CN106106485A - A kind of compositions preventing and treating spider and preparation method thereof - Google Patents
A kind of compositions preventing and treating spider and preparation method thereof Download PDFInfo
- Publication number
- CN106106485A CN106106485A CN201610466112.5A CN201610466112A CN106106485A CN 106106485 A CN106106485 A CN 106106485A CN 201610466112 A CN201610466112 A CN 201610466112A CN 106106485 A CN106106485 A CN 106106485A
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- China
- Prior art keywords
- parts
- caprylic acid
- trihydroxymethylpropanyl ester
- synergist
- tigloidine
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/02—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of compositions preventing and treating spider and preparation method thereof, including the raw material of following weight portion: butanone sulfone prestige, 25～35 parts；Tigloidine, 15～25 parts；Propylene glycol, 135～155 parts；Water, 425～445 parts；Synergist trihydroxymethylpropanyl ester and caprylic acid totally 7～9 parts, the weight ratio of trihydroxymethylpropanyl ester and caprylic acid is 6～8:1.The compositions that the present invention provides can prevent and treat spider, the pesticide of preventing and treating spider can be developed into, prevention effect is relevant with the weight ratio of synergist trihydroxymethylpropanyl ester and caprylic acid in raw material, and when the weight ratio of trihydroxymethylpropanyl ester and caprylic acid is 6～8:1, prevention effect is best.
Description
Technical field
The invention belongs to pesticide field, be specifically related to a kind of compositions preventing and treating spider and preparation method thereof.
Background technology
Spider belongs to Arachnoidea, Acarina.The demodicid mite class of domestic harm Semen Tritici aestivi is mainly by penthaleus major duges and grain spider mite two
Kind.The former belongs to Eupodidae.There is the Winter Wheat Area between north latitude 37 degree is to 29 in penthaleus major duges；Grain spider mite distribution is by north,
Occur mainly in the wheat belt of north latitude 34 to 43 degree.At majority area, Anhui Province occurrence injury is penthaleus major duges, and Anhui is northern
Area such as Dangshan, two kinds of spider mixing occur.Two kinds of spider main harm Semen Tritici aestivis, Fructus Hordei Vulgaris is injured gently.Spider is at Semen Tritici aestivi
Seedling stage sucks leaf sap.Beginning to show many tiny white maculas on killed leaf, later wheat leaf turns yellow.After wheat strain is injured, the lighter affects growth,
Plant is short and small, and yield reduces, the withered death of severe one Herb.Penthaleus major duges harm the Sheng phase in the Semen Tritici aestivi stem elongation stage, after Semen Tritici aestivi is injured
Topdress as watered in time, can significantly alleviate extent of injury.The grain spider mite harm Sheng phase, can be sent out greatly to heading stage at wheat booting
Severe Reduction can be caused time raw.
Have not yet to see butanone sulfone prestige and work in coordination with the report preventing and treating spider with tigloidine.
Summary of the invention
It is an object of the invention to provide the compositions of a kind of preventing and treating spider containing butanone sulfone prestige and tigloidine
And the application in pesticide.
The above-mentioned purpose of the present invention is achieved by techniques below scheme:
A kind of compositions preventing and treating spider, including the raw material of following weight portion: butanone sulfone prestige, 25～35 parts；Crotonocyl
Hyoscyamine, 15～25 parts；Propylene glycol, 135～155 parts；Water, 425～445 parts；Synergist trihydroxymethylpropanyl ester and caprylic acid
Totally 7～9 parts, the weight ratio of trihydroxymethylpropanyl ester and caprylic acid is 6～8:1.
Further, the compositions of described preventing and treating spider includes the raw material of following weight portion: butanone sulfone prestige, 30 parts；
Tigloidine, 20 parts；Propylene glycol, 145 parts；Water, 435 parts；Synergist trihydroxymethylpropanyl ester and caprylic acid totally 8 parts, three
The weight ratio of hydroxymethyl-propane ester and caprylic acid is 7:1.
