WO2017197659A1 - 一种改性聚酰胺阻燃型塑料 - Google Patents

一种改性聚酰胺阻燃型塑料 Download PDF

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WO2017197659A1
WO2017197659A1 PCT/CN2016/083385 CN2016083385W WO2017197659A1 WO 2017197659 A1 WO2017197659 A1 WO 2017197659A1 CN 2016083385 W CN2016083385 W CN 2016083385W WO 2017197659 A1 WO2017197659 A1 WO 2017197659A1
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parts
modified polyamide
flame retardant
retardant plastic
good
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PCT/CN2016/083385
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English (en)
French (fr)
Inventor
徐春华
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苏州新区华士达工程塑胶有限公司
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Publication of WO2017197659A1 publication Critical patent/WO2017197659A1/zh

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/04—Ingredients characterised by their shape and organic or inorganic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K3/2279—Oxides; Hydroxides of metals of antimony
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/06—Ethers; Acetals; Ketals; Ortho-esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3477—Six-membered rings
    • C08K5/3492—Triazines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3477—Six-membered rings
    • C08K5/3492—Triazines
    • C08K5/34924—Triazines containing cyanurate groups; Tautomers thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/02—Fibres or whiskers
    • C08K7/04—Fibres or whiskers inorganic
    • C08K7/14—Glass
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K2003/026—Phosphorus
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2217—Oxides; Hydroxides of metals of magnesium
    • C08K2003/2224—Magnesium hydroxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant

Definitions

  • the invention relates to the field of engineering plastics, in particular to a modified polyamide flame retardant plastic.
  • Engineering plastics can be used as engineering materials and plastics that replace metal parts for machine parts.
  • Engineering plastics have excellent comprehensive performance, high rigidity, small creep, high mechanical strength, good heat resistance, good electrical insulation, long-term use in harsh chemical and physical environments, and can be used as an alternative structural material for metal.
  • the flame retardant properties of existing engineering plastics do not meet the high requirements.
  • the technical problem mainly solved by the invention is to provide a modified polyamide flame-retardant plastic, which is improved by adding flame retardant such as decabromodiphenyl ether or red phosphorus into the polyamide matrix, thereby greatly improving the flame retardancy of the plastic. It has excellent lightness, impact toughness, high strength, good flame retardancy, good wear resistance, good self-lubricating property, good solvent resistance, safety and practicality, and has broad market prospects in the popularization of modified polyamide flame retardant plastics.
  • the present invention provides a modified polyamide flame retardant plastic, and the mass ratio of the components includes:
  • the modified polyamide flame retardant plastic comprises an additive.
  • the additive comprises one or more of a dispersant, a stabilizer, a lubricant, and an antioxidant.
  • the invention has the beneficial effects that the modified polyamide flame-retardant plastic of the invention has light specific gravity, excellent impact toughness, high strength, good flame retardancy, good wear resistance, good self-lubricating property, good solvent resistance, safety and practicality. Such advantages have broad market prospects in the popularity of modified polyamide flame retardant plastics.
  • a modified polyamide flame retardant plastic, the mass ratio of the components includes:
  • the modified polyamide flame retardant plastic comprises an additive.
  • the additive comprises one or more of a dispersant, a stabilizer, a lubricant, and an antioxidant.
  • the flame retardancy of the plastic is greatly improved, the specific gravity is light, the impact toughness is excellent, the strength is high, the flame retardancy is good, and the wear resistance is good. Good lubricity, good solvent resistance, safe and practical.

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

本发明公开了一种改性聚酰胺阻燃型塑料，成分的质量配比包括：聚酰胺20份，玻璃纤维2-5份，十溴联苯醚2-3份，红磷1-2份，三聚氰胺尿酸盐1-2份，三氧化二锑0.5-1份，氢氧化镁0.5-1份。通过上述方式，本发明改性聚酰胺阻燃型塑料具有比重轻、冲击韧性优异、强度高、阻燃性好、耐磨性好、自润滑性好、耐溶剂性好、安全实用等优点，在改性聚酰胺阻燃型塑料的普及上有着广泛的市场前景。

