CN106045533A - 钢铁连铸中间包用方镁石‑镁橄榄石‑碳质座砖及其制备方法 - Google Patents
钢铁连铸中间包用方镁石‑镁橄榄石‑碳质座砖及其制备方法 Download PDFInfo
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Abstract
本发明涉及耐火材料领域,具体涉及钢铁连铸中间包用方镁石‑镁橄榄石‑碳质座砖及其制备方法,包括工作层和隔热层,所述工作层由以下原料组成:方镁石、铁铝尖晶石砂、电熔镁砂、减水剂、结合剂;隔热层由以下原料组成:镁橄榄石、菱镁石、镁砂细粉、石墨、二氧化钛微球、结合剂。本发明提供的钢铁连铸中间包用方镁石‑镁橄榄石‑碳质座砖及其制备方法,制备得到的砖头,导热系数低,具有良好的保温效果,并且抗震和抗腐蚀性好,延长了使用寿命,降低了使用成本。
Description
技术领域
本发明涉及耐火材料领域,具体涉及钢铁连铸中间包用方镁石-镁橄榄石-碳质座砖及其制备方法。
背景技术
目前,钢铁连铸中间包用的耐火砖主要是镁铁砖或者镁铝砖,导热系数均比较高,实际使用过程中节能效果不显著,隔热效果差,浪费能源,而且使用寿命短,使用成本高。
发明内容
针对上技术问题,本发明提供一种隔热效果好的钢铁连铸中间包用方镁石-镁橄榄石-碳质座砖及其制备方法。
具体技术方案为:
钢铁连铸中间包用方镁石-镁橄榄石-碳质座砖,包括工作层和隔热层,所述工作层由以下原料按照重量份数组成:
粒径为3-6mm的方镁石13~18份、粒径为1-3mm的方镁石17~22份、粒径为1-2mm的铁铝尖晶石砂9~15份、粒径为0.088-1mm的方镁石9~12份、粒径为0.088-1mm的铁铝尖晶石砂6~12份、粒径<0.088mm的方镁石细粉27~37份和粒径<0.020mm的电熔镁砂7~12份,减水剂0.05~0.08份和结合剂3.6~4.5份;
所述隔热层由以下原料按照重量份数组成:
粒径为3-6mm的镁橄榄石14~18份、粒径为1-3mm的镁橄榄石22~26份、粒径为0.088-1mm的镁橄榄石8~14份、粒径为0.088-0.5mm的菱镁石颗粒6~11份、粒径<0.088mm的镁砂细粉6~11份、石墨4~7份、粒径<1mm的二氧化钛微球0.5~1.2份、结合剂6~10份。
钢铁连铸中间包用方镁石-镁橄榄石-碳质座砖的制备方法,包括以下步骤:
(1)制备工作层:按工作层原料组成混合均匀后,再加入减水剂和结合剂,在进行混炼至均匀;
(2)制备隔热层:按隔热层原料组成混合均匀后,再加入二氧化钛和结合剂,再进行混炼至均匀;
(3)成型、烧成:用分隔板将砖模具隔开分为热端和冷端两部分,在热端加入工作层,在冷端加入隔热层,然后抽出分隔板,用摩擦压砖机压制成砖坯,将砖坯在干燥窑中110~125℃干燥22~25小时,然后在1550~1600℃烧制5~7小时,出窑。
本发明提供的钢铁连铸中间包用方镁石-镁橄榄石-碳质座砖及其制备方法,制备得到的砖头,导热系数低,具有良好的保温效果,并且抗震和抗腐蚀性好,延长了使用寿命,降低了使用成本。
具体实施方式
结合实施例说明本发明的具体实施方式。
实施例1
粒径为3-6mm的方镁石18份、粒径为1-3mm的方镁石19份、粒径为1-2mm的铁铝尖晶石砂15份、粒径为0.088-1mm的方镁石11份、粒径为0.088-1mm的铁铝尖晶石砂6份、粒径<0.088mm的方镁石细粉33份和粒径<0.020mm的电熔镁砂12份,减水剂0.05~0.08份和结合剂4份;
所述隔热层由以下原料按照重量份数组成:
粒径为3-6mm的镁橄榄石14份、粒径为1-3mm的镁橄榄石25份、粒径为0.088-1mm的镁橄榄石14份、粒径为0.088-0.5mm的菱镁石颗粒6份、粒径<0.088mm的镁砂细粉6份、石墨5份、粒径<1mm的二氧化钛微球1.2份、结合剂8份。
