CN1061393A - The manufacture method of glass imitation of agate wares - Google Patents

The manufacture method of glass imitation of agate wares Download PDF

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Publication number
CN1061393A
CN1061393A CN 90106432 CN90106432A CN1061393A CN 1061393 A CN1061393 A CN 1061393A CN 90106432 CN90106432 CN 90106432 CN 90106432 A CN90106432 A CN 90106432A CN 1061393 A CN1061393 A CN 1061393A
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Prior art keywords
agate
colorant
glass
color
imitation
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CN 90106432
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CN1027585C (en
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马永亮
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DANDONG CITY GLASSWARE MILL
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DANDONG CITY GLASSWARE MILL
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Priority to CN 90106432 priority Critical patent/CN1027585C/en
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Publication of CN1027585C publication Critical patent/CN1027585C/en
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Expired - Fee Related legal-status Critical Current

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Abstract

The present invention is a kind of manufacture method of agate-imitation color glassware.The chromatography technology of present method is.The solid pigment broken glass that produces the agate decorative patterns effect is bonded in the colorant material group that makes the agate background color.After the baking burning combines pigment broken glass fusing and material group together.Be wrapped on the porcelain vesicle, make the further synthesis and ubiquit of each colorant through baking again.The goods made from this chromatography technology can produce the distribution nature, the imitative agate glass goods of the natural agate decorative pattern that smoothness, gradual change, soft exquisiteness, flickering change are infinite.Present method has and is easy to implement.Effect is true to nature, is fit to imitated agate-imitation color glasswork with various different color and lusters and decorative pattern style.

