CN105885739A - Water-based adhesive and preparation method thereof - Google Patents
Water-based adhesive and preparation method thereof Download PDFInfo
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- CN105885739A CN105885739A CN201610341548.1A CN201610341548A CN105885739A CN 105885739 A CN105885739 A CN 105885739A CN 201610341548 A CN201610341548 A CN 201610341548A CN 105885739 A CN105885739 A CN 105885739A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J131/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Adhesives based on derivatives of such polymers
- C09J131/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C09J131/04—Homopolymers or copolymers of vinyl acetate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a water-based adhesive and a preparation method thereof. The preparation method of the water-based adhesive comprises the following steps: (1) weighing 20-40 parts of ethylene-vinyl acetate emulsion, 50-70 parts of acrylate emulsions, 10-40 parts of a water-based viscous emulsion and 0.2-0.6 part of an antifoaming agent, dispersing the weighed raw materials evenly in a high-speed disperser to obtain a base emulsion; (2) adding 0.3-0.8 part of a coalescing agent and 0.2-0.6 part of a mildew preventive to the base emulsion, stirring evenly to obtain the first water-based adhesive. In such manner, the water-based adhesive which is fast cured, high in initial adhesion and excellent in permanent adhesion can be provided.
Description
Technical field
The present invention relates to a kind of Aqueous Adhesives and preparation method thereof.
Background technology
Adhesive is a kind of by interface interaction, and various solid materials are firmly bonded together
Material.Adhesive is mainly by bonding material, curing agent, toughener, diluent, filler with change
Property agent composition, be widely used in auto industry, shipbuilding industry, aerospace industries, electronics electricity
Gas industry, building industry, health care industry, light and textile industries and packaging industry.
Aqueous Adhesives has the features such as solvent-free, safe and environment-friendly, the most progressively replaces solvent
Type adhesive.But existing Aqueous Adhesives exists that initial bonding strength is not enough, curing rate is slow etc. asks
Topic, it is impossible to well meet use demand.
Summary of the invention
The technical problem that present invention mainly solves is to provide a kind of Aqueous Adhesives and preparation side thereof
Method, using the teaching of the invention it is possible to provide the Aqueous Adhesives that a kind of quick solidifying, initial bonding strength are strong, holding power is excellent.
For solving above-mentioned technical problem, the technical scheme that the present invention uses is: provide one
Aqueous Adhesives, described Aqueous Adhesives is made up of the raw material of following weight portion: ethyl vinyl acetate
Vinyl acetate emulsion 20～40 parts；Acrylic acid ester emulsion 50～70 parts；Aqueous tackifier emulsion 10～40
Part；Thickener 0.3～0.8 part；Coalescents 0.3～0.8 part；PH conditioning agent 0.2～0.6 part；
Defoamer 0.2～0.6 part；Mould inhibitor 0.2～0.6 part；The weight portion sum of above-mentioned each component is
100 weight portions.
Wherein, described acrylic acid ester emulsion is by one or both in acrylate and vinyl acetate emulsion, pure-acrylic emulsion
Composition.
Wherein, the solid content of described acrylate and vinyl acetate emulsion is 60～65%, and viscosity is
1500～2500mPa.s, pH are 6～7, and vitrification point is-20 DEG C, and MFT is
-18℃；Described pure-acrylic emulsion solid content is 55～60%, and viscosity is 1500～2000mPa.s,
PH is 6～7, and vitrification point is-40 DEG C, and MFT is-40 DEG C.
Wherein, described ethylene-vinyl acetate emulsion is by ethene-vinyl acetate-acrylic acid ternary altogether
Gather and obtain.
Wherein, described aqueous tackifier emulsion is aqueous acrylic modified rosin Tackified emulsion.
Wherein, described thickener is cellulose；Described pH adjusting agent is ammoniacal liquor；Described film forming
Auxiliary agent is propane diols phenylate；Described defoamer is organic silicon defoamer；Described mould inhibitor is 5-
Chloro-2-methyl-4-isothiazoline-3-ketone.
For solving above-mentioned technical problem, another technical solution used in the present invention is: provide one
Planting the preparation method of Aqueous Adhesives, described preparation method includes: 1) weigh ethyl vinyl acetate second
Alkene ester emulsion 20～40 parts, acrylic acid ester emulsion 50～70 parts, aqueous tackifier emulsion 10～40
Part, defoamer 0.2～0.6 part are uniformly dispersed in high speed dispersor and obtain basic emulsion；2) to
Adding coalescents 0.3～0.8 part, mould inhibitor 0.2～0.6 part in described basic emulsion, stirring is all
Even obtain the first Aqueous Adhesives.
