CN106087389A - 一种阻燃性聚氨酯合成革的制备方法 - Google Patents

一种阻燃性聚氨酯合成革的制备方法 Download PDF

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CN106087389A
CN106087389A CN201610611485.7A CN201610611485A CN106087389A CN 106087389 A CN106087389 A CN 106087389A CN 201610611485 A CN201610611485 A CN 201610611485A CN 106087389 A CN106087389 A CN 106087389A
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synthetic leather
polyurethane
acid
fire
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CN106087389B (zh
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段宝荣
翟智宇
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Jiashan foamtech Furniture Co., Ltd.
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Abstract

阻燃性聚氨酯合成革的制备方法，其特征在于,将12g热塑性聚氨酯与 3g苯乙烯‑丁二烯‑苯乙烯嵌段共聚物、苯乙烯‑乙烯‑丁烯‑苯乙烯嵌段共聚物3g、聚酰胺型热塑性弹性体7g、着色剂2g和物质A2g于90~370℃通过挤压机挤出制得厚度 0.8mm 的聚氨酯膜；在改性聚氨酯膜膜冷却前将其与阻燃基布在 1.0Mpa 的压力下通过挤压辊复合压制，然后在 0.2Mpa 压力下由带有纹络的辊筒压纹，冷却后，制得初级合成革;在制得的初级合成革通过90℃水溶性硅油溶液进行表面处理，在110℃的烘箱中烘干，制得阻燃性聚氨酯合成革，所制的阻燃性聚氨酯合成革阻燃性达到良好以上级别。

Description

一种阻燃性聚氨酯合成革的制备方法
技术领域
本发明涉及一种聚氨酯合成革的制备方法，尤其涉及到一种阻燃性聚氨酯合成革的制备方法。
背景技术
聚氨酯合成革经过多年的发展以其良好的外观手感和透气透湿性、耐磨耐溶剂、高强度、应用广泛等诸多优点,在工业、民用、军用等领域得到了广泛应用，与人们的生产、生活息息相关。
聚氨酯合成革主要采用聚氨酯树脂溶液与无纺布、机织布、针织布等布基进行干、湿法加工而成,此类传统聚氨酯合成革不具有阻燃特性，存在普通高分子材料易于燃烧的缺点,作为一种高分子材料在给人们的生产、生活带来舒适和方便的同时,也潜伏了很大的安全隐患，尤其是汽车坐垫、高速列车、航空、特殊用途的鞋类、建筑装饰对阻燃有特殊用途。
由于聚氨酯材料是一种有机高分子材料，未经阻燃处理的聚氨酯不抗燃，遇火会燃烧并分解，产生大量有毒烟雾和气体，危害人身财产安全。特别在家具汽车行业中，阻燃性能更为重要。如何开发出安全可靠的阻燃合成革产品,是整个合成革行业亟需解决的一个问题。添加阻燃剂是最常用的方法，阻燃剂可以被用来提高皮革的抗燃性，以达到具有阻燃性能的目的。
常规阻燃剂有卤系阻燃剂、磷系阻燃剂和无机类阻燃剂3大类。卤系阻燃剂具有优异的稳定性、分解温度高(300℃以上)、使用量少、阻燃效率高等优点，其主要缺点是分解产物毒性大、燃烧生烟多、有腐蚀性、毒性气体放出，因而近年来正逐步被其他无卤阻燃剂所替代。磷系阻燃剂包括有机磷系和无机磷系两大类。磷系阻燃剂稳定性好、不易挥发、不产生腐蚀性气体、阻燃效果持久、毒性低。磷系阻燃剂具有良好的阻燃性，又不会对环境造成污染，被认为是当今阻燃剂。
