CN108165213A - A kind of preparation method of double-component aqueous environment-friendly type ceramic tile gum - Google Patents

A kind of preparation method of double-component aqueous environment-friendly type ceramic tile gum Download PDF

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Publication number
CN108165213A
CN108165213A CN201711449562.4A CN201711449562A CN108165213A CN 108165213 A CN108165213 A CN 108165213A CN 201711449562 A CN201711449562 A CN 201711449562A CN 108165213 A CN108165213 A CN 108165213A
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China
Prior art keywords
parts
preparation
ceramic tile
double
acrylic acid
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Application number
CN201711449562.4A
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Chinese (zh)
Inventor
李相志
刘成纲
王婷
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Suzhou Kai Yue New Mstar Technology Ltd
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Suzhou Kai Yue New Mstar Technology Ltd
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Priority to CN201711449562.4A priority Critical patent/CN108165213A/en
Publication of CN108165213A publication Critical patent/CN108165213A/en
Withdrawn legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J131/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Adhesives based on derivatives of such polymers
    • C09J131/02—Homopolymers or copolymers of esters of monocarboxylic acids
    • C09J131/04—Homopolymers or copolymers of vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F218/02—Esters of monocarboxylic acids
    • C08F218/04—Vinyl esters
    • C08F218/08—Vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1803—C3-(meth)acrylate, e.g. (iso)propyl (meth)acrylate

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Finishing Walls (AREA)

Abstract

The present invention provides a kind of preparation methods of double-component aqueous environment-friendly type ceramic tile gum.The preparation method, includes the following steps：1) using alkyl methacrylate monomer, function monomer, initiator, compound emulsifying agent as raw material, using water as medium dissolve after reaction prepare acrylic acid ester emulsion；2) using vinyl acetate, acrylate, acrylic acid, initiator, emulsifier as raw material, using water as medium dissolve after reaction prepare vinyl acetate acrylic acid ester copolymer emulsion；3) 30~50 parts of acrylic acid ester emulsion and 40~60 parts of vinyl acetate acrylic acid ester copolymer emulsion by weight, are taken, after mixing, obtains the double-component aqueous environment-friendly type ceramic tile gum.The preparation method of the double-component aqueous environment-friendly type ceramic tile gum of the present invention, simple and convenient, double-component aqueous environment-friendly type ceramic tile gum obtained has environment friendly on the basis of good adhesive property is ensured.

