CN105924913A - 一种可降解防潮阻燃蜂窝纸板的制备方法 - Google Patents
一种可降解防潮阻燃蜂窝纸板的制备方法 Download PDFInfo
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Abstract
本发明公开了一种可降解防潮阻燃蜂窝纸板的制备方法，采用阻燃聚乳酸聚合物、磷酸酯化淀粉‑聚氨酯和碳酸钙作为原料，经高温密炼制造成为造纸母粒再经流延机制成膜状，后再拉伸、冷却和定型、压平，制成原料纸，将原料纸复合、分切、连接制成蜂窝纸芯；并原料纸作为面板纸，将蜂窝纸芯涂胶后，与面板纸粘合制成蜂窝纸板，在面板纸上涂布一层防潮剂，所述防潮剂由改性醇酸树脂，松脂，茶树油，微晶蜡，甲基硅油，凡士林，氢氧化钠，乳化剂，分散剂组成。本发明所提供的一种可降解防潮阻燃蜂窝纸板的制备方法，采用非纸浆材料制备蜂窝纸板，制得的蜂窝纸板可降解，并具有阻燃、防潮、防菌特性，非常适合作为纸箱包装材料使用。
Description
技术领域
本发明涉及一种可降解防潮阻燃蜂窝纸板的制备方法，属于塑料纸制备技术领域。
背景技术
目前，国内外所使用的书写用纸、复制用纸、卫生用纸、生活用纸、装饰用纸等，多使用木浆、纸浆为原料的生产纸，这样就消耗料了大量的树木等自然资源。而且，造纸过程中消耗了大量的水，还产生了大量的污水对环境造成污染。所以，人们都在寻找新的材料代替纸浆生产纸用品，以解决资源问题和环境污染问题。
在寻找新的材料代替纸浆生产纸用品的过程中，人们逐渐把目光注意到塑料纸上，所谓塑料纸就是在聚乙烯、聚丙烯或聚氯乙烯等塑料中加入50～80wt％的碳酸钙钛白粉、二氧化硅、白土等矿石粉或者化学反应的粉末中的一种或几种，但这样的塑料纸不易降解，还会造成对环境的再次污染。
此外，不具有阻燃性质的瓦楞纸板在物流仓储等环节中存在火灾隐患，采用阻燃型包装纸板材料是降低火灾风险的主要措施之一，现有阻燃纸箱，多为在非阻燃材料上涂布一层阻燃剂，阻燃效果不佳。
另一方面，当储运环节比较恶劣时，还需要瓦楞纸箱具备一定的防潮、防水功能，尤其在湿热带和亚湿热带地区使用纸箱储存运输物资时，纸箱易受潮的同时，极易被霉菌等微生物污染，进而污染纸箱内所储存的物品。因此，为了保护商品安全地通过贮存、流通、销售等各个环节，必须使纸箱具有防霉防潮性能。
发明内容
本发明所要解决的技术问题是克服现有技术的缺陷，提供一种可降解防潮阻燃蜂窝纸板的制备方法，采用非纸浆材料制备蜂窝纸板，制得的蜂窝纸板可降解，并具有阻燃特性，同时还具有较好的防潮、抗菌、防蛀性能。
为解决上述技术问题，本发明提供一种可降解防潮阻燃蜂窝纸板的制备方法，包括以下步骤：
S1将阻燃聚乳酸聚合物、磷酸酯化淀粉-聚氨酯和碳酸钙原料放入密炼机中，高温密炼制造成为造纸母粒；将造纸母粒放入流延机制成膜状，后再拉伸、冷却和定型、 压平，制成原料纸；
S2，将原料纸复合、分切、连接制成蜂窝纸芯；
S3，原料纸作为面板纸，将蜂窝纸芯涂胶后，与面板纸粘合制成蜂窝纸板；
S4，在面板纸上涂布一层防潮剂，所述防潮剂由由改性醇酸树脂，松脂，茶树油，微晶蜡，甲基硅油，凡士林，氢氧化钠，乳化剂，分散剂组成。
所述阻燃聚乳酸聚合物为聚乳酸树脂、石墨层间化合物、抗氧剂、协同剂、成炭剂共混而成的混合物。
所述阻燃聚乳酸聚合物为聚乳酸树脂、有机改性土、抗氧剂、协同剂、成炭剂共混而成的混合物。
所述阻燃聚乳酸聚合物、磷酸酯化淀粉-聚氨酯和碳酸钙原料的质量比为30：30：40。
所述碳酸钙原料为碳酸钙粉末、高岭土、硬脂酸、淀粉和乙二醇的混合物。
所述防潮剂各组分的重量份数为改性醇酸树脂4~6份，松脂5~10份，茶树油1~15份，微晶蜡15~20份，甲基硅油5~10份，凡士林8~15份，氢氧化钠2~8份，乳化剂1~5份，分散剂50~70份。
本发明所达到的有益效果：