Description

一种改性聚酰胺阻燃型塑料 技术领域
本发明涉及工程塑料领域，特别是涉及一种改性聚酰胺阻燃型塑料。
背景技术
工程塑料可作工程材料和代替金属制造机器零部件等的塑料。工程塑料具有优良的综合性能，刚性大，蠕变小，机械强度高，耐热性好，电绝缘性好，可在较苛刻的化学、物理环境中长期使用，可替代金属作为工程结构材料使用，但现有的工程塑料阻燃性能达不到较高要求。
发明内容
本发明主要解决的技术问题是提供一种改性聚酰胺阻燃型塑料，通过采用十溴联苯醚、红磷等阻燃剂添加进聚酰胺基体，大大改善了塑料的阻燃性能，比重轻、冲击韧性优异、强度高、阻燃性好、耐磨性好、自润滑性好、耐溶剂性好、安全实用，在改性聚酰胺阻燃型塑料的普及上有着广泛的市场前景。
为解决上述技术问题，本发明提供一种改性聚酰胺阻燃型塑料，成分的质量配比包括：
聚酰胺20份，
玻璃纤维2-5份，
十溴联苯醚2-3份，
红磷1-2份，
三聚氰胺尿酸盐1-2份，
三氧化二锑0.5-1份，
氢氧化镁0.5-1份。
在本发明一个较佳实施例中，所述改性聚酰胺阻燃型塑料包括添加剂。
在本发明一个较佳实施例中，所述添加剂包括分散剂、稳定剂、润滑剂、抗氧化剂的一种或者多种。
本发明的有益效果是：本发明改性聚酰胺阻燃型塑料具有比重轻、冲击韧性优异、强度高、阻燃性好、耐磨性好、自润滑性好、耐溶剂性好、安全实用等优点，在改性聚酰胺阻燃型塑料的普及上有着广泛的市场前景。
具体实施方式
下面将对本发明实施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例仅是本发明的一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其它实施例，都属于本发明保护的范围。
本发明实施例包括：
一种改性聚酰胺阻燃型塑料，成分的质量配比包括：
聚酰胺20份，
玻璃纤维2-5份，
十溴联苯醚2-3份，
红磷1-2份，
三聚氰胺尿酸盐1-2份，
三氧化二锑0.5-1份，
氢氧化镁0.5-1份。
优选地，所述改性聚酰胺阻燃型塑料包括添加剂。
优选地，所述添加剂包括分散剂、稳定剂、润滑剂、抗氧化剂的一种或者多种。
本发明改性聚酰胺阻燃型塑料的有益效果是：
通过采用十溴联苯醚、红磷等阻燃剂添加进聚酰胺基体，大大改善了塑料的阻燃性能，比重轻、冲击韧性优异、强度高、阻燃性好、耐磨性好、自润滑性好、耐溶剂性好、安全实用。
以上所述仅为本发明的实施例，并非因此限制本发明的专利范围，凡是利用本发明说明书内容所作的等效结构或等效流程变换，或直接或间接运用在其它相关的技术领域，均同理包括在本发明的专利保护范围内。

Claims (3)

  1. 一种改性聚酰胺阻燃型塑料，其特征在于，成分的质量配比包括：
    聚酰胺  20份，
    玻璃纤维  2-5份，
    十溴联苯醚  2-3份，
    红磷  1-2份，
    三聚氰胺尿酸盐  1-2份，
    三氧化二锑  0.5-1份，
    氢氧化镁  0.5-1份。
  2. 根据权利要求1所述的改性聚酰胺阻燃型塑料，其特征在于，所述改性聚酰胺阻燃型塑料包括添加剂。
  3. 根据权利要求2所述的改性聚酰胺阻燃型塑料，其特征在于，所述添加剂包括分散剂、稳定剂、润滑剂、抗氧化剂的一种或者多种。
PCT/CN2016/083385 2016-05-16 2016-05-25 一种改性聚酰胺阻燃型塑料 WO2017197659A1 (zh)

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CN105802201A (zh) * 2016-05-16 2016-07-27 苏州新区华士达工程塑胶有限公司 一种改性聚酰胺阻燃型塑料
US20230014510A1 (en) * 2019-12-16 2023-01-19 Basf Se Industrial fan or blower comprising a flame-retardant polyamide composition
CN112679828A (zh) * 2020-12-24 2021-04-20 青岛恒凯橡塑有限公司 一种耐磨阻燃热塑性塑料及其制备方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102108204A (zh) * 2009-12-24 2011-06-29 合肥杰事杰新材料有限公司 一种断路器用塑式外壳材料及其制备方法
CN102604380A (zh) * 2012-03-26 2012-07-25 横店集团得邦工程塑料有限公司 一种高耐热高cti阻燃聚酰胺复合材料及其生产工艺
CN102634200A (zh) * 2012-04-27 2012-08-15 常熟市发东塑业有限公司 一种阻燃改性的尼龙复合材料
CN103044905A (zh) * 2012-12-28 2013-04-17 大河宝利材料科技(苏州)有限公司 聚酰胺组合物及其制备方法
CN105062050A (zh) * 2015-07-17 2015-11-18 中国科学院理化技术研究所 一种耐酸碱无卤阻燃玻璃纤维增强尼龙66复合材料及其制备方法
CN105802201A (zh) * 2016-05-16 2016-07-27 苏州新区华士达工程塑胶有限公司 一种改性聚酰胺阻燃型塑料

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101805494B (zh) * 2010-03-16 2012-05-23 漳州市奈特新型建材有限责任公司 一种天然纤维树脂复合材料及其制备方法
CN102875968B (zh) * 2011-07-11 2016-05-11 滁州格美特科技有限公司 一种阻燃增强型环氧塑料板材及其制备方法
CN103044896B (zh) * 2012-12-06 2015-06-03 上海日之升新技术发展有限公司 一种高灼热丝阻燃增强ppo/pa合金及其制备方法
CN103146189B (zh) * 2013-02-26 2015-11-18 上海凯赛生物技术研发中心有限公司 一种尼龙改性塑料

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102108204A (zh) * 2009-12-24 2011-06-29 合肥杰事杰新材料有限公司 一种断路器用塑式外壳材料及其制备方法
CN102604380A (zh) * 2012-03-26 2012-07-25 横店集团得邦工程塑料有限公司 一种高耐热高cti阻燃聚酰胺复合材料及其生产工艺
CN102634200A (zh) * 2012-04-27 2012-08-15 常熟市发东塑业有限公司 一种阻燃改性的尼龙复合材料
CN103044905A (zh) * 2012-12-28 2013-04-17 大河宝利材料科技(苏州)有限公司 聚酰胺组合物及其制备方法
CN105062050A (zh) * 2015-07-17 2015-11-18 中国科学院理化技术研究所 一种耐酸碱无卤阻燃玻璃纤维增强尼龙66复合材料及其制备方法
CN105802201A (zh) * 2016-05-16 2016-07-27 苏州新区华士达工程塑胶有限公司 一种改性聚酰胺阻燃型塑料

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