Description

A kind of preparation method of double-component aqueous environment-friendly type ceramic tile gum
Technical field
The invention belongs to ceramic tile gum technical fields, are related to a kind of preparation side of double-component aqueous environment-friendly type ceramic tile gum Method.
Background technology
Ceramic tile in paste process, due to by execution conditions, environment temperature, binding material, especially ceramic tile consistency and The influence of water absorption rate, the phenomenon that often coming off；Ceramic tile gum is specifically applied to the back side process of wet combining ceramic tile, is also applied for The stone material that low water absorption, quality are fine and close, surface is smooth, can effectively improve the adhesion strength between ceramic tile and binding material, solve Certainly hollowing common in ceramic tile wet combining, the problems such as coming off.
CN105969308A discloses a kind of vitrified tile ecological environment-friendly type ceramic tile gum, the vitrified tile ecology of the invention Environment-friendly type ceramic tile gum, including following components：Micro-nano acrylic emulsion 20%~40%；Modified pressure-sensitive adhesive lotion 20%~ 40%；Styrene-butadiene emulsion 4%~10%；Thickener 0.1%~0.2%；Coalescents 0.2%~0.5%；Antifoaming agent 0.1%~ 0.3%；Preservative 0.1%~0.5%；Mould inhibitor 0.1%~0.5%；Remaining is deionized water, and the gum adhesion strength is high, A new rough surface can be formed in the adhesive surface of vitrified tile, the cementitiousness being allowed between enhancing and binding material；Flexibility Good, curing shrinkage is small, strong with cement base binding material compatibility, is firmly bonded.
In gum raw material of the prior art, solvent or coalescents need to be often added in improve the compatibility performance of raw material and mix Effect is closed, but solvent or coalescents are generally organic solvent and serious pollution caused to air, and product gum is applied to porcelain There is very big healthy hidden danger to health after brick finishing.Therefore, a kind of ceramic tile of not solvent-laden aqueous environment protection is developed Gum is necessary.
Invention content
In view of the deficiencies of the prior art, the purpose of the present invention is to provide a kind of double-component aqueous environment-friendly type ceramic tile gums Preparation method, it is simple and convenient, double-component aqueous environment-friendly type ceramic tile gum obtained on the basis of good adhesive property is ensured, With environment friendly.
For this purpose, the present invention uses following technical scheme：
The preparation method of the double-component aqueous environment-friendly type ceramic tile gum of the present invention, includes the following steps：
1) using alkyl methacrylate monomer, function monomer, initiator, compound emulsifying agent as raw material, using water as Jie Reaction prepares acrylic acid ester emulsion after matter dissolving；
2) it using vinyl acetate, acrylate, acrylic acid, initiator, emulsifier as raw material, is reacted after being dissolved using water as medium Prepare vinyl acetate-acrylic copolymer emulsion；
3) acrylic acid ester emulsion and 40~60 parts of the vinyl acetate-acrylate for by weight, taking 30~50 parts are common Poly- lotion after mixing, obtains the double-component aqueous environment-friendly type ceramic tile gum.
Wherein, in step 1), double-component aqueous environment-friendly type ceramic tile gum of the invention, by weight, including such as the following group Point：
30~50 parts of acrylic acid ester emulsion
40~60 parts of vinyl acetate-acrylic copolymer emulsion,
Wherein, the acrylic acid ester emulsion and the vinyl acetate-acrylic copolymer emulsion by monomer, initiator, Emulsifier reacts after being dissolved using water as medium to be made.
Wherein, double-component aqueous environment-friendly type ceramic tile gum of the invention, by weight, including following component：
30~50 parts of acrylic acid ester emulsion, for example, acrylic acid ester emulsion parts by weight for 30 parts, 31 parts, 32 parts, 33 parts, 34 Part, 35 parts, 36 parts, 37 parts, 38 parts, 39 parts, 40 parts, 41 parts, 42 parts, 43 parts, 44 parts, 45 parts, 46 parts, 47 parts, 48 parts, 49 Part, 50 parts.
40~60 parts of vinyl acetate-acrylic copolymer emulsion, such as the weight of vinyl acetate-acrylic copolymer emulsion Part for 40 parts, 41 parts, 42 parts, 43 parts, 44 parts, 45 parts, 46 parts, 47 parts, 48 parts, 49 parts, 50 parts, 51 parts, 52 parts, 53 parts, 54 Part, 55 parts, 56 parts, 57 parts, 58 parts, 59 parts, 60 parts.