发明内容
本发明利用膨胀型阻燃剂与环保型氢氧化镁阻燃剂络和对聚氨酯合成革进行阻燃处理，利用邻羧基苯乙酸、双(4-羧基苯基)苯基氧化膦、4-乙酰氨基水杨酸和次氮基三乙酸与氢氧化镁和膨胀型阻燃剂络合，得到氢氧化镁和膨胀型阻燃剂的复合体系，弥补传统氢氧化镁与有机材料相容性差的缺陷，提高环保型氢氧化镁阻燃剂与基布的相容性。
一种阻燃性聚氨酯合成革的制备方法，其特征在于：
（1）氢氧化镁与氮磷膨胀型阻燃剂络合体系:将15.4g三羟甲基丙烷、27.8g四羟甲基硫酸磷、34.5g磷酸，依次加入250ml的三口烧瓶中，放入恒温油浴锅80℃并保持恒温，再加入三聚氯氰4.2g、四羟丙基乙二胺2.2g、四乙酰乙二胺0.3g和四乙基溴化铵0.5g，反应时间为2h，得到膨胀型阻燃剂，再加入氢氧化镁2.7g、邻羧基苯乙酸0.7g、双(4-羧基苯基)苯基氧化膦0.2g、4-乙酰氨基水杨酸0.3g、次氮基三乙酸0.5g和3-羟基扁桃酸0.6g，60℃并保持恒温2h，最终得到红棕色粘稠状液体，即氢氧化镁与氮磷膨胀型阻燃剂络合体系；
（2）相容剂的制备：取丙烯酰胺13g置于三口烧瓶中，并加入0.12g催化剂，取月桂酰氯2ml置于烘干的恒压滴液漏斗中并加入溶剂正己烷2ml；将月桂酰氯溶液滴加到三口烧瓶中，控制滴加速度为5 秒/滴，滴加过程在冰水浴中进行，并用质量分数为10%的氢氧化钠调节反应的pH值为8，冰水浴中滴加反应时间0.6 h，然后升高温度至20℃，反应时间3h，反应结束后减压蒸出溶剂，进行喷雾干燥，得相容剂；
（3）基布的处理：将基布20g浸入到100g的步骤（1）的改性氢氧化镁阻燃剂、步骤（2）的相容剂1.8g和氨基脲0.4g，然后在 100℃的烘道中将其烘干，制得阻燃基布待用；
（4） 改性聚氨酯膜
将12g热塑性聚氨酯与 3g苯乙烯-丁二烯-苯乙烯嵌段共聚物、苯乙烯-乙烯-丁烯-苯乙烯嵌段共聚物3g、聚酰胺型热塑性弹性体7g、着色剂2g和物质A2g于90℃-370℃通过挤压机挤出制得厚度 0.8mm 的聚氨酯膜；
（5） 初级合成革
在步骤 （4）制得的改性聚氨酯膜膜冷却前将其与步骤 （3） 制得的阻燃基布在1.0Mpa 的压力下通过挤压辊复合压制，然后在 0.2Mpa 压力下由带有纹络的辊筒压纹，冷却后，制得初级合成革。
(6) 表面处理及修饰 ：
将步骤 （5） 制得的初级合成革通过90℃水溶性硅油溶液进行表面处理，在110℃的烘箱中烘干，制得阻燃性聚氨酯合成革。
基布为机织布或超纤布；催化剂为二硫代二苯甲酸、甲醇钠、过硫酸铵、二乙基二硫代氨基甲酸钠、苄基三乙基氯化中的任意一种;着色剂为色母料或色粉; 物质A为三羟甲基乙烷、双(4-羧基苯基)苯基氧化膦、2-羧基-5-硝基苯磺酸钾、5-羟基色胺、环亮氨酸、对甲氧基乙酰苯胺、对氰基氯苄、羟乙基纤维素。
本发明与传统技术具有的优点
（1）水溶性硅油选择TS-19水溶性硅油，购买于青岛中宝硅材料科技有限公司；热塑性聚氨酯购买于得创热塑性聚氨酯（东莞）有限公司；聚酰胺型热塑性弹性体购买于美国杜邦公司的聚酰胺型热塑性弹性体TPAE，其它化料常规购买，当然所有材料可以购买于主要成分含有此类的厂家；
（2）利用邻羧基苯乙酸、双(4-羧基苯基)苯基氧化膦、4-乙酰氨基水杨酸和次氮基三乙酸与氢氧化镁和膨胀型阻燃剂络合，得到氢氧化镁和膨胀型阻燃剂的复合体系，弥补传统氢氧化镁与有机材料相容性差的缺陷；
（3）物质A为三羟甲基乙烷、双(4-羧基苯基)苯基氧化膦、2-羧基-5-硝基苯磺酸钾、5-羟基色胺、环亮氨酸、对甲氧基乙酰苯胺、对氰基氯苄、羟乙基纤维素降低聚氨酯燃烧所形成熔滴，避免聚氨酯燃烧进行；
