane foam material and preparation method - Google Patents
A kind of driver's cabin kuppe environmental protection flame retardant polyurethane foam material and preparation method Download PDFInfo
- Publication number
- CN107266643A CN107266643A CN201710539161.1A CN201710539161A CN107266643A CN 107266643 A CN107266643 A CN 107266643A CN 201710539161 A CN201710539161 A CN 201710539161A CN 107266643 A CN107266643 A CN 107266643A
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- parts
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- kuppe
- cabin
- driver
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4018—Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4202—Two or more polyesters of different physical or chemical nature
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
The invention discloses a kind of driver's cabin kuppe environmental protection flame retardant polyurethane foam material and preparation method, a kind of driver's cabin kuppe environmental protection flame retardant polyurethane foam material is made up of following quality proportioning component, second cyanogen polyester：Combination material=1:1.7, the composition of the combination material is based on following mass fraction：Polyester 3628：30 32 parts, polyethers 330：40 45 parts, enhancing glass：200 300 parts, polyester 2056：20 30 parts, polyester 6300：25 35 parts, silicone oil：1.5 2 parts, diethanol amine：8 10 parts, catalyst HP 42,1.5 1.7 parts, catalyst HP 50：1 1.3 parts, water：2.5 3.9 parts, fire retardant DMMP：33 37 parts, wherein the silicone oil is silicone oil AK 8005, combination of the above material composition is added in reactor and carries out hybrid reaction, the 150r/min of mixing speed 130, the 5h of mixing time 4 can must combine material, then again by second cyanogen polyester with combining material by 1:1.7 mass ratio is well mixed, you can the expanded material is made.After above-mentioned material and method so that the driver's cabin kuppe environmental protection flame retardant polyurethane foam material flame-resistant high-temperature-resistant of preparation, intensity are high and environmentally friendly.
Description
Technical field
The present invention relates to a kind of driver's cabin kuppe environmental protection flame retardant polyurethane foam material and preparation method thereof, belong to automobile
Field.
Background technology
At present, with automobile industry development and people's awareness of safety, the enhancing of environmental consciousness, people are to automobile component
It is required that also dramatically increase, driver's cabin kuppe need to possess high temperature resistant, high fire-retardance, high intensity, light as an indispensable part
Quantization, the characteristic of high in environmental protection, the characteristic of traditional driver's cabin kuppe are generally unable to reach comparatively ideal effect, meet burst accident
When, often cause personnel escape's time short because anti-flammability is not good, there is very big potential safety hazard.Thus explore high intensity, high resistant
Combustion, the polyurethane foam material of high-environmental are the fields always in the target of pursuit.
The content of the invention
It is an object of the invention to overcome defect of the prior art, there is provided a kind of poly- ammonia of driver's cabin kuppe environmental protection flame retardant
Ester foaming material, its high temperature resistant, fire resistance height, high intensity and environmental protection.
In order to solve the above-mentioned technical problem, the technical scheme is that：A kind of poly- ammonia of driver's cabin kuppe environmental protection flame retardant
Ester foaming material is made up of following quality proportioning component, second cyanogen polyester：Combination material=1:1.7, it is described combination material composition press with
Lower mass fraction meter, specific mass fraction is as follows：
Polyester 3628：30-32 parts；
Polyethers 330：40-45 parts；
Strengthen glass：200-300 parts；
Polyester 2056：20-30 parts；
Polyester 6300：25-35 parts；
Silicone oil：1.5-2 part；
Diethanol amine：8-10 parts；
Catalyst HP-42：1.5-1.7 part；
Catalyst HP-50：1-1.3 part；
Water：2.5-3.9 part；
Fire retardant DMMP：33-37 parts.
Further, the silicone oil is that silicone oil is chosen as silicone oil AK-8005.
Present invention also offers a kind of preparation method of driver's cabin kuppe environmental protection flame retardant polyurethane foam material, including with
Lower preparation process：Combination material is prepared first：By polyester 3628, polyethers 330, enhancing glass, polyester 2056, polyester 6300, silicone oil,
Diethanol amine, catalyst HP-42, catalyst HP-50, water and fire retardant DMMP are added in reactor and are carried out hybrid reaction, are stirred
Speed 130-150r/min, mixing time 4-5h can must combine material, then again by second cyanogen polyester with combining material by 1:1.7 matter
Amount is than well mixed, you can the driver's cabin kuppe environmental protection flame retardant polyurethane foam material is made.
After above technical scheme, because recipe ingredient collocation is reasonable and preparation method is proper so that the hair of preparation
Foam material fire resistance is high, intensity is high, so that vehicle and personal safety during burst accident have been ensured, further, since expanded material
Use raw material be environmentally friendly raw material, thus will not discharge to the poisonous and hazardous material of human body.
