CN106978107A - The senior strength adhesive of multipurpose - Google Patents
The senior strength adhesive of multipurpose Download PDFInfo
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- CN106978107A CN106978107A CN201710287015.4A CN201710287015A CN106978107A CN 106978107 A CN106978107 A CN 106978107A CN 201710287015 A CN201710287015 A CN 201710287015A CN 106978107 A CN106978107 A CN 106978107A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J125/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Adhesives based on derivatives of such polymers
- C09J125/02—Homopolymers or copolymers of hydrocarbons
- C09J125/04—Homopolymers or copolymers of styrene
- C09J125/08—Copolymers of styrene
- C09J125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J109/00—Adhesives based on homopolymers or copolymers of conjugated diene hydrocarbons
- C09J109/06—Copolymers with styrene
- C09J109/08—Latex
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J131/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Adhesives based on derivatives of such polymers
- C09J131/02—Homopolymers or copolymers of esters of monocarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J143/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Adhesives based on derivatives of such polymers
- C09J143/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention belongs to building chemical field of material technology, a kind of senior strength adhesive of multipurpose is disclosed, the binding agent includes aqueous polymer resin, tackifier resin emulsion and auxiliary agent, wherein, the part by weight of aqueous polymer resin and tackifier resin emulsion is 70 80：10‑20.Product health environment-friendly of the present invention, adhesion strength height, water proof anti-seepage, good weatherability, fundamentally solve the cracking in the presence of faced deorative, hollowing, come off and the disadvantage such as seepage.
Description
Technical field
The invention belongs to building chemical field of material technology, and in particular to a kind of senior strength adhesive of multipurpose, this is more
The senior strength adhesive environmental protection of purposes, strong cohesive force, water-proof climate resisting, easy construction.
Background technology
The quilt now that ceramic tile is developed rapidly with numerous advantages such as the attractive in appearance, changeable of it, cleaning, lasting, top grades in building
Designer is classified as inner-outer wall, the primary material of floor decorative, but the furring tile that bonds of traditional architecture after paving in a timing
In start frequently to come off, or hollowing is tilted, and is all generated to public security, to the economic and reputation of unit in charge of construction huge
Malicious influences.
The content of the invention
The purpose of the present invention is multi-purpose there is provided one kind to solve the defect of the ceramic tile bonds such as above-mentioned conventional cement, powder
Senior strength adhesive on the way, the senior strength adhesive health environment-friendly of the multipurpose, adhesion strength height, water proof anti-seepage, good weatherability,
Fundamentally solve the cracking in the presence of faced deorative, hollowing, come off and the disadvantage such as seepage.The ceramic tile bond can be used for
The firm bases such as coagulation soil matrix, plank, old ceramic tile, glass, steel.
The purpose of the present invention is achieved in the following ways：
A kind of senior strength adhesive of multipurpose, the binding agent includes aqueous polymer resin, tackifier resin emulsion and helped
Agent, wherein, the part by weight of aqueous polymer resin and tackifier resin emulsion is 70-80：10-20.
Described aqueous polymer resin be emulsion resin, preferred emulsion type resin be acrylic emulsion, styrene-butadiene emulsion,
One or two kinds of above emulsion is mixed in VAE emulsions, styrene-acrylic emulsion, tertiary acrylic emulsion, tertiary vinegar milk liquid, silicone acrylic emulsion.
Described tackifier resin emulsion is from one in emulsification rosin ester, emulsification terpene phenolic resin or emulsified petroleum resins
Plant or two or more mixing.Particularly tackifier resin emulsion consumption is very few, and wellability is poor, does not have Efficient Adhesive Promotion；It is too many viscous
Degree is big, increases difficulty of construction, easily hardened, can also destroy the cohesive force of resin.
The preparation method of the above-mentioned senior strength adhesive of multipurpose comprises the following steps：By aqueous polymer resin, thickening
In resin emulsion and auxiliary agent mixing, input high-speed dispersing kettle, stir.
Described auxiliary agent includes filler, wetting dispersing agent, defoamer, thickener, stabilizer, thixotropic agent and preservative.
Described filler is one or both of powdered whiting, precipitated calcium carbonate, silica flour, talcum powder, lithopone
And thing mixed above, particle size range is less than 45 microns.
