CN108148530A - A kind of double-component aqueous environment-friendly type ceramic tile gum - Google Patents
A kind of double-component aqueous environment-friendly type ceramic tile gum Download PDFInfo
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- CN108148530A CN108148530A CN201711445732.1A CN201711445732A CN108148530A CN 108148530 A CN108148530 A CN 108148530A CN 201711445732 A CN201711445732 A CN 201711445732A CN 108148530 A CN108148530 A CN 108148530A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J131/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Adhesives based on derivatives of such polymers
- C09J131/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C09J131/04—Homopolymers or copolymers of vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
- C08F218/02—Esters of monocarboxylic acids
- C08F218/04—Vinyl esters
- C08F218/08—Vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/24—Homopolymers or copolymers of amides or imides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/24—Homopolymers or copolymers of amides or imides
- C09J133/26—Homopolymers or copolymers of acrylamide or methacrylamide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1803—C3-(meth)acrylate, e.g. (iso)propyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Finishing Walls (AREA)
Abstract
The present invention provides a kind of double-component aqueous environment-friendly type ceramic tile gums.The double-component aqueous environment-friendly type ceramic tile gum of the present invention, by weight, including following component：30~50 parts of acrylic acid ester emulsion, 40~60 parts of vinyl acetate acrylic acid ester copolymer emulsion, wherein, the acrylic acid ester emulsion and the vinyl acetate acrylic acid ester copolymer emulsion react after being dissolved by monomer, initiator, emulsifier using water as medium to be made.The double-component aqueous environment-friendly type ceramic tile gum of the present invention, adhesion strength is in more than 1.2MPa, on the basis of good adhesive property is ensured, has environment friendly.
Description
Technical field
The invention belongs to ceramic tile gum technical fields, are related to a kind of double-component aqueous environment-friendly type ceramic tile gum.
Background technology
Ceramic tile in paste process, due to by execution conditions, environment temperature, binding material, especially ceramic tile consistency and
The influence of water absorption rate, the phenomenon that often coming off；Ceramic tile gum is specifically applied to the back side process of wet combining ceramic tile, is also applied for
The stone material that low water absorption, quality are fine and close, surface is smooth, can effectively improve the adhesion strength between ceramic tile and binding material, solve
Certainly hollowing common in ceramic tile wet combining, the problems such as coming off.
CN105969308A discloses a kind of vitrified tile ecological environment-friendly type ceramic tile gum, the vitrified tile ecology of the invention
Environment-friendly type ceramic tile gum, including following components：Micro-nano acrylic emulsion 20%~40%；Modified pressure-sensitive adhesive lotion 20%~
40%；Styrene-butadiene emulsion 4%~10%；Thickener 0.1%~0.2%；Coalescents 0.2%~0.5%；Antifoaming agent 0.1%~
0.3%；Preservative 0.1%~0.5%；Mould inhibitor 0.1%~0.5%；Remaining is deionized water, and the gum adhesion strength is high,
A new rough surface can be formed in the adhesive surface of vitrified tile, the cementitiousness being allowed between enhancing and binding material；Flexibility
Good, curing shrinkage is small, strong with cement base binding material compatibility, is firmly bonded.
In gum raw material of the prior art, solvent or coalescents need to be often added in improve the compatibility performance of raw material and mix
Effect is closed, but solvent or coalescents are generally organic solvent and serious pollution caused to air, and product gum is applied to porcelain
There is very big healthy hidden danger to health after brick finishing.Therefore, a kind of ceramic tile of not solvent-laden aqueous environment protection is developed
Gum is necessary.
Invention content
In view of the deficiencies of the prior art, the purpose of the present invention is to provide a kind of double-component aqueous environment-friendly type ceramic tile gum,
On the basis of good adhesive property is ensured, there is environment friendly.
For this purpose, the present invention uses following technical scheme：
A kind of double-component aqueous environment-friendly type ceramic tile gum, by weight, including following component：
30~50 parts of acrylic acid ester emulsion
40~60 parts of vinyl acetate-acrylic copolymer emulsion,
Wherein, the acrylic acid ester emulsion and the vinyl acetate-acrylic copolymer emulsion by monomer, initiator,
Emulsifier reacts after being dissolved using water as medium to be made.
Wherein, double-component aqueous environment-friendly type ceramic tile gum of the invention, by weight, including following component：
30~50 parts of acrylic acid ester emulsion, for example, acrylic acid ester emulsion parts by weight for 30 parts, 31 parts, 32 parts, 33 parts, 34
Part, 35 parts, 36 parts, 37 parts, 38 parts, 39 parts, 40 parts, 41 parts, 42 parts, 43 parts, 44 parts, 45 parts, 46 parts, 47 parts, 48 parts, 49
Part, 50 parts.
