CN105802201A - 一种改性聚酰胺阻燃型塑料 - Google Patents

一种改性聚酰胺阻燃型塑料 Download PDF

Info

Publication number
CN105802201A
CN105802201A CN201610318363.9A CN201610318363A CN105802201A CN 105802201 A CN105802201 A CN 105802201A CN 201610318363 A CN201610318363 A CN 201610318363A CN 105802201 A CN105802201 A CN 105802201A
Authority
CN
China
Prior art keywords
modified polyamide
parts
good
polyamide flame
flame retardant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610318363.9A
Other languages
English (en)
Inventor
徐春华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou New District Huashida Engineering Plastic Co Ltd
Original Assignee
Suzhou New District Huashida Engineering Plastic Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou New District Huashida Engineering Plastic Co Ltd filed Critical Suzhou New District Huashida Engineering Plastic Co Ltd
Priority to CN201610318363.9A priority Critical patent/CN105802201A/zh
Priority to PCT/CN2016/083385 priority patent/WO2017197659A1/zh
Publication of CN105802201A publication Critical patent/CN105802201A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/04—Ingredients characterised by their shape and organic or inorganic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K3/2279—Oxides; Hydroxides of metals of antimony
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/06—Ethers; Acetals; Ketals; Ortho-esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3477—Six-membered rings
    • C08K5/3492—Triazines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3477—Six-membered rings
    • C08K5/3492—Triazines
    • C08K5/34924—Triazines containing cyanurate groups; Tautomers thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/02—Fibres or whiskers
    • C08K7/04—Fibres or whiskers inorganic
    • C08K7/14—Glass
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K2003/026—Phosphorus
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2217—Oxides; Hydroxides of metals of magnesium
    • C08K2003/2224—Magnesium hydroxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

本发明公开了一种改性聚酰胺阻燃型塑料，成分的质量配比包括：聚酰胺20份，玻璃纤维2‑5份，十溴联苯醚2‑3份，红磷1‑2份，三聚氰胺尿酸盐1‑2份，三氧化二锑0.5‑1份，氢氧化镁0.5‑1份。通过上述方式，本发明改性聚酰胺阻燃型塑料具有比重轻、冲击韧性优异、强度高、阻燃性好、耐磨性好、自润滑性好、耐溶剂性好、安全实用等优点，在改性聚酰胺阻燃型塑料的普及上有着广泛的市场前景。

Description

一种改性聚酰胺阻燃型塑料
技术领域
本发明涉及工程塑料领域，特别是涉及一种改性聚酰胺阻燃型塑料。
背景技术
工程塑料可作工程材料和代替金属制造机器零部件等的塑料。工程塑料具有优良的综合性能，刚性大，蠕变小，机械强度高，耐热性好，电绝缘性好，可在较苛刻的化学、物理环境中长期使用，可替代金属作为工程结构材料使用，但现有的工程塑料阻燃性能达不到较高要求。
发明内容
本发明主要解决的技术问题是提供一种改性聚酰胺阻燃型塑料，通过采用十溴联苯醚、红磷等阻燃剂添加进聚酰胺基体，大大改善了塑料的阻燃性能，比重轻、冲击韧性优异、强度高、阻燃性好、耐磨性好、自润滑性好、耐溶剂性好、安全实用，在改性聚酰胺阻燃型塑料的普及上有着广泛的市场前景。
为解决上述技术问题，本发明提供一种改性聚酰胺阻燃型塑料，成分的质量配比包括：
聚酰胺20份，
玻璃纤维2-5份，
十溴联苯醚2-3份，
红磷1-2份，
三聚氰胺尿酸盐1-2份，
三氧化二锑0.5-1份，
氢氧化镁0.5-1份。
在本发明一个较佳实施例中，所述改性聚酰胺阻燃型塑料包括添加剂。
在本发明一个较佳实施例中，所述添加剂包括分散剂、稳定剂、润滑剂、抗氧化剂的一种或者多种。
本发明的有益效果是：本发明改性聚酰胺阻燃型塑料具有比重轻、冲击韧性优异、强度高、阻燃性好、耐磨性好、自润滑性好、耐溶剂性好、安全实用等优点，在改性聚酰胺阻燃型塑料的普及上有着广泛的市场前景。
具体实施方式
下面将对本发明实施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例仅是本发明的一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其它实施例，都属于本发明保护的范围。
本发明实施例包括：
一种改性聚酰胺阻燃型塑料，成分的质量配比包括：
聚酰胺20份，
玻璃纤维2-5份，
十溴联苯醚2-3份，
红磷1-2份，
三聚氰胺尿酸盐1-2份，
三氧化二锑0.5-1份，
氢氧化镁0.5-1份。
优选地，所述改性聚酰胺阻燃型塑料包括添加剂。
优选地，所述添加剂包括分散剂、稳定剂、润滑剂、抗氧化剂的一种或者多种。
本发明改性聚酰胺阻燃型塑料的有益效果是：
通过采用十溴联苯醚、红磷等阻燃剂添加进聚酰胺基体，大大改善了塑料的阻燃性能，比重轻、冲击韧性优异、强度高、阻燃性好、耐磨性好、自润滑性好、耐溶剂性好、安全实用。
以上所述仅为本发明的实施例，并非因此限制本发明的专利范围，凡是利用本发明说明书内容所作的等效结构或等效流程变换，或直接或间接运用在其它相关的技术领域，均同理包括在本发明的专利保护范围内。