Wherein, described preparation method also includes: 3) add in described first Aqueous Adhesives
Thickener 0.3～0.8 part, and it is uniformly mixing to obtain the second Aqueous Adhesives.
Wherein, described preparation method also includes: 4) add in described second Aqueous Adhesives
PH adjusting agent 0.2～0.6 part, and it is uniformly mixing to obtain the 3rd Aqueous Adhesives.
Wherein, described step 1) rotating speed of high speed dispersion machine is 200～300r/min, stirring
Time is 20～40min；Described step 2) rotating speed of high speed dispersion machine is 500～800r/min,
Mixing time is 20～40min.
The invention has the beneficial effects as follows: be different from the situation of prior art, the water-base cement of the present invention
Glutinous agent and preparation method thereof, make use of acrylate and vinyl acetate emulsion, pure-acrylic emulsion have chemical stability good,
The features such as mechanical stability is excellent, MFT is low, adhesive property is excellent, by being blended
Method combines adding assistant method, with ethylene-vinyl acetate emulsion, aqueous tackifier emulsion, thickener,
Coalescents, PH conditioning agent, defoamer, mould inhibitor prepare such that it is able to provide one solid
Change the Aqueous Adhesives fast, initial bonding strength is strong, holding power is excellent.
Accompanying drawing explanation
Fig. 1 is the schematic of the preparation method of a kind of Aqueous Adhesives that the embodiment of the present invention provides
Flow chart；
Fig. 2 is the signal of the preparation method of the another kind of Aqueous Adhesives that the embodiment of the present invention provides
Property flow chart.
Detailed description of the invention
The embodiment of the present invention provides a kind of Aqueous Adhesives, the Aqueous Adhesives of the embodiment of the present invention
It is made up of the raw material of following weight portion:
Ethylene-vinyl acetate emulsion 20～40 parts；
Acrylic acid ester emulsion 50～70 parts；
Aqueous tackifier emulsion 10～40 parts；
Thickener 0.3～0.8 part；
Coalescents 0.3～0.8 part；
PH conditioning agent 0.2～0.6 part；
Defoamer 0.2～0.6 part；
Mould inhibitor 0.2～0.6 part；The weight portion sum of above-mentioned each component is 100 weight portions.
Wherein, as a kind of preferably technical scheme of the present invention, the embodiment of the present invention aqueous
Adhesive is made up of the raw material of following weight portion:
Ethylene-vinyl acetate emulsion 20～30 parts；
Acrylic acid ester emulsion 55～65 parts；
Aqueous tackifier emulsion 15～25 parts；
Thickener 0.4～0.6 part；
Coalescents 0.4～0.6 part；
PH conditioning agent 0.3～0.5 part；
Defoamer 0.3～0.4 part；
Mould inhibitor 0.3～0.4 part；The weight portion sum of above-mentioned each component is 100 weight portions.
As the most preferred technical scheme of the present invention, Aqueous Adhesives is by the raw material of following weight portion
Composition: ethylene-vinyl acetate emulsion 20 parts, acrylic acid ester emulsion 60 parts, aqueous tackifier
Emulsion 18 parts, thickener 0.5 part, coalescents 0.5 part, PH conditioning agent 0.4 part, disappear
Infusion 0.3 part, mould inhibitor 0.3 part.
Wherein, in the embodiment of the present invention, acrylic acid ester emulsion can be by acrylate and vinyl acetate emulsion, pure third breast
One or both compositions in liquid.
Wherein, the solid content of acrylate and vinyl acetate emulsion used in the embodiment of the present invention is 60～65%, viscous
Degree is 1500～2500mPa.s, and pH is 6～7, and vitrification point is-20 DEG C, minimum film forming temperature
Degree is for-18 DEG C；Pure-acrylic emulsion solid content used is 55～60%, and viscosity is
1500～2000mPa.s, pH are 6～7, and vitrification point is-40 DEG C, and MFT is
-40℃。
Wherein, above-mentioned ethylene-vinyl acetate emulsion is by ethene-vinyl acetate-acrylic acid ternary altogether
Poly-obtain, for Dalian chemical industry DA102H, watt gram chemical V920, watt gram chemical EAF6
One or more compositions.Above-mentioned DA102H is Dalian, Taiwan Chemical Manufacture, solid content >=
55.0%, viscosity is 2500～4000cps, pH are 5～7；Above-mentioned V920 is a watt gram chemistry
Producing, solid content >=54.5%, viscosity are 1500～3500cps, PH are 5～7；Above-mentioned
EAF68 is a watt gram chemical production, solid content >=60.0%, viscosity is 8000～20000cps,
PH is 5～7.