40~60 parts of vinyl acetate-acrylic copolymer emulsion, such as the weight of vinyl acetate-acrylic copolymer emulsion
Part for 40 parts, 41 parts, 42 parts, 43 parts, 44 parts, 45 parts, 46 parts, 47 parts, 48 parts, 49 parts, 50 parts, 51 parts, 52 parts, 53 parts, 54
Part, 55 parts, 56 parts, 57 parts, 58 parts, 59 parts, 60 parts.
Wherein, by weight, the acrylic acid ester emulsion includes following component：
30~50 parts of alkyl methacrylate monomer, such as the parts by weight of alkyl methacrylate monomer are 30
Part, 31 parts, 32 parts, 33 parts, 34 parts, 35 parts, 36 parts, 37 parts, 38 parts, 39 parts, 40 parts, 41 parts, 42 parts, 43 parts, 44 parts, 45
Part, 46 parts, 47 parts, 48 parts, 49 parts, 50 parts.
5~10 parts of function monomer, such as the parts by weight of function monomer are 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts.
1~5 part of initiator, such as the parts by weight of initiator are 1 part, 2 parts, 3 parts, 4 parts, 5 parts.
5~10 parts of compound emulsifying agent, such as the parts by weight of compound emulsifying agent are 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts.
20~40 parts of water, for example, water parts by weight for 20 parts, 21 parts, 22 parts, 23 parts, 24 parts, 25 parts, 26 parts, 27 parts, 28
Part, 29 parts, 30 parts, 31 parts, 32 parts, 33 parts, 34 parts, 35 parts, 36 parts, 37 parts, 38 parts, 39 parts, 40 parts.
The alkyl methacrylate monomer is methyl methacrylate, ethyl methacrylate, methacrylic acid
One kind or at least two mixture in propyl ester, butyl methacrylate.
The function monomer is dimethylaminoethyl methacrylate, N hydroxymethyl acrylamide, N- hydroxymethyl, methyls third
One kind or at least two mixture in acrylamide, acrylamide.
The initiator is potassium peroxydisulfate and/or ammonium persulfate.
The compound emulsifying agent is the compound of anionic surfactant.
The anionic surfactant is stearic acid sodium salt, lauryl sodium sulfate salt and calcium dodecyl benzene sulfonate
One kind or at least two mixture in salt.
By weight, the vinyl acetate-acrylic copolymer emulsion includes following component：
30~40 parts of vinyl acetate, for example, vinyl acetate parts by weight for 30 parts, 31 parts, 32 parts, 33 parts, 34 parts, 35 parts,
36 parts, 37 parts, 38 parts, 39 parts, 40 parts.
20~30 parts of acrylate, for example, acrylate parts by weight for 20 parts, 21 parts, 22 parts, 23 parts, 24 parts, 25 parts,
26 parts, 27 parts, 28 parts, 29 parts, 30 parts.
10~20 parts of acrylic acid, for example, acrylic acid parts by weight for 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts, 16
Part, 17 parts, 18 parts, 19 parts, 20 parts.
1~5 part of initiator, such as the parts by weight of initiator are 1 part, 2 parts, 3 parts, 4 parts, 5 parts.
1~10 part of emulsifier, for example, emulsifier parts by weight for 1 part, 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9
Part, 10 parts.
20~50 parts of water, for example, water parts by weight for 20 parts, 21 parts, 22 parts, 23 parts, 24 parts, 25 parts, 26 parts, 27 parts, 28
Part, 29 parts, 30 parts, 31 parts, 32 parts, 33 parts, 34 parts, 35 parts, 36 parts, 37 parts, 38 parts, 39 parts, 40 parts, 41 parts, 42 parts, 43
Part, 44 parts, 45 parts, 46 parts, 47 parts, 48 parts, 49 parts, 50 parts.
The initiator is potassium peroxydisulfate and/or ammonium persulfate；
Preferably, emulsifier is anion emulsifier.
Preferably, double-component aqueous environment-friendly type ceramic tile gum of the invention, by weight, including following component：
The preparation method of the double-component aqueous environment-friendly type ceramic tile gum of the present invention, includes the following steps：
1) using monomer, initiator, emulsifier as raw material, using water as medium dissolve after reaction prepare acrylic acid ester emulsion；
2) using monomer, initiator, emulsifier as raw material, using water as medium dissolve after reaction prepare vinyl acetate-acrylic acid
Ester copolymer emulsion；
3) acrylic acid ester emulsion and 40~60 parts of the vinyl acetate-acrylate for by weight, taking 30~50 parts are common
Poly- lotion after mixing, obtains the double-component aqueous environment-friendly type ceramic tile gum.