（4）相容剂增加了氢氧化镁与机织布或超纤布的相容性，氨基脲增强相容剂、氢氧化镁与基布结合，相当于相容剂、氢氧化镁之间的催化剂；
（5）苯乙烯-乙烯-丁烯-苯乙烯嵌段共聚物也就是SEBS，苯乙烯-丁二烯-苯乙烯嵌段共聚物可常规方法合成，也可从市场购买；
(6)本发明所用化工材料只要主要成分为其均可适用本发明。
（7）根据膨胀型阻燃剂构成的碳源为三羟甲基丙烷、酸源为四羟甲基硫酸磷和磷酸，三聚氯氰为气源，四羟丙基乙二胺、四乙酰乙二胺、四乙基溴化铵和3-羟基扁桃酸增加了膨胀型阻燃剂的立体型，使所制备的阻燃性成炭性提高。
具体实施方式
实施例1
（1）氢氧化镁与氮磷膨胀型阻燃剂络合体系:将15.4g三羟甲基丙烷、27.8g四羟甲基硫酸磷、34.5g磷酸，依次加入250ml的三口烧瓶中，放入恒温油浴锅80℃并保持恒温，再加入三聚氯氰4.2g、四羟丙基乙二胺2.2g、四乙酰乙二胺0.3g和四乙基溴化铵0.5g，反应时间为2h，得到膨胀型阻燃剂，再加入氢氧化镁2.7g、邻羧基苯乙酸0.7g、双(4-羧基苯基)苯基氧化膦0.2g、4-乙酰氨基水杨酸0.3g、次氮基三乙酸0.5g和3-羟基扁桃酸0.6g，60℃恒温2h，最终得到红棕色粘稠状液体，即氢氧化镁与氮磷膨胀型阻燃剂络合体系；
（2）相容剂的制备：取丙烯酰胺13g置于三口烧瓶中，并加入0.12g二硫代二苯甲酸，取月桂酰氯2ml置于烘干的恒压滴液漏斗中并加入溶剂正己烷2ml；将月桂酰氯溶液滴加到三口烧瓶中，控制滴加速度为5 秒/滴，滴加过程在冰水浴中进行，并用质量分数为10%的氢氧化钠调节反应的pH值为8，冰水浴中滴加反应时间0.6 h，然后升高温度至20℃，反应时间3h，反应结束后减压蒸出溶剂，进行喷雾干燥，得相容剂；
（3）基布的处理：将机织布20g浸入到100g的步骤（1）的改性氢氧化镁阻燃剂、步骤（2）的相容剂1.8g和氨基脲0.4g，然后在 100℃的烘道将其烘干，制得阻燃基布待用；
（4） 改性聚氨酯膜
将12g热塑性聚氨酯与 3g苯乙烯-丁二烯-苯乙烯嵌段共聚物、苯乙烯-乙烯-丁烯-苯乙烯嵌段共聚物3g、聚酰胺型热塑性弹性体7g、色母料2g和三羟甲基乙烷2g于90℃通过挤压机挤出制得厚度 0.8mm 的聚氨酯膜；
（5） 初级合成革
在步骤 （4）制得的改性聚氨酯膜膜冷却前将其与步骤 （3） 制得的阻燃基布在1.0Mpa 的压力下通过挤压辊复合压制，然后在 0.2Mpa 压力下由带有纹络的辊筒压纹，冷却后，制得初级合成革。
(6) 表面处理及修饰 ：
将步骤 （5） 制得的初级合成革通过90℃水溶性硅油溶液进行表面处理，在110℃的烘箱中烘干，制得阻燃性聚氨酯合成革。
实施例2
（1）氢氧化镁与氮磷膨胀型阻燃剂络合体系:将15.4g三羟甲基丙烷、27.8g四羟甲基硫酸磷、34.5g磷酸，依次加入250ml的三口烧瓶中，放入恒温油浴锅80℃并保持恒温，再加入三聚氯氰4.2g、四羟丙基乙二胺2.2g、四乙酰乙二胺0.3g和四乙基溴化铵0.5g，反应时间为2h，得到膨胀型阻燃剂，再加入氢氧化镁2.7g、邻羧基苯乙酸0.7g、双(4-羧基苯基)苯基氧化膦0.2g、4-乙酰氨基水杨酸0.3g、次氮基三乙酸0.5g和3-羟基扁桃酸0.6g，60℃并保持恒温2h，最终得到红棕色粘稠状液体，即氢氧化镁与氮磷膨胀型阻燃剂络合体系；
（2）相容剂的制备：取丙烯酰胺13g置于三口烧瓶中，并加入0.12g甲醇钠，取月桂酰氯2ml置于烘干的恒压滴液漏斗中并加入溶剂正己烷2ml；将月桂酰氯溶液滴加到三口烧瓶中，控制滴加速度为5 秒/滴，滴加过程在冰水浴中进行，并用质量分数为10%的氢氧化钠调节反应的pH值为8，冰水浴中滴加反应时间0.6 h，然后升高温度至20℃，反应时间3h，反应结束后减压蒸出溶剂，进行喷雾干燥，得相容剂；