Embodiment
In order that present disclosure is easier to be clearly understood, the present invention is made into one below according to specific embodiment
Step detailed description.
Embodiment one：
A kind of driver's cabin kuppe environmental protection flame retardant polyurethane foam material, including following preparation process：First with mass parts
Number meter, prepares combination material：
Polyester 3628：30 parts；
Polyethers 330：40 parts；
Strengthen glass：200 parts；
Polyester 2056：20 parts；
Polyester 6300：25 parts；
Silicone oil：1.5 part；
Diethanol amine：8 parts；
Catalyst HP-42：1.5 part；
Catalyst HP-50：1 part；
Water：2.5 part；
Fire retardant DMMP：33 parts.
Above-mentioned material is added in reactor and carries out hybrid reaction, wherein the silicone oil is silicone oil AK-8005, mixing speed
130r/min, mixing time 5h can must combine material, then again by second cyanogen polyester with combining material by 1:1.7 mass ratio mixing is equal
It is even, you can the driver's cabin kuppe environmental protection flame retardant polyurethane foam material is made.
Embodiment two：
A kind of driver's cabin kuppe environmental protection flame retardant polyurethane foam material, including following preparation process：First with mass parts
Number meter, prepares combination material：
Polyester 3628：31 parts；
Polyethers 330：42.5 parts；
Strengthen glass：250 parts；
Polyester 2056：25 parts；
Polyester 6300：30 parts；
Silicone oil：1.75 part；
Diethanol amine：9 parts；
Catalyst HP-42：1.6 part；
Catalyst HP-50：1.15 part；
Water：2.7 part；
Fire retardant DMMP：35 parts.
Above-mentioned material is added in reactor and carries out hybrid reaction, wherein the silicone oil is silicone oil AK-8005, mixing speed
140r/min, mixing time 4.5h can must combine material, then again by second cyanogen polyester with combining material by 1:1.7 mass ratio mixing
Uniformly, you can the driver's cabin kuppe environmental protection flame retardant polyurethane foam material is made.
Embodiment three：
A kind of driver's cabin kuppe environmental protection flame retardant polyurethane foam material, including following preparation process：First with mass parts
Number meter, prepares combination material：
Polyester 3628：32 parts；
Polyethers 330：45 parts；
Strengthen glass：300 parts；
Polyester 2056：30 parts；
Polyester 6300：35 parts；
Silicone oil：2 parts；
Diethanol amine：10 parts；
Catalyst HP-42：1.7 part；
Catalyst HP-50：1.3 part；
Water：3.9 part；
Fire retardant DMMP：37 parts.
Above-mentioned material is added in reactor and carries out hybrid reaction, wherein the silicone oil is silicone oil AK-8005, mixing speed
150r/min, mixing time 4h can must combine material, then again by second cyanogen polyester with combining material by 1:1.7 mass ratio mixing is equal
It is even, you can the driver's cabin kuppe environmental protection flame retardant polyurethane foam material is made.
It is a kind of fire resistance test result of driver's cabin kuppe environmental protection flame retardant polyurethane foam material of the invention below：
Test stone requirement：The burning velocity of fire proofing should be not more than 100mm/min, distinguish if there are following situations
Result of the test is identified on request, and assay is divided into 5 grades of A, B, C, D, E：
A：(0mm/min)：Sample is exposed to 15S in flame, and extinguishing burning things which may cause a fire disaster sample is still unburned, or sample can burn, but
Flame reaches extinguishing before the first measurement graticule, and no burning extent can be counted.
B：When tester, flame self-extinguish in 60s, and burning extent is not more than 50mm, then it is assumed that meet
Standard requirement.
C：Burning velocity measured value (mm/min)
When tester, flame extinguishes between two measurement graticules, and when being unsatisfactory for the 2nd article of situation, then by mark
Standard calculates burning velocity.
D：Burning velocity measured value (mm/min)
When tester, flame combustion reaches the second graticule, or since timing, sample long-time smoulder,
Then can in tester termination test during 20min, and record burning time and burning extent and by criterion calculation burning velocity.
E：Sample has burnt in flame ignition 15s and has reached the first graticule, then it is assumed that sample can not meet burning speed
The requirement of degree.
Assay：A-B (0mm/min), is sent out using driver's cabin kuppe environmental protection flame retardant polyurethane manufactured in the present embodiment
Foam material meets fire resistance requirement.
Particular embodiments described above, pair present invention solves the technical problem that, technical scheme and beneficial effect carry out
It is further described, should be understood that the specific embodiment that the foregoing is only the present invention, is not limited to this
Invention, within the spirit and principles of the invention, any modification, equivalent substitution and improvements done etc. should be included in this hair
Within bright protection domain.