Further, the compositions of described preventing and treating spider includes the raw material of following weight portion: butanone sulfone prestige, 25 parts；
Tigloidine, 15 parts；Propylene glycol, 135 parts；Water, 425 parts；Synergist trihydroxymethylpropanyl ester and caprylic acid totally 7 parts, three
The weight ratio of hydroxymethyl-propane ester and caprylic acid is 6:1.
Further, the compositions of described preventing and treating spider includes the raw material of following weight portion: butanone sulfone prestige, 35 parts；
Tigloidine, 25 parts；Propylene glycol, 155 parts；Water, 445 parts；Synergist trihydroxymethylpropanyl ester and caprylic acid totally 9 parts, three
The weight ratio of hydroxymethyl-propane ester and caprylic acid is 8:1.
The preparation method of above-mentioned composition, it is characterised in that comprise the steps:
Step S1, by butanone sulfone prestige, tigloidine and synergist trihydroxymethylpropanyl ester propylene glycol and water dissolution；
Step S2, by caprylic acid water dissolution；
Step S3, slowly adds the solution of step S2 in the solution of step S1, and interpolation limit, limit is stirred, and to obtain final product.
Advantages of the present invention:
The compositions that the present invention provides can prevent and treat spider, can develop into the pesticide of preventing and treating spider.
Detailed description of the invention
Further illustrate the essentiality content of the present invention below in conjunction with embodiment, but do not limit the present invention with this and protect model
Enclose.Although the present invention being explained in detail with reference to preferred embodiment, it will be understood by those within the art that, can be right
Technical scheme is modified or equivalent, without deviating from the spirit and scope of technical solution of the present invention.
Embodiment 1: the preparation of the compositions of preventing and treating spider
Parts by weight of raw materials compares:
Butanone sulfone prestige, 30 parts；Tigloidine, 20 parts；Propylene glycol, 145 parts；Water, 435 parts；Synergist trihydroxy methyl
Propane ester and caprylic acid totally 8 parts, the weight ratio of trihydroxymethylpropanyl ester and caprylic acid is 7:1.
Preparation method:
Step S1, by butanone sulfone prestige, tigloidine and synergist trihydroxymethylpropanyl ester propylene glycol and water dissolution；
Step S2, by caprylic acid water dissolution；
Step S3, slowly adds the solution of step S2 in the solution of step S1, and interpolation limit, limit is stirred, and to obtain final product.
Embodiment 2: the preparation of the compositions of preventing and treating spider
Parts by weight of raw materials compares:
Butanone sulfone prestige, 25 parts；Tigloidine, 15 parts；Propylene glycol, 135 parts；Water, 425 parts；Synergist trihydroxy methyl
Propane ester and caprylic acid totally 7 parts, the weight ratio of trihydroxymethylpropanyl ester and caprylic acid is 6:1.
Preparation method:
Step S1, by butanone sulfone prestige, tigloidine and synergist trihydroxymethylpropanyl ester propylene glycol and water dissolution；
Step S2, by caprylic acid water dissolution；
Step S3, slowly adds the solution of step S2 in the solution of step S1, and interpolation limit, limit is stirred, and to obtain final product.
Embodiment 3: the preparation of the compositions of preventing and treating spider
Parts by weight of raw materials compares:
Butanone sulfone prestige, 35 parts；Tigloidine, 25 parts；Propylene glycol, 155 parts；Water, 445 parts；Synergist trihydroxy methyl
Propane ester and caprylic acid totally 9 parts, the weight ratio of trihydroxymethylpropanyl ester and caprylic acid is 8:1.
Preparation method:
Step S1, by butanone sulfone prestige, tigloidine and synergist trihydroxymethylpropanyl ester propylene glycol and water dissolution；
Step S2, by caprylic acid water dissolution；
Step S3, slowly adds the solution of step S2 in the solution of step S1, and interpolation limit, limit is stirred, and to obtain final product.
Embodiment 4: the preparation of the compositions of preventing and treating spider
Parts by weight of raw materials compares:
Butanone sulfone prestige, 30 parts；Tigloidine, 20 parts；Propylene glycol, 145 parts；Water, 435 parts；Synergist trihydroxy methyl
Propane ester and caprylic acid totally 8 parts, the weight ratio of trihydroxymethylpropanyl ester and caprylic acid is 6:1.