Described thickener is hydroxyethyl ether cellulose, alkali swelling type thickener, acrylic thickener, polyurethanes increasing
The mixture of the one or two kinds of and above in thick dose.Acrylic thickener includes polyacrylate and acrylate copolymer
(alkali swelling type) two classes.
The thixotropic agent is one kind in magnesium aluminum silicates bentonite；Described preservative is sodium pentachlorophenol or 2,4,5-
Sodium 2,4,5-trichlorophenate.
The stabilizer is PH regulatory functions auxiliary agent or antioxidant；Preferred anti-oxidant is newborn aromatic amine, hindered phenol
Class, phosphite ester kind antioxidant.The preferred ammoniacal liquor of PH regulatory function auxiliary agents, ammonium hydrogen carbonate, sodium acetate etc..
The above-mentioned senior strength adhesive of multipurpose, the component for preferably including following parts by weight is made：
Aqueous polymer resin：70-80 parts by weight,
Tackifier resin emulsion：10-20 parts by weight,
Filler：0-10 parts by weight,
Wetting dispersing agent：0.1-0.3 parts by weight,
Defoamer：0.2-0.3 parts by weight,
Thickener：0.2-0.4 parts by weight,
Stabilizer：0.5-1.0 parts by weight,
Thixotropic agent：0.2-0.5 parts by weight,
Preservative：0.4-0.6 parts by weight,
Deionized water 2-3 parts by weight.
Most preferably component of the senior strength adhesive of multipurpose including following parts by weight is made：
Aqueous polymer resin：70-75 parts by weight,
Tackifier resin emulsion：15-20 parts by weight,
Filler：5-10 parts by weight,
Wetting dispersing agent：0.1-0.3 parts by weight,
Defoamer：0.2-0.3 parts by weight,
Thickener：0.2-0.3 parts by weight,
Stabilizer：0.8-1.0 parts by weight,
Thixotropic agent：0.3-0.4 parts by weight,
Preservative：0.4-0.5 parts by weight,
Deionized water 2-3 parts by weight.
Addition of the deionized water in binder of the present invention can make a significant impact on product：Water consumption is excessive, glues
Knot agent effect is deteriorated, drying time is long；Very few, binding agent mixed performance is poor, solid speed accelerates easy to crack.
Wetting dispersing agent be alcohol ethers wetting dispersing agent, alcohol ethers wetting dispersing agent be preferably AEO,
One kind in methacrylate, copolymer-maleic anhydride.Defoamer is preferably fatty alcohol defoamer.
Stabilizer is aromatic amine stabilizer and Hinered phenols antioxidant, the hexichol of aromatic amine stabilizer preferred emulsion shape
Amine, p-phenylenediamine and EEDQ and its derivative or polymer.Hinered phenols antioxidant majority is with 2,6- di-tert-butyls
Phenol or 2- methyl-6-tert-butylphenols are Material synthesis.Symmetric form hindered phenol antioxygen mainly has:(1) alkyl list phenols:It is anti-
Oxygen agent 264, antioxidant 1076 (2) alkyl Polyphenols:Antioxidant 1010, antioxidant 1098；(3) thiobis phenols:Antioxidant
2246-S, antioxidant 300；Asymmetric hindered phenol antioxygen such as antioxidant KY-586.
Hinered phenols antioxidant is mixed with aromatic amine stabilizer can to play more obvious antioxygen stabilization, mutually it
Between have collaboration facilitation.
Alkali swollen thickener is divided into two classes：Non- association type alkali swollen thickener (ASE) and association type alkali swollen thickener
(HASE), they are all anionic thickeners.The ASE of non-association type is polyacrylate alkali swelling type emulsion, this kind of thickener
Such as the ASE 60 and the Viscalex HV-30 of Ciba companies of Rohm Haas companies；Association type HASE is poly- the third of hydrophobically modified
The saline and alkaline swelling type emulsion of olefin(e) acid, such as SN636 of Nopco companies, TT -935 of Rohm＆Haas companies.
The preparation method of the above-mentioned senior strength adhesive of multipurpose specifically includes following steps：
By aqueous polymer resin, tackifier resin emulsion, filler, thickener, defoamer, wetting dispersing agent, thixotropic agent, surely
Determine in agent, preservative and deionized water mixing, input high-speed dispersing kettle, stir.