Wherein, above-mentioned aqueous tackifier emulsion can be aqueous acrylic modified rosin thickening breast
Liquid, its pH value is preferably 6～7.
Wherein, above-mentioned thickener can be cellulose, preferably hydroxyethyl cellulose, above-mentioned
PH adjusting agent can be ammoniacal liquor, above-mentioned coalescents is propane diols phenylate, and above-mentioned disappears
Infusion can be organic silicon defoamer, preferably polyether modified siloxane, and above-mentioned mould inhibitor can
Think CMIT.
Certainly, particular make-up or the concrete material of above-mentioned cited component is intended only as a citing
Illustrate, not in order to limit protection scope of the present invention.
On the basis of a kind of Aqueous Adhesives that the above embodiment of the present invention provides, the present invention enters
One step provides the preparation method of a kind of Aqueous Adhesives, refers to Fig. 1, the present embodiment water-base cement
The preparation method of glutinous agent comprises the following steps:
S101: weigh ethylene-vinyl acetate emulsion 20～40 parts, acrylic acid ester emulsion 50～70
Part, aqueous tackifier emulsion 10～40 parts, defoamer 0.2～0.6 part disperse in high speed dispersor
Uniformly obtain basic emulsion.
Wherein, when disperseing, the rotating speed of high speed dispersor is 200～300r/min, during stirring
Between be 20～40min.
Wherein, in the embodiment of the present invention, acrylic acid ester emulsion can be by acrylate and vinyl acetate emulsion, pure third breast
One or both compositions in liquid.
Wherein, the solid content of acrylate and vinyl acetate emulsion used in the embodiment of the present invention is 60～65%, viscous
Degree is 1500～2500mPa.s, and pH is 6～7, and vitrification point is-20 DEG C, minimum film forming temperature
Degree is for-18 DEG C；Pure-acrylic emulsion solid content used is 55～60%, and viscosity is
1500～2000mPa.s, pH are 6～7, and vitrification point is-40 DEG C, and MFT is
-40℃。
Wherein, above-mentioned ethylene-vinyl acetate emulsion is by DA102H, V920, EAF68
One of which or several composition.Above-mentioned DA102H is Dalian, Taiwan Chemical Manufacture,
Solid content >=55.0%, viscosity are 2500～4000cps, pH are 5～7；Above-mentioned V920 is
Watt gram chemical production, solid content >=54.5%, viscosity are 1500～3500cps, PH are 5～7；
Above-mentioned EAF68 is a watt gram chemical production, and solid content >=60.0%, viscosity are
8000～20000cps, pH be 5～7.
Wherein, above-mentioned aqueous tackifier emulsion can be aqueous acrylic modified rosin thickening breast
Liquid, its pH value is preferably 6～7.
Above-mentioned defoamer can be organic silicon defoamer, preferably polyether modified siloxane.
S102: add coalescents 0.3～0.8 part, mould inhibitor 0.2～0.6 in basic emulsion
Part, it is uniformly mixing to obtain the first Aqueous Adhesives.
When being stirred in this step, the rotating speed of high speed dispersor is 500～800r/min, stirring
Time is 20～40min.
Wherein, above-mentioned coalescents can be propylene glycol phenyl ether, and above-mentioned mould inhibitor can be
CMIT.
Further referring to Fig. 2, in the preferred implementation of one, the preparation of the present embodiment
Method may further comprise:
S103: add thickener 0.3～0.8 part in the first Aqueous Adhesives, and stir
Obtain the second Aqueous Adhesives.
By the addition of thickener, so that the second Aqueous Adhesives is relative to the first water-base cement
Glutinous agent has viscosity preferably.
Wherein, above-mentioned thickener can be cellulose, preferably hydroxyethyl cellulose.
Further, the preparation method of the present embodiment farther includes:
S104: add pH adjusting agent 0.2～0.6 part in the second Aqueous Adhesives, and stir
Uniformly obtain the 3rd Aqueous Adhesives.
