CN106133001B - 含有机硼烷的组合物及其使用方法 - Google Patents

含有机硼烷的组合物及其使用方法 Download PDF

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CN106133001B
CN106133001B CN201580016386.8A CN201580016386A CN106133001B CN 106133001 B CN106133001 B CN 106133001B CN 201580016386 A CN201580016386 A CN 201580016386A CN 106133001 B CN106133001 B CN 106133001B
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polymerizable
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thiol
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CN106133001A (zh
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R·S·克洛
G·P·卡普
Z·J·汤普森
G·D·乔利
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3M Innovative Properties Co
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/02Polythioethers
    • C08G75/04Polythioethers from mercapto compounds or metallic derivatives thereof
    • C08G75/045Polythioethers from mercapto compounds or metallic derivatives thereof from mercapto compounds and unsaturated compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/54Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/34Introducing sulfur atoms or sulfur-containing groups
    • C08F8/36Sulfonation; Sulfation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/12Polythioether-ethers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04Polysiloxanes
    • C08G77/06Preparatory processes
    • C08G77/08Preparatory processes characterised by the catalysts used
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04Polysiloxanes
    • C08G77/22Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
    • C08G77/28Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen sulfur-containing groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/26Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
    • C08L23/32Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with compounds containing phosphorus or sulfur
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04Polysiloxanes
    • C08L83/08Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04Polysiloxanes
    • C09D183/08Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J183/00Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Adhesives based on derivatives of such polymers
    • C09J183/04Polysiloxanes
    • C09J183/08Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10Esters
    • C08F222/1006Esters of polyhydric alcohols or polyhydric phenols
    • C08F222/103Esters of polyhydric alcohols or polyhydric phenols of trialcohols, e.g. trimethylolpropane tri(meth)acrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/20Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds unconjugated

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Sealing Material Composition (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Polymerization Catalysts (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
CN201580016386.8A 2014-03-27 2015-03-20 含有机硼烷的组合物及其使用方法 Active CN106133001B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201461971352P 2014-03-27 2014-03-27
US61/971,352 2014-03-27
PCT/US2015/021838 WO2015148319A1 (en) 2014-03-27 2015-03-20 Organoborane-containing compositions, and methods of using same

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Publication Number Publication Date
CN106133001A CN106133001A (zh) 2016-11-16
CN106133001B true CN106133001B (zh) 2018-07-24

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US (1) US10513583B2 (https=)
EP (1) EP3122787B1 (https=)
JP (1) JP6694823B2 (https=)
KR (1) KR102335364B1 (https=)
CN (1) CN106133001B (https=)
TW (1) TWI659067B (https=)
WO (1) WO2015148319A1 (https=)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3218442B1 (en) 2014-11-14 2018-09-05 3M Innovative Properties Company Two-part adhesive composition and method of making an adhesive composition
WO2016101129A1 (en) * 2014-12-23 2016-06-30 Henkel (China) Company Limited 1k high temperature debondable adhesive
EP3347406B1 (en) * 2015-09-10 2019-07-03 3M Innovative Properties Company Polymerizable compositions, polymerized compositions, and methods of making and using the same
WO2017177089A1 (en) * 2016-04-07 2017-10-12 Basf Se Curable sealant composition
EP3440148A1 (en) 2016-04-07 2019-02-13 Basf Se Dual-curable sealant composition
WO2018077973A1 (en) * 2016-10-27 2018-05-03 Michael Malkoch A composition comprising thiol, alkene and phosphonic acid containing compounds for use as a primer for adhesion improvement
CN110741050B (zh) * 2017-06-14 2021-05-14 综研化学株式会社 涂布用固化性组合物和层叠体
CN111094398B (zh) * 2017-09-26 2023-02-14 3M创新有限公司 可固化的密封剂组合物、密封帽以及它们的制备和使用方法
US20210252830A1 (en) * 2018-06-15 2021-08-19 3M Innovative Properties Company Assemblies and methods of making a shim
US11667734B2 (en) * 2019-02-14 2023-06-06 Drexel University Oxygen tolerant and room temperature raft through alkylborane initiation
US11015057B2 (en) * 2019-04-03 2021-05-25 Prc-Desoto International, Inc. Dual-cure compositions
FR3098815B1 (fr) * 2019-07-18 2021-06-25 Bostik Sa Procédé de polymérisation avec un complexe de borane-amine
FR3104588B1 (fr) 2019-12-17 2021-12-24 Chryso Composés fluidifiants pour compositions hydrauliques
CN116735784B (zh) * 2023-06-14 2026-02-06 北京林业大学 一种定量检测微塑料的方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1491234A (zh) * 2001-02-21 2004-04-21 3M 工作寿命长的可聚合体系
CN1756821A (zh) * 2003-02-28 2006-04-05 陶氏环球技术公司 胺有机硼烷络合物引发的含有硅氧烷可聚合组分的可聚合组合物
CN102015806A (zh) * 2008-03-28 2011-04-13 汉高公司 两部分杂化粘合剂
CN102458691A (zh) * 2009-06-26 2012-05-16 巴斯夫欧洲公司 于汽车组件上形成固化涂料组合物的方法

