CN105924679A - 一种纳米复合膨胀型阻燃剂及其制备方法 - Google Patents
一种纳米复合膨胀型阻燃剂及其制备方法 Download PDFInfo
- Publication number
- CN105924679A CN105924679A CN201610320040.3A CN201610320040A CN105924679A CN 105924679 A CN105924679 A CN 105924679A CN 201610320040 A CN201610320040 A CN 201610320040A CN 105924679 A CN105924679 A CN 105924679A
- Authority
- CN
- China
- Prior art keywords
- crystalline state
- flame retardant
- app
- nano
- intumescent flame
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003063 flame retardant Substances 0.000 title claims abstract description 33
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 28
- 239000002114 nanocomposite Substances 0.000 title claims abstract description 26
- 238000000034 method Methods 0.000 title claims abstract description 9
- 239000001913 cellulose Substances 0.000 claims abstract description 35
- 229920002678 cellulose Polymers 0.000 claims abstract description 35
- 239000000084 colloidal system Substances 0.000 claims abstract description 29
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 16
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims abstract description 16
- 239000005543 nano-size silicon particle Substances 0.000 claims abstract description 15
- 238000010438 heat treatment Methods 0.000 claims abstract description 11
- 239000011780 sodium chloride Substances 0.000 claims abstract description 8
- 230000033228 biological regulation Effects 0.000 claims abstract description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 5
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 14
- 239000002131 composite material Substances 0.000 claims description 11
- 229910021529 ammonia Inorganic materials 0.000 claims description 7
- 230000015572 biosynthetic process Effects 0.000 claims description 5
- 239000012153 distilled water Substances 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- 229920000137 polyphosphoric acid Polymers 0.000 claims description 4
- 239000003292 glue Substances 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 1
- 238000006116 polymerization reaction Methods 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 11
- 229920001587 Wood-plastic composite Polymers 0.000 abstract description 8
- 239000011155 wood-plastic composite Substances 0.000 abstract description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 7
- 239000001301 oxygen Substances 0.000 abstract description 7
- 229910052760 oxygen Inorganic materials 0.000 abstract description 7
- 238000003756 stirring Methods 0.000 abstract description 4
- 239000004114 Ammonium polyphosphate Substances 0.000 abstract 2
- 235000019826 ammonium polyphosphate Nutrition 0.000 abstract 2
- 229920001276 ammonium polyphosphate Polymers 0.000 abstract 2
- 238000012769 bulk production Methods 0.000 abstract 1
- 238000013329 compounding Methods 0.000 abstract 1
- 235000019441 ethanol Nutrition 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 4
- 238000011056 performance test Methods 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- XYIBRDXRRQCHLP-UHFFFAOYSA-N ethyl acetoacetate Chemical compound CCOC(=O)CC(C)=O XYIBRDXRRQCHLP-UHFFFAOYSA-N 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 239000002023 wood Substances 0.000 description 3
