CN105924459A - 一种钕配合物及其制备方法和应用 - Google Patents
一种钕配合物及其制备方法和应用 Download PDFInfo
- Publication number
- CN105924459A CN105924459A CN201610278006.4A CN201610278006A CN105924459A CN 105924459 A CN105924459 A CN 105924459A CN 201610278006 A CN201610278006 A CN 201610278006A CN 105924459 A CN105924459 A CN 105924459A
- Authority
- CN
- China
- Prior art keywords
- complex
- preparation
- methylene blue
- neodymium
- room temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 title abstract description 5
- 229910052779 Neodymium Inorganic materials 0.000 title abstract 4
- 238000010668 complexation reaction Methods 0.000 title description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 23
- RBTBFTRPCNLSDE-UHFFFAOYSA-N 3,7-bis(dimethylamino)phenothiazin-5-ium Chemical compound C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 RBTBFTRPCNLSDE-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229960000907 methylthioninium chloride Drugs 0.000 claims abstract description 17
- 230000015556 catabolic process Effects 0.000 claims abstract description 10
- 238000006731 degradation reaction Methods 0.000 claims abstract description 10
- 238000001914 filtration Methods 0.000 claims abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000000975 dye Substances 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 7
- 244000178870 Lavandula angustifolia Species 0.000 claims description 3
- 235000010663 Lavandula angustifolia Nutrition 0.000 claims description 3
- 229910017544 NdCl3 Inorganic materials 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 230000033228 biological regulation Effects 0.000 claims description 3
- 239000001102 lavandula vera Substances 0.000 claims description 3
- 235000018219 lavender Nutrition 0.000 claims description 3
- ATINCSYRHURBSP-UHFFFAOYSA-K neodymium(iii) chloride Chemical compound Cl[Nd](Cl)Cl ATINCSYRHURBSP-UHFFFAOYSA-K 0.000 claims description 3
- 239000000706 filtrate Substances 0.000 claims description 2
- 239000000047 product Substances 0.000 claims description 2
- XOAGCJPTMIRCMN-KCJUWKMLSA-N (2S,3S)-2-benzyl-2,3-dihydroxybutanedioic acid Chemical compound C(C1=CC=CC=C1)[C@](C(=O)O)(O)[C@H](O)C(=O)O XOAGCJPTMIRCMN-KCJUWKMLSA-N 0.000 claims 1
- 230000003197 catalytic effect Effects 0.000 abstract description 6
- 239000013078 crystal Substances 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 6
- 239000001045 blue dye Substances 0.000 abstract description 5
- 239000003054 catalyst Substances 0.000 abstract description 4
- GRVDJDISBSALJP-UHFFFAOYSA-N methyloxidanyl Chemical compound [O]C GRVDJDISBSALJP-UHFFFAOYSA-N 0.000 abstract description 3