（3）基布的处理：将超纤布20g浸入到100g的步骤（1）的改性氢氧化镁阻燃剂、步骤（2）的相容剂1.8g和氨基脲0.4g，然后在 100℃的烘道中将其烘干，制得阻燃基布待用；
（4） 改性聚氨酯膜
将12g热塑性聚氨酯与 3g苯乙烯-丁二烯-苯乙烯嵌段共聚物、苯乙烯-乙烯-丁烯-苯乙烯嵌段共聚物3g、聚酰胺型热塑性弹性体7g、色粉2g和双(4-羧基苯基)苯基氧化膦2g于370℃通过挤压机挤出制得厚度 0.8mm 的聚氨酯膜；
（5） 初级合成革
在步骤 （4）制得的改性聚氨酯膜膜冷却前将其与步骤 （3） 制得的阻燃基布在1.0Mpa 的压力下通过挤压辊复合压制，然后在 0.2Mpa 压力下由带有纹络的辊筒压纹，冷却后，制得初级合成革。
(6) 表面处理及修饰 ：
将步骤 （5） 制得的初级合成革通过90℃水溶性硅油溶液进行表面处理，在110℃的烘箱中烘干，制得阻燃性聚氨酯合成革。
实施例3
（1）氢氧化镁与氮磷膨胀型阻燃剂络合体系:将15.4g三羟甲基丙烷、27.8g四羟甲基硫酸磷、34.5g磷酸，依次加入250ml的三口烧瓶中，放入恒温油浴锅80℃并保持恒温，再加入三聚氯氰4.2g、四羟丙基乙二胺2.2g、四乙酰乙二胺0.3g和四乙基溴化铵0.5g，反应时间为2h，得到膨胀型阻燃剂，再加入氢氧化镁2.7g、邻羧基苯乙酸0.7g、双(4-羧基苯基)苯基氧化膦0.2g、4-乙酰氨基水杨酸0.3g、次氮基三乙酸0.5g和3-羟基扁桃酸0.6g，60℃并保持恒温2h，最终得到红棕色粘稠状液体，即氢氧化镁与氮磷膨胀型阻燃剂络合体系；
（2）相容剂的制备：取丙烯酰胺13g置于三口烧瓶中，并加入0.12g过硫酸铵，取月桂酰氯2ml置于烘干的恒压滴液漏斗中并加入溶剂正己烷2ml；将月桂酰氯溶液滴加到三口烧瓶中，控制滴加速度为5 秒/滴，滴加过程在冰水浴中进行，并用质量分数为10%的氢氧化钠调节反应的pH值为8，冰水浴中滴加反应时间0.6 h，然后升高温度至20℃，反应时间3h，反应结束后减压蒸出溶剂，进行喷雾干燥，得相容剂；
（3）基布的处理：将机织布20g浸入到100g的步骤（1）的改性氢氧化镁阻燃剂、步骤（2）的相容剂1.8g和氨基脲0.4g，然后在 100℃的烘道中将其烘干，制得阻燃基布待用；
（4） 改性聚氨酯膜
将12g热塑性聚氨酯与 3g苯乙烯-丁二烯-苯乙烯嵌段共聚物、苯乙烯-乙烯-丁烯-苯乙烯嵌段共聚物3g、聚酰胺型热塑性弹性体7g、色母料2g和2-羧基-5-硝基苯磺酸钾2g于230℃通过挤压机挤出制得厚度 0.8mm 的聚氨酯膜；
（5） 初级合成革
在步骤 （4）制得的改性聚氨酯膜膜冷却前将其与步骤 （3） 制得的阻燃基布在1.0Mpa 的压力下通过挤压辊复合压制，然后在 0.2Mpa 压力下由带有纹络的辊筒压纹，冷却后，制得初级合成革。
(6) 表面处理及修饰 ：
将步骤 （5） 制得的初级合成革通过90℃水溶性硅油溶液进行表面处理，在110℃的烘箱中烘干，制得阻燃性聚氨酯合成革。
实施例4
（1）氢氧化镁与氮磷膨胀型阻燃剂络合体系:将15.4g三羟甲基丙烷、27.8g四羟甲基硫酸磷、34.5g磷酸，依次加入250ml的三口烧瓶中，放入恒温油浴锅80℃并保持恒温，再加入三聚氯氰4.2g、四羟丙基乙二胺2.2g、四乙酰乙二胺0.3g和四乙基溴化铵0.5g，反应时间为2h，得到膨胀型阻燃剂，再加入氢氧化镁2.7g、邻羧基苯乙酸0.7g、双(4-羧基苯基)苯基氧化膦0.2g、4-乙酰氨基水杨酸0.3g、次氮基三乙酸0.5g和3-羟基扁桃酸0.6g，60℃恒温2h，最终得到红棕色粘稠状液体，即氢氧化镁与氮磷膨胀型阻燃剂络合体系；
