CN106045620B - A kind of red soil conditioner and preparation method thereof - Google Patents

A kind of red soil conditioner and preparation method thereof Download PDF

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Publication number
CN106045620B
CN106045620B CN201610384784.1A CN201610384784A CN106045620B CN 106045620 B CN106045620 B CN 106045620B CN 201610384784 A CN201610384784 A CN 201610384784A CN 106045620 B CN106045620 B CN 106045620B
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offal
decomposed
ardealite
parts
red soil
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CN106045620A (en
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梁泉
董文汉
尹元萍
舒艺周
张应虎
杨跃华
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Yunnan Agricultural University
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Yunnan Agricultural University
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05DINORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D3/00Calcareous fertilisers
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F5/00Fertilisers from distillery wastes, molasses, vinasses, sugar plant or similar wastes or residues, e.g. from waste originating from industrial processing of raw material of agricultural origin or derived products thereof
    • C05F5/006Waste from chemical processing of material, e.g. diestillation, roasting, cooking
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F9/00Fertilisers from household or town refuse
    • C05F9/04Biological compost

Abstract

Red soil conditioner is made using chemical industrial waste object ardealite, which is characterized in that by volume, including chemical industrial waste object -90-110 parts of ardealite, 6-8 parts of offal, 5-10 parts of decomposed dung.A kind of red soil conditioner preparation method first crushes offal;Barnyard manure and offal difference stacking curing;Decomposed offal is mixed well with ardealite, is placed 24-48 hours, is then mixed well again with decomposed dung;Each component ratio is ardealite 90-110 parts, decomposed offal 6-8 parts, 5-10 parts of decomposed dung.The technology of invention is improved for red soil, can be solved the problems such as red soil acid strong, soil hardening, nutrient are lacked of proper care, available phosphorus content is low simultaneously, can also be played the effect of expelling parasite and desinsection, materials are easy, and are easy to be promoted in rural area.

