A kind of Margarita antibacterial yarn with moisture absorption sweat discharging functions and preparation method thereof
Technical field
The present invention relates to textile fabric field, especially, relate to a kind of Margarita antibacterial yarn with moisture absorption sweat discharging functions and preparation method thereof.
Background technology
Pearl fiber is to use high-tech means to be added in fiber when viscose rayon spinning by nanometer pearl powder, is uniform-distribution with nano-pearl microgranule with appearance in making corpus fibrosum.Being specially pearl protein function master batch and fibre resin section is constituted, be uniform-distribution with nano-pearl microgranule with appearance in making corpus fibrosum, individual fibers is just as a string pearl necklace, abnormal bright smooth.It is to be cooperated the common a kind of tencel researched and developed by Donghua University with novel spinning center, Shanghai, belongs to the most pioneering high-grade functional fiber.
Pearl fiber existing pearl face skin-care effect, has again the characteristic that viscose rayon moisture absorption is ventilative, comfortable and easy to wear.Pearl fiber surface is uniform-distribution with pearl micro-particle, for a long time in contact skin, have pearl face skin protection, relieve inflammation or internal heat relieve internal heat, tender white muscle skin, anti-ultraviolet effect.Pearl fiber contains several amino acids and trace element, and fiber surface is smooth nice and cool, has pearlescent.
After Margarita powder is absorbed by the body, by participating in body metabolism, reach overall conditioning and the maintenance of whole body skin.It can promote that regenerative cell synthesizes, and constantly adds to skin surface, makes skin smooth, exquisiteness, flexible.Scientifically take Margarita powder and have the effect alleviating serum lipid peroxidation significantly, and this lipid becomes to generate lipofuscin (senile plaque) with protein bound, this just the Empress Dowager with Margarita be apt to skin care hold secret place.
Behind Margarita powder painting face, the activity of human skin superoxide dismutase (SOD) can be promoted, suppress melanic synthesis, keep whitening skin.Additionally, due to SOD has the effect removing free radical, skin aging, wrinkling can be prevented.
(1) beauty care, tender pale skin
Human body wears pearl fiber underwear, pearl nano particle on fiber and skin intimate contact, lactic acid in perspiration can divide pearl nutritional composition by dissolution fiber middles, absorbed by skin, promote the activity of human skin superoxide dismutase (SOD), suppress melanic synthesis to keep whitening skin.Additionally, due to SOD has the effect removing free radical, skin aging can be prevented wrinkling.The traditional Chinese medical science is thought: Margarita sweet-salty cold in nature, GUIXIN Liver Channel, function appearance skin Caring, skin moistening granulation promoting, and clear speckle subtracts wrinkle, slow down aging;It is mainly used in facial freckle, chloasma, senile plagues, wrinkle, of flaccid muscles, the weary pool of pachylosis, has an old and weathered face and acne, burn and scald, skin infection, wound are not received, dermatitis etc..Pearl growth is in water, cold in nature, has the effect that relieves internal heat of relieving inflammation or internal heat, and wears pearl fiber underwear for a long time and can remove skin surface hot pox poison, has speckle dispelling, except pox, effect of maintenance skin.
(2) uvioresistant
Margarita be mainly composed of calcium carbonate, itself there is anti-ultraviolet function, when its be ground into nm regime add fiber time, its function is greatly reinforced.Pearl fiber has anti-ultraviolet anti-skin aging effect.Show according to current research: nanometer Margarita powder also has the function launching infrared waves, and it can improve microcirculation in human body, human body is had health-care effect.
Moisture absorption breathe freely, take comfortable
The carrier of nano-pearl fiber is viscose rayon, and its moisture absorption air permeable dress is with comfortable, and after adding resistance to Margarita powder, fibrous inside and surface are uniform-distribution with pearl nano particle, and fabric hand is smooth nice and cool, and outward appearance is beautiful.
(4) All Pure Nature
Nanometer Margarita powder is to be processed through pure physical method by high-quality mussel pearl, and prezenta is extracted by cotton linter, and therefore the pearl fiber harmful substance without any chemical product, has natural affinity with skin.
The most durable in use
In pearl fiber, pearl nano particle is intimately combined with fiber, has permanent, and long-term washing dress does not comes off.Margarita is alkaline-resisting the most acidproof, and alkaline washing does not hinder the slightest, and only under acidic sweat effect, pearl nano particle just can generating unit analyze, and Margarita underwear is to turn the perfect adaptation with washing in fact.
Chinese invention patent CN1772980A discloses a kind of pearl viscose fiber and production method thereof, and this patent makes public for the first time the preparation method of pearl viscose fiber;Chinese invention patent CN102002767A discloses a kind of important fiber of Margarita with functions of skin protection and health care and preparation method thereof, the method adds Chinese medicine at former pearl viscose fiber in original pearl fiber, in the Margarita of preparation, drug fiber had both possessed moisture absorption sweat discharging functions, difference always according to Chinese medicine possesses certain health care, the moisture permeability of both the above fiber is more or less the same, all good than viscose rayon and cotton fiber, but in order to reach more preferable moisture absorbing and sweat releasing effect, make dress more comfortable, it is necessary to research and develop the fiber that a kind of moisture absorbing and sweat releasing is better.