（2）相容剂的制备：取丙烯酰胺13g置于三口烧瓶中，并加入0.12g二乙基二硫代氨基甲酸钠，取月桂酰氯2ml置于烘干的恒压滴液漏斗中并加入溶剂正己烷2ml；将月桂酰氯溶液滴加到三口烧瓶中，控制滴加速度为5 秒/滴，滴加过程在冰水浴中进行，并用质量分数为10%的氢氧化钠调节反应的pH值为8，冰水浴中滴加反应时间0.6 h，然后升高温度至20℃，反应时间3h，反应结束后减压蒸出溶剂，进行喷雾干燥，得相容剂；
（3）基布的处理：将机织布20g浸入到100g的步骤（1）的改性氢氧化镁阻燃剂、步骤（2）的相容剂1.8g和氨基脲0.4g，然后在 100℃的烘道将其烘干，制得阻燃基布待用；
（4） 改性聚氨酯膜
将12g热塑性聚氨酯与 3g苯乙烯-丁二烯-苯乙烯嵌段共聚物、苯乙烯-乙烯-丁烯-苯乙烯嵌段共聚物3g、聚酰胺型热塑性弹性体7g、色母料2g和对氰基氯苄2g于90℃通过挤压机挤出制得厚度 0.8mm 的聚氨酯膜；
（5） 初级合成革
在步骤 （4）制得的改性聚氨酯膜膜冷却前将其与步骤 （3） 制得的阻燃基布在1.0Mpa 的压力下通过挤压辊复合压制，然后在 0.2Mpa 压力下由带有纹络的辊筒压纹，冷却后，制得初级合成革。
(6) 表面处理及修饰 ：
将步骤 （5） 制得的初级合成革通过90℃水溶性硅油溶液进行表面处理，在110℃的烘箱中烘干，制得阻燃性聚氨酯合成革。
实施例5
（1）氢氧化镁与氮磷膨胀型阻燃剂络合体系:将15.4g三羟甲基丙烷、27.8g四羟甲基硫酸磷、34.5g磷酸，依次加入250ml的三口烧瓶中，放入恒温油浴锅80℃并保持恒温，再加入三聚氯氰4.2g、四羟丙基乙二胺2.2g、四乙酰乙二胺0.3g和四乙基溴化铵0.5g，反应时间为2h，得到膨胀型阻燃剂，再加入氢氧化镁2.7g、邻羧基苯乙酸0.7g、双(4-羧基苯基)苯基氧化膦0.2g、4-乙酰氨基水杨酸0.3g、次氮基三乙酸0.5g和3-羟基扁桃酸0.6g，60℃并保持恒温2h，最终得到红棕色粘稠状液体，即氢氧化镁与氮磷膨胀型阻燃剂络合体系；
（2）相容剂的制备：取丙烯酰胺13g置于三口烧瓶中，并加入0.12g苄基三乙基氯化铵，取月桂酰氯2ml置于烘干的恒压滴液漏斗中并加入溶剂正己烷2ml；将月桂酰氯溶液滴加到三口烧瓶中，控制滴加速度为5 秒/滴，滴加过程在冰水浴中进行，并用质量分数为10%的氢氧化钠调节反应的pH值为8，冰水浴中滴加反应时间0.6 h，然后升高温度至20℃，反应时间3h，反应结束后减压蒸出溶剂，进行喷雾干燥，得相容剂；
（3）基布的处理：将超纤布20g浸入到100g的步骤（1）的改性氢氧化镁阻燃剂、步骤（2）的相容剂1.8g和氨基脲0.4g，然后在 100℃的烘道中将其烘干，制得阻燃基布待用；
（4） 改性聚氨酯膜
将12g热塑性聚氨酯与 3g苯乙烯-丁二烯-苯乙烯嵌段共聚物、苯乙烯-乙烯-丁烯-苯乙烯嵌段共聚物3g、聚酰胺型热塑性弹性体7g、色粉2g和羟乙基纤维素2g于370℃通过挤压机挤出制得厚度 0.8mm 的聚氨酯膜；
（5） 初级合成革
在步骤 （4）制得的改性聚氨酯膜膜冷却前将其与步骤 （3） 制得的阻燃基布在1.0Mpa 的压力下通过挤压辊复合压制，然后在 0.2Mpa 压力下由带有纹络的辊筒压纹，冷却后，制得初级合成革。
(6) 表面处理及修饰 ：
将步骤 （5） 制得的初级合成革通过90℃水溶性硅油溶液进行表面处理，在110℃的烘箱中烘干，制得阻燃性聚氨酯合成革。
表1 阻燃性聚氨酯合成革性能
从表1可以发现，加入阻燃剂的合成革性能优于未加合成革的性能（拉伸负荷、断裂伸长率等方面）。
表2 阻燃性聚氨酯合成革阻燃性能
项目 实施例1 实施例2 实施例3 实施例4 实施例5 未加阻燃剂
燃烧速度mm/min 0 11 14 15 9 132
依据FMVSS-302判断标准，可知燃烧速度为0，为优级；燃烧速度小于50 ，满足燃烧速度要求,良；燃烧速度50～100，满足燃烧速度要求,一般；燃烧速度大于100mm/min，不合格；由此可知，本发明的阻燃性能达到优或者良级，同时在燃烧过程中可以发现本发明的阻燃性合成革无熔滴出现。

