CN104277378A - 一种防静电pvc木塑复合材料及其制备方法 - Google Patents

一种防静电pvc木塑复合材料及其制备方法 Download PDF

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CN104277378A
CN104277378A CN201410617942.4A CN201410617942A CN104277378A CN 104277378 A CN104277378 A CN 104277378A CN 201410617942 A CN201410617942 A CN 201410617942A CN 104277378 A CN104277378 A CN 104277378A
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陈学军
方圆
吴浩然
喻勇
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Anhui Province San Le Door And Window Curtain Wall Engineering Co Ltd
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    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
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Abstract

本发明公开了一种防静电PVC木塑复合材料，其特征是由下述重量份的原料制得：PVCSG-760-80，绢云母粉5-10，石墨粉5-10，锯末粉20-30，钡锌复合稳定剂3-5，AC发泡剂1-2，环氧亚麻油6-8，磷酸锌1-2，太古油1-2，葵花籽油6-8，椰油酰胺丙基氧化胺1-2，发泡调节剂2-4，复合助剂3-5。本发明的木塑复合材料具有优良的防静电性，且抗菌防霉、质量稳定、抗老化性能和机械性能良好，实用性强。

Description

一种防静电PVC木塑复合材料及其制备方法
技术领域
本发明涉及复合材料技术领域，具体涉及一种防静电PVC木塑复合材料及其制备方法。
背景技术
木塑复合材料是一种新兴的复合材料，是以木纤维或植物纤维为主要原料，填充、增强，经热压复合、熔融挤出等不同加工方式制成的改性热塑性材料，主要用于建材、家具、物流包装等行业。木塑复合材料融合了“木”和“塑”的双重优点，既能克服因木材强度低、变异性大及有机材料弹性模量低等造成的使用局限性，又能充分利用废弃的木材和塑料，节能减排，减少环境污染，提升材料的附加价值，是一种极具发展前途的新型材料。尤其是随着天然资源的日益减少和需求的增加，木塑复合材料的应用领域不断扩大，技术水平随之升级，市场前景十分广阔。
发明内容
本发明的目的是提供一种防静电PVC木塑复合材料。
本发明是通过以下技术方案实现的：
一种防静电PVC木塑复合材料，其特征在于，其是由下述重量份的原料制得：
PVC SG-7 60-80，绢云母粉5-10，石墨粉5-10，锯末粉20-30，钡锌复合稳定剂3-5，AC发泡剂1-2，环氧亚麻油6-8，磷酸锌1-2，太古油1-2，葵花籽油6-8，椰油酰胺丙基氧化胺1-2，发泡调节剂2-4，复合助剂3-5；
其中复合助剂由下列重量份的原料制成：
纳米氧化锌8-10，纳米氧化铝4-6，纳米二氧化硅3-5，三氧化二锑3-5，三乙醇胺2-4，白矿油4-6，橄榄油6-10，单宁酸0.3-0.5，单硬脂酸甘油酯1-2，铝酸酯偶联剂2-4；
其中复合助剂的制备方法是：
将纳米氧化锌、纳米氧化铝、纳米二氧化硅和三氧化二锑加入适量乙醇中超声分散10-15min，再加入单宁酸、三乙醇胺和铝酸酯偶联剂200-400r/min搅拌0.5-1h，过滤并洗涤，真空干燥后加入白矿油、橄榄油和单硬脂酸甘油酯80-90℃、800-1000r/min搅拌2-4h，过滤后洗涤干燥，即得。
一种防静电PVC木塑复合材料的制备方法，其包括以下步骤：
（1）将绢云母粉、石墨粉、锯末粉和磷酸锌混合后充分干燥，加入葵花籽油和椰油酰胺丙基氧化胺研磨均匀，于80-90℃、800-1000r/min条件下搅拌0.5-1h，得混合填料；
（2）将（1）中得到的混合填料与PVC SG-7、环氧亚麻油、太古油和复合助剂混合后共同加入高混机，先于80-90℃高速混合20-30min，再加入其余原料120-140℃高速混合10-15min，随后加入螺杆挤出机中挤出成型，最后进行表面处理，即得成品。
本发明的优点是：
1. 通过配方与工艺的改进，使制得的木塑复合材料具有优良的防静电性，且抗菌防霉、质量稳定、机械性能良好，实用性强；
2. 通过添加复合助剂，使产品具有优异的抗菌性、抗老化性和抗蠕变性，质量稳定，使用寿命长。
具体实施方式
本发明非限定实施例如下：
一种防静电PVC木塑复合材料，由下列重量(kg)的组分原料制备而成：
PVC SG-7 70，绢云母粉8，石墨粉8，锯末粉25，钡锌复合稳定剂4，AC发泡剂1.5，环氧亚麻油7，磷酸锌1.5，太古油1.5，葵花籽油7，椰油酰胺丙基氧化胺1.5，发泡调节剂3，复合助剂4；
其中，复合助剂由下列重量（kg）的原料制成：
纳米氧化锌9，纳米氧化铝5，纳米二氧化硅4，三氧化二锑4，三乙醇胺3，白矿油5，橄榄油8，单宁酸0.4，单硬脂酸甘油酯1.5，铝酸酯偶联剂3；
复合助剂的制备方法：
将纳米氧化锌、纳米氧化铝、纳米二氧化硅和三氧化二锑加入适量乙醇中超声分散10min，再加入单宁酸、三乙醇胺和铝酸酯偶联剂400r/min搅拌0.5h，过滤并洗涤，真空干燥后加入白矿油、橄榄油和单硬脂酸甘油酯90℃、1000r/min搅拌3h，过滤后洗涤干燥，即得。
防静电PVC木塑复合材料的制备方法包括以下步骤：
（1）将绢云母粉、石墨粉、锯末粉和磷酸锌混合后充分干燥，加入葵花籽油和椰油酰胺丙基氧化胺研磨均匀，于90℃、1000r/min条件下搅拌0.5h，得混合填料；
（2）将（1）中得到的混合填料与PVC SG-7、环氧亚麻油、太古油和复合助剂混合后共同加入高混机，先于90℃高速混合30min，再加入其余原料140℃高速混合15min，随后加入螺杆挤出机中挤出成型，最后进行表面处理，即得成品。
本实施例产品按GB/T 29418-2012标准检测性能指标如下：
拉伸强度：26.8MPa，弯曲强度：29.1MPa。