Description

The manufacture method of glass imitation of agate wares
The present invention relates to a kind of manufacture method of overlapping the colorant glassware, be used to make ornamental glassware with natural agate decorative pattern and color and luster.
The natural gemstone agate is that the decorative pattern of the multiple different colours of distribution on a kind of background color of bright face is formed.Its decorative pattern has the ridge gradual change.Flickering, the characteristics of soft exquisiteness.Interpenetrate between each color patterned and background color, transition is changeable naturally, and in general, background color and decorative pattern present a kind of multilayer sandwich structure again, gives the artistic appeal of a kind of special U.S. of people.Have agate decorative patterns and color and luster if can make ornamental flashed glass ware, will have very high enjoying value and good decoration effect.But existing cover colorant technology can not imitated agate decorative patterns.Produce cover colorant glassware at present.All to pass through operations such as batching be founded, moulding, annealing, cold working.Moulding through being stained with bright material, blown post, cover ceramic whiteware material, cover colorant and implementing decorative machining, is overlapped bright material again at last, goes into the operation of mould blow molding.Because the method difference of cover colorant, can produce colour glassware with different-style, manufacture method as disclosed colour glassware among the CN88105150, its cover colorant method is directly the colorant of different colours to be stained with on the porcelain vesicle successively by smearing pulling method in molten glass level, form parallel one by one colour band, adjacent colour band edge all will form overlapped district, toast then to make and interpenetrate between each colorant and to reach temperature even, overlap bright material at last, go into the mould blow molding, form various colour bands and move towards neat and consistent.Change the transition nature between of all kinds, tonal match, soft, the smooth coloured strip glassware that is rich in decorative effect are and for example, present commercially available natural scape glassware, its cover colorant method is, prior ready-formed colorant glass block is directly sticked on the porcelain vesicle, implement through overbaking fusing back and arbitrarily to smear processing, go into the mould blow molding after overlapping the bright material of one deck again, the formation scenery is just as the decorative pattern of scenery with hills and waters.Goods with above-mentioned existing chromatography technology manufacturing.No matter be colour bar or takes landscape, its decorative pattern is all more spacious, and level is simple.It is soft, flickering to can not form the sort of multi-level distribution exquisiteness of natural agate, jewelly decorative pattern
The object of the present invention is to provide a kind of manufacturing to have the method for the glassware of natural gemstone agate color and luster and decorative pattern wind coloured silk.
The chromatography technology of imitative natural agate is among the present invention: with the molten color glass metal that the coefficient of expansion is complementary, be prefabricated into the solid pigment broken glass of unicolor or colour mixture.Will have at least the solid pigment broken glass of two kinds of colors, optionally stick on the fusion colorant material group surface of making the agate background color.Make pigment broken glass fusing and combine together through baking,, toast again and further permeate between the various colorants that make after the winding and to reach temperature even then with this colorant material group's stretching slivering and be wrapped on the ceramic whiteware material vesicle with colorant material group.Overlap bright material at last, go into the mould blow molding, promptly become glassware with natural agate color and luster and decorative pattern.
Among the present invention, because pigment broken glass arbitrarily is stained with on the colorant material group surface, and make it fusing through baking and combine together with colorant material group, when the stretching slivering of colorant material group, the pigment broken glass that is melted is also along with being stretched, become the similar colorant striped that is embedded in the background color colorant material bar, when again it being wrapped on the data vesicle, the distribution of striped of all kinds presents multilayered structure by the level that twines along whole surface, also show the distribution of about different deep layers along wall thickness, make decorative pattern changes in distribution multiterminal, molecular migration further takes place in changeable making through baking again between each material, infiltration is merged mediation and is generated new middle shade and various intermediate color, so need only can produce goods with a few colorant with numerous different colours decorative patterns, after blow molding, towards expansion, decorative pattern is distributed more seem natural and tripping, gradual change, soft exquisiteness, flickering, it is infinite to change irregularly, bright and glittering, present the wind coloured silk of natural agate jewel, make the vessel goods have very high enjoying value and good decoration effect.Present method effect that is easy to implement is true to nature, is fit to imitated agate-imitation color glassware with various different color and lusters and decorative pattern style.
Embodiment below in conjunction with making agate-imitation color glass vase describes in detail the present invention.
Among the present invention, bright material is selected Na for use 2O-CaO-SiO 2System, the ceramic whiteware material is selected Na for use 2O-CaO-Al 2O 3-SlO 2System, various colorants such as that colorant is selected for use is red, yellow, black, cobalt aluminate.Its concrete prescription can adopt the existing various colorant formulas of producing cased hollow ware, but must guarantee that the coefficient of expansion of bright material, ceramic whiteware material and each colorant is complementary, in case goods break, bright material, ceramic whiteware material and each colorant that the preparation coefficient of expansion is complementary also melts to 1380 ℃~1540 ℃ glass metal respectively.With above-mentioned material glass metal of all kinds, prefabricated solid pigment broken glass unicolor or colour mixture is stand-by, pigment broken glass can be the chunk glass that size and thickness do not wait, and the glass cullet bar that glass cullet piece that differs in size or length thickness do not wait also can mix sheet, piece, bar and use.Preparation method can utilize by being broken into little method greatly, their dimensions distribution is formed naturally, has randomness, be example with the stained glass vase of making imitative cobalt aluminate look agate earlier, from fused cobalt aluminate look glass metal, take out a colorant material group that makes the agate background color, it is fixed that the required material amount of vase that its size will be done to draw up is come, get red, yellow two kinds of pigment broken glass, after mixing, optionally stick in colorant material group surrounded surface, the way that can adopt colorant material group to roll on the pigment broken glass heap is stained with, on baking oven, toast the purpose of baking then.The one, make solid pigment broken glass fusing and combine together with colorant material group; The 2nd, prepare in next step operation colorant material group being wrapped on the porcelain vesicle, promptly reaching can the stringy degree.For this reason, storing temperature generally will be at 1000~1400 ℃, and the operation viscosity of colorant must be controlled at 10 2~10 8Pool, the little realization that more helps above-mentioned baking purpose of healing of operation viscosity, and raising technological effect, but it will be subjected to the restriction of operational condition, therefore under the situation that operational condition allows, should exhaust the little operation viscosity number of possibility, in the above-mentioned colorant material of making group, the operation that be stained with bright material, blown post, cover ceramic whiteware material; The colorant material group's stretching slivering that obtains above also is wrapped on the above-mentioned porcelain vesicle, and then toast, the purpose of current baking is to make to twine the molecular migration motion further takes place between each later colorant, better interpenetrate fusion, be in harmonious proportion between of all kinds and generate new middle shade and intermediate color, and it is even to reach temperature.For this reason, storing temperature generally will be at 1100~1400 ℃, and its operation viscosity must be controlled at 10 2~10 7Pool, the operation viscosity little above-mentioned baking purpose that more helps realizing that heals, and improve effect.Therefore, under the situation that operational condition allows, should exhaust may be little the operation viscosity number, go into the mould blow molding after overlapping the bright material of one deck at last again.Vase surface detail color and luster is to be background color with the cobalt aluminate after the moulding, distributing with red, yellow above is the agate glyptograph of dominant hue, orange, the ashen that is distributing again wherein that blending generates between red, yellow, the Lan Sanse, green and the intermediate color decorative pattern between them, if at above-mentioned cobalt aluminate is in the colorant material group of background color, be stained with red, yellow, black three kinds of pigment broken glass.Make vase with above-mentioned same method, then its surface color decorative pattern be with the cobalt aluminate be distribute above the background color with red, yellow, to deceive be the agate glyptograph of dominant hue, wherein being mingled with blending generates between red, yellow, blue, black four looks the orange purple of distributing, green, ashen, blackish green, brown again and the decorative pattern of intermediate color between them, whole decorative pattern distribution nature, smoothness, gradual change, soft exquisiteness, flickering, it is infinite, bright and glittering to change irregularly.Its pattern texture has not a particle of manually modified vestige, is the wind coloured silk of the blue look agate jewel of one natural formation fully.Among the present invention, the dominant hue of the imitative agate goods of color decision of colorant material group, what obtain as the blue look colorant of above-mentioned usefulness material group is imitative blue look agate goods, equally, if adopt the colorant material group of red, white, green or other colors, can obtain the imitative agate goods of imitative carnelian, white agate, green agate or other colors etc. respectively, and the decision of the color of pigment broken glass is distributed in the color of the decorative pattern on the agate, the present invention can form by the color that changes colorant material group's color and pigment broken glass, makes the imitative agate goods with various different-styles.
The embodiment of imitative red agate goods: do colorant material group with red colorant and select pigment broken glass by required decorative pattern color, make vase by a last embodiment same procedure, then can obtain having the agate-imitation color glass vase of red agate wind coloured silk, if on red colorant material is rolled into a ball, be stained with the cobalt aluminate look, the pigment broken glass of yellow two kinds of colors, to form with the redness after the moulding is to be distributed with above the background color with yellow, the cobalt aluminate look is the imitative agate decorative patterns of dominant hue, wherein be mingled with again and distributing by red, yellow, the orange green that blending generates between the Lan Sanse, ashen and the intermediate color decorative pattern between them, if in red stain group, be stained with cobalt aluminate, yellow, black three kinds of pigment broken glass, to form with the redness after the moulding is background color, distributing above with yellow, the cobalt aluminate look, black is the imitative agate decorative patterns of dominant hue, wherein be mingled with again and distributing by red, Huang Lan, what blending generated between black four looks is orange, ashen, green, blackish green, brown and the intermediate color decorative pattern between them, its outward appearance presents ruddiness and sparkles, the wind coloured silk of multicoloured natural red agate jewel, the present invention can produce the decorative imitating agate colour glassware of various types top grade if be equipped with suitable shape-designing.

