CN106064889B - The noble metal glaze art pottery and its production method - Google Patents
The noble metal glaze art pottery and its production method Download PDFInfo
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- CN106064889B CN106064889B CN201610372871.5A CN201610372871A CN106064889B CN 106064889 B CN106064889 B CN 106064889B CN 201610372871 A CN201610372871 A CN 201610372871A CN 106064889 B CN106064889 B CN 106064889B
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- 229910000510 noble metal Inorganic materials 0.000 title claims abstract description 48
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 13
- 239000000919 ceramic Substances 0.000 claims abstract description 28
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 26
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 24
- 229910021532 Calcite Inorganic materials 0.000 claims abstract description 23
- 229910052593 corundum Inorganic materials 0.000 claims abstract description 23
- 239000010453 quartz Substances 0.000 claims abstract description 23
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 23
- 229910001845 yogo sapphire Inorganic materials 0.000 claims abstract description 23
- 238000005476 soldering Methods 0.000 claims abstract description 22
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 15
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 claims abstract description 15
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 claims abstract description 13
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 claims abstract description 13
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910052845 zircon Inorganic materials 0.000 claims abstract description 12
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 9
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 9
- 238000000034 method Methods 0.000 claims abstract description 9
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 22
- 239000000203 mixture Substances 0.000 claims description 14
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 claims description 11
- 239000011787 zinc oxide Substances 0.000 claims description 11
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 claims description 8
- 238000010304 firing Methods 0.000 claims description 6
- 239000002994 raw material Substances 0.000 claims description 6
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 4
- 229910052737 gold Inorganic materials 0.000 claims description 4
- 239000010931 gold Substances 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 3
- 238000003837 high-temperature calcination Methods 0.000 claims description 3
- 238000007493 shaping process Methods 0.000 claims description 3
- 238000007873 sieving Methods 0.000 claims description 3
- QPLDLSVMHZLSFG-UHFFFAOYSA-N CuO Inorganic materials [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 abstract description 10
- 230000000694 effects Effects 0.000 abstract description 10
- FFRBMBIXVSCUFS-UHFFFAOYSA-N 2,4-dinitro-1-naphthol Chemical compound C1=CC=C2C(O)=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 FFRBMBIXVSCUFS-UHFFFAOYSA-N 0.000 abstract description 6
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 abstract description 6
- 229910052709 silver Inorganic materials 0.000 abstract description 6
- 239000004332 silver Substances 0.000 abstract description 6
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract description 5
- 229910052804 chromium Inorganic materials 0.000 abstract description 5
- 239000011651 chromium Substances 0.000 abstract description 5
- 230000002045 lasting effect Effects 0.000 abstract description 5
- 239000002932 luster Substances 0.000 abstract description 3
- GNRSAWUEBMWBQH-UHFFFAOYSA-N nickel(II) oxide Inorganic materials [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 238000005457 optimization Methods 0.000 description 6
- 239000011195 cermet Substances 0.000 description 4
- 229910052788 barium Inorganic materials 0.000 description 3
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 3
- 229910052622 kaolinite Inorganic materials 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- 238000000498 ball milling Methods 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000005751 Copper oxide Substances 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 229910000480 nickel oxide Inorganic materials 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/04—Frit compositions, i.e. in a powdered or comminuted form containing zinc
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Inorganic Chemistry (AREA)
- Structural Engineering (AREA)
- Glass Compositions (AREA)
Abstract
The present invention relates to ceramic fabrication technique field, be specifically related to a kind of noble metal glaze art pottery and its production method.This kind of noble metal glaze art pottery, glaze uses lead free soldering, calcite, kaolin, quartz, iron oxide yellow, MnO2, NiO, Al2O3, CrO3, ZrSiO4, V2O5, CuO, TiO2, CMC is formed, pass through unique making, burning process, the produced noble metal glaze art pottery, glazing effect has very strong metallic luster, adjustable formula makes glaze at golden yellow, silver color, the metallochromes such as grey black, glaze is smooth, in mirror-reflection, gloss keeps lasting, it is with good stability, in addition lead is free of in this kind of noble metal glaze art pottery glaze, chromium, it is safe to use.
Description
Technical field
The present invention relates to ceramic fabrication technique field, be specifically related to a kind of noble metal glaze art pottery and its making
Method.