Claims (3)

1.一种改性聚酰胺阻燃型塑料，其特征在于，成分的质量配比包括：
聚酰胺20份，
玻璃纤维2-5份，
十溴联苯醚2-3份，
红磷1-2份，
三聚氰胺尿酸盐1-2份，
三氧化二锑0.5-1份，
氢氧化镁0.5-1份。
2.根据权利要求1所述的改性聚酰胺阻燃型塑料，其特征在于，所述改性聚酰胺阻燃型塑料包括添加剂。
3.根据权利要求2所述的改性聚酰胺阻燃型塑料，其特征在于，所述添加剂包括分散剂、稳定剂、润滑剂、抗氧化剂的一种或者多种。
CN201610318363.9A 2016-05-16 2016-05-16 一种改性聚酰胺阻燃型塑料 Pending CN105802201A (zh)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201610318363.9A CN105802201A (zh) 2016-05-16 2016-05-16 一种改性聚酰胺阻燃型塑料
PCT/CN2016/083385 WO2017197659A1 (zh) 2016-05-16 2016-05-25 一种改性聚酰胺阻燃型塑料

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610318363.9A CN105802201A (zh) 2016-05-16 2016-05-16 一种改性聚酰胺阻燃型塑料

Publications (1)

Publication Number Publication Date
CN105802201A true CN105802201A (zh) 2016-07-27

Family

ID=56456042

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610318363.9A Pending CN105802201A (zh) 2016-05-16 2016-05-16 一种改性聚酰胺阻燃型塑料

Country Status (2)

Country Link
CN (1) CN105802201A (zh)
WO (1) WO2017197659A1 (zh)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017197659A1 (zh) * 2016-05-16 2017-11-23 苏州新区华士达工程塑胶有限公司 一种改性聚酰胺阻燃型塑料
CN112679828A (zh) * 2020-12-24 2021-04-20 青岛恒凯橡塑有限公司 一种耐磨阻燃热塑性塑料及其制备方法
CN115244133A (zh) * 2019-12-16 2022-10-25 巴斯夫欧洲公司 包含阻燃聚酰胺组合物的工业风扇或鼓风机

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101805494A (zh) * 2010-03-16 2010-08-18 龙海市奈特化工有限责任公司 一种天然纤维树脂复合材料及其制备方法
CN102875968A (zh) * 2011-07-11 2013-01-16 滁州格美特科技有限公司 一种阻燃增强型环氧塑料板材及其制备方法
CN103044896A (zh) * 2012-12-06 2013-04-17 上海日之升新技术发展有限公司 一种高灼热丝阻燃增强ppo/pa合金及其制备方法
CN103146189A (zh) * 2013-02-26 2013-06-12 上海凯赛生物技术研发中心有限公司 一种尼龙改性塑料
CN105062050A (zh) * 2015-07-17 2015-11-18 中国科学院理化技术研究所 一种耐酸碱无卤阻燃玻璃纤维增强尼龙66复合材料及其制备方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102108204B (zh) * 2009-12-24 2013-03-20 合肥杰事杰新材料股份有限公司 一种断路器用塑式外壳材料及其制备方法
CN102604380A (zh) * 2012-03-26 2012-07-25 横店集团得邦工程塑料有限公司 一种高耐热高cti阻燃聚酰胺复合材料及其生产工艺
CN102634200A (zh) * 2012-04-27 2012-08-15 常熟市发东塑业有限公司 一种阻燃改性的尼龙复合材料
CN103044905B (zh) * 2012-12-28 2015-04-22 大河宝利材料科技(苏州)有限公司 聚酰胺组合物及其制备方法
CN105802201A (zh) * 2016-05-16 2016-07-27 苏州新区华士达工程塑胶有限公司 一种改性聚酰胺阻燃型塑料

