CN105862419A - 一种用于针织的防起球剂、其制备方法及其应用 - Google Patents
一种用于针织的防起球剂、其制备方法及其应用 Download PDFInfo
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Abstract
本发明公开了一种用于针织的防起球剂、其制备方法及其应用，用于针织的防起球剂的原料组分包括：壬基酚聚氧乙烯醚6‑10份、硬脂酸2‑4份、松香乙酯25‑28份、氢化松香甲酯30‑33份、丙烯酸甘油酯3‑5份、聚乙二醇10‑15份、硫酸钠1‑2份、硝酸锌1.5‑1.8份、碳酸锌0.5‑0.8份、甲醇12‑15份和水220‑230份，所述份数为质量份数。本发明用于针织的防起球剂的各原料组分之间有着很好的协同效应，所得处理剂有着很好的稳定性，用其处理过的针织物经久耐穿、不起球。
Description
技术领域
本发明涉及一种用于针织的防起球剂、其制备方法及其应用，属于针织领域。
背景技术
针织物品种繁多，例如各类针织布、针织衫、羊毛衫等，这些针织物在实际的穿着和洗涤过程中，由于不断受到或大或小的摩擦，使得针织物表面的纤维露出织物的表面，在织物表面出现毛茸，而这些毛茸久而久之会互相纠缠在一起形成许多球形小粒，俗称起球，这些突出在织物外表面的毛球，对针织物的美观和服用性能都有严重的影响,随着生活水平的提高，人们对织物外观及服用性能的要求也越来越高，因此，对织物进行抗起毛起球整理，提高织物的服用舒适性与品质，日益受到国内外染整工作者的重视。
发明内容
为了解决现有技术中针织物易起球等缺陷，本发明提供一种用于针织的防起球剂。
为解决上述技术问题，本发明所采用的技术方案如下：
一种用于针织的防起球剂，其原料组分包括：壬基酚聚氧乙烯醚6-10份、硬脂酸2-4份、松香乙酯25-28份、氢化松香甲酯30-33份、丙烯酸甘油酯3-5份、聚乙二醇10-15份、硫酸钠1-2份、硝酸锌1.5-1.8份、碳酸锌0.5-0.8份、甲醇12-15份和水220-230份，所述份数为质量份数。
为了进一步提高防起球效果，优选，聚乙二醇为聚乙二醇8000。
作为本申请的一种优选方案，用于针织的防起球剂的原料组分包括：壬基酚聚氧乙烯醚8份、硬脂酸3份、松香乙酯26份、氢化松香甲酯31份、丙烯酸甘油酯4份、聚乙二醇12份、硫酸钠2份、硝酸锌1.7份、碳酸锌0.6份、甲醇13份和水225份，所述份数为质量份数。
为了进一步提高防起球效果，优选，用于针织的防起球剂的原料组分还包括松香甘油酯2-3份，所述份数为质量份数。
为了进一步提高所得产品的稳定性，优选，用于针织的防起球剂的原料组分还包括月桂酸5-8份，所述份数为质量份数。
上述用于针织的防起球剂的制备方法，包括顺序相接的如下步骤：
A、将松香乙酯和氢化松香甲酯加热搅拌熔融；
B、将壬基酚聚氧乙烯醚和硬脂酸与水混匀，然后加热到90-95℃；
C、将步骤B所得物料在以30滴/min的速度滴入处于搅拌状态的步骤A所得物料中，转相成功后将剩余的步骤B所得物料一起倒入步骤A所得物料中；
D、将聚乙二醇、硫酸钠、硝酸锌和碳酸锌混匀，加入步骤C所得物料中；
E、将丙烯酸甘油酯和甲醇混匀，加入步骤D所得物料中，并在温度为55-60℃、搅拌速度为1300-1500r/min的条件下，继续搅拌15-20分钟，即得。
进一步优选，步骤C中的搅拌速度为1500-1800r/min。
若原料组分还包括松香甘油酯和月桂酸，则松香甘油酯在步骤A中与松香乙酯和氢化松香甲酯一起加热搅拌熔融；月桂酸在步骤B中与壬基酚聚氧乙烯醚和硬脂酸一起与水混匀。
上述用于针织的防起球剂的应用，用于针织的防起球剂的用量为每克针织物0.01-0.03克。
本发明未提及的技术均参照现有技术。
本发明用于针织的防起球剂的各原料组分之间有着很好的协同效应，所得处理剂有着很好的稳定性，用其处理过的针织物经久耐穿、不起球。
具体实施方式
为了更好地理解本发明，下面结合实施例进一步阐明本发明的内容，但本发明的内容不仅仅局限于下面的实施例。
实施例1
用于针织的防起球剂的原料组分包括：壬基酚聚氧乙烯醚(NP-21邢台市梃亿发助剂厂)8份、硬脂酸3份、松香乙酯26份、氢化松香甲酯31份、丙烯酸甘油酯4份、聚乙二醇12份、硫酸钠2份、硝酸锌1.7份、碳酸锌0.6份、甲醇13份、松香甘油酯2份、月桂酸6份和水225份，所述份数为质量份数。