Preparation method:
Step S1, by butanone sulfone prestige, tigloidine and synergist trihydroxymethylpropanyl ester propylene glycol and water dissolution；
Step S2, by caprylic acid water dissolution；
Step S3, slowly adds the solution of step S2 in the solution of step S1, and interpolation limit, limit is stirred, and to obtain final product.
Embodiment 5: the preparation of the compositions of preventing and treating spider
Parts by weight of raw materials compares:
Butanone sulfone prestige, 30 parts；Tigloidine, 20 parts；Propylene glycol, 145 parts；Water, 435 parts；Synergist trihydroxy methyl
Propane ester and caprylic acid totally 8 parts, the weight ratio of trihydroxymethylpropanyl ester and caprylic acid is 8:1.
Preparation method:
Step S1, by butanone sulfone prestige, tigloidine and synergist trihydroxymethylpropanyl ester propylene glycol and water dissolution；
Step S2, by caprylic acid water dissolution；
Step S3, slowly adds the solution of step S2 in the solution of step S1, and interpolation limit, limit is stirred, and to obtain final product.
The weight ratio of embodiment 6: comparative example, trihydroxymethylpropanyl ester and caprylic acid is 5:1
Parts by weight of raw materials compares:
Butanone sulfone prestige, 30 parts；Tigloidine, 20 parts；Propylene glycol, 145 parts；Water, 435 parts；Synergist trihydroxy methyl
Propane ester and caprylic acid totally 8 parts, the weight ratio of trihydroxymethylpropanyl ester and caprylic acid is 5:1.
Preparation method:
Step S1, by butanone sulfone prestige, tigloidine and synergist trihydroxymethylpropanyl ester propylene glycol and water dissolution；
Step S2, by caprylic acid water dissolution；
Step S3, slowly adds the solution of step S2 in the solution of step S1, and interpolation limit, limit is stirred, and to obtain final product.
The weight ratio of embodiment 7: comparative example, trihydroxymethylpropanyl ester and caprylic acid is 9:1
Parts by weight of raw materials compares:
Butanone sulfone prestige, 30 parts；Tigloidine, 20 parts；Propylene glycol, 145 parts；Water, 435 parts；Synergist trihydroxy methyl
Propane ester and caprylic acid totally 8 parts, the weight ratio of trihydroxymethylpropanyl ester and caprylic acid is 9:1.
Preparation method:
Step S1, by butanone sulfone prestige, tigloidine and synergist trihydroxymethylpropanyl ester propylene glycol and water dissolution；
Step S2, by caprylic acid water dissolution；
Step S3, slowly adds the solution of step S2 in the solution of step S1, and interpolation limit, limit is stirred, and to obtain final product.
Embodiment 8: effect example
Use the field test compositions that respectively prepared by the testing example 1～7 preventing and treating effective percentage (%) to spider.
Test sets chemicals treatment group 1～7 and blank group, and chemicals treatment group 1～7 is sprayed embodiment 1～7 respectively and prepared
Compositions, blank group spray clear water.Chemicals treatment group agent fountain height 40g/hm in terms of butanone sulfone prestige2.Plot area is
50m2, random district group arranges.It is repeated 4 times.Use workers and peasants-16 aerosol apparatus spray medicine, spouting liquid 750kg/hm2.With reference to Ministry of Agriculture field
Test of pesticide effectiveness criterion, 15d after medicine, calculate preventing and treating effective percentage (%).
Result such as following table.
| Preventing and treating effective percentage (%) | |
| Embodiment 1 | 96 |
| Embodiment 4 | 91 |
| Embodiment 5 | 92 |
| Embodiment 6 | 66 |
| Embodiment 7 | 67 |
The effect of embodiment 2,3 is basically identical with embodiment 4,5.
The above results shows, the compositions that the present invention provides can prevent and treat spider, can develop into preventing and treating spider
Pesticide, prevention effect is relevant with the weight ratio of synergist trihydroxymethylpropanyl ester and caprylic acid in raw material, trihydroxy methyl third
When the weight ratio of alkyl ester and caprylic acid is 6～8:1, prevention effect is best.If without tigloidine, of the present invention group
The preventing and treating effective percentage of compound is less than 50%.And, it is little that the present composition sprays dose, is difficult to residual.