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101805494A (zh) * 2010-03-16 2010-08-18 龙海市奈特化工有限责任公司 一种天然纤维树脂复合材料及其制备方法
CN102875968A (zh) * 2011-07-11 2013-01-16 滁州格美特科技有限公司 一种阻燃增强型环氧塑料板材及其制备方法
CN103044896A (zh) * 2012-12-06 2013-04-17 上海日之升新技术发展有限公司 一种高灼热丝阻燃增强ppo/pa合金及其制备方法
CN103146189A (zh) * 2013-02-26 2013-06-12 上海凯赛生物技术研发中心有限公司 一种尼龙改性塑料
CN105062050A (zh) * 2015-07-17 2015-11-18 中国科学院理化技术研究所 一种耐酸碱无卤阻燃玻璃纤维增强尼龙66复合材料及其制备方法

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017197659A1 (zh) * 2016-05-16 2017-11-23 苏州新区华士达工程塑胶有限公司 一种改性聚酰胺阻燃型塑料
CN115244133A (zh) * 2019-12-16 2022-10-25 巴斯夫欧洲公司 包含阻燃聚酰胺组合物的工业风扇或鼓风机
CN112679828A (zh) * 2020-12-24 2021-04-20 青岛恒凯橡塑有限公司 一种耐磨阻燃热塑性塑料及其制备方法

Also Published As

Publication number Publication date
WO2017197659A1 (zh) 2017-11-23

Similar Documents

Publication Publication Date Title
CN101759977B (zh) 一种无卤阻燃增强型聚碳酸酯组合物
CN105802201A (zh) 一种改性聚酰胺阻燃型塑料
CN102807699B (zh) 一种阻燃聚乙烯塑料的配方
CN104004330A (zh) 户外电信箱专用高耐候无卤阻燃pc/abs合金材料及制备方法
CN104086926A (zh) 一种改性耐磨聚四氟乙烯塑料配方
CN103740038B (zh) 高光泽无卤阻燃abs材料及其制备方法
CN104725817A (zh) 环保阻燃增强抗冲击pc复合材料
CN105924887A (zh) 一种改性聚甲醛抗静电型塑料
CN103483690B (zh) 一种改性聚丙烯复合材料
CN102634202B (zh) 耐磨高强尼龙复合材料
CN104962073A (zh) 一种多功能特氟龙塑料
CN105670081A (zh) 一种新型聚乙烯
CN105802224A (zh) 一种改性聚苯硫醚塑料
CN105802225A (zh) 一种改性聚苯硫醚增强型塑料
CN105820502A (zh) 一种改性聚甲醛增强型塑料
CN105820503A (zh) 一种改性聚甲醛阻燃型塑料
CN103289380A (zh) 一种阻燃耐热尼龙配方
CN104045955A (zh) 一种阻燃聚甲基丙烯酸甲酯
CN105802202A (zh) 一种改性聚酰胺填充型塑料
CN104962074A (zh) 一种新型阻燃特氟龙塑料
CN102993696A (zh) 无卤阻燃的耐磨尼龙复合材料
CN105199219A (zh) 一种耐拉伸聚丙烯复合材料
CN105968690A (zh) 一种改性聚甲醛增韧型塑料
CN105924947A (zh) 一种改性聚酰胺增强型塑料
CN105820555A (zh) 一种改性聚酰胺增韧型塑料

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20160727

RJ01 Rejection of invention patent application after publication