CN106117888A - 一种光伏组件用边框及其制备方法 - Google Patents
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- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 claims abstract description 24
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims abstract description 23
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 22
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000011347 resin Substances 0.000 claims abstract description 12
- 229920005989 resin Polymers 0.000 claims abstract description 12
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims abstract description 11
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 11
- 239000000463 material Substances 0.000 claims abstract description 11
- 239000012760 heat stabilizer Substances 0.000 claims abstract description 8
- 239000004014 plasticizer Substances 0.000 claims abstract description 8
- 238000001125 extrusion Methods 0.000 claims abstract description 5
- 229920003023 plastic Polymers 0.000 claims abstract description 4
- 239000004033 plastic Substances 0.000 claims abstract description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 7
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 4
- 235000013539 calcium stearate Nutrition 0.000 claims description 4
- 239000008116 calcium stearate Substances 0.000 claims description 4
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 4
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 4
- 239000002344 surface layer Substances 0.000 claims description 4
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims description 4
- 239000000470 constituent Substances 0.000 claims description 2
- 229920001971 elastomer Polymers 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 238000006116 polymerization reaction Methods 0.000 claims description 2
- 239000005060 rubber Substances 0.000 claims description 2
- IHBCFWWEZXPPLG-UHFFFAOYSA-N [Ca].[Zn] Chemical compound [Ca].[Zn] IHBCFWWEZXPPLG-UHFFFAOYSA-N 0.000 claims 1
- 229910052599 brucite Inorganic materials 0.000 claims 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 1
- 239000002994 raw material Substances 0.000 claims 1
- 239000003381 stabilizer Substances 0.000 claims 1
- 229920001909 styrene-acrylic polymer Polymers 0.000 claims 1
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical class CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 claims 1
- 230000003712 anti-aging effect Effects 0.000 abstract description 2
- 230000009286 beneficial effect Effects 0.000 abstract 1
