CN106118819A - 新戊基多元醇酯含有十八烷氧基氮代硼酸钙的润滑油 - Google Patents

新戊基多元醇酯含有十八烷氧基氮代硼酸钙的润滑油 Download PDF

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CN106118819A
CN106118819A CN201610467397.4A CN201610467397A CN106118819A CN 106118819 A CN106118819 A CN 106118819A CN 201610467397 A CN201610467397 A CN 201610467397A CN 106118819 A CN106118819 A CN 106118819A
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polyol ester
neopentyl polyol
nitrogen
calcium pyroborate
npe
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陈卓君
李柏姝
吴英良
李增强
司行
何琼
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Shenyang Ligong University
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C10M169/045—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution and non-macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/283—Esters of polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/223—Five-membered rings containing nitrogen and carbon only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/06—Organic compounds derived from inorganic acids or metal salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives

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  • Chemical & Material Sciences (AREA)
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  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

新戊基多元醇酯（NPE‑3）含有十八烷基氮代硼酸钙的润滑油，其特征在于：其配方为：在新戊基多元醇酯（NPE‑3）加入占新戊基多元醇酯重量百分比：十八烷氧基氮代硼酸钙T366：0‑0.96%,二烃基五硫化物RC2540：0‑0.48%,磷之星P120：0.‑0.4%、硫化异丁烯T321：0.‑0.4%：苯三唑脂肪胺盐T406E.0‑0.72%。本发明具有较好抗磨和承载性能。

Description

新戊基多元醇酯含有十八烷氧基氮代硼酸钙的润滑油
技术领域
本发明涉及润滑油技术，特别是涉及一种环保齿轮润滑油。
背景技术
将新戊基多元醇酯（NPE-3）按一定比例十八烷基氮代硼酸钙T366，配成油样。通过均匀设计方法选取配比方案在以新戊基多元醇酯（NPE-3）中加入五种添加剂的含量配采用优化设计。在新戊基多元醇酯（NPE-3） 加入十八烷基氮代硼酸钙T366：0-0.96%, RC2540：0-0.48%, 磷之星P120：0.-0.4%、硫化异丁烯T321：0.-0.4%：苯三唑脂肪胺盐T-406E.0-0.72%,最大无卡咬负荷Pb为1970N，d =0.333mm，d=0.337mm。
在新戊基多元醇酯（NPE-3）添加十八烷基氮代硼酸钙T366：0-0.96%, RC2540：0-0.48%, 磷之星P120：0.-0.4%、硫化异丁烯T321：0.-0.4%；T406E.0-0.72%进行配比，使用人工神经网络方法优化计算，并进行了复证。由于含有硫元素，因此承载能力较高，最高可达Pb=1970N，d=0.333mm，d=0.337mm。不足是因为含有一定的磷。
在新戊基多元醇酯（NPE-3）中添加十八烷基氮代硼酸钙T366：0-0.96%, RC2540：0-0.48%, 磷之星P120：0.-0.4%、硫化异丁烯T321：0.-0.4%：苯三唑脂肪胺盐T-406E.0-0.72%, 5因素8水平，试验做出Pb值和长磨值，Pb最大可达1970N,磨痕直径可在d=0.333mm，d=0.337mm。
发明内容
本发明要解决的技术问题是，提供一种具有优良的高低温承载性能、耐压抗磨性能，满足各种汽车齿轮箱润滑的新戊基多元醇酯和癸二酸异辛酯混合汽车齿轮润滑油。
采用的技术方案是：
新戊基多元醇酯含有十八烷基氮代硼酸钙的润滑油，是以新戊基多元醇酯（NPE-3）经混合均匀制成。
其配方为：
在新戊基多元醇酯（NPE-3）加入占新戊基多元醇酯重量百分比：
十八烷基氮代硼酸钙T366：0-0.96%,
二烃基五硫化物RC2540：0-0.48%,
磷之星P120：0.-0.4%、
硫化异丁烯T321：0.-0.4%：
金属减磨剂T-406E.0-0.72%,
本发明具有对新戊基多元醇酯（NPE-3）润滑性能，承载能力高。
具体实施方式
实施例一
以新戊基多元醇酯（NPE-3）加入占新戊基多元醇酯重量百分比十八烷氧基氮代硼酸钙T366：0.96%, 二烃基五硫化物RC2540：0.36%, 磷之星P120：0.1%、硫化异丁烯T321：0.20%：苯三唑脂肪胺盐T406E. 0.45%,混合搅拌均匀后加热80度上40分钟，即得。
润滑油添加剂配方选十八烷氧基氮代硼酸钙T366：0.12%, 二烃基五硫化物RC2540：0.30%, 磷之星P120：0.40%、硫化异丁烯T321：0.05%：苯三唑脂肪胺盐T-406E.0.27%，混合搅拌均匀后加热80度上40分钟，即得。
实施例二
以新戊基多元醇酯（NPE-3）基础油加入占新戊基多元醇酯（NPE-3）重量百分比：十八烷氧基氮代硼酸钙T366：0.84%, 二烃基五硫化物RC2540：0.06%, 磷之星P120：0.2%、硫化异丁烯T321：0%：苯三唑脂肪胺盐T-406E.0.54%,混合搅拌均匀后加热80℃40分钟，即得。
实施例三
是以新戊基多元醇酯（NPE-3）基础油，加入十八烷氧基氮代硼酸钙T366：0-0.96%,二烃基五硫化物RC2540：0-0.48%, 磷之星P120：0.-0.4%、硫化异丁烯T321：0.-0.4%，苯三唑脂肪胺盐：T-406E.0-0.72%,经混合均匀制成。
所述新戊基多元醇酯（NPE-3）酯基邻位为季碳原子的一类合成酯，比双酯具有更优异的热和水解稳定性，主要包括新戊二醇酯、三羟甲基丙烷酯和季戊四醇酯；经混合均匀制成。
表1 新戊基多元醇酯NPE-3的理化性能
表2 液体猪油cd-1的理化性能
表3磷之星（P120）的理化性能
表4硫化异丁烯（T321）理化性能
表5苯三唑脂肪胺盐（T-406E）理化性能
外观 氮含量 wt% 油溶性%≥ 铜片腐蚀(100℃,3h,级 闪点 ℃
黄色透明油状液体 10 20 1级 115