Description

A kind of red soil conditioner and preparation method thereof
Technical field
The present invention relates to the regeneration fields of chemical industrial waste object and agricultural wastes, and in particular to a kind of red soil conditioner And preparation method thereof.
Background technique
South China of China distribution of red soil is extensive, but since (soil hardening holds for dry (not drought-resistant), sour (pH value is low), plate It is great), the bad character such as thin (available phosphorus is low, nutrient is unbalance), be a kind of low productive soil.Generally by increasing stone in production Ash is but often ineffective to reduce soil acidity degree.For many years, the researchs such as improvement about red soil acidity are by extensive Concern, the project as related to red soil acidification improvement in national " 15 ", Eleventh Five-Year Plan plan of science and technology.In the prior art, There is multidigit scholar to study red soil conditioning technology, but has not been able to solve acid strong, soil hardening, nutrient imbalance, effectively simultaneously The obstacle for the influence crop growthing developments such as phosphorus content is low, aluminium is malicious.
Patentee is " Jiangxi Institute of Red Soil ", and patent name is " a kind of deacidification moisture control method of Upland Red Soil ", The patent of Patent No. " 201210518904.4 " discloses a kind of method for improving red soil: utilizing calper calcium peroxide or peroxidating Magnesium reduces the acidity of soil, changes soil redox potential, adjusts the aqueous vapor ratio of soil, generate simultaneously to Upland Red Soil Deacidification and damping effect.The defect of the technology is not solve soil hardening, nutrient imbalance, this low three big influence of available phosphorus content The reason of crop planting.
Patentee is " Institute of Environment and Sustainable Development in Agriculture, CAAS ", and patent name is " a kind of Red soil improving agent ", the patent of Patent No. " 201110240926.4 " disclose a kind of method for improving red soil, by 30%~ 40% red mud, 15%~25% sepiolite, 20%~30% straw biomass be burnt, 10%~15% calcium hydroxide and 10%~15% magnesia mixing is used as conditioner, so that the moderate-elements such as soil acidification, calcium and magnesium supply wretched insufficiency etc. is led The problem of plant growth of cause is poor, low output is addressed.But the defect of the technology is not solve soil hardening and available phosphorus This low two large problems of content.Meanwhile the component that the technology is previously mentioned is too many, is unfavorable for being generalized in the vast rural area of China.
Summary of the invention
In order to solve the above technical problems, the present invention utilizes chemical industrial waste object ardealite and agricultural wastes offal and matting Fertilizer prepares a kind of red soil conditioner, can effectively solve red soil acid strong, soil hardening, nutrient are lacked of proper care, available phosphorus content is low etc. Problem, and be easy to be promoted in rural area.
Its technical solution are as follows:
A kind of red soil conditioner, by volume, including 90-110 parts of ardealite, decomposed offal 6-8 parts, decomposed dung 5-10 Part.
A kind of red soil conditioner preparation method first crushes offal for 20-40 mesh;Barnyard manure and offal difference stacking curing; Decomposed offal is mixed well with ardealite, is placed 24-48 hours, is then mixed well again with decomposed dung;Each component ratio is 100 parts of ardealite, decomposed offal 6-8 parts, 5-10 parts of decomposed dung.
The solid waste that ardealite gives off when being phosphate fertilizer, phosphoric acid production.China is the first big ardealite pair in the world State is produced, 50,000,000 tons of annual emissions, accounts for 70% of industry by-product gypsum or more, and increase every year with 15% speed.Its medium cloud South saves ardealite annual emissions and accounts for the whole nation 1/5 or so.The country is from the 1970's, in soil such as saline-alkali soil, brown earth, yellow earth, red soil The research of some ardealite agricultural effects has been carried out on earth, the results showed that, ardealite helps to improve the yield and quality of crop. But due to the problems such as ardealite itself is acid by force, it is great to glue, and long-term excessive application will lead to soil acidification, bulk density increase.
Microelement is abundant in ardealite, there are also a small amount of available phosphorus, can solve that available phosphorus content in red soil is low and nutrient The problem of imbalance.If individually using ardealite in red soil, the pH value of red soil can become lower, cause nutrient imbalance tighter Weight, so that soil is more hardened.Ardealite is mainly used for improving basic soil in northern China, has no on acid soil There is research.There is ardealite to should not be used in the technology prejudice of red soil conditioning in the art.
Offal is the leftover bits and pieces of production of cigarettes, light, alkaline, and the elements such as organic matter rich in, biological clamps are a kind of The nuisanceless ecological organic fertilizer of fully natural green.
The problem of offal contains potassium abundant, nitrogen, can solve soil nutrients and soil imbalance.Offal is alkaline matter, be can solve The acid strong problem of red soil, while the acid strong defect of ardealite can also be offset.Offal bulk density is small, can also be effectively improved soil Loamy texture, the problem of alleviating soil hardening, while can also offset the big defect of ardealite bulk density.Offal is in Yunnan vast rural area It can obtain easily, and most of soil in Yunnan belongs to red soil.If offal is used alone, wherein the nicotine contained will affect The growth and development of crop root.So offal in the art of not applying singly generally is for soil conditioning.
Although decomposed dung nutrient is more comprehensive, since nutrient content is relatively low, when exclusive use, is tended not to effectively Meets the needs of crop is to nutrient.Therefore, the usual organic fertilizer inorganic fertilizer that needs to arrange in pairs or groups is used in conjunction with.Meanwhile the macromolecular of barnyard manure Such as humic acid etc, the harmful element in ardealite can be coupled.Application barnyard manure can improve the soil texture, and increasing soil can be thoroughly Property, it is shared with ardealite, the big defect of ardealite bulk density can also be offset.Farmyard manure and offal ferment together, are easier to send out Ferment is decomposed, and content of humic acid will increase.
Ardealite, decomposed offal, decomposed dung three ratio according to the invention can solve simultaneously for adjusting red soil The problems such as red soil acid strong, soil hardening, nutrient are lacked of proper care, available phosphorus content is low, aluminium content is excessively high.
It should be noted that could be mixed in proportion with ardealite after barnyard manure and offal need independent stacking fermentation maturity, And mixed program is that decomposed offal and ardealite first uniformly mix 24-48 hours, is then sufficiently mixed again with decomposed dung, It can applied.This is different and determine by pH value and the chemical property of three.According to the source of barnyard manure and composition, pH Value is not quite similar, generally between 5.6-7.5.Nutriment contained by barnyard manure is more comprehensive, existing a great number of elements, and has one slightly Secondary element, but these nutrients are in organic matter state more, it is difficult to it is directly absorbed and utilized by crop, it is necessary to by the change in soil It learns the fermentation of physical action and microorganism, decompose, discharge nutrient gradually, thus fertilizer efficiency is longer and stablize.The general meta-alkali of offal Property (pH value > 8), ardealite slant acidity (pH value < 4).It can be seen that due to ardealite peracid, offal meta-alkali, the two is unsuitable It is used alone.And decomposed barnyard manure can be administered alone.Decomposed offal and ardealite mixes 24-48 hours, Ke Yiqi To the effect of acid-base neutralization.It is mixed again with decomposed dung, three's mix products pH value, can be to avoid singly applying offal close to 6 or so Or when singly applying ardealite, the problem of leading to peracid or cross alkali.By test, N(12 kg/667m2), P(7 kg/667m2), K (4.5 kg/667m2) three's mixture ph be 6.8, bulk density 0.786;NPK+ offal (decomposed) mixture ph is 8.6, Bulk density is 0.436;NPK+ barnyard manure (decomposed) mixture ph is 6.4, bulk density 0.689;NPK+ ardealite mixture ph is 4.7, bulk density 0.946;And NPK+ offal (decomposed)+barnyard manure (decomposed)+ardealite mixture ph is 5.96, bulk density is 0.822。
It should be noted that barnyard manure and offal need difference stacking decomposed before use, could be mixed with ardealite.This is Because nutrient is in organic matter state more in barnyard manure and offal, directly application is difficult to directly be absorbed and utilized by crop, it is necessary to pass through Stacking is crossed, under the action of chemistry, physics and microorganism, nutrient could gradually discharge.Certainly, not decomposed barnyard manure and offal are straight The time for connecing and being applied to soil, can also ferment, decompose by the effect of chemical physical action and microorganism in soil, but need It is longer, and the two is fermented in the soil, it is most likely that cause crop to burn root.
By repeatedly matching screening and field comparison test, and in view of the materials of ardealite, three kinds of offal, barnyard manure substances Convenient and use cost finally determines the formula of this red soil conditioner are as follows: phosphorus according to the minimum usage amount of offal and barnyard manure It 1 part of gypsum, decomposed offal 0.06-0.08 parts, 0.05-0.10 parts of decomposed dung (volume ratio), in production practice, can basis It needs, properly increases the quantity of offal and barnyard manure.With red soil conditioner made of above-mentioned formula, Kaiyuan City, E Shan in Yunnan Province On the ground such as county, Xuanwei City red soil, tested on four kinds of sugarcane, soybean, corn, potato crops respectively, with N(12 kg/ 667m2), P(7 kg/667m2), K(4.5 kg/667m2) it is basic fertilizer (CK), offal (decomposed) (T1), barnyard manure are applied respectively (decomposed) (T2), ardealite (T3), red soil conditioner, as a result, it has been found that: compared with CK, sugarcane, soybean, corn, potato difference Volume increase 10.7%, 8.9%, 8.6% and 9.2%;More singly apply offal (decomposed), barnyard manure (decomposed), ardealite averagely increase production 3.53 times, 2.90 times and 3.53 times, difference reaches the level of signifiance;Soil pH value is respectively 5.54,6.43,6.21,5.38,5.93;The soil weight Respectively 1.43,1.22,1.28,1.49,1.36;Soil alkali-hydrolyzable nitrogen (mg/kg) is respectively 89,129,117,87,109;It is quick-acting Phosphorus (mg/kg) is respectively 4.15,5.45,5.56,4.43,6.41;Available potassium (mg/kg) is respectively 77,113,97,82,104; Effective sulphur (mg/kg) is respectively 20.7,26.1,37.4,101.9,97.3;Exchangeable calcium (cmol (1/2Ca2+)/kg) be respectively 0.066,0.82,0.99,0.142,0.135;Exchangeable aluminum (cmol (1/3Al3+)/kg) it is respectively 0.129,0.964,0.104, 0.115,0.105.
Specific embodiment
A kind of red soil conditioner, by volume, including 90-110 parts of ardealite, decomposed offal 6-8 parts, decomposed dung 5-10 Part.
A kind of red soil conditioner preparation method first crushes offal (20-40 mesh);Barnyard manure and offal difference stacking curing (according to different weather conditions, rotting so that offal blacks, barnyard manure whitens);Decomposed offal is mixed well with ardealite, is placed It 24-48 hours, is then mixed well again with decomposed dung;Each component ratio is ardealite 90-110 parts, 6-8 parts of offal, decomposed 5-10 parts of barnyard manure.