本发明采用阻燃聚乳酸聚合物、磷酸酯化淀粉-聚氨酯和碳酸钙作为原料，聚乳酸是一种来源于可再生农作物的生物可降解聚合物材料，无毒无刺激，易降解，其本身阻燃性能较差，但可通过对聚乳酸进行卤系、磷系、氮系、硅系、金属化合物阻燃剂、多种阻燃成分复配等方式进行阻燃改性；而磷酸酯化淀粉~聚氨酯材料通过对淀粉的磷酸酯化改性，并以磷酸酯化淀粉为反应性阻燃剂，合成出既具生物降解特性，又具阻燃特性的聚氨酯，将这两种具有可降解及阻燃特性的材料与碳酸钙混合，制得的原料纸具有良好的可降解及阻燃特性，既解决了传统纸质材料的资源匮问题，又解决了使用中的火灾隐患问题，并且不会造成对环境的二次污染。
本发明在面板纸上涂布一层防潮剂，所述防潮剂由改性醇酸树脂，松脂，茶树油，微晶蜡，甲基硅油，凡士林，氢氧化钠，乳化剂，分散剂组成，其中所含改性醇酸树脂，松脂，茶树油，微晶蜡，甲基硅油，凡士林等成分混合后与分散剂在乳化剂作用下形成稳定的乳化体系，将其涂布在纸板表面后可均匀覆盖在纸板外表面，形成一层隔水膜，以防止纸板吸水受潮，其中松脂、茶树油均有杀菌、驱虫作用，混合使用后使纸板具有良好的防霉防蛀效果，且所使用成分较安全，对人体无毒，对环境无污染。
因此，本发明所提供的一种可降解防潮阻燃蜂窝纸板的制备方法，采用非纸浆材料制备蜂窝纸板，制得的蜂窝纸板可降解，并具有阻燃、防潮、防菌特性，非常适合作为纸箱包装材料使用。
具体实施方式
下面对本发明作进一步描述。以下实施例仅用于更加清楚地说明本发明的技术方案，而不能以此来限制本发明的保护范围。
一种可降解防潮阻燃蜂窝纸板的制备方法，包括以下步骤：
S1将阻燃聚乳酸聚合物、磷酸酯化淀粉-聚氨酯和碳酸钙原料放入密炼机中，高温密炼制造成为造纸母粒；将造纸母粒放入流延机制成膜状，后再拉伸、冷却和定型、 压平，制成原料纸；
S2，将原料纸复合、分切、连接制成蜂窝纸芯；
S3，原料纸作为面板纸，将蜂窝纸芯涂胶后，与面板纸粘合制成蜂窝纸板；
S4，在面板纸上涂布一层防潮剂，所述防潮剂由由改性醇酸树脂，松脂，茶树油，微晶蜡，甲基硅油，凡士林，氢氧化钠，乳化剂，分散剂组成。
所述阻燃聚乳酸聚合物为聚乳酸树脂、石墨层间化合物、抗氧剂、协同剂、成炭剂共混而成的混合物。
所述阻燃聚乳酸聚合物为聚乳酸树脂、有机改性土、抗氧剂、协同剂、成炭剂共混而成的混合物。
所述阻燃聚乳酸聚合物、磷酸酯化淀粉-聚氨酯和碳酸钙原料的质量比为30：30：40。
所述碳酸钙原料为碳酸钙粉末、高岭土、硬脂酸、淀粉和乙二醇的混合物。
所述防潮剂各组分的重量份数为改性醇酸树脂4份，松脂5份，茶树油1份，微晶蜡15份，甲基硅油5份，凡士林8份，氢氧化钠2份，乳化剂1份，分散剂50份。
本发明所达到的有益效果：
本发明采用阻燃聚乳酸聚合物、磷酸酯化淀粉-聚氨酯和碳酸钙作为原料，聚乳酸是一种来源于可再生农作物的生物可降解聚合物材料，无毒无刺激，易降解，其本身阻燃性能较差，但可通过对聚乳酸进行卤系、磷系、氮系、硅系、金属化合物阻燃剂、多种阻燃成分复配等方式进行阻燃改性；而磷酸酯化淀粉-聚氨酯材料通过对淀粉的磷酸酯化改性，并以磷酸酯化淀粉为反应性阻燃剂，合成出既具生物降解特性，又具阻燃特性的聚氨酯，将这两种具有可降解及阻燃特性的材料与碳酸钙混合，制得的原料纸具有良好的可降解及阻燃特性，既解决了传统纸质材料的资源匮问题，又解决了使用中的火灾隐患问题，并且不会造成对环境的二次污染。
本发明在面板纸上涂布一层防潮剂，所述防潮剂由改性醇酸树脂，松脂，茶树油，微晶蜡，甲基硅油，凡士林，氢氧化钠，乳化剂，分散剂组成，其中所含改性醇酸树脂，松脂，茶树油，微晶蜡，甲基硅油，凡士林等成分混合后与分散剂在乳化剂作用下形成稳定的乳化体系，将其涂布在纸板表面后可均匀覆盖在纸板外表面，形成一层隔水膜，以防止纸板吸水受潮，其中松脂、茶树油均有杀菌、驱虫作用，混合使用后使纸板具有良好的防霉防蛀效果，且所使用成分较安全，对人体无毒，对环境无污染。
以上所述仅是本发明的优选实施方式，应当指出，对于本技术领域的普通技术人员来说，在不脱离本发明技术原理的前提下，还可以做出若干改进和变形，这些改进和变形也应视为本发明的保护范围。
Claims (6)
1.一种可降解防潮阻燃蜂窝纸板的制备方法，其特征在于，包括以下步骤：
S1将阻燃聚乳酸聚合物、磷酸酯化淀粉-聚氨酯和碳酸钙原料放入密炼机中，高温密炼制造成为造纸母粒；将造纸母粒放入流延机制成膜状，后再拉伸、冷却和定型、
