CN106047508A - Preparation method of detergent capable of removing fruit and vegetable pesticide residues - Google Patents
Preparation method of detergent capable of removing fruit and vegetable pesticide residues Download PDFInfo
- Publication number
- CN106047508A CN106047508A CN201610376987.6A CN201610376987A CN106047508A CN 106047508 A CN106047508 A CN 106047508A CN 201610376987 A CN201610376987 A CN 201610376987A CN 106047508 A CN106047508 A CN 106047508A
- Authority
- CN
- China
- Prior art keywords
- filtrate
- sodium carbonate
- detergent
- preparation
- garden stuff
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Detergent Compositions (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a preparation method of a detergent capable of removing fruit and vegetable pesticide residues. The preparation method includes the following steps that 1, crushed tea-oil tree fruit shell particles and distilled water are mixed according to the mass-volume ratio of 1 to 2.5-5, the mixture is put into a reaction kettle, sodium carbonate is added, and stirring is performed at the temperature of 30-100 DEG C for 0.5-3 hours; 2, filtration is performed, filtrate is collected, filter residues are arranged in a carbonization furnace, heating is performed to reach the temperature of 300 DEG C at the heating rate of 3-5 DEG C/min for carbonization, and the heat preservation time is 2.5 hours; 3, carbonized filter residues are smashed, and screening is performed by using a 200-mesh screen; 4, the filter residue powder in the step 3 is added to the filtrate in the step 2, and even stirring and mixing are performed; 5, tea saponin and sodium carbonate are added, and the detergent special for removing the fruit and vegetable pesticide residues can be obtained after even mixing. The raw materials are wide in source, a formula is mild, the pesticide residues in fruits and vegetables can be effectively removed, and the preparation method has the advantages of being low in cost, safe, environmentally friendly and the like.
Description
Technical field
The invention belongs to washing product field, be specifically related to the detergent preparation side of a kind of removable garden stuff pesticide residue thing
Method.
Background technology
The edible food caused containing a large amount of high poison, highly toxic pesticide residual can cause people, animal acute poisoning accident.Long-term food
The agricultural byproducts exceeded standard by pesticide residues, although be not result in acute poisoning, but the chronic poisoning of humans and animals may be caused, lead
Cause the generation of disease, even have influence on the next generation.Pesticide enters in grain, veterinary antibiotics, fish, shrimp, meat, egg, milk, causes food
Thing pollutes, the health of harm people.General organochlorine pesticide is very slow in human body metabolism's speed, and accumulated time is long.
Along with video quality safety and living environment requirement are improved constantly by people, the control to Safety of Food Quality,
The requirement being purged by persticide residue also improves constantly.Main in prior art use clear water to soak, remove the peel, heat, smelly
The methods such as oxygen remove the pesticide residues of fruit and vegerable, but these methods are little to the effect removing pesticide residues, and are unfavorable for fruit and vegerable
Storage, using value is the highest.
Tea saponin belongs to triterpenoid saponin, is made up of sugar body, aglucon and organic acid.Have emulsifying, disperse, moisten, decontamination,
Foaming, obvious antiinflammatory, impermeabilisation, antiinflammatory, cough-relieving, eliminate the phlegm, ease pain, sterilize, parasite killing, the effect such as promotion plant growing.Tea soap
Element can be degraded in nature, so tea saponin series of products do not produce pollution to environment, to person poultry harmless, uses safety.
Oil tea and Elaeis guineensis Jacq., Fructus oleae europaeae and Cortex cocois radicis the referred to as big woody edible oil tannin plant in the world four.Oil tea is the distinctive woody oil of China
Material, according to statistics, nearly 4,000,000 hectares of national existing oil tea area, produce Semen Camelliae more than 700 hundred million kg, about more than 3000 of oil-tea camellia husks per year
Ten thousand tons.But substantial amounts of oil-tea camellia husks is taken as fuel or as fertilizer, cause the great wasting of resources and environmental pollution,
If being prepared into the detergent of removable garden stuff pesticide residue thing, it is not only the abluent of a kind of Environmental Safety, simultaneously can
Improve the benefit of oil tea plantation, there is good economy and Significance for Environment.
Summary of the invention
It is an object of the invention to provide the detergent preparation method of a kind of removable garden stuff pesticide residue thing, for natural plants
It is made.