上述用于针织的防起球剂的制备方法，包括顺序相接的如下步骤：
A、将松香乙酯、松香甘油酯和氢化松香甲酯加热搅拌熔融；
B、将壬基酚聚氧乙烯醚、月桂酸和硬脂酸与水混匀，然后加热到90℃；
C、将步骤B所得物料在以30滴/min的速度滴入处于搅拌状态(1600r/min)的步骤A所得物料中，转相成功后将剩余的步骤B所得物料一起倒入步骤A所得物料中；
D、将聚乙二醇、硫酸钠、硝酸锌和碳酸锌混匀，加入步骤C所得物料中；
E、将丙烯酸甘油酯和甲醇混匀，加入步骤D所得物料中，并在温度为55℃、搅拌速度为1400r/min的条件下，继续搅拌18分钟，即得。
实施例2
与实施例1基本相同，所不同的是：用于针织的防起球剂的原料组分包括：壬基酚聚氧乙烯醚(NP-21邢台市梃亿发助剂厂)6份、硬脂酸2份、松香乙酯25份、氢化松香甲酯30份、丙烯酸甘油酯3份、聚乙二醇8000 10份、硫酸钠1份、硝酸锌1.5份、碳酸锌0.5份、甲醇12份、松香甘油酯2份、月桂酸5份和水220份，所述份数为质量份数。
实施例3
与实施例1基本相同，所不同的是：用于针织的防起球剂的原料组分包括：壬基酚聚氧乙烯醚(NP-21邢台市梃亿发助剂厂)10份、硬脂酸4份、松香乙酯28份、氢化松香甲酯33份、丙烯酸甘油酯5份、聚乙二醇8000 15份、硫酸钠2份、硝酸锌1.8份、碳酸锌0.8份、甲醇15份、松香甘油酯3份、月桂酸8份和水230份，所述份数为质量份数。
将平纹布分别用上述各实施例所得的用于针织的防起球剂浸渍，用量为每克针织物0.02克处理剂，然后烘干，所得针织物用60号砂纸双向摩擦20次，无任何起球现象；将所得针织物制作为衣物，隔天洗涤机洗一次，持续穿着2月后无任何起球现象。
Claims (9)
1.一种用于针织的防起球剂，其特征在于：其原料组分包括：壬基酚聚氧乙烯醚6-10份、硬脂酸2-4份、松香乙酯25-28份、氢化松香甲酯30-33份、丙烯酸甘油酯3-5份、聚乙二醇10-15份、硫酸钠1-2份、硝酸锌1.5-1.8份、碳酸锌0.5-0.8份、甲醇12-15份和水220-230份，所述份数为质量份数。
2.如权利要求1所述的用于针织的防起球剂，其特征在于：聚乙二醇为聚乙二醇8000。
3.如权利要求1或2所述的用于针织的防起球剂，其特征在于：其原料组分包括：壬基酚聚氧乙烯醚8份、硬脂酸3份、松香乙酯26份、氢化松香甲酯31份、丙烯酸甘油酯4份、聚乙二醇12份、硫酸钠2份、硝酸锌1.7份、碳酸锌0.6份、甲醇13份和水225份，所述份数为质量份数。
4.如权利要求1或2所述的用于针织的防起球剂，其特征在于：其原料组分还包括松香甘油酯2-3份，所述份数为质量份数。
5.如权利要求1或2所述的用于针织的防起球剂，其特征在于：其原料组分还包括月桂酸5-8份，所述份数为质量份数。
6.权利要求1-5任意一项所述的用于针织的防起球剂的制备方法，其特征在于：包括顺序相接的如下步骤：
A、将松香乙酯和氢化松香甲酯加热搅拌熔融；
B、将壬基酚聚氧乙烯醚和硬脂酸与水混匀，然后加热到90-95℃；
C、将步骤B所得物料在以30滴/min的速度滴入处于搅拌状态的步骤A所得物料中，转相成功后将剩余的步骤B所得物料一起倒入步骤A所得物料中；
D、将聚乙二醇、硫酸钠、硝酸锌和碳酸锌混匀，加入步骤C所得物料中；
E、将丙烯酸甘油酯和甲醇混匀，加入步骤D所得物料中，并在温度为55-60℃、搅拌速度为1300-1500r/min的条件下，继续搅拌15-20分钟，即得。
7.如权利要求6所述的制备方法，其特征在于：步骤C中的搅拌速度为1500-1800r/min。
8.如权利要求6或7所述的制备方法，其特征在于：若原料组分还包括松香甘油酯和月桂酸，则松香甘油酯在步骤A中与松香乙酯和氢化松香甲酯一起加热搅拌熔融；月桂酸在步骤B中与壬基酚聚氧乙烯醚和硬脂酸一起与水混匀。
9.权利要求1-5任意一项所述的用于针织的防起球剂的应用，其特征在于：用于针织的防起球剂的用量为每克针织物0.01-0.03克。
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