- -1 neodymium ions Chemical class 0.000 abstract description 2
- VKIBVKXPIIXYBK-DOMZBBRYSA-N (2S,3S)-2-(2,3-diacetyl-4-methylphenyl)-2,3-dihydroxybutanedioic acid Chemical compound C(C)(=O)C1=C(C=CC(=C1C(C)=O)[C@](C(=O)O)(O)[C@H](O)C(=O)O)C VKIBVKXPIIXYBK-DOMZBBRYSA-N 0.000 abstract 1
- 150000001450 anions Chemical class 0.000 abstract 1
- 230000000593 degrading effect Effects 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- LUMVCLJFHCTMCV-UHFFFAOYSA-M potassium;hydroxide;hydrate Chemical compound O.[OH-].[K+] LUMVCLJFHCTMCV-UHFFFAOYSA-M 0.000 abstract 1
- 230000001105 regulatory effect Effects 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 description 14
- 238000000034 method Methods 0.000 description 10
- 239000000243 solution Substances 0.000 description 5
- 230000036561 sun exposure Effects 0.000 description 5
- 238000004043 dyeing Methods 0.000 description 4
- 239000002351 wastewater Substances 0.000 description 4
- 229960001270 d- tartaric acid Drugs 0.000 description 3
- 238000013033 photocatalytic degradation reaction Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000006555 catalytic reaction Methods 0.000 description 2
- 125000004430 oxygen atom Chemical group O* 0.000 description 2
- 239000011941 photocatalyst Substances 0.000 description 2
- 238000000634 powder X-ray diffraction Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- AGIJRRREJXSQJR-UHFFFAOYSA-N 2h-thiazine Chemical compound N1SC=CC=C1 AGIJRRREJXSQJR-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 238000002835 absorbance Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000000862 absorption spectrum Methods 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000004696 coordination complex Chemical class 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 238000005564 crystal structure determination Methods 0.000 description 1
- 238000002447 crystallographic data Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- ZHUXMBYIONRQQX-UHFFFAOYSA-N hydroxidodioxidocarbon(.) Chemical group [O]C(O)=O ZHUXMBYIONRQQX-UHFFFAOYSA-N 0.000 description 1
- 239000010842 industrial wastewater Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- MCPLVIGCWWTHFH-UHFFFAOYSA-L methyl blue Chemical compound [Na+].[Na+].C1=CC(S(=O)(=O)[O-])=CC=C1NC1=CC=C(C(=C2C=CC(C=C2)=[NH+]C=2C=CC(=CC=2)S([O-])(=O)=O)C=2C=CC(NC=3C=CC(=CC=3)S([O-])(=O)=O)=CC=2)C=C1 MCPLVIGCWWTHFH-UHFFFAOYSA-L 0.000 description 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
