CN105918334A - Sterilization composition containing pyribencarb and boscalid - Google Patents
Sterilization composition containing pyribencarb and boscalid Download PDFInfo
- Publication number
- CN105918334A CN105918334A CN201610266474.XA CN201610266474A CN105918334A CN 105918334 A CN105918334 A CN 105918334A CN 201610266474 A CN201610266474 A CN 201610266474A CN 105918334 A CN105918334 A CN 105918334A
- Authority
- CN
- China
- Prior art keywords
- boscalid
- pyrrole bacterium
- benzene prestige
- bacterium benzene
- pyribencarb
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a sterilization composition containing pyribencarb and boscalid. The sterilization composition comprises pyribencarb, boscalid, and a pesticide preparation auxiliary component, a weight part ratio of pyribencarb to boscalid is 1:10-10:1, and the sum of weight percentages of pyribencarb and boscalid in the sterilization composition is 5-70%. The sterilization composition is suitable for preventing and controlling cucumber powdery mildew. The composition has an obvious synergistic effect than single doses in prevention and control, reduces the use dosage of pesticides, reduces the pesticide use frequency, reduces the pesticide use cost, reduces untoward effects of the pesticides on the ecology environment, is safe to crops, and is of great significance to comprehensively treat the disease resistance.
Description
Technical field
The present invention relates to a kind of agricultural bactericidal composition, effective ingredient includes pyrrole bacterium benzene prestige, pyridine acyl
Bacterium amine.
Background technology
Pyrrole bacterium benzene prestige, belongs to the novel antibacterial of Benzylcarbamate structure, main by broken
MC electron transport system in bad pathogen cell, hinders pathogen spore germination and prevents
After spore germination, host is infected and play a role, to gray mold, sclerotiniose specially good effect.
Boscalid is Novel tobacco acid amide fungicides, in 2004 Britain, Germany and
Switzerland registers.Boscalid belongs to succinic acid ubiquinone reductase suppression in mitochondrial respiratory chain
Agent, has a strongest rejection ability to the sprouting of spore, and with other antibacterial no interactions resistance.
Boscalid is mainly shifted in plant by blade face infiltration, suppresses mitochondrial succinate acid esters dehydrogenation
Enzyme, hinders tricarboxylic acid cycle, makes aminoacid, sugar shortage, energy reduce, dividing of interference cell
Split and grow, disease is had neural activity, there is protection and therapeutical effect.Suppression spore germination,
The extension of antibacterial pipe, mycelial growth and spore mother cell form fungus growth and the main rank of breeding
Section, bactericidal action is directly caused by parent active agent, does not has corresponding metabolic activity.With many bacterium
The no interactions resistances such as spirit, Sukeling, are mainly used in preventing and treating powdery mildew, gray mold, various rot
Disease, brown rot and root rot etc..
Grey mould fruit rot of strawberry is disease common during strawberry cultivating, and China's cultivated strawberry area is all
Having generation, 20 century 70 sequela gradually increase the weight of, especially south the fruit picking phase on the occasion of
In the spring rain time, fall ill even more serious.Grey mould fruit rot of strawberry often results in real rotten susceptible variety
Diseased fruit rate is about 30%, serious up to more than 60%, to Fructus Fragariae Ananssae yield, qualitative effects very
Greatly.Main infringement blade and petiole, morbidity is many from the florescence, and pathogenic bacteria initially loses from by opening
Flower or weaker position are infected, and make flower rot in light brown necrosis, produce the mould layer of Lycoperdon polymorphum Vitt.Leaf
How to invade from base portion strong yellow limb edge, form " V " font brown spot, or drop along petal
Position infect, formed subcircular ecthyma gangrenosa, it has and the most significantly takes turns stricture of vagina, upper life is diluter
Dredge grey mold.Fruit is caught an illness many from the beginning of the petal remained or the position coming close to or in contact with ground, also
Can invade from the position of early stage with invalid contact tissue, just downright bad, subsequently in water stain shape taupe
Darkening, fruit rot, surface produces the dense mould layer of Lycoperdon polymorphum Vitt.Petiole is fallen ill, in shallow brown
Color is downright bad, drying shrinkage, and it produces sparse grey mold.
In actual survey is studied, it has been found that pyrrole bacterium benzene prestige, Boscalid are compounded,
Have obviously preventive and therapeutic effect to grey mould fruit rot of strawberry, according to long-term tracking test, this compounds
Dosage form, is difficult to produce resistance in actual application, and in use, consumption is non-
The lowest, the negative effect to environment is the least.
