CN106120343A - 一种涤纶、棉纶丝用油剂、制备方法及其应用 - Google Patents

一种涤纶、棉纶丝用油剂、制备方法及其应用 Download PDF

Info

Publication number
CN106120343A
CN106120343A CN201610534200.4A CN201610534200A CN106120343A CN 106120343 A CN106120343 A CN 106120343A CN 201610534200 A CN201610534200 A CN 201610534200A CN 106120343 A CN106120343 A CN 106120343A
Authority
CN
China
Prior art keywords
preparation
terylene
alcohol
synthetic fibre
stirring
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610534200.4A
Other languages
English (en)
Inventor
徐水林
钱国忠
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou Charles Vegetable Science And Technology Co Ltd
Original Assignee
Suzhou Charles Vegetable Science And Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou Charles Vegetable Science And Technology Co Ltd filed Critical Suzhou Charles Vegetable Science And Technology Co Ltd
Priority to CN201610534200.4A priority Critical patent/CN106120343A/zh
Publication of CN106120343A publication Critical patent/CN106120343A/zh
Pending legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144—Alcohols; Metal alcoholates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
    • D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32—Polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/34—Polyamides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

本发明公开了一种涤纶、棉纶丝用油剂、制备方法及其应用，按重量百分比计，由以下组分组成：白油5‑10%，C16‑C18醇1‑3.5%，乳化剂10‑15%，集束剂1‑5%，抗静电剂1‑5%，添加剂1‑5%，余量为去离子水，所述乳化剂选自：失水山梨醇酯、丙二醇脂肪酸酯、乙二醇脂肪酸酯、单硬脂酸甘油酯、失水山梨醇三油酸酯中的一种或多种。使用本发明油剂后的纤维具有良好的平滑性、集束性，纤维成品质量好；油剂的制备过程无需清洗、无需排废料，安全环保，且制备温度只有20‑40℃，节约能源的同时降低了生产成本。

Description

一种涤纶、棉纶丝用油剂、制备方法及其应用
技术领域
本发明涉及一种纺丝用助剂，具体涉及一种涤纶、棉纶丝用油剂、制备方法及其应用。
背景技术
油剂是在化学纤维的纺丝、牵伸及后处理过程中，喷附在纤维表面上的化学助剂，用以提高纤维的平滑、集束和抗静电性能，改善纤维的牵伸、卷曲、卷绕及纺织加工性能，避免生产过程中出现的毛丝、断头现象，确保生产工艺的顺利进行。油剂是涤纶等纺丝过程中必不可少的加工助剂。
良好的油剂要求具有质量稳定、不腐蚀设备、对人体无害等优点，现有技术中油剂制备过程仍需较高温度（大于40℃），且油剂质量有待提高。
发明内容
本发明要解决的技术问题是克服现有技术的缺陷，提供一种涤纶、棉纶丝用油剂、制备方法及其应用，该油剂性质稳定，安全无害，能使纤维获得较好的平滑性、集束性，且制备过程节省能源，成本较低。
为解决上述技术问题，本发明采用的技术方案是：
一种涤纶、棉纶丝用油剂，其特征在于，按重量百分比计，由以下组分组成：
白油5-10%，C16-C18醇1-3.5%，乳化剂10-15%，集束剂1-5%，抗静电剂1-5%，添加剂1-5%，余量为去离子水，所述乳化剂选自：失水山梨醇酯、丙二醇脂肪酸酯、乙二醇脂肪酸酯、单硬脂酸甘油酯、失水山梨醇三油酸酯中的一种或多种。
优选地，按重量百分比计，由以下组分组成：
白油7.2%，C16-C18醇2.3%，乳化剂12.1%，集束剂1.5%，抗静电剂3.5%，添加剂3%，余量为去离子水，所述乳化剂为失水山梨醇酯何丙二醇脂肪酸酯的混合物。
优选地，所述集束剂为饱和脂肪醇聚氧乙烯醚。
优选地，所述抗静电剂选自脂肪醇磷酸酯钾盐、脂肪醇聚氧乙烯醚磷酸酯钾盐、十八醇磷酸酯钾盐、十六醇磷酸酯钾盐中的一种或多种混合物。
优选地，所述添加剂包括防腐剂。
制备上述一种涤纶、棉纶丝用油剂的方法，包括步骤：
（1）按比例称取白油、C16-C18醇、乳化剂、集束剂、抗静电剂，并在反应釜中依次加入乳化剂、集束剂和抗静电剂，搅拌10-30min后，边搅拌边加入白油和C16-C18醇，在20-40℃温度下继续搅拌30-60min，搅拌速度为400-500r/min，得混合油，
（2）在去离子水中边搅拌边加入添加剂，搅拌5-20min后，再边搅拌边加入混合油。
以上所述的油剂在涤纶、棉纶加工中的应用。
本发明所达到的有益效果：
使用本发明油剂后的纤维具有良好的平滑性、集束性，纤维成品质量好；
油剂的制备过程无需清洗、无需排废料，安全环保，且制备温度只有20-40℃，节约能源的同时降低了生产成本。
具体实施方式
下面结合具体实施例对本发明作进一步描述。以下实施例仅用于更加清楚地说明本发明的技术方案，而不能以此来限制本发明的保护范围。
实施例1
（1）按重量百分比计，准确称取白油5%、C16-C18醇1%、失水山梨醇酯乳化剂10%、集束剂10%、抗静电剂2%，防腐剂1%，余量为水，然后在反应釜中依次加入乳化剂、集束剂和抗静电剂，搅拌10min后，边搅拌边加入白油和C16-C18醇，在35℃温度下继续搅拌30min，搅拌速度为400r/min，得混合油，
（2）在去离子水中边搅拌边加入防腐剂，搅拌10min后，再边搅拌边加入混合油，混合油添加完后继续在20-30℃条件下搅拌20min，得产品。
实施例2
（1）按重量百分比计，准确称取白油10%、C16-C18醇3.5%、乙二醇脂肪酸酯乳化剂15%、集束剂5%、抗静电剂5%，防腐剂5%，余量为去离子水，并在反应釜中依次加入乳化剂、集束剂和抗静电剂，搅拌10min后，边搅拌边加入白油和C16-C18醇，在28℃温度下继续搅拌35min，搅拌速度为400r/min，得混合油，
（2）在去离子水中边搅拌边加入防腐剂，搅拌10min后，再边搅拌边加入混合油，混合油添加完后继续在20-30℃条件下搅拌20min，得产品。
实施例3
（1）按重量百分比计，准确称取白油8%、C16-C18醇1%、乙二醇脂肪酸酯乳化剂10%、集束剂1%、抗静电剂1%，防腐剂1%，余量为去离子水，并在反应釜中依次加入乳化剂、集束剂和抗静电剂，搅拌10min后，边搅拌边加入白油和C16-C18醇，在35℃温度下继续搅拌30min，搅拌速度为450r/min，得混合油，
（2）在去离子水中边搅拌边加入防腐剂，搅拌10min后，再边搅拌边加入混合油，混合油添加完后继续在20-30℃条件下搅拌20min，得产品。
产品性能及使用效果：
实施例1-3中混合油外观呈淡黄色或黄色透明液体，PH值6.0-8.0，加入去离子水后形成的最终产品性能：在25℃的室温中72h后，仍透明，无变化，升温至85℃时，20h后不破乳不挂壁；使用该油剂纺纤时均未出现毛丝，纤维具有良好的平滑性、集束性，且泡沫少，上油故障小。
以上所述仅是本发明的优选实施方式，应当指出，对于本技术领域的普通技术人员来说，在不脱离本发明技术原理的前提下，还可以做出若干改进和变形，这些改进和变形也应视为本发明的保护范围。