A kind of garden stuff pesticide residue detergent and preparation method thereof, mainly includes following step:
(1) particle diameter oil-tea camellia husks granule between 600～800um will be crushed to distilled water by mass volume ratio 1:2.5～5
Mixing, is placed in reactor, adds distilled water quality 2～the sodium carbonate of 5%, stirs 1～3h at 30～100 DEG C；
(2) filter, collect filtrate；And filtering residue is placed in retort, under the heating rate of 3～5 DEG C/min, temperature is risen to
300 DEG C carry out carbonization, temperature retention time 2.5h；
(3) filtering residue after carbonization is pulverized, cross 200 mesh sieves；
(4) filtering residue powder step (3) obtained, joins in the filtrate in step (2), is uniformly mixed；
(5) add the 2 of filtrate quality～tea saponin and filtrate quality 1～the sodium carbonate of 2% of 5%, after mix homogeneously, obtain and can go
Detergent except garden stuff pesticide residue thing.
Detailed description of the invention
Below with reference to embodiment, the present invention will be further described.
Embodiment 1
(1) distilled water being crushed to particle size range oil-tea camellia husks granule 10kg with 30kg between 600～800um is mixed,
It is placed in reactor, adds the sodium carbonate of 0.9kg, at 50 DEG C, stir 2.5h；(2) filter, collect filtrate；And filtering residue is placed in
In retort, under the heating rate of 5 DEG C/min, temperature is risen to 300 DEG C and carries out carbonization, temperature retention time 2.5h；(3) will carry out
Filtering residue after carbonization is pulverized, and crosses 200 mesh sieves；(4) by the filtering residue powder of step (3), join in the filtrate in step (2), stirring
Mix homogeneously；(5) add the tea saponin of 0.9kg and the sodium carbonate of filtrate quality 0.45kg, after mix homogeneously, obtain removable fruit
The detergent of vegetables pesticide residue.
Embodiment 2
(1) distilled water being crushed to particle size range oil-tea camellia husks granule 10kg with 33kg between 600～800um is mixed,
It is placed in reactor, adds the sodium carbonate of 1kg, at 50 DEG C, stir 2.5h；(2) filter, collect filtrate；And filtering residue is placed in charcoal
Change in stove, under the heating rate of 3 DEG C/min, temperature is risen to 300 DEG C and carries out carbonization, temperature retention time 2.5h；(3) charcoal will be carried out
Filtering residue after change is pulverized, and crosses 200 mesh sieves；(4) by the filtering residue powder of step (3), joining in the filtrate in step (2), stirring is mixed
Close uniformly；(5) add the tea saponin of 1kg and the sodium carbonate of filtrate quality 0.5kg, after mix homogeneously, obtain removable fruit and vegerable agriculture
The detergent of medicine residue.
Embodiment 3
(1) distilled water being crushed to particle size range oil-tea camellia husks granule 10kg with 40kg between 600～800um is mixed,
It is placed in reactor, adds the sodium carbonate of 1.1kg, at 50 DEG C, stir 2h；(2) filter, collect filtrate；And filtering residue is placed in charcoal
Change in stove, under the heating rate of 3-5 DEG C/min, temperature is risen to 300 DEG C and carries out carbonization, temperature retention time 2.5h；(3) will carry out
Filtering residue after carbonization is pulverized, and crosses 200 mesh sieves；(4) by the filtering residue powder of step (3), join in the filtrate in step (2), stirring
Mix homogeneously；(5) add the tea saponin of 1.1kg and the sodium carbonate of filtrate quality 0.6kg, after mix homogeneously, obtain removable fruit
The detergent of vegetables pesticide residue.
Embodiment 4
(1) distilled water being crushed to particle size range oil-tea camellia husks granule 10kg with 40kg between 600～800um is mixed,
It is placed in reactor, adds the sodium carbonate of 1.1kg, at 75 DEG C, stir 1.5h；(2) filter, collect filtrate；And filtering residue is placed in
In retort, under the heating rate of 3-5 DEG C/min, temperature is risen to 300 DEG C and carries out carbonization, temperature retention time 2.5h；(3) will enter
Filtering residue after row carbonization is pulverized, and crosses 200 mesh sieves；(4) by the filtering residue powder of step (3), join in the filtrate in step (2), stir
Mix mix homogeneously；(5) add the tea saponin of 1.2kg and the sodium carbonate of filtrate quality 0.5kg, after mix homogeneously, obtain removable
The detergent of garden stuff pesticide residue thing.
Embodiment 5
(1) distilled water being crushed to particle size range oil-tea camellia husks granule 10kg with 40kg between 600～800um is mixed,
It is placed in reactor, adds the sodium carbonate of 0.9kg, at 85 DEG C, stir 1h；(2) filter, collect filtrate；And filtering residue is placed in charcoal
Change in stove, under the heating rate of 3-5 DEG C/min, temperature is risen to 300 DEG C and carries out carbonization, temperature retention time 2.5h；(3) will carry out
Filtering residue after carbonization is pulverized, and crosses 200 mesh sieves；(4) by the filtering residue powder of step (3), join in the filtrate in step (2), stirring
Mix homogeneously；(5) add the tea saponin of 1.5kg and the sodium carbonate of filtrate quality 0.75kg, after mix homogeneously, obtain removable fruit
The detergent of vegetables pesticide residue.
