CN105940019B - 用于烯烃聚合的催化剂体系 - Google Patents

用于烯烃聚合的催化剂体系 Download PDF

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Publication number
CN105940019B
CN105940019B CN201480074778.5A CN201480074778A CN105940019B CN 105940019 B CN105940019 B CN 105940019B CN 201480074778 A CN201480074778 A CN 201480074778A CN 105940019 B CN105940019 B CN 105940019B
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procatalyst
compound
alkyl
aryl
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Chinese (zh)
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CN105940019A (zh
Inventor
M·A·祖依德委尔德
A·A·巴提拿斯-格茨
G·D·布卡托夫
S·A·赛尔格夫
V·A·扎哈洛夫
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SABIC Global Technologies BV
Saudi Basic Industries Corp
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SABIC Global Technologies BV
Saudi Basic Industries Corp
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/651Pretreating with non-metals or metal-free compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652Pretreating with metals or metal-containing compounds
    • C08F4/656Pretreating with metals or metal-containing compounds with silicon or compounds thereof
    • C08F4/6565Pretreating with metals or metal-containing compounds with silicon or compounds thereof and magnesium or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/04Broad molecular weight distribution, i.e. Mw/Mn > 6
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/15Isotactic

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
CN201480074778.5A 2013-12-20 2014-12-19 用于烯烃聚合的催化剂体系 Active CN105940019B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP13199172 2013-12-20
EP13199172.1 2013-12-20
EP14170835 2014-06-02
EP14170835.4 2014-06-02
PCT/EP2014/078794 WO2015091980A1 (en) 2013-12-20 2014-12-19 Catalyst system for polymerization of an olefin

Publications (2)

Publication Number Publication Date
CN105940019A CN105940019A (zh) 2016-09-14
CN105940019B true CN105940019B (zh) 2018-05-18

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CN201480074778.5A Active CN105940019B (zh) 2013-12-20 2014-12-19 用于烯烃聚合的催化剂体系

Country Status (8)

Country Link
US (1) US9926391B2 (https=)
EP (1) EP3083717B1 (https=)
KR (1) KR102288227B1 (https=)
CN (1) CN105940019B (https=)
BR (1) BR112016013799B1 (https=)
EA (1) EA033164B1 (https=)
MX (1) MX2016008039A (https=)
WO (1) WO2015091980A1 (https=)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015091984A1 (en) 2013-12-20 2015-06-25 Saudi Basic Industries Corporation Procatalyst for polymerization of olefins
EP3083722B1 (en) 2013-12-20 2021-11-10 Saudi Basic Industries Corporation Catalyst system for polymerisation of an olefin
CN105934449B (zh) 2013-12-20 2018-07-10 沙特基础工业公司 用于烯烃聚合的催化剂组合物
CN105940023B (zh) 2013-12-20 2019-01-18 沙特基础工业公司 用于烯烃聚合的催化剂体系
MX2016008041A (es) 2013-12-20 2017-03-03 Saudi Basic Ind Corp Sistema catalizador para polimerizacion de una olefina.
US10059656B2 (en) 2013-12-20 2018-08-28 Sabic Global Technologies B.V. Catalyst composition for polymerization of olefins
EA038377B1 (ru) * 2015-12-02 2021-08-18 Сабик Глоубл Текнолоджиз Б.В. Прокатализатор для полимеризации олефинов
CN118515799A (zh) * 2016-10-12 2024-08-20 Sabic环球技术有限责任公司 制备适用于烯烃聚合的主催化剂的固体载体的方法
CN108570120B (zh) * 2017-03-10 2019-12-31 北京利和知信科技有限公司 含有邻苯二胺类化合物的固体催化剂组分和催化剂及其应用
EA202091168A1 (ru) 2017-12-28 2020-11-24 Бореалис Аг Катализатор и его получение