- 239000002957 persistent organic pollutant Substances 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 230000005469 synchrotron radiation Effects 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/003—Compounds containing elements of Groups 3 or 13 of the Periodic Table without C-Metal linkages
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/39—Photocatalytic properties
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
- B01J2531/38—Lanthanides other than lanthanum
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/40—Organic compounds containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/30—Nature of the water, waste water, sewage or sludge to be treated from the textile industry
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/10—Photocatalysts
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B2200/00—Indexing scheme relating to specific properties of organic compounds
- C07B2200/13—Crystalline forms, e.g. polymorphs
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Toxicology (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
本发明涉及一种钕配合物及其制备方法，结构简式为：[Nd(D‑DTTA)3(CH3O)3]n，其中D‑H2DTTA为(+)‑2,3‑二乙酰对甲苯‑D‑酒石酸，CH3OH为甲醇。制备方法：将D‑H2DTTA的甲醇溶液和NdCl3·3H2O水溶液混合，加入一定量的KOH水溶液调pH至3.0～4.5，搅拌，静置，直到有淡紫色三棱柱状晶体充分析出，过滤，收集产品，产率为40％。该配合物结构中包含九配位的钕离子，配体分别为D‑DTTA2‑和CH3O‑阴离子。在室温、日光照射下该配合物对亚甲基蓝染料具有很好的催化降解效果，可以用作降解亚甲基蓝染料的催化剂。
Description
技术领域
本发明涉及金属配合物，具体涉及一种一维链状钕配合物，特别是一种基于钕(III)离子和(+)-2,3-二乙酰对甲苯-D-酒石酸钕配合物的制备，以及该钕配合物在降解亚甲基蓝染料中的应用。
背景技术
我国是全球染料业第一大国，印染废水已成为我国工业废水主要来源之一。印染废水中含有大量以芳环为母体的有机组分，它们的处理和降解已成为当前环境工作的重点与难点之一。以亚甲基蓝为例，亚甲基蓝(MB)是一种硫氮杂苯染料，广泛应用于化学指示剂、染料、生物染色剂和药物等方面，不易被降解，是印染废水的典型代表，容易引起一系列环境问题。目前，国内外处理印染废水的主要方法包括物理法、化学法、物理化学法、生物化学法等。其中，光催化降解法是近几十年发展起来的处理污水的新方法。光催化降解法能有效降解多种有机污染物并将其矿化为CO2、H2O或毒性更小的有机物，是一种节能、高效、污染物降解彻底的处理方法。常用的光催化降解催化剂包括金属氧化物、硫化物、配合物和分子筛等，其中金属配合物类光催化剂由于本身易形成超分子聚集体，易于过滤，而且其多孔、多层、网状等特殊的结构使其具有较大比表面积，使催化活性的点位有所增加，并使反应中产物或底物具有较快的扩散速度，可有效提高其再生和回收效率，因此研究这类光催化剂的分子结构和光催化活性之间的规律，可以为设计和合成具有高效催化活性的催化剂提供理论借鉴和实际帮助。
发明内容
本发明的目的是提供一种钕配合物及其制备方法，以及该钕配合物在降解亚甲基蓝染料中的应用。
本发明提供的一种钕配合物，结构简式为：[Nd(D-DTTA)3(CH3O)3]n，其中D-H2DTTA为(+)-2,3-二乙酰对甲苯-D-酒石酸，CH3OH为甲醇。其化学结构式为：
该配合物的晶体属于三方晶系，空间群为R3，晶胞参数： α＝β＝90°，γ＝120°。该配合物中钕离子采用九配位模式，与Nd(III)配位的氧原子分别来自六个DTTA2-中的羧基氧原子(O4,O4B,O4D,O5A,O5C,O5E)和三个配位甲醇分子中的氧原子(O9,O9B,O9D)，通过配体两端羧基桥连Nd(III)离子在c方向形成无限的一维链状结构。Nd-O键长的范围为X射线粉末衍射证实晶体样品均一稳定。在室温条件、日光照射下该配合物对亚甲基蓝染料具有很好的降解效果，可以用作降解亚甲基蓝染料的催化剂。
本发明提供的一种钕配合物的制备方法，包括如下步骤：
((1)将摩尔比为1:1～1.5的NdCl3·3H2O和(+)-2,3-二乙酰对甲苯-D-酒石酸分别溶解于水和甲醇中，将二者混合；
(2)室温下搅拌均匀，并加入适量KOH水溶液，调节pH至3.0～4.5，常温搅拌7-10小时，过滤，将滤液于室温条件下静置，直到有淡紫色三棱柱状单晶充分析出，过滤，收集产品。
优选调节pH为3.5，优选NdCl3·3H2O和(+)-2,3-二乙酰对甲苯-D-酒石酸的摩尔比为1:1.5时晶体质量最好，产率最高。
只有溶剂为甲醇和水时才能得到该配合物的晶体。
本发明的优点和效果：
本发明提供的钕配合物是基于(+)-2,3-二乙酰对甲苯-D-酒石酸配体构成的一种新配合物，使用常规化学合成方法，制备方法工艺简单，样品稳定性好，纯度高，成本低，推广应用前景良好。在常温、日光照射条件下可快速催化降解亚甲基蓝染料，40分钟降解率可达78％；120分钟降解率可达85％。