Embodiment 6
(1) distilled water being crushed to particle size range oil-tea camellia husks granule 10kg with 40kg between 600～800um is mixed,
It is placed in reactor, adds the sodium carbonate of 1kg, at 75 DEG C, stir 1.5h；(2) filter, collect filtrate；And filtering residue is placed in charcoal
Change in stove, under the heating rate of 3-5 DEG C/min, temperature is risen to 300 DEG C and carries out carbonization, temperature retention time 2.5h；(3) will carry out
Filtering residue after carbonization is pulverized, and crosses 200 mesh sieves；(4) by the filtering residue powder of step (3), join in the filtrate in step (2), stirring
Mix homogeneously；(5) add the tea saponin of 1.15kg and the sodium carbonate of filtrate quality 0.55kg, after mix homogeneously, obtain removable
The detergent of garden stuff pesticide residue thing.
Embodiment 7
(1) distilled water being crushed to particle size range oil-tea camellia husks granule 10kg with 35kg between 600～800um is mixed,
It is placed in reactor, adds the sodium carbonate of 1kg, at 80 DEG C, stir 1.5h；(2) filter, collect filtrate；And filtering residue is placed in charcoal
Change in stove, under the heating rate of 3-5 DEG C/min, temperature is risen to 300 DEG C and carries out carbonization, temperature retention time 2.5h；(3) will carry out
Filtering residue after carbonization is pulverized, and crosses 200 mesh sieves；(4) by the filtering residue powder of step (3), join in the filtrate in step (2), stirring
Mix homogeneously；(5) add the tea saponin of 1.2kg and the sodium carbonate of filtrate quality 0.45kg, after mix homogeneously, obtain removable fruit
The detergent of vegetables pesticide residue.
Embodiment 8
(1) distilled water being crushed to particle size range oil-tea camellia husks granule 10kg with 40kg between 600～800um is mixed,
It is placed in reactor, adds the sodium carbonate of 1.1kg, at 50 DEG C, stir 2.5h；(2) filter, collect filtrate；And filtering residue is placed in
In retort, under the heating rate of 3-5 DEG C/min, temperature is risen to 300 DEG C and carries out carbonization, temperature retention time 2.5h；(3) will enter
Filtering residue after row carbonization is pulverized, and crosses 200 mesh sieves；(4) by the filtering residue powder of step (3), join in the filtrate in step (2), stir
Mix mix homogeneously；(5) add the tea saponin of 1.15kg and the sodium carbonate of filtrate quality 0.55kg, after mix homogeneously, obtain and can go
Detergent except garden stuff pesticide residue thing.
Embodiment 9
(1) distilled water being crushed to particle size range oil-tea camellia husks granule 10kg with 45kg between 600～800um is mixed,
It is placed in reactor, adds the sodium carbonate of 1.3kg, at 65 DEG C, stir 2.5h；(2) filter, collect filtrate；And filtering residue is placed in
In retort, under the heating rate of 3-5 DEG C/min, temperature is risen to 300 DEG C and carries out carbonization, temperature retention time 2.5h；(3) will enter
Filtering residue after row carbonization is pulverized, and crosses 200 mesh sieves；(4) by the filtering residue powder of step (3), join in the filtrate in step (2), stir
Mix mix homogeneously；(5) add the tea saponin of 1.25kg and the sodium carbonate of filtrate quality 0.75kg, after mix homogeneously, obtain and can go
Detergent except garden stuff pesticide residue thing.
The detergent preparing above example, the pesticide residue fast detection card being respectively adopted current measurement sensitivity higher enters
Row test, according to pesticide residues national standard, (in GB/T5009.199-2003 vegetable, Organophosphorus and carbamate pesticides class pesticide is residual
Staying quickly detection) product tested, finds that the fruit and vegerable being originally positive the most all reach negative, this product is described by method
Product can effective removing garden stuff pesticide residue.
The foregoing is only embodiments of the invention, not thereby limit the protection domain of the patent application of the present invention, all
It is the equivalent structure utilizing description of the invention content to be made or equivalence flow process conversion, or it is relevant to be directly or indirectly used in other
Technical field, in the protection domain of the patent application being the most in like manner included in the present invention.