Family Cites Families (60)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5077357A (en) 1990-10-22 1991-12-31 Shell Oil Company Olefin polymerization catalyst
US5106806A (en) 1990-10-18 1992-04-21 Shell Oil Company Olefin polymerization catalyst
GB1128724A (en) 1966-05-30 1968-10-02 Mitsubishi Petrochemical Co Process for producing crystalline homopolymers or copolymers of olefin
IT1098272B (it) 1978-08-22 1985-09-07 Montedison Spa Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine
US4211670A (en) * 1979-01-25 1980-07-08 Hercules Incorporated Titanium trichloride catalyst component for propylene polymerization
CA1141093A (en) 1979-05-17 1983-02-08 Brian L. Goodall Olefin polymerization catalyst compositions and a process for the polymerization of olefins employing such compositions
US4246383A (en) * 1979-06-25 1981-01-20 The Dow Chemical Company Process for polymerizing olefins in the presence of a catalyst prepared from an organomagnesium component which does not reduce TiCl4
US4384087A (en) 1980-03-24 1983-05-17 Phillips Petroleum Company Composition of matter and method of preparing same, catalyst, method of producing the catalyst and polymerization process employing the catalyst
IT1190681B (it) 1982-02-12 1988-02-24 Montedison Spa Componenti e catalizzatori per la polimerizzazione di olefine
US4866022A (en) 1984-03-23 1989-09-12 Amoco Corporation Olefin polymerization catalyst
US5567665A (en) 1994-03-31 1996-10-22 Union Carbide Chemicals & Plastics Technology Corporation Shape-shifted magnesium alkoxide component for polymerizing olefins
US4771024A (en) 1986-02-28 1988-09-13 Shell Oil Company Olefin polymerization catalyst composition
US5093415A (en) 1987-05-19 1992-03-03 Union Carbide Chemicals & Plastics Technology Corporation Process for producing stereoregular polymers having a narrow molecular weight distribution
IT1227259B (it) 1988-09-30 1991-03-28 Himont Inc Catalizzatori per la polimerizzazione di olefine.
JP2838310B2 (ja) 1989-05-17 1998-12-16 三菱化学株式会社 オレフィン重合体の製造方法
US5556820A (en) 1989-12-28 1996-09-17 Idemitsu Petrochemical Co., Ltd. Catalyst component for olefin polymerization and process for producing polyolefins
CN1038755C (zh) * 1995-02-20 1998-06-17 三井石油化学工业株式会社 乙烯聚合物和乙烯聚合物的制备方法
WO1996032426A1 (en) 1995-04-10 1996-10-17 Dsm N.V. Method for the preparation of a catalyst suitable for the polymerisation of an olefine
US5820981A (en) 1996-04-02 1998-10-13 Montell North America Inc. Radiation visbroken polypropylene and fibers made therefrom
CA2204464A1 (en) 1996-11-06 1998-11-05 Ube Industries Limited Process for polymerization of .alpha.-olefin
WO1999057160A1 (en) 1998-05-06 1999-11-11 Montell Technology Company B.V. Catalyst components for the polymerization of olefins
EP1086961A1 (en) 1999-09-27 2001-03-28 Dsm N.V. Process for the preparation of a catalyst component for the polymerisation of an olefin
ES2224049T3 (es) 2001-03-05 2005-03-01 Stichting Dutch Polymer Institute Componente catalizador de la polimerizacion de olefinas, sistema catalizador y procedimiento de polimerizacion que usa dicho sitema catalizador.
ES2387885T5 (es) 2001-03-30 2019-11-28 Toho Titanium Co Ltd Procedimiento para producir un componente catalizador sólido para la polimerización de olefinas
US6825146B2 (en) 2001-05-29 2004-11-30 Union Carbide Chemicals & Plastics Technology Corporation Olefin polymerization catalyst compositions and method of preparation
PT1273595E (pt) 2001-06-20 2006-10-31 Borealis Tech Oy Preparacao de um componente catalisador para polimerizacao de olefina
ATE370184T1 (de) 2001-06-27 2007-09-15 Borealis Tech Oy Verfahren zur herstellung einer polymerfolie die ein statistisches propylencopolymer enthält
CN1169845C (zh) 2002-02-07 2004-10-06 中国石油化工股份有限公司 用于烯烃聚合的固体催化剂组分和含该催化剂组分的催化剂及其应用
BR0303381B1 (pt) 2002-03-08 2012-08-21 processo para preparar um componente catalìtico com base em diéter e processo para a homo- ou copolimerização de alfa-olefinas.
AU2003257555A1 (en) 2002-08-19 2004-03-03 Ube Industries, Ltd. CATALYSTS FOR POLYMERIZATION OR COPOLYMERIZATION OF Alpha-OLEFINS, CATALYST COMPONENTS THEREOF, AND PROCESSES FOR POLYMERIZATION OF Alpha-OLEFINS WITH THE CATALYSTS