Background technology
The polished rear surface of the noble metals such as noble metal such as gold, silver, titanium is one layer of bright minute surface, this kind of mirror effect
It is combined with unique artistic effect, the side of the noble metal minute surface generally use plating of existing ceramic surface with ceramic material
Formula obtains, but the excessively bright deviation standard gold/silver color of the effect being electroplated, and gap is big compared with true noble metal minute surface；In addition,
Ceramic electroplating cost is high, and the product content of beary metal obtained after being electroplated is high, can not be used as domestic ceramics.
To solve the above problems, application publication number be 104496555 A of CN imitative cermet artistic glaze and its prepare and
Application method discloses a kind of imitative cermet artistic glaze, this kind of imitative cermet artistic glaze is using frit, wollastonite, Tuo Pa
Stone, mica, copper oxide, talcum, titanium dioxide, manganese dioxide, nickel oxide, aluminium oxide are made, the imitative metal art prepared
Ceramic product, for glaze in golden yellow, metallic luster is strong, is in mirror-reflection, and appearance can match in excellence or beauty metal product.This kind of imitative metal
Though ceramic artistic glaze glaze, at mirror effect, color is to be only capable of embodying golden yellow, and noble metal also has other than golden yellow
The multiple colors such as silver color, platinum color, Zijin, copper red color, this kind of imitative cermet artistic glaze glazing effect be single, production cost
It is high.
Invention content
In order to solve the deficiencies in the prior art, the present invention provides a kind of noble metal glaze art pottery and its making side
Method.
To achieve the above object, this noble metal glaze art pottery, which is characterized in that the noble metal glaze art pottery
Glaze component it is as follows：45-70 parts of lead free soldering, 5-10 parts of calcite, 5-10 parts of kaolin, 5-10 parts of quartz, iron oxide yellow 5-
10 parts, MnO25-10 parts, 1-10 parts of NiO, Al2O31-5 parts, CrO31-5 parts, ZrSiO41-5 parts, V2O51-5 parts, CuO
1-5 parts, TiO21-3 parts, 0.5-1 parts of CMC；The composition of wherein lead free soldering is as follows：30-45 parts of potassium feldspar, zinc oxide 10-20
Part, 5-10 parts of quartz, calcite 5-10,5-10 parts of barium carbonate, Al2O35-10 parts, WO35-10 parts, K21-5 parts of O, Na2O 1-
5 parts, Li21-5 parts of O.
Optimization, the glaze component of the noble metal glaze art pottery is as follows：49 parts of lead free soldering, 6 parts of calcite, kaolinite
6 parts of soil, 7 parts of quartz, 9 parts of iron oxide yellow, MnO26 parts, 2 parts of NiO, Al2O33 parts, CrO31 part, ZrSiO42 parts, V2O55 parts,
1 part of CuO, TiO22.5 parts, 0.5 part of CMC.
Optimization, the composition of lead free soldering is as follows：42 parts of potassium feldspar, 18 parts of zinc oxide, 6 parts of quartz, calcite 7, carbonic acid
6 parts of barium, Al2O35 parts, WO36 parts, K23 parts of O, Na22 parts of O, Li25 parts of O.
Optimization, the glaze component of the noble metal glaze art pottery is as follows：53 parts of lead free soldering, 5 parts of calcite, kaolinite
8 parts of soil, 6 parts of quartz, 5 parts of iron oxide yellow, MnO25 parts, 1 part of NiO, Al2O33 parts, CrO34 parts, ZrSiO42 parts, V2O51 part,
5 parts of CuO, TiO21 part, 1 part of CMC.
Optimization, the composition of lead free soldering is as follows：36 parts of potassium feldspar, 16 parts of zinc oxide, 7 parts of quartz, calcite 8, carbonic acid
8 parts of barium, Al2O38 parts, WO37 parts, K23 parts of O, Na22 parts of O, Li25 parts of O.
Optimization, the glaze component of the noble metal glaze art pottery is as follows：62 parts of lead free soldering, 5 parts of calcite, kaolinite
5 parts of soil, 5 parts of quartz, 8 parts of iron oxide yellow, MnO25 parts, 2 parts of NiO, Al2O32 parts, CrO31 part, ZrSiO41 part, V2O51 part,
1 part of CuO, TiO21 part, 1 part of CMC.
Optimization, the composition of lead free soldering is as follows：40 parts of potassium feldspar, 16 parts of zinc oxide, 8 parts of quartz, calcite 7, carbonic acid
4 parts of barium, Al2O39 parts, WO37 parts, K23 parts of O, Na23 parts of O, Li23 parts of O.