- 241000209094 Oryza Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 231100000053 low toxicity Toxicity 0.000 description 2
- 230000000979 retarding effect Effects 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- 210000001367 artery Anatomy 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000003913 materials processing Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 239000002121 nanofiber Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 125000004469 siloxy group Chemical group [SiH3]O* 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L97/00—Compositions of lignin-containing materials
- C08L97/02—Lignocellulosic material, e.g. wood, straw or bagasse
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/322—Ammonium phosphate
- C08K2003/323—Ammonium polyphosphate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
Abstract
Description
Claims (2)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610320040.3A CN105924679B (zh) | 2016-05-11 | 2016-05-11 | 一种纳米复合膨胀型阻燃剂及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610320040.3A CN105924679B (zh) | 2016-05-11 | 2016-05-11 | 一种纳米复合膨胀型阻燃剂及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN105924679A true CN105924679A (zh) | 2016-09-07 |
CN105924679B CN105924679B (zh) | 2018-03-06 |
Family
ID=56835826
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201610320040.3A Expired - Fee Related CN105924679B (zh) | 2016-05-11 | 2016-05-11 | 一种纳米复合膨胀型阻燃剂及其制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN105924679B (zh) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106752055A (zh) * | 2017-01-05 | 2017-05-31 | 南京林业大学 | 一种层层自组装阻燃木塑复合材料的制备方法 |
CN106832571A (zh) * | 2016-12-22 | 2017-06-13 | 阜阳市三郁包装材料有限公司 | 一种杂化纤维素硅气凝胶改性的阻燃聚丙烯发泡板及其制备方法 |
CN107129599A (zh) * | 2017-06-20 | 2017-09-05 | 南京林业大学 | 一种纳米纤维素模板制备膨胀型阻燃剂的方法 |
CN111421632A (zh) * | 2020-02-27 | 2020-07-17 | 南京林业大学 | 一种功能性竹或木单板加工方法 |
CN113818105A (zh) * | 2021-09-10 | 2021-12-21 | 潍坊欣龙生物材料有限公司 | 一种改性膨胀型阻燃纤维素纤维的制备方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101864215A (zh) * | 2009-04-15 | 2010-10-20 | 江苏省华建建设股份有限公司 | 环保型钢结构防火涂料及其制备方法 |
CN102702767A (zh) * | 2012-06-01 | 2012-10-03 | 南京林业大学 | 一种协效阻燃木塑复合材料及其制造方法 |
CN103319111A (zh) * | 2013-05-10 | 2013-09-25 | 张洋 | 一种新型复合耐热材料 |
CN105034108A (zh) * | 2015-06-19 | 2015-11-11 | 南京林业大学 | 一种纳米微晶纤维素模板制备高分散性聚磷酸铵胶体的方法 |
-
2016
- 2016-05-11 CN CN201610320040.3A patent/CN105924679B/zh not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101864215A (zh) * | 2009-04-15 | 2010-10-20 | 江苏省华建建设股份有限公司 | 环保型钢结构防火涂料及其制备方法 |
CN102702767A (zh) * | 2012-06-01 | 2012-10-03 | 南京林业大学 | 一种协效阻燃木塑复合材料及其制造方法 |
CN103319111A (zh) * | 2013-05-10 | 2013-09-25 | 张洋 | 一种新型复合耐热材料 |
CN105034108A (zh) * | 2015-06-19 | 2015-11-11 | 南京林业大学 | 一种纳米微晶纤维素模板制备高分散性聚磷酸铵胶体的方法 |
Non-Patent Citations (5)
Title |
---|
MINGZHU PAN等: "Synergistic effect of nano silicon dioxide and ammonium polyphosphate on flame retardancy of wood fiber–polyethylene composites", 《COMPOSITES: PART A》 * |
PAN MINGZHU 等: "Flammability of nano silicon dioxide–wood fiber–polyethylene composites", 《JOURNAL OF COMPOSITE MATERIALS》 * |