Claims (5)

1.一种阻燃性聚氨酯合成革的制备方法，其特征在于：
（1）氢氧化镁与氮磷膨胀型阻燃剂络合体系:将15.4g三羟甲基丙烷、27.8g四羟甲基硫酸磷、34.5g磷酸，依次加入250ml的三口烧瓶中，放入恒温油浴锅80℃并保持恒温，再加入三聚氯氰4.2g、四羟丙基乙二胺2.2g、四乙酰乙二胺0.3g和四乙基溴化铵0.5g，反应时间为2h，得到膨胀型阻燃剂，再加入氢氧化镁2.7g、邻羧基苯乙酸0.7g、双(4-羧基苯基)苯基氧化膦0.2g、4-乙酰氨基水杨酸0.3g、次氮基三乙酸0.5g和3-羟基扁桃酸0.6g，60℃并保持恒温2h，最终得到红棕色粘稠状液体，即氢氧化镁与氮磷膨胀型阻燃剂络合体系；
（2）相容剂的制备：取丙烯酰胺13g置于三口烧瓶中，并加入0.12g催化剂，取月桂酰氯2ml置于烘干的恒压滴液漏斗中并加入溶剂正己烷2ml；将月桂酰氯溶液滴加到三口烧瓶中，控制滴加速度为5 秒/滴，滴加过程在冰水浴中进行，并用质量分数为10%的氢氧化钠调节反应的pH值为8，冰水浴中滴加反应时间0.6 h，然后升高温度至20℃，反应时间3h，反应结束后减压蒸出溶剂，进行喷雾干燥，得相容剂；
（3）基布的处理：将基布20g浸入到100g的步骤（1）的改性氢氧化镁阻燃剂、步骤（2）的相容剂1.8g和氨基脲0.4g，然后在 100℃的烘道中将其烘干，制得阻燃基布待用；
（4） 改性聚氨酯膜
将12g热塑性聚氨酯与 3g苯乙烯-丁二烯-苯乙烯嵌段共聚物、苯乙烯-乙烯-丁烯-苯乙烯嵌段共聚物3g、聚酰胺型热塑性弹性体7g、着色剂2g和物质A2g于90℃-370℃通过挤压机挤出制得厚度 0.8mm 的聚氨酯膜；
（5） 初级合成革
在步骤 （4）制得的改性聚氨酯膜膜冷却前将其与步骤 （3） 制得的阻燃基布在1.0Mpa 的压力下通过挤压辊复合压制，然后在 0.2Mpa 压力下由带有纹络的辊筒压纹，冷却后，制得初级合成革；
(6) 表面处理及修饰 ：
将步骤 （5） 制得的初级合成革通过90℃水溶性硅油溶液进行表面处理，在110℃的烘箱中烘干，制得阻燃性聚氨酯合成革。
2.根据权利1所述的阻燃性聚氨酯合成革的制备方法， 所述的基布为机织布或超纤布。
3.根据权利1所述的阻燃性聚氨酯合成革的制备方法， 所述的催化剂为二硫代二苯甲酸、甲醇钠、过硫酸铵、二乙基二硫代氨基甲酸钠、苄基三乙基氯化铵中的任意一种。
4.根据权利1所述的一种阻燃性聚氨酯合成革的制备方法， 所述的着色剂为色母料或色粉。
5.根据权利1所述的一种阻燃性聚氨酯合成革的制备方法， 所述的物质A为三羟甲基乙烷、双(4-羧基苯基)苯基氧化膦、2-羧基-5-硝基苯磺酸钾、5-羟基色胺、环亮氨酸、对甲氧基乙酰苯胺、对氰基氯苄、羟乙基纤维素的任意一种。
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110527306A (zh) * 2019-09-11 2019-12-03 烟台大学 利用含铬革屑制作颗粒板的方法

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109228551A (zh) * 2018-09-30 2019-01-18 华祥（中国）高纤有限公司 一种超柔革基布纤维及其制造方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010138318A (ja) * 2008-12-12 2010-06-24 Nippon Polyurethane Ind Co Ltd 難燃性艶消し樹脂組成物