Wherein, by weight, the acrylic acid ester emulsion includes following component：
30~50 parts of alkyl methacrylate monomer, such as the parts by weight of alkyl methacrylate monomer are 30 Part, 31 parts, 32 parts, 33 parts, 34 parts, 35 parts, 36 parts, 37 parts, 38 parts, 39 parts, 40 parts, 41 parts, 42 parts, 43 parts, 44 parts, 45 Part, 46 parts, 47 parts, 48 parts, 49 parts, 50 parts.
5~10 parts of function monomer, such as the parts by weight of function monomer are 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts.
1~5 part of initiator, such as the parts by weight of initiator are 1 part, 2 parts, 3 parts, 4 parts, 5 parts.
5~10 parts of compound emulsifying agent, such as the parts by weight of compound emulsifying agent are 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts.
20~40 parts of water, for example, water parts by weight for 20 parts, 21 parts, 22 parts, 23 parts, 24 parts, 25 parts, 26 parts, 27 parts, 28 Part, 29 parts, 30 parts, 31 parts, 32 parts, 33 parts, 34 parts, 35 parts, 36 parts, 37 parts, 38 parts, 39 parts, 40 parts.
The alkyl methacrylate monomer is methyl methacrylate, ethyl methacrylate, methacrylic acid One kind or at least two mixture in propyl ester, butyl methacrylate.
The function monomer is dimethylaminoethyl methacrylate, N hydroxymethyl acrylamide, N- hydroxymethyl, methyls third One kind or at least two mixture in acrylamide, acrylamide.
The initiator is potassium peroxydisulfate and/or ammonium persulfate.
The compound emulsifying agent is the compound of anionic surfactant.
The anionic surfactant is stearic acid sodium salt, lauryl sodium sulfate salt and calcium dodecyl benzene sulfonate One kind or at least two mixture in salt.
In step 2), by weight, the vinyl acetate-acrylic copolymer emulsion includes following component：
30~40 parts of vinyl acetate, for example, vinyl acetate parts by weight for 30 parts, 31 parts, 32 parts, 33 parts, 34 parts, 35 parts, 36 parts, 37 parts, 38 parts, 39 parts, 40 parts.
20~30 parts of acrylate, for example, acrylate parts by weight for 20 parts, 21 parts, 22 parts, 23 parts, 24 parts, 25 parts, 26 parts, 27 parts, 28 parts, 29 parts, 30 parts.
10~20 parts of acrylic acid, for example, acrylic acid parts by weight for 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts, 16 Part, 17 parts, 18 parts, 19 parts, 20 parts.
1~5 part of initiator, such as the parts by weight of initiator are 1 part, 2 parts, 3 parts, 4 parts, 5 parts.
1~10 part of emulsifier, for example, emulsifier parts by weight for 1 part, 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 Part, 10 parts.
20~50 parts of water, for example, water parts by weight for 20 parts, 21 parts, 22 parts, 23 parts, 24 parts, 25 parts, 26 parts, 27 parts, 28 Part, 29 parts, 30 parts, 31 parts, 32 parts, 33 parts, 34 parts, 35 parts, 36 parts, 37 parts, 38 parts, 39 parts, 40 parts, 41 parts, 42 parts, 43 Part, 44 parts, 45 parts, 46 parts, 47 parts, 48 parts, 49 parts, 50 parts.
The initiator is potassium peroxydisulfate and/or ammonium persulfate；
Preferably, emulsifier is anion emulsifier.
Preferably, double-component aqueous environment-friendly type ceramic tile gum of the invention, by weight, including following component：
Compared with prior art, beneficial effects of the present invention are：
The preparation method of the double-component aqueous environment-friendly type ceramic tile gum of the present invention, the solvent used are deionized water, are not added It is pollution-free, environment friendly is good added with solvent and coalescents.The system of the double-component aqueous environment-friendly type ceramic tile gum of the present invention Preparation Method, the adhesion strength of double-component aqueous environment-friendly type ceramic tile gum obtained are ensureing good bonding in more than 1.2MPa On the basis of performance, there is good environment friendly.
Specific embodiment
The technical solution further illustrated the present invention below by specific embodiment.
Unless specific instructions, various raw materials of the invention are commercially available buys or is prepared according to the conventional method of this field It obtains.
The preparation method of the double-component aqueous environment-friendly type ceramic tile gum of the present invention, includes the following steps：
1) using alkyl methacrylate monomer, function monomer, initiator, compound emulsifying agent as raw material, using water as Jie Reaction prepares acrylic acid ester emulsion after matter dissolving；
2) it using vinyl acetate, acrylate, acrylic acid, initiator, emulsifier as raw material, is reacted after being dissolved using water as medium Prepare vinyl acetate-acrylic copolymer emulsion；