刘丽华 等: "阻燃纳米二氧化硅气凝胶的仿生制备进展", 《广州化工》 * |
潘明珠 等: "纳米SiO2-APP对木塑复合材料界面特性及力学性能的影响", 《北京林业大学学报》 * |
蔡欣 等: "晶态纳米纤维素/聚磷酸铵胶体对刨花板性能的影响", 《林产工业》 * |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106832571A (zh) * | 2016-12-22 | 2017-06-13 | 阜阳市三郁包装材料有限公司 | 一种杂化纤维素硅气凝胶改性的阻燃聚丙烯发泡板及其制备方法 |
CN106752055A (zh) * | 2017-01-05 | 2017-05-31 | 南京林业大学 | 一种层层自组装阻燃木塑复合材料的制备方法 |
CN106752055B (zh) * | 2017-01-05 | 2019-04-12 | 南京林业大学 | 一种层层自组装阻燃木塑复合材料的制备方法 |
CN107129599A (zh) * | 2017-06-20 | 2017-09-05 | 南京林业大学 | 一种纳米纤维素模板制备膨胀型阻燃剂的方法 |
CN107129599B (zh) * | 2017-06-20 | 2019-09-10 | 南京林业大学 | 一种纳米纤维素模板制备膨胀型阻燃剂的方法 |
CN111421632A (zh) * | 2020-02-27 | 2020-07-17 | 南京林业大学 | 一种功能性竹或木单板加工方法 |
CN111421632B (zh) * | 2020-02-27 | 2021-11-09 | 南京林业大学 | 一种功能性竹或木单板加工方法 |
CN113818105A (zh) * | 2021-09-10 | 2021-12-21 | 潍坊欣龙生物材料有限公司 | 一种改性膨胀型阻燃纤维素纤维的制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN105924679B (zh) | 2018-03-06 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN105924679A (zh) | 一种纳米复合膨胀型阻燃剂及其制备方法 | |
Zhang et al. | Nickel metal–organic framework derived hierarchically mesoporous nickel phosphate toward smoke suppression and mechanical enhancement of intumescent flame retardant wood fiber/poly (lactic acid) composites | |
CN105034108B (zh) | 一种纳米微晶纤维素模板制备高分散性聚磷酸铵胶体的方法 | |
Zhang et al. | Chitosan/phytic acid polyelectrolyte complex: a green and renewable intumescent flame retardant system for ethylene–vinyl acetate copolymer | |
CN102391797B (zh) | 建筑用玉米淀粉胶粘剂及其制备方法 | |
CN106752055B (zh) | 一种层层自组装阻燃木塑复合材料的制备方法 | |
CN105504352B (zh) | 一种磷氮系树枝状大分子功能化石墨烯阻燃剂及其应用 | |
CN112876740B (zh) | 一种苯硼酸接枝改性磷酸锆基阻燃剂及其制备方法 | |
CN107815116B (zh) | 一种石墨烯杂化粒子阻燃剂及其制备方法和应用 | |
CN101942227B (zh) | 一种提高聚磷酸铵耐水性的方法 | |
WO2023039939A1 (zh) | 一种纳米磷酸锆基阻燃抑菌剂及其制备的膨胀型防火抑菌涂料 | |
CN106146866B (zh) | 一种聚酰亚胺复合薄膜及其制备方法 | |
CN101775161A (zh) | 用微波远红外方法生产变性淀粉的工艺 | |
CN104986982B (zh) | 一种氧化石墨烯阻燃秸秆材料及其制备方法 | |
Gao et al. | Design, preparation, and application of a novel, microencapsulated, intumescent, flame-retardant-based mimicking mussel | |
CN105566682A (zh) | 一种基于核苷酸的阻燃微球及其制备方法和应用 | |
CN106003887B (zh) | 一种膨胀型复合阻燃膜及其制备方法 | |
Zhang et al. | Facile Strategy to Design a Cellulose Nanocrystal-Based Nanocomposite Fire Retardant with Strong Smoke Suppression Efficiency | |
CN109897232A (zh) | 一种改性可降解薄膜材料的方法 | |
CN105860594A (zh) | 一种有机硅改性超细次磷酸铝的合成方法 | |
CN109056411A (zh) | 一种核壳结构的纸用阻燃剂及其制备方法和应用 | |
CN101475645A (zh) | 高均匀性羧甲基纤维素钠的制备方法 | |
CN107129599B (zh) | 一种纳米纤维素模板制备膨胀型阻燃剂的方法 | |
CN105542332A (zh) | 一种制备聚苯乙烯/石墨烯/贵金属复合粒子的方法 | |
CN108912671A (zh) | 一种三聚氰胺改性木质素/氢氧化镁双重包覆红磷阻燃剂及其在pa6树脂中的应用 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20160907 Assignee: Guangxi Prince Wood Industry Co.,Ltd. Assignor: NANJING FORESTRY University Contract record no.: X2020980002822 Denomination of invention: Nano composite intumescent flame retardant and preparation method thereof Granted publication date: 20180306 License type: Common License Record date: 20200605 |
|
EE01 | Entry into force of recordation of patent licensing contract | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20180306 |