Family Cites Families (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3275611A (en) 1960-12-30 1966-09-27 Monsanto Co Process for polymerizing unsaturated monomers with a catalyst comprising an organoboron compound, a peroxygen compound and an amine
US3661744A (en) 1966-07-26 1972-05-09 Grace W R & Co Photocurable liquid polyene-polythiol polymer compositions
US3898349A (en) * 1966-07-26 1975-08-05 Grace W R & Co Polyene/polythiol paint vehicle
US4008341A (en) * 1968-10-11 1977-02-15 W. R. Grace & Co. Curable liquid polymer compositions
JPS55152737A (en) * 1979-02-13 1980-11-28 Gen Electric Ultraviolet ray hardening composition
US4538920A (en) 1983-03-03 1985-09-03 Minnesota Mining And Manufacturing Company Static mixing device
US5082147A (en) 1988-02-29 1992-01-21 Richard Jacobs Composition dispensing system
DE3837569A1 (de) 1988-11-04 1990-05-10 Espe Stiftung Mit sichtbarem licht aushaertbare dentalmassen
US5106928A (en) 1991-04-29 1992-04-21 National Starch And Chemical Investment Holding Corporation Acrylic adhesive composition and organoboron initiator system
US5616796A (en) 1995-04-14 1997-04-01 Minnesota Mining And Manufacturing Company Organoborane polyamine complexes and adhesive composition made therewith
US5621143A (en) 1995-04-14 1997-04-15 Minnesota Mining And Manufacturing Company Organoborane polyoxyalkylenepolyamine complexes and adhesive compositions made therewith
EP0843708B1 (en) * 1995-08-11 2000-08-02 Minnesota Mining And Manufacturing Company Initiator system and adhesive composition made therewith
JP3661717B2 (ja) * 1996-07-30 2005-06-22 三菱瓦斯化学株式会社 新規な高屈折率レンズ材料
US6252023B1 (en) 1999-03-19 2001-06-26 3M Innovative Properties Company Organoborane amine complex inatator systems and polymerizable compositions made therewith
DE19919581A1 (de) 1999-04-29 2000-11-02 Espe Dental Ag Dentalmaterialien, Verfahren zu ihrer Aushärtung und deren Verwendung
AU4710400A (en) 1999-05-10 2000-11-21 3M Innovative Properties Company Compositions for making ene-thiol elastomers
US6486090B1 (en) 1999-11-04 2002-11-26 3M Innovative Properties Company Initiator/hydroxide and initiator/alkoxide complexes, systems comprising the complexes, and polymerized compositions made therewith
US6410667B1 (en) 1999-11-04 2002-06-25 3M Innovative Properties Company Initiator/amidine complexes, systems comprising the complexes, and polymerized compositions made therewith
EP1201722A1 (en) 2000-10-23 2002-05-02 Loctite (R & D) Limited Polymerisation initiators, polymerisable compositions, and uses thereof
IE20020293A1 (en) * 2002-04-23 2003-10-29 Loctite R & D Ltd Initiator systems, polymerisable compositions, and uses thereof for bonding low surface energy substrates
US6740716B2 (en) * 2001-10-30 2004-05-25 Dow Global Technologies Inc. Organoborane amine complex polymerization initiators and polymerizable compositions
US6849569B2 (en) 2001-12-31 2005-02-01 3M Innovative Properties Company Initiator systems comprising β-ketone compounds
AU2003225512A1 (en) 2002-04-19 2003-11-03 Loctite (R And D) Limited Polymerisation initiators based on ammonium tetraalkyl boranes, polymerisable compositions, and uses thereof for bonding low surface energy substrates
US7105584B2 (en) * 2003-04-18 2006-09-12 Nscg, Inc. Dual-cure silicone compounds exhibiting elastomeric properties
US7732543B2 (en) 2005-01-04 2010-06-08 Dow Corning Corporation Siloxanes and silanes cured by organoborane amine complexes
JP5039567B2 (ja) * 2005-02-16 2012-10-03 ダウ・コーニング・コーポレイション ポリマー粒子、および、有機ボランアミン錯体を用いた封入(encapsulated)組成物
JP5663495B2 (ja) * 2009-02-04 2015-02-04 ダウ コーニング コーポレーションDow Corning Corporation 非ランダムコポリマーの形成方法
WO2010149746A1 (en) 2009-06-26 2010-12-29 Basf Se Paint coating system and method of producing multilayered paint coating
WO2012071243A2 (en) 2010-11-22 2012-05-31 3M Innovative Properties Company Assembly and electronic devices including the same
ES2523451T3 (es) 2010-12-17 2014-11-26 Dow Global Technologies Llc Composiciones curables

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1491234A (zh) * 2001-02-21 2004-04-21 3M 工作寿命长的可聚合体系
CN1756821A (zh) * 2003-02-28 2006-04-05 陶氏环球技术公司 胺有机硼烷络合物引发的含有硅氧烷可聚合组分的可聚合组合物
CN102015806A (zh) * 2008-03-28 2011-04-13 汉高公司 两部分杂化粘合剂
CN102458691A (zh) * 2009-06-26 2012-05-16 巴斯夫欧洲公司 于汽车组件上形成固化涂料组合物的方法

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KR102335364B1 (ko) 2021-12-06
KR20160132490A (ko) 2016-11-18
EP3122787B1 (en) 2022-12-21
WO2015148319A1 (en) 2015-10-01
JP2017512866A (ja) 2017-05-25
JP6694823B2 (ja) 2020-05-20
TWI659067B (zh) 2019-05-11
TW201638217A (zh) 2016-11-01
CN106133001A (zh) 2016-11-16
US10513583B2 (en) 2019-12-24
EP3122787A1 (en) 2017-02-01
US20170174839A1 (en) 2017-06-22

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