- 238000005520 cutting process Methods 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- -1 triacetic acid glycerol Ester Chemical class 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000012536 packaging technology Methods 0.000 description 1
- 239000002990 reinforced plastic Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/022—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/16—Articles comprising two or more components, e.g. co-extruded layers
- B29C48/18—Articles comprising two or more components, e.g. co-extruded layers the components being layers
- B29C48/21—Articles comprising two or more components, e.g. co-extruded layers the components being layers the layers being joined at their surfaces
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- H—ELECTRICITY
- H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
- H02S—GENERATION OF ELECTRIC POWER BY CONVERSION OF INFRARED RADIATION, VISIBLE LIGHT OR ULTRAVIOLET LIGHT, e.g. USING PHOTOVOLTAIC [PV] MODULES
- H02S30/00—Structural details of PV modules other than those related to light conversion
- H02S30/10—Frame structures
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2027/00—Use of polyvinylhalogenides or derivatives thereof as moulding material
- B29K2027/06—PVC, i.e. polyvinylchloride
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2055/00—Use of specific polymers obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in a single one of main groups B29K2023/00 - B29K2049/00, e.g. having a vinyl group, as moulding material
- B29K2055/02—ABS polymers, i.e. acrylonitrile-butadiene-styrene polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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Abstract
本发明公开了一种光伏组件用边框及其制备方法,其材质配方主要包括如下组份:聚氯乙烯(PVC)、丙烯腈‑丁二烯‑苯乙烯塑料(ABS)、碳酸钙、增塑剂、热稳定剂、抗紫外树脂。本发明光伏组件用边框的制备方法,首先称取一定质量的聚氯乙烯(PVC)、丙烯腈‑丁二烯‑苯乙烯塑料(ABS)、碳酸钙、增塑剂、热稳定剂于高速混合机中共混,然后采用双螺杆挤出,并在板材上表面共挤出抗紫外树脂。采用该材料做成的光伏组件用边框,质地轻、耐光、耐热、防老化,且符合可持续发展的环保需求,利于推广。
Description
技术领域
本发明涉及高分子材料领域,尤其涉及一种光伏组件用边框及其制备方法。
背景技术
光伏平板组件必须有边框,以保护组件和方便组件的连接固定。边框的主要材料有不锈钢、铝合金、橡胶、增强塑料等。组件的寿命主要受封装材料的寿命、封装工艺和使用环境的影响,其中封装材料的寿命是决定光伏组件寿命的重要因素之一;
本发明涉及一种光伏组件用边框及其制备方法,该方法采用双螺杆挤出边框异型材,并在异型材外表面共挤出抗紫外树脂。本发明所制备的光伏组件用边框质地轻、耐热、耐光、防老化等性能均也有所提升。
发明内容
有鉴于此,本发明所解决的技术问题在于丰富塑料类光伏组件用边框的选择性,同时改善传统光伏组件用边框热稳定性与光稳定性差等问题
本发明所解决的技术问题采用如下技术方案来实现:
一种光伏组件用边框,其配方及制备工艺采用如下步骤:步骤一:按既定用量称取各原料,即聚氯乙烯(PVC)100质量份、丙烯腈-丁二烯-苯乙烯塑料(ABS)10~30质量份、碳酸钙5~30份、增塑剂3~10质量份、热稳定剂0.5~2质量份;步骤二:将称取的PVC、ABS、碳酸钙、增塑剂、热稳定剂置于高速混合机中混合均匀;步骤三:步骤二中混合后的物料采用双螺杆挤出所需边框异型材,并在表面共挤出抗紫外树脂面层,即为光伏组件用边框异型材
优选的,所述的聚氯乙烯(PVC)的聚合度处于741~1535,即SG2~SG7
优选的,所述的丙烯腈-丁二烯-苯乙烯塑料(ABS)中AS组分含量为70%~95%
说明书附图
图1为组装后的光伏组件边框
其中,1为边框异型材;2为固定用螺孔。
具体实施方式
实施例1
称取聚氯乙烯10Kg、丙烯腈-丁二烯-苯乙烯塑料(ABS)3kg、碳酸钙0.5kg、三乙酸甘油酯0.5、硬脂酸钙0.1kg在高速混合机中共混,挤出光伏组件用边框异型材,表面共挤出0.1mm厚PMMA树脂。即得光伏组件用边框,后续用于裁剪焊接成所需尺寸边框