Claims (3)

1, a kind of manufacture method of glass imitation of agate wares, this method comprises:
A, the preparation coefficient of expansion mutually bright material, ceramic whiteware material and various colorant and melt to 1380 ℃~1540 ℃ glass metal respectively;
B, get the solid pigment broken glass that each colorant among a is processed into unicolor or colour mixture;
C, be stained with bright material, blown post, cover ceramic whiteware material;
D, pick a colorant material group that makes the agate background color, and optionally be stained with the pigment broken glass that has two kinds of different colours at least, toast then, make its operation viscosity reach 10 on its surface 2Pool~10 8Pool.Make pigment broken glass fusing and combine together, and reach can the stringy degree with colorant material group;
E, with the stretching slivering of the colorant material that obtains in steps d group.And it is wrapped on the ceramic whiteware material vesicle among the step c;
F, be baked to the operation viscosity that makes colorant again and reach 10 2Pool~10 7Pool makes between each colorant after the winding further to interpenetrate.And it is even to reach temperature;
G, overlap the bright material of one deck again.Go into the mould blow molding.
2, according to the manufacture method of the described glass imitation of agate wares of claim 1, it is characterized in that colorant material group adopts red, white or cobalt aluminate look colorant, that described pigment broken glass adopts is red, yellow, two or three colorant in cobalt aluminate look and the black.
3, the glass imitation of agate wares of making according to the manufacture method of claim 1 or 2 described glass imitation of agate wares.
CN 90106432 1990-11-13 1990-11-13 Process for making glass imitation of agate wares Expired - Fee Related CN1027585C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 90106432 CN1027585C (en) 1990-11-13 1990-11-13 Process for making glass imitation of agate wares

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 90106432 CN1027585C (en) 1990-11-13 1990-11-13 Process for making glass imitation of agate wares

Publications (2)

Publication Number Publication Date
CN1061393A true CN1061393A (en) 1992-05-27
CN1027585C CN1027585C (en) 1995-02-08

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CN 90106432 Expired - Fee Related CN1027585C (en) 1990-11-13 1990-11-13 Process for making glass imitation of agate wares

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102503134A (en) * 2011-10-14 2012-06-20 关润明 Application technology for colorful glass grains and powder colored glazes in glass crafts
CN102786202A (en) * 2012-07-26 2012-11-21 淄博市宝泉社会福利玻璃制品厂 Manufacturing method for colored fluorine-free imitation ceramic glaze
CN102826743A (en) * 2012-08-28 2012-12-19 梅玉德 Production process of manufacturing decorative glass with cracked-ice patterns
CN104609731A (en) * 2015-01-19 2015-05-13 朱晓明 Manufacturing technology of microcrystalline stone material with colorful lines

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102503134A (en) * 2011-10-14 2012-06-20 关润明 Application technology for colorful glass grains and powder colored glazes in glass crafts
CN102786202A (en) * 2012-07-26 2012-11-21 淄博市宝泉社会福利玻璃制品厂 Manufacturing method for colored fluorine-free imitation ceramic glaze
CN102786202B (en) * 2012-07-26 2014-08-20 淄博市宝泉轻工制品有限公司 Manufacturing method for colored fluorine-free imitation ceramic glaze
CN102826743A (en) * 2012-08-28 2012-12-19 梅玉德 Production process of manufacturing decorative glass with cracked-ice patterns
CN102826743B (en) * 2012-08-28 2016-08-03 梅玉德 A kind of production technology making decoration cracked ice pattern glass
CN104609731A (en) * 2015-01-19 2015-05-13 朱晓明 Manufacturing technology of microcrystalline stone material with colorful lines
CN104609731B (en) * 2015-01-19 2017-03-15 朱晓明 There is the processing technology of the crystallite stone material of colored lines

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