Compared with prior art, beneficial effects of the present invention are：
The double-component aqueous environment-friendly type ceramic tile gum of the present invention, the solvent used are deionized water, do not add organic solvent
And coalescents, it is pollution-free, environment friendly is good.The double-component aqueous environment-friendly type ceramic tile gum of the present invention, adhesion strength exist
More than 1.2MPa on the basis of good adhesive property is ensured, has good environment friendly.
Specific embodiment
The technical solution further illustrated the present invention below by specific embodiment.
Unless specific instructions, various raw materials of the invention are commercially available buys or is prepared according to the conventional method of this field
It obtains.
Embodiment 1
The double-component aqueous environment-friendly type ceramic tile gum of the present embodiment, by weight, including following component：
40 parts of acrylic acid ester emulsion
60 parts of vinyl acetate-acrylic copolymer emulsion,
Wherein, by weight, the acrylic acid ester emulsion includes following component：
By weight, the vinyl acetate-acrylic copolymer emulsion includes following component：
The adhesion strength of double-component aqueous environment-friendly type ceramic tile gum made from the present embodiment is 1.3MPa, is dried in 1h solid
Change, environment friendly is good.
Embodiment 2
The double-component aqueous environment-friendly type ceramic tile gum of the present embodiment, by weight, including following component：
50 parts of acrylic acid ester emulsion
45 parts of vinyl acetate-acrylic copolymer emulsion,
Wherein, by weight, the acrylic acid ester emulsion includes following component：
By weight, the vinyl acetate-acrylic copolymer emulsion includes following component：
The adhesion strength of double-component aqueous environment-friendly type ceramic tile gum made from the present embodiment is 1.2MPa, is dried in 1h solid
Change, environment friendly is good.
Embodiment 3
The double-component aqueous environment-friendly type ceramic tile gum of the present embodiment, by weight, including following component：
50 parts of acrylic acid ester emulsion
40 parts of vinyl acetate-acrylic copolymer emulsion,
Wherein, by weight, the acrylic acid ester emulsion includes following component：
By weight, the vinyl acetate-acrylic copolymer emulsion includes following component：
The adhesion strength of double-component aqueous environment-friendly type ceramic tile gum made from the present embodiment is 1.5MPa, is dried in 1h solid
Change, environment friendly is good.
Embodiment 4
The double-component aqueous environment-friendly type ceramic tile gum of the present embodiment, by weight, including following component：
46 parts of acrylic acid ester emulsion
55 parts of vinyl acetate-acrylic copolymer emulsion,
Wherein, by weight, the acrylic acid ester emulsion includes following component：
By weight, the vinyl acetate-acrylic copolymer emulsion includes following component：
The adhesion strength of double-component aqueous environment-friendly type ceramic tile gum made from the present embodiment is 1.3MPa, is dried in 1h solid
Change, environment friendly is good.
Embodiment 5
The double-component aqueous environment-friendly type ceramic tile gum of the present embodiment, by weight, including following component：
30 parts of acrylic acid ester emulsion
40 parts of vinyl acetate-acrylic copolymer emulsion,
Wherein, by weight, the acrylic acid ester emulsion includes following component：
By weight, the vinyl acetate-acrylic copolymer emulsion includes following component：
The adhesion strength of double-component aqueous environment-friendly type ceramic tile gum made from the present embodiment is 1.4MPa, is dried in 1h solid
Change, environment friendly is good.
Comparative example
The type ceramic tile gum of this comparative example, by weight, including following component：
40 parts of acrylic acid ester emulsion
60 parts of vinyl acetate-acrylic copolymer emulsion,
Wherein, by weight, the acrylic acid ester emulsion includes following component：
By weight, the vinyl acetate-acrylic copolymer emulsion includes following component：
The adhesion strength of double-component aqueous environment-friendly type ceramic tile gum made from this comparative example is 0.9MPa, is dried in 1h solid
Change, environment friendly is good.
The present invention illustrates the detailed process equipment of the present invention and technological process, but the present invention is not by above-described embodiment
Above-mentioned detailed process equipment and technological process are confined to, that is, does not mean that the present invention has to rely on above-mentioned detailed process equipment and work
Skill flow could be implemented.Person of ordinary skill in the field is it will be clearly understood that any improvement in the present invention, to product of the present invention
The equivalence replacement of each raw material and the addition of auxiliary element, the selection of concrete mode etc., all fall within protection scope of the present invention and public affairs
Within the scope of opening.