The effect of above-described embodiment indicates that the essentiality content of the present invention, but does not limit the protection of the present invention with this
Scope.It will be understood by those within the art that, technical scheme can be modified or equivalent,
Essence and protection domain without deviating from technical solution of the present invention.
Claims (5)
1. the compositions preventing and treating spider, it is characterised in that include the raw material of following weight portion: butanone sulfone prestige, 25～35
Part；Tigloidine, 15～25 parts；Propylene glycol, 135～155 parts；Water, 425～445 parts；Synergist trihydroxymethylpropanyl ester
With caprylic acid totally 7～9 parts, the weight ratio of trihydroxymethylpropanyl ester and caprylic acid is 6～8:1.
The compositions of preventing and treating spider the most according to claim 1, it is characterised in that include the raw material of following weight portion:
Butanone sulfone prestige, 30 parts；Tigloidine, 20 parts；Propylene glycol, 145 parts；Water, 435 parts；Synergist trihydroxymethylpropanyl ester and
Caprylic acid totally 8 parts, the weight ratio of trihydroxymethylpropanyl ester and caprylic acid is 7:1.
The compositions of preventing and treating spider the most according to claim 1, it is characterised in that include the raw material of following weight portion:
Butanone sulfone prestige, 25 parts；Tigloidine, 15 parts；Propylene glycol, 135 parts；Water, 425 parts；Synergist trihydroxymethylpropanyl ester and
Caprylic acid totally 7 parts, the weight ratio of trihydroxymethylpropanyl ester and caprylic acid is 6:1.
The compositions of preventing and treating spider the most according to claim 1, it is characterised in that include the raw material of following weight portion:
Butanone sulfone prestige, 35 parts；Tigloidine, 25 parts；Propylene glycol, 155 parts；Water, 445 parts；Synergist trihydroxymethylpropanyl ester and
Caprylic acid totally 9 parts, the weight ratio of trihydroxymethylpropanyl ester and caprylic acid is 8:1.
5. the preparation method of the arbitrary described compositions of Claims 1 to 4, it is characterised in that comprise the steps:
Step S1, by butanone sulfone prestige, tigloidine and synergist trihydroxymethylpropanyl ester propylene glycol and water dissolution；
Step S2, by caprylic acid water dissolution；
Step S3, slowly adds the solution of step S2 in the solution of step S1, and interpolation limit, limit is stirred, and to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610466112.5A CN106106485A (en) | 2016-06-22 | 2016-06-22 | A kind of compositions preventing and treating spider and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610466112.5A CN106106485A (en) | 2016-06-22 | 2016-06-22 | A kind of compositions preventing and treating spider and preparation method thereof |
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| CN106106485A true CN106106485A (en) | 2016-11-16 |
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| CN201610466112.5A Pending CN106106485A (en) | 2016-06-22 | 2016-06-22 | A kind of compositions preventing and treating spider and preparation method thereof |
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Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104672085A (en) * | 2014-12-12 | 2015-06-03 | 诺泰生物科技(合肥)有限公司 | Synthesis of trimethylolpropane organic acid ester and application in special oil |
-
2016
- 2016-06-22 CN CN201610466112.5A patent/CN106106485A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104672085A (en) * | 2014-12-12 | 2015-06-03 | 诺泰生物科技(合肥)有限公司 | Synthesis of trimethylolpropane organic acid ester and application in special oil |
Non-Patent Citations (4)
| Title |
|---|
| 中国医学科学院药物研究所: "《薄层层离及其在中草药分析中的应用》", 31 August 1978, 科学出版社 * |
| 柯铭清 编: "《中草药有效成分理化与药理特性》", 29 February 1980, 湖南科学技术出版社 * |
| 熊振华 等: "简述农药悬浮剂的概括", 《江西科技师范大学学报》 * |
| 石得中 主编: "《中国农药大辞典》", 30 April 2008, 北京：化学工业出版社 * |
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Application publication date: 20161116 |