By the addition of pH adjusting agent, so that the 3rd Aqueous Adhesives is relative to the second water
The performance of property adhesive is more excellent.
Wherein, as the pH adjusting agent of the embodiment of the present invention, can be ammoniacal liquor.
By a kind of aqueous adhesive that the above embodiment of the present invention provides and preparation method thereof
Describe in detail, it will be understood that the preparation method of the present invention make use of acrylate and vinyl acetate emulsion, pure-acrylic emulsion
Have that chemical stability is good, mechanical stability is excellent, MFT is low, adhesive property is excellent
The feature such as different, combines adding assistant method by blending method, with ethylene-vinyl acetate emulsion, water
Property Tackified emulsion, thickener, coalescents, PH conditioning agent, defoamer, mould inhibitor prepare,
It is thus possible to provide the Aqueous Adhesives that a kind of quick solidifying, initial bonding strength are strong, holding power is excellent.
In order to further describe technical scheme in detail, below by way of specific embodiment
Technical scheme is further elaborated, but, following example simply can
Realize several concrete implementation modes of technical solution of the present invention, not in order to limit the present invention's
Protection domain.
Embodiment 1:
(1) each 10 parts of DA102H, EAF68, pure-acrylic emulsion 60 parts, water are accurately weighed
Property acrylic acid modified rosin Tackified emulsion 18 parts, organic silicon defoamer 0.3 part are in high speed dispersion
In machine, 300r/min, stirs 30min, obtains basic emulsion；
(2) basic emulsion prepared to (1) adds propane diols phenylate 0.5 part, mould inhibitor 0.3
Part, 600r/min, stirring 30min obtain environment-friendly water-based adhesive；
(3) the environment-friendly water-based adhesive prepared to (2) adds THICKENERS Thickeners 0.5 part,
Obtain the environment-friendly water-based adhesive that viscosity is suitable；
(4) the environment-friendly water-based adhesive prepared to (3) adds PH conditioning agent 0.4 part,
Environment-friendly water-based adhesive to excellent performance；
(5) it is applied on full-automatic paper box box machine survey by the environment-friendly water-based adhesive of preparation
Trial production speed, and add up first-time qualification rate；
(6) by packaged world hamper, in constant temperature perseverance item, high temperature bonding performance is carried out
Test, test condition is: temperature 60 C, humidity 65%, testing time 8h, adds up qualified
Rate；
Test result is as shown in table 1.
The Aqueous Adhesives test result statistics of table 1 embodiment 1
| Index | Throughput rate (individual/min) | First-time qualification rate (%) | High temperature test qualification rate (%) |
| Result | 60 | 93 | 87 |
Embodiment 2:
(1) each 10 parts of DA102H, EAF68, acrylate and vinyl acetate emulsion 60 parts, water are accurately weighed
Property acrylic acid modified rosin Tackified emulsion 18 parts, organic silicon defoamer 0.3 part are in high speed dispersion
In machine, 300r/min, stirs 30min, obtains basic emulsion；
(2) basic emulsion prepared to (1) adds propane diols phenylate 0.5 part, mould inhibitor 0.3
Part, 600r/min, stirring 30min obtain environment-friendly water-based adhesive；
(3) the environment-friendly water-based adhesive prepared to (2) adds THICKENERS Thickeners 0.5 part,
Obtain the water environmental protection Aqueous Adhesives that viscosity is suitable；
(4) the environment-friendly water-based adhesive prepared to (3) adds PH conditioning agent 0.4 part,
Environment-friendly water-based adhesive to excellent performance；
(5) it is applied on full-automatic paper box box machine survey by the environment-friendly water-based adhesive of preparation
Trial production speed, and add up first-time qualification rate；
(6) by packaged world hamper, in constant temperature perseverance item, high temperature bonding performance is carried out
Test, test condition is: temperature 60 C, humidity 65%, testing time 8h, adds up qualified
Rate；
Test result is as shown in table 2.