Compared to the prior art the good effect having：
(1) by the way that aqueous polymer resin and tackifying resin is newborn in the binder formula that technical solution of the present invention is provided
Liquid is combined according to certain ratio, solves the poor adhesive force of the grounds such as common gluing knot and cement basal plane, ceramic tile, water-alkali resistance
Difference, easy aging etc. causes the problem of ceramic tile hollowing comes off, and realizes that binder interface bonding force is strong, stability is good, water-fast, resistance to
Alkali, weather-proof, not easy to crack, hollowing, the characteristic such as come off, and with reference to other auxiliary agents and Gradation Optimization, is further ensured that the steady of binding agent
It is qualitative.
(2) tackifier resin emulsion selected is in emulsification rosin ester, emulsification terpene phenolic resin or emulsified petroleum resins one
Plant or two or more mixing, the peel strength of the binding agent made is further improved.
(3) by Fillers selection and Gradation Optimization, it can to greatest extent improve and mix painting with adhesive during use
The suspension effect of material, meanwhile, by the suction-operated of filler, resin boundary surface, reinforced resin and coating titanium white particle etc. can be obscured
Compatibility.
(4) cost of raw material selected by is cheap, nontoxic.It is production, packaging, construction, easy to use, belong to ring
Guarantor's type product, possesses great promotional value.
The present invention, as attachment function material, takes into account the requirement that bonds of various base materials from Multiple components, and selection is specific
Ratio causes binding agent to have broad applicability, while realizing multi-functional effect, it is ensured that its bulk properties is improved.
Embodiment
For convenience of the understanding of technical solution of the present invention, the specific composition for now illustrating the ceramic tile bond is constituted and its matter
Measure proportion relation.
Embodiment 1, the selection parts by weight of styrene-acrylic emulsion 35, the parts by weight of silicone acrylic emulsion 35 mixing composition aqueous polymer resin,
Emulsify the parts by weight of terpene phenolic resin 15, the parts by weight of powdered whiting 5 (particle size range is less than 45 microns), the weight of superfine talcum powder 5
Measure part (particle size range is less than 45 microns), the parts by weight of Polyacrylic Acid Thickener 0.3, the parts by weight of fatty alcohol defoamer 0.3, methyl
The parts by weight of acrylate 0.2, the parts by weight of aluminium-magnesium silicate thixotropic agent 0.4, the parts by weight of diphenylamines 0.7 of emulsion form, antioxidant
10100.1 parts by weight, the parts by weight of sodium pentachlorophenol 0.5, the parts by weight of deionized water 2.5 proportionally mix above-mentioned each component
Put into high-speed dispersing kettle, stir and binding agent is made.
Embodiment 2, the selection parts by weight of styrene-acrylic emulsion 70, emulsify the parts by weight of rosin ester 15, the parts by weight (grain of precipitated calcium carbonate 5
Footpath scope is less than 45 microns), the parts by weight of superfine talcum powder 5 (particle size range is less than 45 microns), acrylate copolymer thickener
0.3 parts by weight, the parts by weight of fatty alcohol defoamer 0.3, the parts by weight of AEO 0.2, organobentonite thixotropic agent 0.4
Parts by weight, the parts by weight of diphenylamines 0.3 of emulsion form, the parts by weight of antioxidant 1076 0.5, the weight of 2,4,5- sodium 2,4,5-trichlorophenate 0.5
Part, the parts by weight of deionized water 2.5.Material is mixed to input high-speed dispersing kettle in proportion to stir, binding agent is made.
Embodiment 3, take the parts by weight of acrylic emulsion 75, the parts by weight of emulsified petroleum resins 15, the parts by weight (particle diameter of silica flour 8
Scope is less than 45 microns), the parts by weight of hydroxyethyl ether cellulose thickener 0.3, the parts by weight of fatty alcohol defoamer 0.3, maleic anhydride
The parts by weight of copolymer 0.2, the parts by weight of organobentonite thixotropic agent 0.4, the parts by weight of EEDQ 0.5, the weight of antioxidant 1076 0.5
Measure part, the parts by weight of 2,4,5- sodium 2,4,5-trichlorophenate 0.5, the parts by weight of deionized water 2.5.Above-mentioned substance is mixed, proportionally put into
High-speed dispersing kettle is stirred, and binding agent is made.