钢铁连铸中间包用方镁石-镁橄榄石-碳质座砖的制备方法,包括以下步骤:
(1)制备工作层:按工作层原料组成混合均匀后,再加入减水剂和结合剂,在进行混炼至均匀;
(2)制备隔热层:按隔热层原料组成混合均匀后,再加入二氧化钛和结合剂,再进行混炼至均匀;
(3)成型、烧成:用分隔板将砖模具隔开分为热端和冷端两部分,在热端加入工作层,在冷端加入隔热层,然后抽出分隔板,用摩擦压砖机压制成砖坯,将砖坯在干燥窑中110~125℃干燥22~25小时,然后在1550~1600℃烧制5~7小时,出窑。
实施例2
粒径为3-6mm的方镁石13份、粒径为1-3mm的方镁石22份、粒径为1-2mm的铁铝尖晶石砂10份、粒径为0.088-1mm的方镁石9份、粒径为0.088-1mm的铁铝尖晶石砂12份、粒径<0.088mm的方镁石细粉37份和粒径<0.020mm的电熔镁砂7份,减水剂0.05~0.08份和结合剂3.6份;
所述隔热层由以下原料按照重量份数组成:
粒径为3-6mm的镁橄榄石16份、粒径为1-3mm的镁橄榄石26份、粒径为0.088-1mm的镁橄榄石8份、粒径为0.088-0.5mm的菱镁石颗粒7份、粒径<0.088mm的镁砂细粉11份、石墨4份、粒径<1mm的二氧化钛微球0.9份、结合剂6份。
钢铁连铸中间包用方镁石-镁橄榄石-碳质座砖的制备方法,包括以下步骤:
(1)制备工作层:按工作层原料组成混合均匀后,再加入减水剂和结合剂,在进行混炼至均匀;
(2)制备隔热层:按隔热层原料组成混合均匀后,再加入二氧化钛和结合剂,再进行混炼至均匀;
(3)成型、烧成:用分隔板将砖模具隔开分为热端和冷端两部分,在热端加入工作层,在冷端加入隔热层,然后抽出分隔板,用摩擦压砖机压制成砖坯,将砖坯在干燥窑中110~125℃干燥22~25小时,然后在1550~1600℃烧制5~7小时,出窑。
实施例3
粒径为3-6mm的方镁石16份、粒径为1-3mm的方镁石17份、粒径为1-2mm的铁铝尖晶石砂9份、粒径为0.088-1mm的方镁石12份、粒径为0.088-1mm的铁铝尖晶石砂9份、粒径<0.088mm的方镁石细粉27份和粒径<0.020mm的电熔镁砂11份,减水剂0.05~0.08份和结合剂4.5份;
所述隔热层由以下原料按照重量份数组成:
粒径为3-6mm的镁橄榄石18份、粒径为1-3mm的镁橄榄石22份、粒径为0.088-1mm的镁橄榄石11份、粒径为0.088-0.5mm的菱镁石颗粒11份、粒径<0.088mm的镁砂细粉9份、石墨7份、粒径<1mm的二氧化钛微球0.5份、结合剂10份。
钢铁连铸中间包用方镁石-镁橄榄石-碳质座砖的制备方法,包括以下步骤:
(1)制备工作层:按工作层原料组成混合均匀后,再加入减水剂和结合剂,在进行混炼至均匀;
(2)制备隔热层:按隔热层原料组成混合均匀后,再加入二氧化钛和结合剂,再进行混炼至均匀;
(3)成型、烧成:用分隔板将砖模具隔开分为热端和冷端两部分,在热端加入工作层,在冷端加入隔热层,然后抽出分隔板,用摩擦压砖机压制成砖坯,将砖坯在干燥窑中110~125℃干燥22~25小时,然后在1550~1600℃烧制5~7小时,出窑。
Claims (2)
1.钢铁连铸中间包用方镁石-镁橄榄石-碳质座砖,包括工作层和隔热层,其特征在于:所述工作层由以下原料按照重量份数组成:
粒径为3-6mm的方镁石13~18份、粒径为1-3mm的方镁石17~22份、粒径为1-2mm的铁铝尖晶石砂9~15份、粒径为0.088-1mm的方镁石9~12份、粒径为0.088-1mm的铁铝尖晶石砂6~12份、粒径<0.088mm的方镁石细粉27~37份和粒径<0.020mm的电熔镁砂7~12份,减水剂0.05~0.08份和结合剂3.6~4.5份;