The Aqueous Adhesives test result statistics of table 2 embodiment 2
| Index | Throughput rate (individual/min) | First-time qualification rate (%) | High temperature test qualification rate (%) |
| Result | 70 | 97 | 95 |
Embodiment 3:
(1) each 20 parts of DA102H, EAF68, acrylate and vinyl acetate emulsion 40 parts, water are accurately weighed
Property acrylic acid modified rosin Tackified emulsion 18 parts, organic silicon defoamer 0.3 part are in high speed dispersion
In machine, 300r/min, stirs 30min, obtains basic emulsion；
(2) basic emulsion prepared to (1) adds propane diols phenylate 0.5 part, mould inhibitor 0.3
Part, 600r/min, stirring 30min obtain environment-friendly water-based adhesive；
(3) the environment-friendly water-based adhesive prepared to (2) adds THICKENERS Thickeners 0.5 part,
Obtain the water environmental protection Aqueous Adhesives that viscosity is suitable；
(4) the environment-friendly water-based adhesive prepared to (3) adds PH conditioning agent 0.4 part,
Environment-friendly water-based adhesive to excellent performance；
(5) it is applied on full-automatic paper box box machine survey by the environment-friendly water-based adhesive of preparation
Trial production speed, and add up first-time qualification rate；
(6) by packaged world hamper, in constant temperature perseverance item, high temperature bonding performance is carried out
Test, test condition is: temperature 60 C, humidity 65%, testing time 8h, adds up qualified
Rate；
Test result is as shown in table 3.
The Aqueous Adhesives test result statistics of table 3 embodiment 3
| Index | Throughput rate (individual/min) | First-time qualification rate (%) | High temperature test qualification rate (%) |
| Result | 55 | 92 | 95 |
Illustrating by above-described embodiment, it will be understood that compared with prior art: this
The bright Aqueous Adhesives prepared, initial bonding strength is excellent, and holding power highlights, in the full-automatic world
On lid box machine process velocity can reach 70 per minute.
The foregoing is only embodiments of the invention, not thereby limit the scope of the claims of the present invention, all
It is the equivalent structure utilizing description of the invention and accompanying drawing content to be made or equivalence flow process conversion, or
Directly or indirectly it is used in other relevant technical fields, is the most in like manner included in the patent of the present invention
In protection domain.
Claims (10)
1. an Aqueous Adhesives, it is characterised in that described Aqueous Adhesives is made up of the raw material of following weight portion:
Ethylene-vinyl acetate emulsion 20 ~ 40 parts；
Acrylic acid ester emulsion 50 ~ 70 parts；
Aqueous tackifier emulsion 10 ~ 40 parts；
Thickener 0.3 ~ 0.8 part；
Coalescents 0.3 ~ 0.8 part；
PH conditioning agent 0.2 ~ 0.6 part；
Defoamer 0.2 ~ 0.6 part；
Mould inhibitor 0.2 ~ 0.6 part；The weight portion sum of above-mentioned each component is 100 weight portions.
Aqueous Adhesives the most according to claim 1, it is characterised in that described acrylic acid ester emulsion is made up of one or both in acrylate and vinyl acetate emulsion, pure-acrylic emulsion.
Aqueous Adhesives the most according to claim 2, it is characterised in that the solid content of described acrylate and vinyl acetate emulsion is 60 ~ 65%, viscosity be 1500 ~ 2500mPa.s, pH be 6 ~ 7, vitrification point is-20 DEG C, and MFT is-18 DEG C；Described pure-acrylic emulsion solid content is 55 ~ 60%, viscosity be 1500 ~ 2000mPa.s, pH be 6 ~ 7, vitrification point is-40 DEG C, and MFT is-40 DEG C.
Aqueous Adhesives the most according to claim 1, it is characterised in that described ethylene-vinyl acetate emulsion is obtained by ethene-vinyl acetate-acrylic acid ternary polymerization.
Aqueous Adhesives the most according to claim 1, it is characterised in that described aqueous tackifier emulsion is aqueous acrylic modified rosin Tackified emulsion.
Aqueous Adhesives the most according to claim 1, it is characterised in that described thickener is cellulose；Described pH adjusting agent is ammoniacal liquor；Described coalescents is propane diols phenylate；Described defoamer is organic silicon defoamer；Described mould inhibitor is CMIT.
7. the preparation method of an Aqueous Adhesives, it is characterised in that described preparation method includes:
1) weigh ethylene-vinyl acetate emulsion 20 ~ 40 parts, acrylic acid ester emulsion 50 ~ 70 parts, aqueous tackifier emulsion 10 ~ 40 parts, defoamer 0.2 ~ 0.6 part are uniformly dispersed in high speed dispersor and obtain basic emulsion；
2) in described basic emulsion, add coalescents 0.3 ~ 0.8 part, mould inhibitor 0.2 ~ 0.6 part, be uniformly mixing to obtain the first Aqueous Adhesives.