Pyrrole bacterium benzene prestige and Boscalid mixture are used for preventing and treating grey mould fruit rot of strawberry, there is no relevant report at present
Road.
Summary of the invention
It is an object of the invention to provide a kind of efficient, safe and environment-friendly, low toxicity and the lasting period be long,
Having the bactericidal composition of potentiation, it can effectively prevent and treat grey mould fruit rot of strawberry.
For achieving the above object, the technical solution adopted in the present invention is: a kind of containing pyrrole bacterium benzene
Prestige and the bactericidal composition of Boscalid, auxiliary including pyrrole bacterium benzene prestige and Boscalid and pesticidal preparations
Co-ingredients, the ratio of weight and number of pyrrole bacterium benzene prestige and Boscalid is 1:10~10:1, pyrrole bacterium
Benzene prestige and Boscalid weight summation percentage by weight in bactericidal composition are 5%~70%.
Further, in bactericidal composition, pyrrole bacterium benzene prestige and Boscalid preferred weight portion rate are
3:1。
The bactericidal composition of the present invention can have been selected according to well known to a person skilled in the art method
The pesticidal preparations auxiliary element known, is configured to Multiple Pesticides dosage form.In the present invention, the present invention
Bactericidal composition is preferably formulated to two kinds of environmental protection dosage forms such as suspending agent and water dispersible granules.
The bactericidal composition of the present invention is used for preventing and treating grey mould fruit rot of strawberry, Ying.
The bactericidal composition of the present invention, generally uses the method for spraying to use, it is also possible to according to need
Use other use technology agriculturally applied.
The bactericidal composition of the present invention has the advantages that:
1, the bactericidal composition of the present invention, shows obvious potentiation in certain ratio range
Effect, the prevention effect of compositions is significantly improved than single dose, reduces the use agent of pesticide
Amount, decreases times for spraying, reduces drug cost, decrease pesticide to ecological environment not
Profit impact.
2, the bactericidal composition of the present invention, two kinds of effective ingredient mechanism of action are different, can
To overcome long-term single use easily to produce the shortcoming of resistance, extend the service life of medicament, right
The comprehensive control important in inhibiting of Disease Resistance.
3, the bactericidal composition of the present invention, drug effect plays rapidly, and the lasting period is long, use cost
Low, easy to use, time saving and energy saving, its popularization and application have huge economic benefit and society's effect
Benefit.
4, the bactericidal composition dosage form environmental protection of the present invention, to crop safety.
Detailed description of the invention
In order to be more fully understood that the essence of the present invention, it is described further by following example,
But the present invention is not limited to these embodiments.In these embodiments, unless otherwise indicated, institute
Percentage ratio is had all to be weight percentage.
Embodiment 1: Botrytis cinerea pathogenic bacteria colony growth inhibition test
Test method is entered with reference to Wu Wenjun " chemical protection of plant experimental technique introduction " (1993)
OK.After pyrrole bacterium benzene prestige by 95%, 95.4% Boscalid former medicine folding hundred respectively with acetone, tell
Temperature-80 makes 1.0 μ g/mL mother solutions, utilizes mother liquor to become Boscalid, pyrrole bacterium benzene prestige weight
Amount ratio is respectively 1:10-10:1, gradient be respectively 0.5 μ g/mL, 1.0 μ g/mL,
2.0 μ g/mL, the PDA plate of 4.0 μ g/mL.The concrete data of result of the test are shown in Table 1.
Botrytis cinerea pathogenic bacteria Indoor antibacterial is tried by table 1, Boscalid and pyrrole bacterium benzene prestige and mixture thereof
Test data
Toxicity index and the co-toxicity coefficient (CTC of mixture of each medicament is calculated according to the abundant method of Sun Yun
Value), when CTC≤80 are antagonism, 80 CTC 120 are summation action, CTC >=120
For potentiation.
Found by indoor bacterium colony Developing restraint test, Boscalid, pyrrole bacterium benzene prestige according to
Grey mould fruit rot of strawberry colony growth is respectively provided with after the ratio of 1:10-10:1 is compounding potentiation suppression make
With, wherein with 3:1 potentiation the most substantially, co-toxicity coefficient is 148.4 for pyrrole bacterium benzene prestige, Boscalid,
The two compound synergic is notable, it is possible to the extension of significantly more efficient suppression bacterium colony.