Claims (1)

1. 新戊基多元醇酯含有十八烷氧基氮代硼酸钙的润滑油，其特征在于：其配方为：在新戊基多元醇酯（NPE-3）加入占新戊基多元醇酯（NPE-3）重量百分比：十八烷基氮代硼酸钙T366：0-0.96%, 二烃基五硫化物RC2540：0-0.48%, 磷之星P120：0.-0.4%、硫化异丁烯T321：0.-0.4%：苯三唑脂肪胺盐T406E.0-0.72%。
CN201610467397.4A 2016-06-24 2016-06-24 新戊基多元醇酯含有十八烷氧基氮代硼酸钙的润滑油 Pending CN106118819A (zh)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103122266A (zh) * 2012-12-25 2013-05-29 乌鲁木齐市隆成实业有限公司 复合磺酸钙基润滑脂及其制备方法
CN103374452A (zh) * 2012-04-27 2013-10-30 中国石油化工股份有限公司 一种手动变速箱润滑油组合物
CN103614195A (zh) * 2013-11-26 2014-03-05 沈阳理工大学 汽车齿轮润滑油
CN103614193A (zh) * 2013-11-19 2014-03-05 沈阳理工大学 新戊基多元醇酯汽车齿轮润滑油
CN103614194A (zh) * 2013-11-22 2014-03-05 沈阳理工大学 一种新戊基多元醇酯汽车齿轮润滑油组合物
CN103756765A (zh) * 2013-12-27 2014-04-30 沈阳理工大学 一种含有硫稀的新戊基多元醇酯汽车齿轮润滑油

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103374452A (zh) * 2012-04-27 2013-10-30 中国石油化工股份有限公司 一种手动变速箱润滑油组合物
CN103122266A (zh) * 2012-12-25 2013-05-29 乌鲁木齐市隆成实业有限公司 复合磺酸钙基润滑脂及其制备方法
CN103614193A (zh) * 2013-11-19 2014-03-05 沈阳理工大学 新戊基多元醇酯汽车齿轮润滑油
CN103614194A (zh) * 2013-11-22 2014-03-05 沈阳理工大学 一种新戊基多元醇酯汽车齿轮润滑油组合物
CN103614195A (zh) * 2013-11-26 2014-03-05 沈阳理工大学 汽车齿轮润滑油
CN103756765A (zh) * 2013-12-27 2014-04-30 沈阳理工大学 一种含有硫稀的新戊基多元醇酯汽车齿轮润滑油

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