Claims (3)
1. a kind of driver's cabin kuppe environmental protection flame retardant polyurethane foam material, it is characterised in that：By following quality proportioning component structure
Into second cyanogen polyester：Combination material=1:1.7, the composition of the combination material is based on following mass fraction, and specific mass fraction is as follows：
Polyester 3628：30-32 parts；
Polyethers 330：40-45 parts；
Strengthen glass：200-300 parts；
Polyester 2056：20-30 parts；
Polyester 6300：25-35 parts；
Silicone oil：1.5-2 part；
Diethanol amine：8-10 parts；
Catalyst HP-42：1.5-1.7 part；
Catalyst HP-50：1-1.3 part；
Water：2.5-3.9 part；
Fire retardant DMMP：33-37 parts.
2. driver's cabin kuppe environmental protection flame retardant polyurethane foam material according to claim 1, it is characterised in that：The silicon
Oil is silicone oil AK-8005.
3. the preparation method of driver's cabin kuppe environmental protection flame retardant polyurethane foam material according to claim 1 or 2, including
Following preparation process：Combination material is prepared first：By polyester 3628, polyethers 330, enhancing glass, polyester 2056, polyester 6300, silicon
Oil, diethanol amine, catalyst HP-42, catalyst HP-50, water and fire retardant DMMP are added in reactor and are carried out hybrid reaction, are stirred
Speed 130-150r/min is mixed, mixing time 4-5h can must combine material, then again by second cyanogen polyester with combining material by 1:1.7
Mass ratio is well mixed, you can the driver's cabin kuppe environmental protection flame retardant polyurethane foam material is made.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710539161.1A CN107266643A (en) | 2017-07-04 | 2017-07-04 | A kind of driver's cabin kuppe environmental protection flame retardant polyurethane foam material and preparation method |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710539161.1A CN107266643A (en) | 2017-07-04 | 2017-07-04 | A kind of driver's cabin kuppe environmental protection flame retardant polyurethane foam material and preparation method |
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| Publication Number | Publication Date |
|---|---|
| CN107266643A true CN107266643A (en) | 2017-10-20 |
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ID=60069733
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710539161.1A Pending CN107266643A (en) | 2017-07-04 | 2017-07-04 | A kind of driver's cabin kuppe environmental protection flame retardant polyurethane foam material and preparation method |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108676145A (en) * | 2018-06-28 | 2018-10-19 | 扬中市天正合成材料研究中心 | Environmental protection flame retardant polyurethane foam material and preparation method thereof for instrument board |
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| CN102391775A (en) * | 2011-09-14 | 2012-03-28 | 可利亚多元醇（南京）有限公司 | High-temperature-resistant composite material for polyurethane heat-preserving pipeline |
| CN105131244A (en) * | 2015-09-08 | 2015-12-09 | 沈阳化工大学 | Polyurethane foaming material for insulation of trees in north |
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| CN106146794A (en) * | 2016-07-07 | 2016-11-23 | 扬中市天正合成材料研究中心 | A kind of automobile-used ceiling environmental protection high flame-retardant foamed material and preparation method thereof |
| CN106146793A (en) * | 2016-07-07 | 2016-11-23 | 扬中市天正合成材料研究中心 | A kind of hard suitcase environmental protection high flame-retardant foamed material and preparation method thereof |
| CN106188460A (en) * | 2016-07-07 | 2016-12-07 | 扬中市天正合成材料研究中心 | A kind of sanitary ware environmental protection high flame-retardant foamed material and preparation method thereof |
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2017
- 2017-07-04 CN CN201710539161.1A patent/CN107266643A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101787109A (en) * | 2009-10-30 | 2010-07-28 | 上海交通大学 | Polyurethane heat insulation foaming material and preparation method thereof |
| CN102391775A (en) * | 2011-09-14 | 2012-03-28 | 可利亚多元醇（南京）有限公司 | High-temperature-resistant composite material for polyurethane heat-preserving pipeline |
| CN105131244A (en) * | 2015-09-08 | 2015-12-09 | 沈阳化工大学 | Polyurethane foaming material for insulation of trees in north |
| CN105237710A (en) * | 2015-09-18 | 2016-01-13 | 扬中市天正合成材料研究中心 | All-water-blown high flame resistance civil electrical control cabinet composite material, and preparation method thereof |
| CN106008873A (en) * | 2016-07-07 | 2016-10-12 | 扬中市天正合成材料研究中心 | Environment-friendly high-flame-retardant foaming material for tap water pipe and preparation method of environment-friendly high-flame-retardant foaming material |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108676145A (en) * | 2018-06-28 | 2018-10-19 | 扬中市天正合成材料研究中心 | Environmental protection flame retardant polyurethane foam material and preparation method thereof for instrument board |
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Application publication date: 20171020 |