Embodiment 2:24% pyrrole bacterium benzene prestige Boscalid suspending agent
Weigh 18% pyrrole bacterium benzene prestige, 6% Boscalid, 2% agriculture breast 500,3%NP-10,3% fat
Polyoxyethylenated alcohol, 0.2% xanthan gum, 3% ethylene glycol, 0.5% organic silicon defoamer, add from
Sub-water is mended to 100%.After being mixed by above-mentioned raw materials, prepare 24% through sand milling high speed shear emulsifying
Pyrrole bacterium benzene prestige Boscalid suspending agent.
Embodiment 3:40% pyrrole bacterium benzene prestige Boscalid water dispersible granules
Weigh 30% pyrrole bacterium benzene prestige, 10% Boscalid, 2%OP-10,2% Tween-60 #,
1% triphenyl phosphite, 2% di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate, 1.5% xanthan gum, 0.8% poly-second
Enol, 0.2% benzoic acid, bentonite are mended to 100%.Above-mentioned raw materials is fully mixed through gas
Stream is pulverized, then prepares 40% pyrrole bacterium benzene prestige Boscalid water dispersible granules by pelletize.
Embodiment 4: preventing and treating grey mould fruit rot of strawberry field test
Reagent agent and dispenser dosage:
(1) 24% pyrrole bacterium benzene prestige Boscalid suspending agent (embodiment 2), 30 grams of preparation of mu.
(2) 40% pyrroles bacterium benzene prestige Boscalid water dispersible granules (embodiment 3), mu preparation 20
Gram.
(3) 20% pyrrole bacterium benzene prestige wettable powders, mu is with 40 grams of preparation (comparison medicament).
(4) 30% Boscalid wettable powders, mu is with 30 grams of preparation (comparison medicament).
Spraying time and application method: grey mould fruit rot of strawberry their early stage dispenser, be watered even spraying.
Table 2, the field control effectiveness test result of preventing and treating grey mould fruit rot of strawberry
Reagent agent | Preparation usage amount (gram/acre) | 7 days preventive effects (%) after medicine | 14 days preventive effects (%) after medicine |
(1) | 30 | 77.5 | 86.4 |
(2) | 20 | 75.8 | 85.8 |
(3) | 40 | 68.1 | 71.3 |
(4) | 30 | 63.7 | 70.2 |
The bactericidal composition of the present invention is better than single dose, it is possible to increase actual prevention effect, reduces and uses
Dose, reduces cost, reduces the medicament adverse effect to environment, delays the product of disease drug resistance
Raw, agricultural synthesis is administered and has great significance.
Claims (4)
1. one kind contains pyrrole bacterium benzene prestige and the bactericidal composition of Boscalid, it is characterised in that:
Including pyrrole bacterium benzene prestige and Boscalid and pesticidal preparations auxiliary element, pyrrole bacterium benzene prestige and Boscalid
Ratio of weight and number be 1:10~10:1, pyrrole bacterium benzene prestige and Boscalid weight summation are being killed
Percentage by weight in bacteria composition is 5%~70%.
The most according to claim 1 a kind of containing pyrrole bacterium benzene prestige and the sterilization of Boscalid
Compositions, it is characterised in that: the ratio of weight and number of pyrrole bacterium benzene prestige and Boscalid is 3:1.
The most according to claim 1 and 2 a kind of containing pyrrole bacterium benzene prestige and Boscalid
Bactericidal composition, it is characterised in that: the dosage form of described bactericidal composition is suspending agent, water-dispersible
Granule.
4. a kind of the killing containing pyrrole bacterium benzene prestige and Boscalid described in claim 1 or 2
Bacteria composition is in the purposes of preventing and treating grey mould fruit rot of strawberry.
Priority Applications (1)
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CN201610266474.XA CN105918334A (en) | 2016-04-25 | 2016-04-25 | Sterilization composition containing pyribencarb and boscalid |
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CN201610266474.XA CN105918334A (en) | 2016-04-25 | 2016-04-25 | Sterilization composition containing pyribencarb and boscalid |
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CN201610266474.XA Withdrawn CN105918334A (en) | 2016-04-25 | 2016-04-25 | Sterilization composition containing pyribencarb and boscalid |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106577704A (en) * | 2016-12-08 | 2017-04-26 | 深圳诺普信农化股份有限公司 | Pyribencarb-containing fungicidal composition |
-
2016
- 2016-04-25 CN CN201610266474.XA patent/CN105918334A/en not_active Withdrawn
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106577704A (en) * | 2016-12-08 | 2017-04-26 | 深圳诺普信农化股份有限公司 | Pyribencarb-containing fungicidal composition |
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Application publication date: 20160907 |