压平，制成原料纸；
S2，将原料纸复合、分切、连接制成蜂窝纸芯；
S3，原料纸作为面板纸，将蜂窝纸芯涂胶后，与面板纸粘合制成蜂窝纸板；
S4，在面板纸上涂布一层防潮剂，所述防潮剂由由改性醇酸树脂，松脂，茶树油，微晶蜡，甲基硅油，凡士林，氢氧化钠，乳化剂，分散剂组成。
2.根据权利要求1所述的一种可降解防潮阻燃蜂窝纸板的制备方法，其特征在于， 所述阻燃聚乳酸聚合物为聚乳酸树脂、石墨层间化合物、抗氧剂、协同剂、成炭剂共混而成的混合物。
3.根据权利要求1所述的一种可降解防潮阻燃蜂窝纸板的制备方法，其特征在于，所述阻燃聚乳酸聚合物为聚乳酸树脂、有机改性土、抗氧剂、协同剂、成炭剂共混而成的混合物。
4.根据权利要求1所述的一种可降解防潮阻燃蜂窝纸板的制备方法，其特征在于，所述阻燃聚乳酸聚合物、磷酸酯化淀粉-聚氨酯和碳酸钙原料的质量比为30：30：40。
5.根据权利要求1所述的一种可降解防潮阻燃蜂窝纸板的制备方法，其特征在于，所述碳酸钙原料为碳酸钙粉末、高岭土、硬脂酸、淀粉和乙二醇的混合物。
6.根据权利要求1所述的一种可降解防潮阻燃蜂窝纸板的制备方法，其特征在于，所述防潮剂各组分的重量份数为改性醇酸树脂4~6份，松脂5~10份，茶树油1~15份，微晶蜡15~20份，甲基硅油5~10份，凡士林8~15份，氢氧化钠2~8份，乳化剂1~5份，分散剂50~70份。
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| Publication number | Priority date | Publication date | Assignee | Title |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103101228A (zh) * | 2012-11-14 | 2013-05-15 | 合肥朗胜新材料有限公司 | 一种改性纳米碳的蜂窝纸板的制作方法 |
| CN104098879A (zh) * | 2013-04-09 | 2014-10-15 | 汉达精密电子(昆山)有限公司 | 阻燃聚乳酸组合物及其制备方法 |
| CN104672417A (zh) * | 2015-03-17 | 2015-06-03 | 四川凯本新材料科技有限公司 | 一种可生物降解自阻燃聚氨酯发泡材料的制备方法 |
| CN104805731A (zh) * | 2015-04-24 | 2015-07-29 | 句容市鼎盛纸箱包装有限公司 | 一种纸箱防潮剂及其制备方法 |
-
2016
- 2016-04-28 CN CN201610271539.XA patent/CN105924913A/zh active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103101228A (zh) * | 2012-11-14 | 2013-05-15 | 合肥朗胜新材料有限公司 | 一种改性纳米碳的蜂窝纸板的制作方法 |
| CN104098879A (zh) * | 2013-04-09 | 2014-10-15 | 汉达精密电子(昆山)有限公司 | 阻燃聚乳酸组合物及其制备方法 |
| CN104672417A (zh) * | 2015-03-17 | 2015-06-03 | 四川凯本新材料科技有限公司 | 一种可生物降解自阻燃聚氨酯发泡材料的制备方法 |
| CN104805731A (zh) * | 2015-04-24 | 2015-07-29 | 句容市鼎盛纸箱包装有限公司 | 一种纸箱防潮剂及其制备方法 |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108060614A (zh) * | 2017-12-18 | 2018-05-22 | 温州市新丰装饰材料有限公司 | 一种防潮格拉辛离型纸的制备方法 |
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