Claims (5)
1. the detergent preparation method of a removable garden stuff pesticide residue thing, it is characterised in that include following step:
(1) the oil-tea camellia husks granule crushed is mixed by mass volume ratio 1:2.5～5 with distilled water, be placed in reactor, add
Enter sodium carbonate, at 30～100 DEG C, stir 0.5～3h；
(2) filter, collect filtrate；And filtering residue is placed in retort, under the heating rate of 3-5 DEG C/min, temperature is risen to
300 DEG C carry out carbonization, temperature retention time 2.5h；
(3) filtering residue after carrying out carbonization is pulverized, and crosses 200 mesh sieves；
(4) by the filtering residue powder of step (3), join in the filtrate in step (2), be uniformly mixed；
(5) add tea saponin and sodium carbonate, after mix homogeneously, obtain garden stuff pesticide residue special purpose detergent.
The detergent preparation method of a kind of removable garden stuff pesticide residue thing the most according to claim 1, it is characterised in that
Addition sodium carbonate described in step (1), its addition is the 2-5% of distilled water quality.
The detergent preparation method of a kind of removable garden stuff pesticide residue thing the most according to claim 1, it is characterised in that
Oil-tea camellia husks granule described in step (1), its particle diameter is between 600～800um.
The detergent preparation method of a kind of removable garden stuff pesticide residue thing the most according to claim 1, it is characterised in that
The 2-5% that consumption is filtrate quality of the tea saponin described in step (5).
The detergent preparation method of a kind of removable garden stuff pesticide residue thing the most according to claim 1, it is characterised in that
Sodium carbonate amount described in step (1) is the 1-2% for filtrate quality.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610376987.6A CN106047508A (en) | 2016-05-31 | 2016-05-31 | Preparation method of detergent capable of removing fruit and vegetable pesticide residues |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610376987.6A CN106047508A (en) | 2016-05-31 | 2016-05-31 | Preparation method of detergent capable of removing fruit and vegetable pesticide residues |
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| Publication Number | Publication Date |
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| CN106047508A true CN106047508A (en) | 2016-10-26 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610376987.6A Pending CN106047508A (en) | 2016-05-31 | 2016-05-31 | Preparation method of detergent capable of removing fruit and vegetable pesticide residues |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109576082A (en) * | 2018-12-27 | 2019-04-05 | 福建师范大学 | A kind of Tea Saponin fast dissolving solid detergent and preparation method thereof removing fruit and vegetable residual pesticide |
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|---|---|---|---|---|
| CN1563313A (en) * | 2004-04-06 | 2005-01-12 | 中国计量学院 | Natural scavenging agent for removing residual pesticide on vegetable and fruitage |
| CN101463306A (en) * | 2009-01-13 | 2009-06-24 | 刘佳文 | Active carbon abstergent |
| CN103030710A (en) * | 2013-01-05 | 2013-04-10 | 广西大学 | Resource utilization method of camellia oleifera shells |
| CN103232902A (en) * | 2013-04-25 | 2013-08-07 | 覃永良 | Camellia saponin detergent powder for removing greasy dirt of natural plants |
| CN104803381A (en) * | 2015-03-25 | 2015-07-29 | 长沙国容新能源有限公司 | Method for preparing activated carbon from Hunan camellia oleifera shells, activated carbon and application of activated carbon |
| CN105462715A (en) * | 2015-12-30 | 2016-04-06 | 李素萍 | Natural fruit detergent |
-
2016
- 2016-05-31 CN CN201610376987.6A patent/CN106047508A/en active Pending
Patent Citations (6)
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| CN1563313A (en) * | 2004-04-06 | 2005-01-12 | 中国计量学院 | Natural scavenging agent for removing residual pesticide on vegetable and fruitage |
| CN101463306A (en) * | 2009-01-13 | 2009-06-24 | 刘佳文 | Active carbon abstergent |
| CN103030710A (en) * | 2013-01-05 | 2013-04-10 | 广西大学 | Resource utilization method of camellia oleifera shells |
| CN103232902A (en) * | 2013-04-25 | 2013-08-07 | 覃永良 | Camellia saponin detergent powder for removing greasy dirt of natural plants |
| CN104803381A (en) * | 2015-03-25 | 2015-07-29 | 长沙国容新能源有限公司 | Method for preparing activated carbon from Hunan camellia oleifera shells, activated carbon and application of activated carbon |
| CN105462715A (en) * | 2015-12-30 | 2016-04-06 | 李素萍 | Natural fruit detergent |
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| Title |
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| 晏立豪: "《生活日用化工800例》", 30 September 1994, 广西科学技术出版社 * |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109576082A (en) * | 2018-12-27 | 2019-04-05 | 福建师范大学 | A kind of Tea Saponin fast dissolving solid detergent and preparation method thereof removing fruit and vegetable residual pesticide |
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Application publication date: 20161026 |
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