Claims (2)

1.一种防静电PVC木塑复合材料，其特征在于，其是由下述重量份的原料制得：
PVC SG-7 60-80，绢云母粉5-10，石墨粉5-10，锯末粉20-30，钡锌复合稳定剂3-5，AC发泡剂1-2，环氧亚麻油6-8，磷酸锌1-2，太古油1-2，葵花籽油6-8，椰油酰胺丙基氧化胺1-2，发泡调节剂2-4，复合助剂3-5；
所述复合助剂由下列重量份的原料制成：
纳米氧化锌8-10，纳米氧化铝4-6，纳米二氧化硅3-5，三氧化二锑3-5，三乙醇胺2-4，白矿油4-6，橄榄油6-10，单宁酸0.3-0.5，单硬脂酸甘油酯1-2，铝酸酯偶联剂2-4；
所述复合助剂的制备方法是：
将纳米氧化锌、纳米氧化铝、纳米二氧化硅和三氧化二锑加入适量乙醇中超声分散10-15min，再加入单宁酸、三乙醇胺和铝酸酯偶联剂200-400r/min搅拌0.5-1h，过滤并洗涤，真空干燥后加入白矿油、橄榄油和单硬脂酸甘油酯80-90℃、800-1000r/min搅拌2-4h，过滤后洗涤干燥，即得。
2.根据权利要求1所述的一种防静电PVC木塑复合材料的制备方法，其特征在于，包括以下步骤：
（1）将绢云母粉、石墨粉、锯末粉和磷酸锌混合后充分干燥，加入葵花籽油和椰油酰胺丙基氧化胺研磨均匀，于80-90℃、800-1000r/min条件下搅拌0.5-1h，得混合填料；
（2）将（1）中得到的混合填料与PVC SG-7、环氧亚麻油、太古油和复合助剂混合后共同加入高混机，先于80-90℃高速混合20-30min，再加入其余原料120-140℃高速混合10-15min，随后加入螺杆挤出机中挤出成型，最后进行表面处理，即得成品。
CN201410617942.4A 2014-11-06 2014-11-06 一种防静电pvc木塑复合材料及其制备方法 Pending CN104277378A (zh)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105348696A (zh) * 2015-12-02 2016-02-24 安徽天星光纤通信设备有限公司 一种抗菌电缆料
CN107312267A (zh) * 2017-07-27 2017-11-03 山东霞光实业有限公司 一种实心木塑快装墙板及其生产工艺
CN107418234A (zh) * 2017-04-28 2017-12-01 安徽以诺木塑板材科技有限公司 一种木塑地板及其制备工艺
CN108017858A (zh) * 2018-01-08 2018-05-11 安徽以诺木塑板材科技有限公司 一种耐水pvc木塑发泡复合材料及其制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001240715A (ja) * 2000-02-29 2001-09-04 Zeon Kasei Co Ltd 塩化ビニル系樹脂組成物
CN100999610A (zh) * 2006-01-12 2007-07-18 中国林业科学研究院木材工业研究所 木塑复合材料组合物及成型板以及它们的制备方法
CN102382399A (zh) * 2011-10-09 2012-03-21 常熟市威腾进出口有限公司 一种防静电木粉与聚氯乙烯复合材料及制备方法
CN102477192A (zh) * 2010-11-29 2012-05-30 山东博拓塑业股份有限公司 抗静电聚氯乙烯发泡板材

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001240715A (ja) * 2000-02-29 2001-09-04 Zeon Kasei Co Ltd 塩化ビニル系樹脂組成物
CN100999610A (zh) * 2006-01-12 2007-07-18 中国林业科学研究院木材工业研究所 木塑复合材料组合物及成型板以及它们的制备方法
CN102477192A (zh) * 2010-11-29 2012-05-30 山东博拓塑业股份有限公司 抗静电聚氯乙烯发泡板材
CN102382399A (zh) * 2011-10-09 2012-03-21 常熟市威腾进出口有限公司 一种防静电木粉与聚氯乙烯复合材料及制备方法

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
吕百龄: "《实用橡胶手册》", 30 April 2010, 化学工业出版社 *
高俊刚等: "《改性聚氯乙烯新材料》", 31 October 2002, 化学工业出版社 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105348696A (zh) * 2015-12-02 2016-02-24 安徽天星光纤通信设备有限公司 一种抗菌电缆料
CN107418234A (zh) * 2017-04-28 2017-12-01 安徽以诺木塑板材科技有限公司 一种木塑地板及其制备工艺
CN107312267A (zh) * 2017-07-27 2017-11-03 山东霞光实业有限公司 一种实心木塑快装墙板及其生产工艺
CN108017858A (zh) * 2018-01-08 2018-05-11 安徽以诺木塑板材科技有限公司 一种耐水pvc木塑发泡复合材料及其制备方法

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