附图说明
图1实施例1制备的钕配合物的不对称结构单元及钕离子配位的单晶结构图。
图2实施例1制备的钕配合物在298K的X射线粉末衍射图(实验及模拟图)。
图3本发明配合物存在下，在室温条件日光照射下亚甲基蓝溶液的紫外吸收光谱。
图4室温条件日光照射下，本发明配合物对亚甲基蓝的催化降解以及不加配合物的对比试验。
具体实施方式
下面结合附图和实例对本发明作进一步说明。
实施例1.将D-H2DTTA(0.1mmol,0.0386g)溶于2.5mL甲醇中，然后加入2.5mLNdCl3·3H2O(0.066mmol,0.0165g)的水溶液，常温搅拌10分钟，再向其中缓慢加入KOH溶液(0.2mol/L,150μL)，常温搅拌7小时，过滤后将得到的澄清溶液置于室温下，2天后有淡紫色三棱柱状单晶析出，过滤收集，产率约为40％。
钕配合物的结构测定：
晶体结构测定采用北京同步辐射1W2B工作线站光源为入射辐射，MAR165CCD探测器，marccd和HKL2000程序收集并还原数据，经过最小二乘法修正得到晶胞参数，从差值Fourier电子密度图利用SHELXL-97直接法解得晶体结构，并经Lorentz和极化效应修正。C原子采用理论加氢。详细的晶体测定数据见表1。结构见图1。
表1配合物的晶体学数据
实施例2：本发明配合物在室温、日光照射条件下对亚甲基蓝染料的催化降解。
室温条件下，将15ml 0.03mmol/L的亚甲基蓝溶液在黑暗处机械搅拌10分钟，测其吸光度，再将2.0mg本发明配合物分散到亚甲基蓝溶液中得到悬浊液。将悬浊液置于普通日光下照射，并不停进行搅拌，每20分钟取1次样品，测试其吸收曲线。如图3所示，120分钟后配合物对亚甲基蓝的催化降解达到85％。相比之下，在同样的条件下，如果体系中不使用配合物，则120分钟后，亚甲基蓝基本不降解，如图4所示。结果表明，本发明配合物对亚甲基蓝染料的降解具有很好的催化效果。
Claims (6)
1.一种钕配合物，其特征在于，结构式为：
2.如权利要求1所述的一种钕配合物的制备方法，其特征在于，包括如下步骤：
(1)将摩尔比为1:1～1.5的NdCl3·3H2O和(+)-2,3-二乙酰对甲苯-D-酒石酸分别溶解于水和甲醇中，将二者混合；
(2)室温下搅拌均匀，并加入适量KOH水溶液，调节pH至3.0～4.5，常温搅拌7～10小时，过滤，将滤液于室温条件下静置，直到有淡紫色三棱柱状单晶充分析出，过滤，收集产品。
3.如权利要求2所述的一种钕配合物的制备方法，其特征在于，所述NdCl3·3H2O和(+)-2,3-二乙酰对甲苯-D-酒石酸的摩尔比为1:1.5。
4.如权利要求2所述的一种钕配合物的制备方法，其特征在于，所述常温搅拌7小时。
5.如权利要求2所述的一种钕配合物的制备方法，其特征在于，所述调节pH至3.5。
6.如权利要求1所述的一种钕配合物在降解亚甲基蓝染料中的应用。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610278006.4A CN105924459B (zh) | 2016-04-29 | 2016-04-29 | 一种钕配合物及其制备方法和应用 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610278006.4A CN105924459B (zh) | 2016-04-29 | 2016-04-29 | 一种钕配合物及其制备方法和应用 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105924459A true CN105924459A (zh) | 2016-09-07 |
| CN105924459B CN105924459B (zh) | 2018-04-03 |
Family
ID=56836742
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610278006.4A Expired - Fee Related CN105924459B (zh) | 2016-04-29 | 2016-04-29 | 一种钕配合物及其制备方法和应用 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105924459B (zh) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106633096A (zh) * | 2017-01-09 | 2017-05-10 | 山西大学 | 一种双核铕(iii)配位聚合物及其制备方法与应用 |
| CN109485606A (zh) * | 2018-10-19 | 2019-03-19 | 江苏理工学院 | 纳米管结构的吡唑啉酮锌配合物及其制备方法和应用 |
| CN109806912A (zh) * | 2019-03-11 | 2019-05-28 | 山西大学 | 可磁回收的钕配合物/GO/Fe3O4三元复合物及其制备方法和应用 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101921285A (zh) * | 2009-06-15 | 2010-12-22 | 浙江师范大学 | 溶剂热合成d-酒石酸稀土配合物的方法 |
| CN101921187A (zh) * | 2009-06-15 | 2010-12-22 | 浙江师范大学 | 溶剂热合成l-酒石酸稀土配合物的方法 |
| CN103949261A (zh) * | 2014-04-10 | 2014-07-30 | 西安工程大学 | 稀土钕掺杂纳米三氧化二铁改性空心玻璃微珠的制备方法 |
-
2016