Claims (7)

1.一种涤纶、棉纶丝用油剂，其特征在于，按重量百分比计，由以下组分组成：
白油5-10%，C16-C18醇1-3.5%，乳化剂10-15%，集束剂1-5%，抗静电剂1-5%，添加剂1-5%，余量为去离子水，所述乳化剂选自：失水山梨醇酯、丙二醇脂肪酸酯、乙二醇脂肪酸酯、单硬脂酸甘油酯、失水山梨醇三油酸酯中的一种或多种。
2.根据权利要求1所述的一种涤纶、棉纶丝用油剂，其特征在于，按重量百分比计，由以下组分组成：
白油7.2%，C16-C18醇2.3%，乳化剂12.1%，集束剂1.5%，抗静电剂3.5%，添加剂3%，余量为去离子水，所述乳化剂为失水山梨醇酯何丙二醇脂肪酸酯的混合物。
3.根据权利要求1所述的一种涤纶、棉纶丝用油剂，其特征在于，所述集束剂为饱和脂肪醇聚氧乙烯醚。
4.根据权利要求1所述的一种涤纶、棉纶丝用油剂，其特征在于，所述抗静电剂选自脂肪醇磷酸酯钾盐、脂肪醇聚氧乙烯醚磷酸酯钾盐、十八醇磷酸酯钾盐、十六醇磷酸酯钾盐中的一种或多种混合物。
5.根据权利要求1所述的一种涤纶、棉纶丝用油剂，其特征在于，所述添加剂包括防腐剂。
6.制备权利要求1-5任一项所述的一种涤纶、棉纶丝用油剂的方法，其特征在于，包括步骤：
（1）按比例称取白油、C16-C18醇、乳化剂、集束剂、抗静电剂，并在反应釜中依次加入乳化剂、集束剂和抗静电剂，搅拌10-30min后，边搅拌边加入白油和C16-C18醇，在20-40℃温度下继续搅拌30-60min，搅拌速度为400-500r/min，得混合油，
（2）在去离子水中边搅拌边加入添加剂，搅拌5-20min后，再边搅拌边加入混合油。
7.权利要求1-6任一项权利要求所述的油剂在涤纶、棉纶加工中的应用。
CN201610534200.4A 2016-07-08 2016-07-08 一种涤纶、棉纶丝用油剂、制备方法及其应用 Pending CN106120343A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610534200.4A CN106120343A (zh) 2016-07-08 2016-07-08 一种涤纶、棉纶丝用油剂、制备方法及其应用