3) acrylic acid ester emulsion and 40~60 parts of the vinyl acetate-acrylate for by weight, taking 30~50 parts are common Poly- lotion after mixing, obtains the double-component aqueous environment-friendly type ceramic tile gum.
The double-component aqueous environment-friendly type ceramic tile gum of following embodiment is prepared using above-mentioned preparation method.
Embodiment 1
The double-component aqueous environment-friendly type ceramic tile gum of the present embodiment, by weight, including following component：
40 parts of acrylic acid ester emulsion
60 parts of vinyl acetate-acrylic copolymer emulsion,
Wherein, by weight, the acrylic acid ester emulsion includes following component：
By weight, the vinyl acetate-acrylic copolymer emulsion includes following component：
The adhesion strength of double-component aqueous environment-friendly type ceramic tile gum made from the present embodiment is 1.3MPa, is dried in 1h solid Change, environment friendly is good.
Embodiment 2
The double-component aqueous environment-friendly type ceramic tile gum of the present embodiment, by weight, including following component：
50 parts of acrylic acid ester emulsion
45 parts of vinyl acetate-acrylic copolymer emulsion,
Wherein, by weight, the acrylic acid ester emulsion includes following component：
By weight, the vinyl acetate-acrylic copolymer emulsion includes following component：
The adhesion strength of double-component aqueous environment-friendly type ceramic tile gum made from the present embodiment is 1.2MPa, is dried in 1h solid Change, environment friendly is good.
Embodiment 3
The double-component aqueous environment-friendly type ceramic tile gum of the present embodiment, by weight, including following component：
50 parts of acrylic acid ester emulsion
40 parts of vinyl acetate-acrylic copolymer emulsion,
Wherein, by weight, the acrylic acid ester emulsion includes following component：
By weight, the vinyl acetate-acrylic copolymer emulsion includes following component：
The adhesion strength of double-component aqueous environment-friendly type ceramic tile gum made from the present embodiment is 1.5MPa, is dried in 1h solid Change, environment friendly is good.
Embodiment 4
The double-component aqueous environment-friendly type ceramic tile gum of the present embodiment, by weight, including following component：
46 parts of acrylic acid ester emulsion
55 parts of vinyl acetate-acrylic copolymer emulsion,
Wherein, by weight, the acrylic acid ester emulsion includes following component：
By weight, the vinyl acetate-acrylic copolymer emulsion includes following component：
The adhesion strength of double-component aqueous environment-friendly type ceramic tile gum made from the present embodiment is 1.3MPa, is dried in 1h solid Change, environment friendly is good.
Embodiment 5
The double-component aqueous environment-friendly type ceramic tile gum of the present embodiment, by weight, including following component：
30 parts of acrylic acid ester emulsion
40 parts of vinyl acetate-acrylic copolymer emulsion,
Wherein, by weight, the acrylic acid ester emulsion includes following component：
By weight, the vinyl acetate-acrylic copolymer emulsion includes following component：
The adhesion strength of double-component aqueous environment-friendly type ceramic tile gum made from the present embodiment is 1.4MPa, is dried in 1h solid Change, environment friendly is good.
Comparative example
The type ceramic tile gum of this comparative example, by weight, including following component：
40 parts of acrylic acid ester emulsion
60 parts of vinyl acetate-acrylic copolymer emulsion,
Wherein, by weight, the acrylic acid ester emulsion includes following component：
By weight, the vinyl acetate-acrylic copolymer emulsion includes following component：
The adhesion strength of double-component aqueous environment-friendly type ceramic tile gum made from this comparative example is 0.9MPa, is dried in 1h solid Change, environment friendly is good.
The present invention illustrates the detailed process equipment of the present invention and technological process, but the present invention is not by above-described embodiment Above-mentioned detailed process equipment and technological process are confined to, that is, does not mean that the present invention has to rely on above-mentioned detailed process equipment and work Skill flow could be implemented.Person of ordinary skill in the field is it will be clearly understood that any improvement in the present invention, to product of the present invention The equivalence replacement of each raw material and the addition of auxiliary element, the selection of concrete mode etc., all fall within protection scope of the present invention and public affairs Within the scope of opening.