A kind of production method with the noble metal glaze art pottery, prepares the noble metal glaze described in above-mentioned any one
The art pottery is as follows：
Step 1, the shraff during Production of Ceramics is collected, shraff is cleaned, crushes, 1100- after sieving
1200 DEG C of high-temperature calcinations, for use；
Step 2, according to traditional shaping method of ceramics, ceramic body is produced；
Step 3, it weighs, mix according to the glaze component of noble metal glaze art pottery progress raw material, by raw material wet bulb
It grinds, glaze crosses 200 mesh sieve after wet ball mill, obtains glaze；
Step 4, ceramic body is put into baking oven after glazing and toasts 5-20 in 45-50 DEG C by the glazing on ceramic body
Hour, removal is for use；
Step 5, the ceramic body after glazing is put into kiln, is formed by a firing, firing temperature is 1200-1260 DEG C, is protected
Natural cooling after 30-60 minutes warm.
Further, in step 3, when wet ball mill, expects：Ball：Water=1:2:1：1-0.8, ball milling 30-60 minutes, tails over 1%.
Further, in step 4, glaze thickness 0.3-0.5mm.
By the above-mentioned description of this invention it is found that the noble metal glaze art pottery provided by the invention, glazing effect have very
Strong metallic luster, adjustable formula make glaze at metallochromes such as golden yellow, silver color, grey blacks, and glaze is smooth, anti-in minute surface
It penetrates, gloss keeps lasting, with good stability, makes in addition without lead, chromium in this kind of noble metal glaze art pottery glaze
With safety.
Specific implementation mode
Below by way of specific implementation mode, the invention will be further described.
The glaze component of this noble metal glaze art pottery, the noble metal glaze art pottery is as follows：Lead free soldering
45-70 parts, 5-10 parts of calcite, 5-10 parts of kaolin, 5-10 parts of quartz, 5-10 parts of iron oxide yellow, MnO25-10 parts, NiO 1-10
Part, Al2O31-5 parts, CrO31-5 parts, ZrSiO41-5 parts, V2O51-5 parts, 1-5 parts of CuO, TiO21-3 parts, CMC 0.5-
1 part；
The composition of wherein lead free soldering is as follows：30-45 parts of potassium feldspar, 10-20 parts of zinc oxide, 5-10 parts of quartz, calcite
5-10,5-10 parts of barium carbonate, Al2O35-10 parts, WO35-10 parts, K21-5 parts of O, Na21-5 parts of O, Li21-5 parts of O.
Specific embodiment one：
The glaze component of the noble metal glaze art pottery is as follows：49 parts of lead free soldering, 6 parts of calcite, 6 parts of kaolin,
7 parts of quartz, 9 parts of iron oxide yellow, MnO26 parts, 2 parts of NiO, Al2O33 parts, CrO31 part, ZrSiO42 parts, V2O55 parts, CuO 1
Part, TiO22.5 parts, 0.5 part of CMC；
The composition of lead free soldering is as follows：42 parts of potassium feldspar, 18 parts of zinc oxide, quartz 6 parts, calcite 7,6 parts of barium carbonate,
Al2O35 parts, WO36 parts, K23 parts of O, Na22 parts of O, Li25 parts of O.
The noble metal glaze art pottery background color being burnt into the present embodiment has very strong metal in golden yellow, glazing effect
Gloss, glaze is smooth, is in mirror-reflection, and gloss keeps lasting, with good stability, in addition this kind of noble metal glaze art
It is safe to use without lead, chromium in ceramic glaze.
Specific embodiment two：
The glaze component of the noble metal glaze art pottery is as follows：53 parts of lead free soldering, 5 parts of calcite, 8 parts of kaolin,
6 parts of quartz, 5 parts of iron oxide yellow, MnO25 parts, 1 part of NiO, Al2O33 parts, CrO34 parts, ZrSiO42 parts, V2O51 part, CuO 5
Part, TiO21 part, 1 part of CMC；
The composition of lead free soldering is as follows：36 parts of potassium feldspar, 16 parts of zinc oxide, quartz 7 parts, calcite 8,8 parts of barium carbonate,
Al2O38 parts, WO37 parts, K23 parts of O, Na22 parts of O, Li25 parts of O.
The noble metal glaze art pottery background color being burnt into the present embodiment is in gold and silver color, and glazing effect has very strong metal
Gloss, glaze is smooth, is in mirror-reflection, and gloss keeps lasting, with good stability, in addition this kind of noble metal glaze art
It is safe to use without lead, chromium in ceramic glaze.