Embodiment 4, take the parts by weight of styrene-butadiene emulsion 80, emulsify the parts by weight of rosin ester 15, the parts by weight (particle size range of talcum powder 5
Less than 45 microns), the parts by weight of SN636 0.3 of Nopco companies, the parts by weight of fatty alcohol defoamer 0.3, AEO
0.2 parts by weight, the parts by weight of organobentonite thixotropic agent 0.4, the parts by weight of p-phenylenediamine 0.4, the parts by weight of antioxidant 1076 0.4, five
The parts by weight of chlorophenol sodium 0.5, the parts by weight of deionized water 2.Above-mentioned substance is proportionally mixed to input high-speed dispersing kettle fully to stir
Mix uniform, binding agent is made.
Embodiment 5, take the tertiary parts by weight of vinegar milk liquid 35, the parts by weight of silicone acrylic emulsion 35, the emulsification parts by weight of rosin ester 20, lithopone
8 parts by weight (particle size range is less than 45 microns), the parts by weight of polyurethane thickener 0.4, the parts by weight of fatty alcohol defoamer 0.2, fat
The parts by weight of alcohol APEO 0.3, the parts by weight of organobentonite thixotropic agent 0.5, the parts by weight of diphenylamines 0.5 of emulsion form, antioxygen
The parts by weight of agent 1,010 0.5, the parts by weight of 2,4,5- sodium 2,4,5-trichlorophenate 0.4, the parts by weight of deionized water 3.By above-mentioned substance proportionally
Mixing input high-speed dispersing kettle is stirred, and binding agent is made.
The preparation-obtained product quality of above-described embodiment the results are shown in Table 1：
Table 1
Claims (10)
1. a kind of senior strength adhesive of multipurpose, it is characterised in that the binding agent includes aqueous polymer resin, tackifying resin
Emulsion and auxiliary agent, wherein, the part by weight of aqueous polymer resin and tackifier resin emulsion is 70-80：10-20.
2. the senior strength adhesive of multipurpose according to claim 1, it is characterised in that described aqueous polymer resin
For emulsion resin, preferred emulsion type resin is acrylic emulsion, styrene-butadiene emulsion, VAE emulsions, styrene-acrylic emulsion, tertiary acrylic emulsion, uncle
One or two kinds of above emulsion is mixed in vinegar milk liquid, silicone acrylic emulsion.
3. the senior strength adhesive of multipurpose according to claim 1, it is characterised in that described tackifier resin emulsion choosing
It is mixed above with emulsification rosin ester, emulsification one or both of terpene phenolic resin or emulsified petroleum resins.
4. the senior strength adhesive of multipurpose according to claim 1, it is characterised in that described auxiliary agent includes filler, profit
Hygroscopic water powder, defoamer, thickener, stabilizer, thixotropic agent and preservative.
5. the senior strength adhesive of multipurpose according to claim 4, it is characterised in that described filler is heavy carbonic acid
Calcium, one or both of precipitated calcium carbonate, silica flour, talcum powder, lithopone and thing mixed above, it is micro- that particle size range is less than 45
Rice.
6. the senior strength adhesive of multipurpose according to claim 4, it is characterised in that described thickener is ethoxy
One or more kinds of mixing in cellulose ether, alkali swelling type thickener, acrylic thickener, polyurethanes thickener
Thing.
7. the senior strength adhesive of multipurpose according to claim 4, it is characterised in that the described thixotropic agent is silicon
One kind in sour magnalium or organobentonite；Described preservative is sodium pentachlorophenol or 2,4,5- sodium 2,4,5-trichlorophenates；Wetting point
Powder is alcohol ethers wetting dispersing agent, and defoamer is fatty alcohol defoamer.
8. the senior strength adhesive of multipurpose according to claim 4, it is characterised in that the described stabilizer is PH
Regulatory function auxiliary agent or antioxidant；Preferred anti-oxidant is newborn aromatic amine, Hinered phenols, phosphite ester kind antioxidant.
9. the senior strength adhesive of multipurpose according to claim 1, it is characterised in that the senior strong bond of the multipurpose
The component that agent includes following parts by weight is made：
Aqueous polymer resin：70-80 parts by weight,
Tackifier resin emulsion：10-20 parts by weight,
Filler：0-10 parts by weight,
Wetting dispersing agent：0.1-0.3 parts by weight,
Defoamer：0.2-0.3 parts by weight,
Thickener：0.2-0.4 parts by weight,
Stabilizer：0.5-1.0 parts by weight,
Thixotropic agent：0.2-0.5 parts by weight,
Preservative：0.4-0.6 parts by weight.