所述隔热层由以下原料按照重量份数组成:
粒径为3-6mm的镁橄榄石14~18份、粒径为1-3mm的镁橄榄石22~26份、粒径为0.088-1mm的镁橄榄石8~14份、粒径为0.088-0.5mm的菱镁石颗粒6~11份、粒径<0.088mm的镁砂细粉6~11份、石墨4~7份、粒径<1mm的二氧化钛微球0.5~1.2份、结合剂6~10份。
2.根据权利要求1所述的钢铁连铸中间包用方镁石-镁橄榄石-碳质座砖的制备方法,其特征在于:包括以下步骤:
(1)制备工作层:按工作层原料组成混合均匀后,再加入减水剂和结合剂,在进行混炼至均匀;
(2)制备隔热层:按隔热层原料组成混合均匀后,再加入二氧化钛和结合剂,再进行混炼至均匀;
(3)成型、烧成:用分隔板将砖模具隔开分为热端和冷端两部分,在热端加入工作层,在冷端加入隔热层,然后抽出分隔板,用摩擦压砖机压制成砖坯,将砖坯在干燥窑中110~125℃干燥22~25小时,然后在1550~1600℃烧制5~7小时,出窑。
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CN110950669A (zh) * | 2019-11-05 | 2020-04-03 | 泰州市旺鑫耐火材料有限公司 | 一种镁橄榄石座砖配方及其制备方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101412629A (zh) * | 2008-08-29 | 2009-04-22 | 瑞泰科技股份有限公司 | 方镁石-镁铝尖晶石复合耐火砖及其生产工艺 |
CN102674866A (zh) * | 2012-06-06 | 2012-09-19 | 郑州真金耐火材料有限责任公司 | 镁铁尖晶石隔热复合砖 |
CN104725058A (zh) * | 2015-03-10 | 2015-06-24 | 河南瑞泰耐火材料科技有限公司 | 方镁石-镁铁铁铝尖晶石/镁橄榄石复合砖 |
CN105565794A (zh) * | 2015-12-16 | 2016-05-11 | 淄博市鲁中耐火材料有限公司 | 一种低导热镁铝尖晶石砖的制备方法 |
-
2016
- 2016-06-03 CN CN201610385193.6A patent/CN106045533A/zh active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101412629A (zh) * | 2008-08-29 | 2009-04-22 | 瑞泰科技股份有限公司 | 方镁石-镁铝尖晶石复合耐火砖及其生产工艺 |
CN102674866A (zh) * | 2012-06-06 | 2012-09-19 | 郑州真金耐火材料有限责任公司 | 镁铁尖晶石隔热复合砖 |
CN104725058A (zh) * | 2015-03-10 | 2015-06-24 | 河南瑞泰耐火材料科技有限公司 | 方镁石-镁铁铁铝尖晶石/镁橄榄石复合砖 |
CN105565794A (zh) * | 2015-12-16 | 2016-05-11 | 淄博市鲁中耐火材料有限公司 | 一种低导热镁铝尖晶石砖的制备方法 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110950669A (zh) * | 2019-11-05 | 2020-04-03 | 泰州市旺鑫耐火材料有限公司 | 一种镁橄榄石座砖配方及其制备方法 |
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