Claims (2)

1. a kind of preparation method of red soil conditioner, which is characterized in that offal is first crushed, stacking it is decomposed;Barnyard manure stacking is decomposed; Decomposed offal is mixed well with ardealite, is placed 24-48 hours, is then mixed well again with decomposed dung.
2. a kind of red soil conditioner, which is characterized in that the preparation method as described in claim 1 obtains, by volume, including phosphorus stone 90-110 parts of cream, decomposed offal 6-8 parts, 5-10 parts of decomposed dung.
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Publication number Priority date Publication date Assignee Title
CN107011913A (en) * 2017-04-18 2017-08-04 广东丰康生物科技有限公司 A kind of acid soil improving agent
CN107365232A (en) * 2017-08-24 2017-11-21 王伯仁 A kind of new red soil acidifying improvement conditioner and preparation method thereof

Citations (2)

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Publication number Priority date Publication date Assignee Title
CN101693641A (en) * 2009-10-22 2010-04-14 南京信息工程大学 Compound bio-fertilizer containing ardealite and application thereof
CN105131970A (en) * 2015-09-21 2015-12-09 潍坊友容实业有限公司 Conditioner for improvement of saline-alkali soil

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101693641A (en) * 2009-10-22 2010-04-14 南京信息工程大学 Compound bio-fertilizer containing ardealite and application thereof
CN105131970A (en) * 2015-09-21 2015-12-09 潍坊友容实业有限公司 Conditioner for improvement of saline-alkali soil

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