- 2016-04-29 CN CN201610278006.4A patent/CN105924459B/zh not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101921285A (zh) * | 2009-06-15 | 2010-12-22 | 浙江师范大学 | 溶剂热合成d-酒石酸稀土配合物的方法 |
| CN101921187A (zh) * | 2009-06-15 | 2010-12-22 | 浙江师范大学 | 溶剂热合成l-酒石酸稀土配合物的方法 |
| CN103949261A (zh) * | 2014-04-10 | 2014-07-30 | 西安工程大学 | 稀土钕掺杂纳米三氧化二铁改性空心玻璃微珠的制备方法 |
Non-Patent Citations (2)
| Title |
|---|
| 苏晓红: "L-DMTA/DTTA稀土配合物的合成、结构及发光性能研究", 《中国优秀硕士学位论文全文数据库 工程科技Ⅰ辑》 * |
| 韩忠华: "D-H2DBTA稀土配合物的合成及荧光性能研究", 《中国优秀硕士学位论文全文数据库 工程科技I辑》 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106633096A (zh) * | 2017-01-09 | 2017-05-10 | 山西大学 | 一种双核铕(iii)配位聚合物及其制备方法与应用 |
| CN109485606A (zh) * | 2018-10-19 | 2019-03-19 | 江苏理工学院 | 纳米管结构的吡唑啉酮锌配合物及其制备方法和应用 |
| CN109485606B (zh) * | 2018-10-19 | 2021-10-19 | 江苏理工学院 | 纳米管结构的吡唑啉酮锌配合物及其制备方法和应用 |
| CN109806912A (zh) * | 2019-03-11 | 2019-05-28 | 山西大学 | 可磁回收的钕配合物/GO/Fe3O4三元复合物及其制备方法和应用 |
| CN109806912B (zh) * | 2019-03-11 | 2021-05-14 | 山西大学 | 可磁回收的钕配合物/GO/Fe3O4三元复合物及其制备方法和应用 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105924459B (zh) | 2018-04-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Zhou et al. | Facile fabrication and enhanced photocatalytic performance of visible light responsive UiO-66-NH2/Ag2CO3 composite | |
| CN101791558B (zh) | 中空结构铁酸铋微球光催化剂及其制备方法 | |
| CN103386304B (zh) | 用于挥发性有机化合物催化燃烧的催化剂的制备方法 | |
| CN103316714A (zh) | 一种光催化分解水制氢用催化剂及其制备方法 | |
| CN101367042B (zh) | 一种掺杂二氧化钛光催化剂的制备方法 | |
| CN105879715A (zh) | 一种聚醚砜支撑体上金属有机骨架膜的制备方法 | |
| CN103447090B (zh) | 一种对甲基苯甲酸铀酰配合物光催化剂 | |
| CN105924459B (zh) | 一种钕配合物及其制备方法和应用 | |
| CN104525266A (zh) | 一种金属有机骨架材料光催化剂的制备方法与应用 | |
| CN105367591B (zh) | 一种具有催化光降解亚甲基蓝的镉配合物单晶及其制备方法 | |
| CN109967128B (zh) | 一种降解罗丹明b的光催化复合材料及其制备方法和应用 | |
| CN111450858B (zh) | 一种复合光催化剂Ag/AgCl@Co3O4的制备方法及由此制得的复合光催化剂 | |
| CN109225331A (zh) | 一种金属卟啉骨架材料敏化的二氧化钛可见光响应的光催化剂的制备方法 | |
| CN115254189B (zh) | 一种铁尾矿砂mof复合光催化剂及其制备方法、应用 | |
| CN104262275B (zh) | 一种银-偶氮四唑金属有机框架材料及其制备方法和应用 | |
| CN105061474B (zh) | 一种铜配合物及其制备方法和应用 | |
| CN107486213B (zh) | 一种中空BiVO4微米片光催化剂的制备方法 | |
| CN104258907B (zh) | 一种银-氨基四唑金属有机框架材料及其制备方法和应用 | |
| Zhu et al. | Synergistic photocatalysis of bimetal mixed ZIFs in enhancing degradation of organic pollutants: Experimental and computational studies | |
| CN113398995B (zh) | 光催化剂1-(氨甲基)环己基乙酸缩水杨醛席夫碱-铜(ii)微晶的合成及应用 | |
| CN104399531A (zh) | 一种AgI基无机-有机杂化半导体材料的合成及光催化降解染料的应用 | |
| CN106000433B (zh) | 一种Bi(Ⅲ)‑金属氧簇无机骨架及其制备方法与应用 | |
| CN111171054A (zh) | 具有催化光降解和吸附染料性质的铜配合物及其制备方法 | |
| CN108250450A (zh) | 一种镉配位聚合物及其制备方法和用途 | |
| CN110105584B (zh) | 多孔镉/铜掺杂配合物及其制备方法和应用 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20180403 Termination date: 20210429 |