Specific embodiment three：
The glaze component of the noble metal glaze art pottery is as follows：62 parts of lead free soldering, 5 parts of calcite, 5 parts of kaolin,
5 parts of quartz, 8 parts of iron oxide yellow, MnO25 parts, 2 parts of NiO, Al2O32 parts, CrO31 part, ZrSiO41 part, V2O51 part, CuO 1
Part, TiO21 part, 1 part of CMC；
The composition of lead free soldering is as follows：40 parts of potassium feldspar, 16 parts of zinc oxide, quartz 8 parts, calcite 7,4 parts of barium carbonate,
Al2O39 parts, WO37 parts, K23 parts of O, Na23 parts of O, Li23 parts of O.
The noble metal glaze art pottery background color being burnt into the present embodiment is in grey black, and glazing effect has very strong metal
Gloss, glaze is smooth, is in mirror-reflection, and gloss keeps lasting, with good stability, in addition this kind of noble metal glaze art
It is safe to use without lead, chromium in ceramic glaze.
A kind of production method with the noble metal glaze art pottery, prepares the arbitrary noble metal of specific embodiment one or three
The glaze art pottery, is as follows：
Step 1, the shraff during Production of Ceramics is collected, shraff is cleaned, crushes, 1100- after sieving
1200 DEG C of high-temperature calcinations, for use；
Step 2, according to traditional shaping method of ceramics, ceramic body is produced；
Step 3, it weighs, mix according to the glaze component of noble metal glaze art pottery progress raw material, by raw material wet bulb
Mill, glaze crosses 200 mesh sieve after wet ball mill, obtains glaze, and when wet ball mill expects：Ball：Water=1:2:1：1-0.8,30-60 points of ball milling
Clock tails over 1%；
Step 4, ceramic body, is put into baking oven by the glazing on ceramic body, glaze thickness 0.3-0.5mm after glazing
It is toasted 5-20 hours in 45-50 DEG C, removal is for use；
Step 5, the ceramic body after glazing is put into kiln, is formed by a firing, firing temperature is 1200-1260 DEG C, is protected
Natural cooling after 30-60 minutes warm.
A specific implementation mode of the present invention is above are only, but the design concept of the present invention is not limited thereto, all utilizations
This design carries out the present invention change of unsubstantiality, should all belong to the behavior for invading the scope of the present invention.
Claims (7)
1. the noble metal glaze art pottery, which is characterized in that the glaze component of the noble metal glaze art pottery is as follows：It is unleaded
45-70 parts of frit, 5-10 parts of calcite, 5-10 parts of kaolin, 5-10 parts of quartz, 5-10 parts of iron oxide yellow, MnO25-10 parts, NiO1-
10 parts, Al2O31-5 parts, CrO31-5 parts, ZrSiO41-5 parts, V2O51-5 parts, 1-5 parts of CuO, TiO21-3 parts, CMC 0.5-1
Part；
The composition of wherein lead free soldering is as follows：30-45 parts of potassium feldspar, 10-20 parts of zinc oxide, 5-10 parts of quartz, calcite 5-10
Part, 5-10 parts of barium carbonate, Al2O35-10 parts, WO35-10 parts, K21-5 parts of O, Na21-5 parts of O, Li21-5 parts of O.
2. the noble metal glaze art pottery according to claim 1, which is characterized in that the noble metal glaze art pottery
Glaze component it is as follows：49 parts of lead free soldering, 6 parts of calcite, 6 parts of kaolin, 7 parts of quartz, 9 parts of iron oxide yellow, MnO26 parts, NiO 2
Part, Al2O33 parts, CrO31 part, ZrSiO42 parts, V2O55 parts, 1 part of CuO, TiO22.5 parts, 0.5 part of CMC.
3. the noble metal glaze art pottery according to claim 1 or 2, which is characterized in that the composition of the lead free soldering
It is as follows：42 parts of potassium feldspar, 18 parts of zinc oxide, 6 parts of quartz, 7 parts of calcite, 6 parts of barium carbonate, Al2O35 parts, WO36 parts, K2O 3
Part, Na22 parts of O, Li25 parts of O.
4. the noble metal glaze art pottery according to claim 1 or 2, which is characterized in that the composition of the lead free soldering
It is as follows：36 parts of potassium feldspar, 16 parts of zinc oxide, 7 parts of quartz, 8 parts of calcite, 8 parts of barium carbonate, Al2O38 parts, WO37 parts, K2O 3
Part, Na22 parts of O, Li25 parts of O.