Preparation method the most according to claim 1, it is characterised in that described preparation method also includes:
3) in described first Aqueous Adhesives, add thickener 0.3 ~ 0.8 part, and be uniformly mixing to obtain the second Aqueous Adhesives.
Preparation method the most according to claim 8, it is characterised in that described preparation method also includes:
4) in described second Aqueous Adhesives, add pH adjusting agent 0.2～0.6 part, and be uniformly mixing to obtain the 3rd Aqueous Adhesives.
Preparation method the most according to claim 7, it is characterised in that the rotating speed of described step 1) high speed dispersion machine is 200 ~ 300r/min, and mixing time is 20 ~ 40min；Described step 2) rotating speed of high speed dispersion machine is 500 ~ 800r/min, mixing time is 20 ~ 40min.
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| CN114316845A (en) * | 2021-12-24 | 2022-04-12 | 厦门创业人环保科技股份有限公司 | Environment-friendly water-based adhesive and preparation method thereof |
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| CN106381073A (en) * | 2016-08-29 | 2017-02-08 | 无锡市宝来电池有限公司 | Environmental-protection alkaline storage battery seal material |
| CN106634715A (en) * | 2016-12-13 | 2017-05-10 | 鹤山市知墨印刷粘合材料有限公司 | Environment-friendly packing box machine-painting adhesive and preparation method thereof |
| CN106634716A (en) * | 2016-12-26 | 2017-05-10 | 广州市优伟家居用品有限公司 | Water-based adhesive, and preparation method and application thereof |
| CN106634716B (en) * | 2016-12-26 | 2018-08-28 | 广州市优伟家居用品有限公司 | A kind of Aqueous Adhesives, preparation method and its application |
| CN106978107B (en) * | 2017-04-27 | 2020-10-13 | 无锡市福享天下科技有限公司 | Multipurpose high-grade strong binder |
| CN106978107A (en) * | 2017-04-27 | 2017-07-25 | 无锡市福享天下科技有限公司 | The senior strength adhesive of multipurpose |
| CN107573873A (en) * | 2017-09-26 | 2018-01-12 | 康菲胶粘剂技术（广东）有限公司 | A kind of High-Speed Automatic mounting box glue of low smell |
| CN108148530A (en) * | 2017-12-27 | 2018-06-12 | 苏州启跃新材料科技有限公司 | A kind of double-component aqueous environment-friendly type ceramic tile gum |
| CN108165213A (en) * | 2017-12-27 | 2018-06-15 | 苏州启跃新材料科技有限公司 | A kind of preparation method of double-component aqueous environment-friendly type ceramic tile gum |
| CN109401635A (en) * | 2018-09-21 | 2019-03-01 | 三峡大学 | Graphene Aqueous Adhesives and preparation method thereof |
| CN109439235A (en) * | 2018-11-08 | 2019-03-08 | 东莞市彩龙包装材料有限公司 | A kind of liquid glue and preparation method thereof |
| CN109517540A (en) * | 2018-11-16 | 2019-03-26 | 上海瀚氏科技集团有限公司 | Environmentally friendly vehicle article shading curtain and its production technology |
| CN110093126A (en) * | 2019-03-27 | 2019-08-06 | 广州市永添生物科技有限公司 | A kind of preparation method of medical aqueous multiple emulsion paper-plastic lamination adhesive |
| CN110343492A (en) * | 2019-08-12 | 2019-10-18 | 四川顶立胶业有限公司 | Low-cost high-strength vacuum plastic-absorption and preparation method thereof |
| CN111910860A (en) * | 2020-08-14 | 2020-11-10 | 安徽山水空间装饰有限责任公司 | Wallpaper paving method |
| CN113004835A (en) * | 2021-04-02 | 2021-06-22 | 深圳市力德邦实业有限公司 | Water-based all-purpose adhesive and preparation method thereof |
| CN114316845A (en) * | 2021-12-24 | 2022-04-12 | 厦门创业人环保科技股份有限公司 | Environment-friendly water-based adhesive and preparation method thereof |
| CN115449320A (en) * | 2022-09-28 | 2022-12-09 | 广州立邦涂料有限公司 | Adhesive material and preparation method and application thereof |
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Application publication date: 20160824 |