Claims (10)
1. a kind of double-component aqueous environment-friendly type ceramic tile gum, which is characterized in that by weight, including following component：
30~50 parts of acrylic acid ester emulsion
40~60 parts of vinyl acetate-acrylic copolymer emulsion,
Wherein, the acrylic acid ester emulsion and the vinyl acetate-acrylic copolymer emulsion are by monomer, initiator, emulsification
Agent is reacted after being dissolved using water as medium to be made.
2. double-component aqueous environment-friendly type ceramic tile gum according to claim 1, which is characterized in that by weight, described
Acrylic acid ester emulsion includes following component：
3. double-component aqueous environment-friendly type ceramic tile gum according to claim 2, which is characterized in that the methacrylic acid alkane
Base esters monomer is one in methyl methacrylate, ethyl methacrylate, propyl methacrylate, butyl methacrylate
Kind or at least two mixture.
4. the double-component aqueous environment-friendly type ceramic tile gum according to Claims 2 or 3, which is characterized in that the function monomer
For one in dimethylaminoethyl methacrylate, N hydroxymethyl acrylamide, N- methylol methacrylamides, acrylamide
Kind or at least two mixture.
5. the double-component aqueous environment-friendly type ceramic tile gum according to one of claim 2-4, which is characterized in that the initiator
For potassium peroxydisulfate and/or ammonium persulfate.
6. the double-component aqueous environment-friendly type ceramic tile gum according to one of claim 2-5, which is characterized in that the Composite Milk
Agent is the compound of anionic surfactant.
7. double-component aqueous environment-friendly type ceramic tile gum according to claim 6, which is characterized in that the anionic surface
Activating agent is stearic acid sodium salt, lauryl sodium sulfate salt and one kind in calcium salt of dodecylbenzene sulfonate or at least two it is mixed
Close object.
8. the double-component aqueous environment-friendly type ceramic tile gum according to one of claim 1-7, which is characterized in that by weight
Meter, the vinyl acetate-acrylic copolymer emulsion include following component：
9. double-component aqueous environment-friendly type ceramic tile gum according to claim 8, which is characterized in that the initiator is
Potassium peroxydisulfate and/or ammonium persulfate；
Preferably, emulsifier is anion emulsifier.
10. the double-component aqueous environment-friendly type ceramic tile gum according to one of claim 1-9, which is characterized in that by weight
Meter, including following component：
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711445732.1A CN108148530A (en) | 2017-12-27 | 2017-12-27 | A kind of double-component aqueous environment-friendly type ceramic tile gum |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201711445732.1A CN108148530A (en) | 2017-12-27 | 2017-12-27 | A kind of double-component aqueous environment-friendly type ceramic tile gum |
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| CN201711445732.1A Withdrawn CN108148530A (en) | 2017-12-27 | 2017-12-27 | A kind of double-component aqueous environment-friendly type ceramic tile gum |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109294453A (en) * | 2018-10-12 | 2019-02-01 | 扬州中涂科技集团有限公司 | A kind of ceramic tile back gluing lotion |
| CN110791234A (en) * | 2019-10-30 | 2020-02-14 | 广州全系建材有限公司 | Continuous-bonding ceramic tile adhesive and preparation method thereof |
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| CN101481592A (en) * | 2009-01-16 | 2009-07-15 | 上海漠王复合材料科技有限公司 | Anti-cracking adhesive for energy-saving lamp and preparation thereof |
| CN105885739A (en) * | 2016-05-19 | 2016-08-24 | 东莞铭丰生物质科技有限公司 | Water-based adhesive and preparation method thereof |
| CN106675457A (en) * | 2016-12-21 | 2017-05-17 | 安徽山水空间装饰有限责任公司 | Tile binder and application method thereof |
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2017
- 2017-12-27 CN CN201711445732.1A patent/CN108148530A/en not_active Withdrawn
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|---|---|---|---|---|
| CN101481592A (en) * | 2009-01-16 | 2009-07-15 | 上海漠王复合材料科技有限公司 | Anti-cracking adhesive for energy-saving lamp and preparation thereof |
| CN105885739A (en) * | 2016-05-19 | 2016-08-24 | 东莞铭丰生物质科技有限公司 | Water-based adhesive and preparation method thereof |
| CN106675457A (en) * | 2016-12-21 | 2017-05-17 | 安徽山水空间装饰有限责任公司 | Tile binder and application method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109294453A (en) * | 2018-10-12 | 2019-02-01 | 扬州中涂科技集团有限公司 | A kind of ceramic tile back gluing lotion |
| CN110791234A (en) * | 2019-10-30 | 2020-02-14 | 广州全系建材有限公司 | Continuous-bonding ceramic tile adhesive and preparation method thereof |
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Application publication date: 20180612 |