5. the noble metal glaze art pottery according to claim 1, which is characterized in that the noble metal glaze art pottery
Glaze component it is as follows：62 parts of lead free soldering, 5 parts of calcite, 5 parts of kaolin, 5 parts of quartz, 8 parts of iron oxide yellow, MnO25 parts, NiO 2
Part, Al2O32 parts, CrO31 part, ZrSiO41 part, V2O51 part, 1 part of CuO, TiO21 part, 1 part of CMC.
6. a kind of production method with the noble metal glaze art pottery prepares your gold described in claim 1-5 any one
Belong to the glaze art pottery, is as follows：
Step 1, the shraff during Production of Ceramics is collected, shraff is cleaned, crushes, 1100-1200 DEG C after sieving
High-temperature calcination, for use；
Step 2, according to traditional shaping method of ceramics, ceramic body is produced；
Step 3, it weighs, mix according to the glaze component of noble metal glaze art pottery progress raw material, by raw material wet ball mill, wet bulb
Glaze crosses 200 mesh sieve after mill, obtains glaze；
Step 4, ceramic body is put into baking oven after glazing and is toasted 5-20 hours in 45-50 DEG C, gone by the glazing on ceramic body
Except for use；
Step 5, the ceramic body after glazing is put into kiln, is formed by a firing, firing temperature is 1200-1260 DEG C, keeps the temperature 30-
Natural cooling after sixty minutes.
7. the production method of the noble metal glaze art pottery according to claim 6, it is characterised in that：In the step 4,
Glaze thickness is 0.3-0.5mm.
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| CN108558211A (en) * | 2018-04-23 | 2018-09-21 | 卢皆彬 | A kind of low fever at temperature metal bright glaze preparation method |
| CN108821590A (en) * | 2018-08-16 | 2018-11-16 | 醴陵市良盛陶瓷制造有限公司 | The unleaded metal glaze of Gold production and its preparation process |
| CN109264994A (en) * | 2018-09-21 | 2019-01-25 | 醴陵市良盛陶瓷制造有限公司 | Unglazed golden metallic glaze and preparation method thereof |
| CN109133630A (en) * | 2018-09-22 | 2019-01-04 | 醴陵市良盛陶瓷制造有限公司 | Unglazed argentine glaze and preparation method thereof |
| CN109734316A (en) * | 2019-02-18 | 2019-05-10 | 西安文理学院 | A kind of ceramet glaze and preparation method thereof |
| CN110002756A (en) * | 2019-04-15 | 2019-07-12 | 南京弥盛陶瓷制品有限公司 | The production method of metal reaction glaze and the ceramics with metal reaction glaze |
| CN111777330B (en) * | 2020-06-01 | 2022-06-07 | 福建良瓷科技有限公司 | Sanitary ceramic mirror patterned glaze and preparation method thereof |
| CN112410610A (en) * | 2020-10-26 | 2021-02-26 | 齐齐哈尔大学 | Alloy for casting industrial artworks and art ceramic using alloy |
| CN112694256A (en) * | 2021-01-13 | 2021-04-23 | 醴陵市格瑞瓷陶瓷科技有限公司 | Purple red oxidized Grignard metal glaze and processing technology thereof |
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|---|---|---|---|---|
| US5262363A (en) * | 1989-06-19 | 1993-11-16 | Saga Prefecture | Overglaze colors for pottery |
| CN102303970A (en) * | 2011-07-08 | 2012-01-04 | 晋江恒达陶瓷有限公司 | Method for producing metal enamelled bricks |
| CN103253987A (en) * | 2013-05-24 | 2013-08-21 | 醴陵陶润实业发展有限公司 | Method for manufacturing metal glaze |
| CN105152685A (en) * | 2015-10-19 | 2015-12-16 | 福建省德化县华茂陶瓷有限公司 | Matte metal glaze, matte metal glaze ceramic product prepared from same and preparation method of matte metal glaze ceramic product |
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| JP2014201477A (en) * | 2013-04-04 | 2014-10-27 | 京都市 | Low melting point leadless glass composition for ceramics |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5262363A (en) * | 1989-06-19 | 1993-11-16 | Saga Prefecture | Overglaze colors for pottery |
| CN102303970A (en) * | 2011-07-08 | 2012-01-04 | 晋江恒达陶瓷有限公司 | Method for producing metal enamelled bricks |
| CN103253987A (en) * | 2013-05-24 | 2013-08-21 | 醴陵陶润实业发展有限公司 | Method for manufacturing metal glaze |
| CN105152685A (en) * | 2015-10-19 | 2015-12-16 | 福建省德化县华茂陶瓷有限公司 | Matte metal glaze, matte metal glaze ceramic product prepared from same and preparation method of matte metal glaze ceramic product |
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