10. the preparation method of the senior strength adhesive of multipurpose described in claim 1-9 any one claims, its feature
It is that this method comprises the following steps：By aqueous polymer resin, tackifier resin emulsion and auxiliary agent mixing put into high-speed dispersing kettle
In, stir.
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| CN201710287015.4A CN106978107B (en) | 2017-04-27 | 2017-04-27 | Multipurpose high-grade strong binder |
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| CN201710287015.4A CN106978107B (en) | 2017-04-27 | 2017-04-27 | Multipurpose high-grade strong binder |
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Cited By (11)
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| CN107586495A (en) * | 2017-09-28 | 2018-01-16 | 马鞍山松鹤信息科技有限公司 | A kind of environment-friendly waterproof paint and its preparation technology |
| CN107936878A (en) * | 2017-12-04 | 2018-04-20 | 中山富洲胶粘制品有限公司 | A kind of high viscous emulsion-type pressure-sensitive adhesive and preparation method thereof |
| CN108276933A (en) * | 2018-01-11 | 2018-07-13 | 湘潭大学 | Environment-friendly type aqueous fitting adhesive of one kind and preparation method thereof and bonding process |
| CN108753211A (en) * | 2018-06-22 | 2018-11-06 | 苏州金螳螂建筑装饰股份有限公司 | Fall off the glue and preparation method thereof of repairing, application for finishing material hollowing |
| CN109868098A (en) * | 2019-01-21 | 2019-06-11 | 桐城市桐佳装饰有限公司 | A kind of family bathroom space marine glue preparation method |
| CN110157359A (en) * | 2019-06-21 | 2019-08-23 | 江苏国胶新材料有限公司 | A kind of environment protection tile gum and preparation method thereof |
| CN110205059A (en) * | 2019-07-15 | 2019-09-06 | 湖北碱克新材料有限公司 | A kind of ceramic tile stone material gum of high-weatherability and preparation method thereof |
| CN110205062A (en) * | 2019-05-07 | 2019-09-06 | 杨涛 | A kind of aqueous binder and preparation method thereof |
| CN110776863A (en) * | 2019-10-31 | 2020-02-11 | 湖南高瑞电源材料有限公司 | Special adhesive for modified lithium battery ceramic diaphragm and preparation method and application thereof |
| CN112608107A (en) * | 2020-12-31 | 2021-04-06 | 苏州佳固士新材料科技有限公司 | Grouting material and preparation method and application thereof |
| CN113512205A (en) * | 2021-05-17 | 2021-10-19 | 平顶山市杰胜化工有限公司 | Formula and preparation method of aqueous tackifying emulsion |
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Cited By (12)
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| CN107586495A (en) * | 2017-09-28 | 2018-01-16 | 马鞍山松鹤信息科技有限公司 | A kind of environment-friendly waterproof paint and its preparation technology |
| CN107936878A (en) * | 2017-12-04 | 2018-04-20 | 中山富洲胶粘制品有限公司 | A kind of high viscous emulsion-type pressure-sensitive adhesive and preparation method thereof |
| CN108276933A (en) * | 2018-01-11 | 2018-07-13 | 湘潭大学 | Environment-friendly type aqueous fitting adhesive of one kind and preparation method thereof and bonding process |
| CN108753211A (en) * | 2018-06-22 | 2018-11-06 | 苏州金螳螂建筑装饰股份有限公司 | Fall off the glue and preparation method thereof of repairing, application for finishing material hollowing |
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| CN110205062A (en) * | 2019-05-07 | 2019-09-06 | 杨涛 | A kind of aqueous binder and preparation method thereof |
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| CN110776863B (en) * | 2019-10-31 | 2021-08-10 | 湖南高瑞电源材料有限公司 | Special adhesive for modified lithium battery ceramic diaphragm and preparation method and application thereof |
| CN112608107A (en) * | 2020-12-31 | 2021-04-06 | 苏州佳固士新材料科技有限公司 | Grouting material and preparation method and application thereof |
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