CN105885384A - 一种改性聚苯醚热固型塑料 - Google Patents

一种改性聚苯醚热固型塑料 Download PDF

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Publication number
CN105885384A
CN105885384A CN201610318378.5A CN201610318378A CN105885384A CN 105885384 A CN105885384 A CN 105885384A CN 201610318378 A CN201610318378 A CN 201610318378A CN 105885384 A CN105885384 A CN 105885384A
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China
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good
parts
polyphenyl ether
thermosetting plastic
modified polyphenyl
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徐春华
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Suzhou New District Huashida Engineering Plastic Co Ltd
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Suzhou New District Huashida Engineering Plastic Co Ltd
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Priority to CN201610318378.5A priority Critical patent/CN105885384A/zh
Priority to PCT/CN2016/083380 priority patent/WO2017197655A1/zh
Publication of CN105885384A publication Critical patent/CN105885384A/zh
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/14Peroxides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/08Polyethers derived from hydroxy compounds or from their metallic derivatives
    • C08L71/10Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
    • C08L71/12Polyphenylene oxides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/29Compounds containing one or more carbon-to-nitrogen double bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02Homopolymers or copolymers of hydrocarbons
    • C08L25/04Homopolymers or copolymers of styrene
    • C08L25/08Copolymers of styrene
    • C08L25/10Copolymers of styrene with conjugated dienes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L47/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Polyethers (AREA)

Abstract

本发明公开了一种改性聚苯醚热固型塑料,成分的质量配比包括:聚苯醚50份,聚丁二烯4‑6份,苯乙烯一丁二烯共聚物4‑6份,三烯丙基氰酸酯2‑3份,三烯丙基异氰酸酯2‑3份,过氧化二异丙苯1‑2份。通过上述方式,本发明改性聚苯醚热固型塑料具有热固性好、尺寸稳定性好、使用温度范围广、耐水汽性能好、强度高、硬度高、刚性好、韧性好、冲击强度高、耐腐蚀性好、自润滑性好、耐溶剂性好、安全实用等优点,在改性聚苯醚热固型塑料的普及上有着广泛的市场前景。

Description

一种改性聚苯醚热固型塑料
技术领域
本发明涉及工程塑料领域,特别是涉及一种改性聚苯醚热固型塑料。
背景技术
工程塑料可作工程材料和代替金属制造机器零部件等的塑料。工程塑料具有优良的综合性能,刚性大,蠕变小,机械强度高,耐热性好,电绝缘性好,可在较苛刻的化学、物理环境中长期使用,可替代金属作为工程结构材料使用,但现有的工程塑料的性能达不到较高要求。
发明内容
本发明主要解决的技术问题是提供一种改性聚苯醚热固型塑料,通过采用多种热固性物质添加进聚甲醛基体中形成改性热固型塑料,热固性好、尺寸稳定性好、使用温度范围广、耐水汽性能好、强度高、硬度高、刚性好、韧性好、冲击强度高、耐腐蚀性好、自润滑性好、耐溶剂性好、安全实用,在改性聚苯醚热固型塑料的普及上有着广泛的市场前景。
为解决上述技术问题,本发明提供一种改性聚苯醚热固型塑料,成分的质量配比包括:
聚苯醚50份,
聚丁二烯4-6份,
苯乙烯一丁二烯共聚物4-6份,
三烯丙基氰酸酯2-3份,
三烯丙基异氰酸酯2-3份,
过氧化二异丙苯1-2份。
在本发明一个较佳实施例中,所述改性聚苯醚热固型塑料包括添加剂。
在本发明一个较佳实施例中,所述添加剂包括增容剂、稳定剂、润滑剂的一种或者多种。
本发明的有益效果是:本发明改性聚苯醚热固型塑料具有热固性好、尺寸稳定性好、使用温度范围广、耐水汽性能好、强度高、硬度高、刚性好、韧性好、冲击强度高、耐腐蚀性好、自润滑性好、耐溶剂性好、安全实用等优点,在改性聚苯醚热固型塑料的普及上有着广泛的市场前景。
具体实施方式
下面将对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅是本发明的一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其它实施例,都属于本发明保护的范围。
本发明实施例包括:
一种改性聚苯醚热固型塑料,成分的质量配比包括:
聚苯醚50份,
聚丁二烯4-6份,
苯乙烯一丁二烯共聚物4-6份,
三烯丙基氰酸酯2-3份,
三烯丙基异氰酸酯2-3份,
过氧化二异丙苯1-2份。
优选地,所述改性聚苯醚热固型塑料包括添加剂。
优选地,所述添加剂包括增容剂、稳定剂、润滑剂的一种或者多种。
本发明改性聚苯醚热固型塑料的有益效果是:
通过采用多种热固性物质添加进聚甲醛基体中形成改性热固型塑料,热固性好、尺寸稳定性好、使用温度范围广、耐水汽性能好、强度高、硬度高、刚性好、韧性好、冲击强度高、耐腐蚀性好、自润滑性好、耐溶剂性好、安全实用。
以上所述仅为本发明的实施例,并非因此限制本发明的专利范围,凡是利用本发明说明书内容所作的等效结构或等效流程变换,或直接或间接运用在其它相关的技术领域,均同理包括在本发明的专利保护范围内。

Claims (3)

1.一种改性聚苯醚热固型塑料,其特征在于,成分的质量配比包括:
聚苯醚50份,
聚丁二烯4-6份,
苯乙烯一丁二烯共聚物4-6份,
三烯丙基氰酸酯2-3份,
三烯丙基异氰酸酯2-3份,
过氧化二异丙苯1-2份。
2.根据权利要求1所述的改性聚苯醚热固型塑料,其特征在于,所述改性聚苯醚热固型塑料包括添加剂。
3.根据权利要求2所述的改性聚苯醚热固型塑料,其特征在于,所述添加剂包括增容剂、稳定剂、润滑剂的一种或者多种。
CN201610318378.5A 2016-05-16 2016-05-16 一种改性聚苯醚热固型塑料 Pending CN105885384A (zh)

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PCT/CN2016/083380 WO2017197655A1 (zh) 2016-05-16 2016-05-25 一种改性聚苯醚热固型塑料

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Application publication date: 20160824