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610534200.4A CN106120343A (zh) 2016-07-08 2016-07-08 一种涤纶、棉纶丝用油剂、制备方法及其应用

Publications (1)

Publication Number Publication Date
CN106120343A true CN106120343A (zh) 2016-11-16

Family

ID=57282379

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610534200.4A Pending CN106120343A (zh) 2016-07-08 2016-07-08 一种涤纶、棉纶丝用油剂、制备方法及其应用

Country Status (1)

Country Link
CN (1) CN106120343A (zh)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108385379A (zh) * 2018-01-15 2018-08-10 宏杰内衣股份有限公司 一种亲肤型文胸背扣
CN111576046A (zh) * 2020-04-23 2020-08-25 桐乡市恒隆化工有限公司 一种原油上油的纺丝拉伸一步法用油剂及其制备方法
CN114158268A (zh) * 2020-07-07 2022-03-08 竹本油脂株式会社 交织拉伸丝用处理剂的稀释液以及交织拉伸丝的制造方法
CN115387121A (zh) * 2022-09-22 2022-11-25 罗莱生活科技股份有限公司 一种高吸湿性碳素磨毛面料及其生产方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101235592A (zh) * 2008-03-07 2008-08-06 吴江市良燕纺织助剂厂 涤纶fdy纳米纺丝油剂及其制备方法
CN101250812A (zh) * 2008-03-12 2008-08-27 桐昆集团股份有限公司 抗黄变涤纶后加工油剂及其制造方法
CN101633602A (zh) * 2008-07-24 2010-01-27 上海中远化工有限公司 一种脂肪酸甲酯固定床加氢制备脂肪醇的方法
CN102767075A (zh) * 2012-06-25 2012-11-07 桐乡市恒隆化工有限公司 用于生产高f涤纶dty的油剂及其生产方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101235592A (zh) * 2008-03-07 2008-08-06 吴江市良燕纺织助剂厂 涤纶fdy纳米纺丝油剂及其制备方法
CN101250812A (zh) * 2008-03-12 2008-08-27 桐昆集团股份有限公司 抗黄变涤纶后加工油剂及其制造方法
CN101633602A (zh) * 2008-07-24 2010-01-27 上海中远化工有限公司 一种脂肪酸甲酯固定床加氢制备脂肪醇的方法
CN102767075A (zh) * 2012-06-25 2012-11-07 桐乡市恒隆化工有限公司 用于生产高f涤纶dty的油剂及其生产方法

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108385379A (zh) * 2018-01-15 2018-08-10 宏杰内衣股份有限公司 一种亲肤型文胸背扣
CN111576046A (zh) * 2020-04-23 2020-08-25 桐乡市恒隆化工有限公司 一种原油上油的纺丝拉伸一步法用油剂及其制备方法
CN114158268A (zh) * 2020-07-07 2022-03-08 竹本油脂株式会社 交织拉伸丝用处理剂的稀释液以及交织拉伸丝的制造方法
CN115387121A (zh) * 2022-09-22 2022-11-25 罗莱生活科技股份有限公司 一种高吸湿性碳素磨毛面料及其生产方法

Similar Documents

Publication Publication Date Title
CN106120343A (zh) 一种涤纶、棉纶丝用油剂、制备方法及其应用
CN104047156B (zh) 一种羊绒低温漂白剂及其漂白方法
CN103668985A (zh) 一种抗紫外线三防整理剂
CN106244351A (zh) 一种纳米洗衣片配方及其生产工艺
JP2016535112A5 (zh)
CN105647322A (zh) 一种环保内墙涂料
CN106192419A (zh) 一种织物柔软剂及其制备方法
CN106436296A (zh) 涤纶纺丝用油剂
CN103603203A (zh) 一种涤纶poy油剂及其制造方法
CN114574295A (zh) 一种浓缩型光解洗衣液及其制备方法
CN104060468B (zh) 一种湿法腈纶油剂及其制备方法
CN105132150A (zh) 一种米糠油精炼工艺
CN103061119B (zh) 棉纤维用油剂
CN103725397A (zh) 不锈钢线材拉伸工艺用的拉丝液及其配制方法
CN109722888A (zh) 一种新型涤纶纺丝用油剂
CN111097200A (zh) 一种改性有机硅消泡剂
CN105861180A (zh) 一种浸润能力强的杀菌清洁剂及其制备方法
CN106560509B (zh) 移动洗衣房用环保洗衣助剂及其制备方法和应用
CN107312654A (zh) 一种含丝素蛋白的皮肤修复肥皂的制备方法
CN106087402A (zh) 一种涤纶dty型专用油剂及其制备方法
CN107326125B (zh) 一种抗菌型皮革加脂剂及其生产工艺
CN103590256B (zh) 人发纤维有机硅乳液硬挺剂
CN104887726A (zh) 月见草油胶丸及其制备方法
CN105925387B (zh) 一种氧泡泡有氧洗衣凝胶
CN104003912B (zh) 一种沐浴露型α-烯基磺酸盐的制备方法及其应用

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20161116