Claims (10)

1. a kind of preparation method of double-component aqueous environment-friendly type ceramic tile gum, which is characterized in that the preparation method includes as follows Step：
1) it is molten by medium of water using alkyl methacrylate monomer, function monomer, initiator, compound emulsifying agent as raw material Reaction prepares acrylic acid ester emulsion after solution；
2) it using vinyl acetate, acrylate, acrylic acid, initiator, emulsifier as raw material, reacts and prepares after being dissolved using water as medium Vinyl acetate-acrylic copolymer emulsion；
3) 30~50 parts of acrylic acid ester emulsion and 40~60 parts of vinyl acetate-acrylic ester copolymer breast by weight, is taken Liquid after mixing, obtains the double-component aqueous environment-friendly type ceramic tile gum.
2. preparation method according to claim 1, which is characterized in that in step 1), by weight, the acrylate Lotion includes following component：
3. preparation method according to claim 2, which is characterized in that the alkyl methacrylate monomer is methyl One kind in methyl acrylate, ethyl methacrylate, propyl methacrylate, butyl methacrylate or at least two it is mixed Close object.
4. the preparation method according to Claims 2 or 3, which is characterized in that the function monomer is dimethylaminoethyl acrylate methyl Amino ethyl ester, N hydroxymethyl acrylamide, N- methylol methacrylamides, one kind in acrylamide or at least two it is mixed Close object.
5. according to the preparation method described in one of claim 2-4, which is characterized in that the initiator for potassium peroxydisulfate and/or Ammonium persulfate.
6. according to the preparation method described in one of claim 2-5, which is characterized in that the compound emulsifying agent is anionic table The compound of face activating agent.
7. preparation method according to claim 6, which is characterized in that the anionic surfactant is odium stearate Salt, lauryl sodium sulfate salt and one kind or at least two mixture in calcium salt of dodecylbenzene sulfonate.
8. according to the preparation method described in one of claim 1-7, which is characterized in that in step 2), by weight, the vinegar Sour ethylene-acrylate copolymers lotion includes following component：
9. preparation method according to claim 8, which is characterized in that the initiator is potassium peroxydisulfate and/or mistake Ammonium sulfate；
Preferably, emulsifier is anion emulsifier.
10. according to the preparation method described in one of claim 1-9, which is characterized in that by weight, including following component：
CN201711449562.4A 2017-12-27 2017-12-27 A kind of preparation method of double-component aqueous environment-friendly type ceramic tile gum Withdrawn CN108165213A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109294453A (en) * 2018-10-12 2019-02-01 扬州中涂科技集团有限公司 A kind of ceramic tile back gluing lotion
CN109468096A (en) * 2018-11-07 2019-03-15 温雄权 A kind of acrylate adhesive and preparation method thereof

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CN104193881A (en) * 2014-09-05 2014-12-10 江苏李文甲化工有限公司 Acrylate emulsion for waterborne multicolor paint and production process of acrylate emulsion
CN105885739A (en) * 2016-05-19 2016-08-24 东莞铭丰生物质科技有限公司 Water-based adhesive and preparation method thereof

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CN104193881A (en) * 2014-09-05 2014-12-10 江苏李文甲化工有限公司 Acrylate emulsion for waterborne multicolor paint and production process of acrylate emulsion
CN105885739A (en) * 2016-05-19 2016-08-24 东莞铭丰生物质科技有限公司 Water-based adhesive and preparation method thereof

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109294453A (en) * 2018-10-12 2019-02-01 扬州中涂科技集团有限公司 A kind of ceramic tile back gluing lotion
CN109468096A (en) * 2018-11-07 2019-03-15 温雄权 A kind of acrylate adhesive and preparation method thereof

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