JP4137736B2 (ja) 2003-07-28 2008-08-20 宇部興産株式会社 オレフィン類重合用触媒
EP1783145A1 (en) 2004-07-28 2007-05-09 Mitsui Chemicals, Inc. Olefin polymerization catalyst and method of polymerization using the catalyst
EP1781737B1 (en) 2004-07-30 2008-12-03 Saudi Basic Industries Corporation Propylene copolymer compositions with high transparency
EP1661917A1 (en) 2004-11-26 2006-05-31 Saudi Basic Industries Corporation (Sabic) Process for the preparation of a catalyst component for the polymerization of an olefin
EP1717269A1 (en) 2005-04-28 2006-11-02 Borealis Technology Oy Alpha-olefin homo-or copolymer compositions
EP1780225A1 (en) * 2005-11-01 2007-05-02 Borealis Technology Oy Ziegler-Natta catalyst and its use to prepare multimodal polyolefin
BRPI0711891B1 (pt) 2006-05-24 2018-05-02 Saudi Basic Industries Corporation Processo para a preparação de um componente catalisador para a polimerização de propileno
EP2845868A1 (en) 2006-05-31 2015-03-11 Borealis Technology Oy Oxidation state of Ti as means for increasing catalyst activity
CN101104656B (zh) 2006-07-13 2010-11-10 中国石油化工股份有限公司 用于烯烃聚合反应的催化剂组分及其催化剂
WO2008007770A1 (fr) 2006-07-14 2008-01-17 Dai Nippon Printing Co., Ltd. Film revêtu d'une couche conductrice transparente et son utilisation
JP2008106089A (ja) 2006-10-23 2008-05-08 Japan Polypropylene Corp ポリプロピレン系射出成形半導体関連部品搬送ケース
US8344079B2 (en) * 2007-12-31 2013-01-01 Basf Corporation Molar ratio modifications to larger polyolefin catalysts
CN102186889B (zh) 2008-08-21 2013-11-06 陶氏环球技术有限责任公司 具有混合的选择性控制剂的催化剂组合物和使用它的聚合反应方法
US8088872B2 (en) 2008-11-25 2012-01-03 Dow Global Technologies Llc Procatalyst composition including silyl ester internal donor and method
CN102333749B (zh) 2008-12-31 2015-04-22 陶氏环球技术有限责任公司 取代的亚苯基芳族二酯的生产方法
MY181149A (en) * 2010-02-26 2020-12-19 Grace W R & Co Amide ester internal electron donor and process
RU2632200C2 (ru) * 2010-02-26 2017-10-03 У.Р.Грейс Энд Ко.-Конн. Галогенированный сложный амидоэфир и его применение в качестве внутреннего донора электронов
EP2545087B1 (en) * 2010-02-26 2016-06-22 W.R. Grace & Co.-Conn. Procatalyst composition with substituted amide ester internal electron donor
EP2621961B1 (en) 2010-09-28 2016-12-07 Basell Polyolefine GmbH Method for feeding an antistatic compound to a polymerization reactor
KR101912965B1 (ko) * 2011-04-12 2019-01-14 바셀 폴리올레핀 이탈리아 에스.알.엘 올레핀 중합용 촉매 성분
EP2736971A1 (en) 2011-07-29 2014-06-04 Dow Global Technologies LLC Semi-crystalline polyolefin composition, method of producing the same, and articles made therefrom
MX2014010130A (es) 2012-02-22 2014-09-08 Saudi Basic Ind Corp Componente catalizador para la polimerizacion de olefinas.
EP2867264B1 (en) 2012-06-29 2016-04-20 Saudi Basic Industries Corporation Catalyst composition for polymerization of olefins
US9587051B2 (en) 2013-01-31 2017-03-07 Saudi Basic Industries Corporation Process for preparing a catalyst component for polymerization of olefins
CN105934449B (zh) 2013-12-20 2018-07-10 沙特基础工业公司 用于烯烃聚合的催化剂组合物
EP3083722B1 (en) 2013-12-20 2021-11-10 Saudi Basic Industries Corporation Catalyst system for polymerisation of an olefin
WO2015091984A1 (en) 2013-12-20 2015-06-25 Saudi Basic Industries Corporation Procatalyst for polymerization of olefins
US10059656B2 (en) 2013-12-20 2018-08-28 Sabic Global Technologies B.V. Catalyst composition for polymerization of olefins
CN105940023B (zh) 2013-12-20 2019-01-18 沙特基础工业公司 用于烯烃聚合的催化剂体系
MX2016008041A (es) 2013-12-20 2017-03-03 Saudi Basic Ind Corp Sistema catalizador para polimerizacion de una olefina.

Also Published As

Publication number Publication date
WO2015091980A1 (en) 2015-06-25
EA201691283A1 (ru) 2016-12-30
KR20160102020A (ko) 2016-08-26
EP3083717B1 (en) 2019-08-28
US9926391B2 (en) 2018-03-27
BR112016013799A2 (https=) 2017-08-08
EA033164B1 (ru) 2019-09-30
US20160311946A1 (en) 2016-10-27
MX2016008039A (es) 2017-05-12
EP3083717A1 (en) 2016-10-26
BR112016013799B1 (pt) 2022-02-22
CN105940019A (zh) 2016-09-14
KR102288227B1 (ko) 2021-08-11

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