实施例2
称取聚氯乙烯10Kg、丙烯腈-丁二烯-苯乙烯塑料(ABS)2kg、碳酸钙1kg、柠檬酸甘油酯1kg、硬脂酸钙/硬脂酸锌0.2kg在高速混合机中共混,挤出光伏组件用边框异型材,表面共挤出0.1mm厚ASA树脂。即得光伏组件用边框,后续用于裁剪焊接成所需尺寸边框
实施例3
称取聚氯乙烯20Kg、丙烯腈-丁二烯-苯乙烯塑料(ABS)4kg、碳酸钙1.5kg、二乙酸甘油酯2kg、硬脂酸钙/硬脂酸锌0.5kg在高速混合机中共混,挤出光伏组件用边框异型材,表面共挤出0.2mm厚ASA树脂。即得光伏组件用边框,后续用于裁剪焊接成所需尺寸边框
实施例4
称取聚氯乙烯5Kg、丙烯腈-丁二烯-苯乙烯塑料(ABS)0.9kg、碳酸钙2kg、柠檬酸甘油酯0.5kg、硬脂酸锌0.2kg在高速混合机中共混,挤出光伏组件用边框异型材,表面共挤出0.1mm厚PMMA树脂。即得光伏组件用边框,后续用于裁剪拼接成所需尺寸边框
由此可见,本发明提供的制备光伏组件用边框及制备方法具有以下优点:(1)所述光伏组件用边框,质地轻、耐光性、耐热性等性能均也有所提升;(2)本发明提供的光伏组件用边框及制备方法工艺简单、生产周期短,易于实现产业化生产
所属领域的普通技术人员应当理解:以上所述仅为本发明的具体实施例而已,并不用于限制本发明,凡在本发明的精神和原则之内,所做的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。
Claims (8)
1.一种光伏组件用边框,其特征在于,包括如下质量百分比的各组份:
聚氯乙烯(PVC) 100份
丙烯腈-丁二烯-苯乙烯塑料(ABS) 10~30份
碳酸钙 5~30份
增塑剂 3~10份
热稳定剂 0.5~2份
抗紫外树脂 面层据需而定。
2.根据权利要求1所述的光伏组件用边框,其特征在于,所述的聚氯乙烯(PVC)的聚合度处于741~1535,即SG2~SG7。
3.根据权利要求1所述的光伏组件用边框,其特征在于,所述的丙烯腈-丁二烯-苯乙烯塑料(ABS)中AS组分含量为70%~95%。
4.根据权利要求1所述的光伏组件用边框,其特征在于,所述的增塑剂包括柠檬酸脂类、乙酸甘油酯类等工业生产中常见的环保型增塑剂。
5.根据权利要求1所述的光伏组件用边框,其特征在于,所述的热稳定剂为硬脂酸钙、硬脂酸锌、水滑石等钙锌稳定剂。
6.根据权利要求1所述的光伏组件用边框,其特征在于,所述的抗紫外树脂面层为丙烯腈-苯乙烯-丙烯酸橡胶(ASA)、聚甲基丙烯酸甲酯(PMMA)等抗紫外树脂。
7.根据权利要求1~6所述的光伏组件用边框,其特征在于,包括如下制备步骤:步骤一:按既定用量称取各原料,即聚氯乙烯(PVC)100质量份、丙烯腈-丁二烯-苯乙烯塑料(ABS)10~30质量份、碳酸钙5~30质量份、增塑剂3~10质量份、热稳定剂0.5~2质量份;步骤二:将称取的PVC、ABS、碳酸钙、增塑剂、热稳定剂置于高速混合机中混合均匀;步骤三:步骤二中混合后的物料采用双螺杆挤出所需边框异型材,并在表面共挤出抗紫外树脂面层,即为光伏组件用边框异型材。
8.根据权利要求7所述的光伏组件用边框,其特征在于,所述的边框异型材为直角异型材,且一边具有固定组件的螺孔,厚度为1~10mm。
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Cited By (4)
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CN109021436A (zh) * | 2018-06-29 | 2018-12-18 | 江苏德溢利新材料科技有限公司 | 一种新型阻燃塑料光伏支架 |
CN109111651A (zh) * | 2018-06-29 | 2019-01-01 | 江苏德溢利新材料科技有限公司 | 一种高韧耐候塑料光伏支架 |
CN110311005A (zh) * | 2019-08-07 | 2019-10-08 | 河海大学常州校区 | 一种光伏轻质组件 |
CN110527216A (zh) * | 2019-09-07 | 2019-12-03 | 常州中信博新能源科技有限公司 | 一种耐低温塑料光伏支架 |
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CN105670180A (zh) * | 2016-04-12 | 2016-06-15 | 桂林舒康建材有限公司 | 一种木塑衣架及其制备工艺 |
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CN104309245A (zh) * | 2014-10-13 | 2015-01-28 | 山东理工大学 | 一种聚氯乙烯基包覆共挤木塑橱柜板及其制法 |
CN105670180A (zh) * | 2016-04-12 | 2016-06-15 | 桂林舒康建材有限公司 | 一种木塑衣架及其制备工艺 |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN109021436A (zh) * | 2018-06-29 | 2018-12-18 | 江苏德溢利新材料科技有限公司 | 一种新型阻燃塑料光伏支架 |
CN109111651A (zh) * | 2018-06-29 | 2019-01-01 | 江苏德溢利新材料科技有限公司 | 一种高韧耐候塑料光伏支架 |
CN110311005A (zh) * | 2019-08-07 | 2019-10-08 | 河海大学常州校区 | 一种光伏轻质组件 |
CN110527216A (zh) * | 2019-09-07 | 2019-12-03 | 常州中信博新能源科技有限公司 | 一种耐低温塑料光伏支架 |
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