JP2012052092A (ja) * 2010-08-06 2012-03-15 Fire Proof Technology Co Ltd 難燃性樹脂組成物及びその製造方法
CN102558482A (zh) * 2011-12-29 2012-07-11 上海东大聚氨酯有限公司 环保阻燃型聚氨酯仿木材料
CN104497268A (zh) * 2014-11-28 2015-04-08 苏州市安特菲尔新材料有限公司 一种阻燃导电聚氨酯材料及其制备方法

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7091139B2 (en) * 2002-06-12 2006-08-15 Kuraray Co., Ltd. Flame-retardant leather-like sheet substrate and production method thereof
CN1317447C (zh) * 2005-05-09 2007-05-23 烟台万华超纤股份有限公司 一种阻燃性聚氨酯合成革及其制备方法
WO2008026895A1 (en) * 2006-08-31 2008-03-06 Lg Chem. Ltd. Nonflammable artificial leather and the preparation method of the same
JP4891167B2 (ja) * 2007-07-12 2012-03-07 本田技研工業株式会社 難燃性合成皮革
CN101575802B (zh) * 2009-05-15 2011-01-26 上海旭森非卤消烟阻燃剂有限公司 非卤消烟阻燃涤纶纤维非织造布的制备方法
CN101824182B (zh) * 2009-11-17 2012-02-29 上海化工研究院 一种无卤膨胀型阻燃热塑性弹性体组合物
MX2012014004A (es) * 2010-06-03 2013-01-24 Dow Global Technologies Llc Compuesto tpu retardador de flama, libre de halogeno.
CN104861851A (zh) * 2015-05-05 2015-08-26 段宝荣 阻燃性水性聚氨酯涂料与胶黏剂的制备方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010138318A (ja) * 2008-12-12 2010-06-24 Nippon Polyurethane Ind Co Ltd 難燃性艶消し樹脂組成物
JP2012052092A (ja) * 2010-08-06 2012-03-15 Fire Proof Technology Co Ltd 難燃性樹脂組成物及びその製造方法
CN102558482A (zh) * 2011-12-29 2012-07-11 上海东大聚氨酯有限公司 环保阻燃型聚氨酯仿木材料
CN104497268A (zh) * 2014-11-28 2015-04-08 苏州市安特菲尔新材料有限公司 一种阻燃导电聚氨酯材料及其制备方法

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110527306A (zh) * 2019-09-11 2019-12-03 烟台大学 利用含铬革屑制作颗粒板的方法
CN113025063A (zh) * 2019-09-11 2021-06-25 烟台大学 一种利用含铬革屑制作颗粒板及其所需有机物

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