Summary of the invention
Present invention aim at providing a kind of moisture absorbing and sweat releasing better, wear more comfortable Margarita antibacterial yarn and preparation method thereof, to solve technical problem.
For achieving the above object, the invention provides a kind of Margarita antibacterial yarn with moisture absorption sweat discharging functions and preparation method thereof.
A kind of Margarita antibacterial yarn with moisture absorption sweat discharging functions, including the composition of following main by weight percentage ratio:
Modified pearl fiber 60-75%
Modified ramie 25-40%.
The preparation method of a kind of Margarita antibacterial yarn with moisture absorption sweat discharging functions, comprises the following steps:
A, ramee is put in glycerol after simple cleaning, drying;
B, to add particle diameter in glycerol be the Margarita powder of 50-200 micron, then solution is carried out ultrasonic Treatment, and treatment conditions are 500-700Hz, and the time is 4-6h, obtains modified ramie;
C, pretreatment: modified pearl fiber is added in the glycerol in step b, and stands 24-30 hour, carry out pretreatment;
D, mixed cotton: pretreated raw material is sent into cotton blender machine, mix modified pearl fiber and modified ramie;
E, shredding scutching cotton: respectively the modified pearl fiber after mixed cotton and modified ramie are sent into opener, carry out shredding scutching cotton;
F, comb and parallel cotton fibers prior to spinning: modified pearl fiber and the modified ramie through shredding scutching cotton is carried out comb and parallel cotton fibers prior to spinning, be completely decomposed into single fiber by fibre bundle, removes the impurity of residual;
G, drafting: the carded sliver is processed further ripe bar through mixing in doubling step, to improve cotton sliver quality;
H, rove: ripe bar is processed into same number and the rove of the different twist, uses for spinning process;
I, spun yarn: rove is spun into the spun yarn having certain special number, meeting quality standard or customer requirement;
J, winder: scribbled is carried out winder by the requirement of client.
Preferably, the water content of the ramee after drying in described step a is less than 2%, and the purity of described glycerol is higher than 99%.
Preferably, the preparation method of described modified pearl fiber, comprise the following steps:
A, the Mel in Apis Nidus Vespae is taken out completely after, under the condition of ultralow temperature of-40 to-30 DEG C, carry out machinery after freezing 8-10h repeatedly pulverize, cross 80 mesh sieves, obtain Nidus Vespae powder;
B, under the cryogenic conditions of-10 to-8 DEG C, Nidus Vespae powder is added in glycerol, carries out wet grinding, the particle diameter of Nidus Vespae powder is ground to 50-100 micron, obtain Nidus Vespae powder glycerol suspension;
C, at normal temperatures, adds Nidus Vespae powder glycerol suspension in deionized water, adds Petiolus Trachycarpi oil, and adding particle diameter is 50-100 micron pearl powder and Broussonetia papyrifera juice, after stirring, carries out wet grinding, makes slurry, makes diameter of particle reach less than 1 micron;
D, it is 15-25% by pulp dilution to concentration, filters;
E, will filter after slurry press formula ratio addition viscose rayon spinning slurry, blended, filtration, spray webbing, drawing-off, be shaped into modified pearl fiber.
Preferably, described modified pearl fiber, including the composition of following main by weight percentage ratio:
Viscose rayon 90-95%
Margarita powder 2-7%
Broussonetia papyrifera juice 0.05-0.1%
Nidus Vespae powder 0.5-1%
Glycerol 2-3%
Petiolus Trachycarpi oil surplus.
Preferably, in described modified pearl fiber, Margarita powder is (30-140) with the part by weight of Broussonetia papyrifera juice: 1.
Preferably, in described modified pearl fiber, Nidus Vespae powder is (5-20) with the part by weight of Broussonetia papyrifera juice: 1.
Boehmeria, for China's special product, is described as " China's grass, middle national treasure " by the world.The beneficial elements such as ramee sucting wet air permeability is about 3-5 times of cotton fiber, contains simultaneously and gives repeated exhortations, pyrimidine, purine, have the functions such as antibacterial, ventilative, nice and cool, anticorrosion, mildew-resistant, absorbing sweat, are universally acknowledged " kings of natural fiber ";It is best suitable for makeing the fabric of pillowcase, bed-mat for summer.The peel of stem fiber of Boehmeria is elongated, tough, pure white, glossy, pulling force is strong, water-fast wet, rich elastic force and insulating properties, grass cloth (grass cloth that the ground such as liuyang hunan and Jiangxi ten thousand years produces is the most famous), the wing cloth of aircraft can be made into, the lining cloth of rubber industry, electric wire are coated, incandescent lamp yarn, fishing net, artificial silk processed, synthetic cotton etc., senior dress material can be made with Pilus Caprae seu Ovis, Cotton Gossypii blending;Chopped fiber can be the raw material of fine paper, gunpowder, artificial silk etc., again can weavening carpet, gunnysack etc..In various bast-fibres, ramee is the longest, and strength is maximum, and fiber is the thickest.Fibre length is longer than five-star Cotton Gossypii by two, three times to six, seven times, ramee than Caulis et Folium Lini, thick two to three times of Fructus Cannabis,
But ramee end is pointed, contact skin has prodding and itching feeling, is not the most recognized and does the weaving face fabric directly contacting skin.By ramee is rubbed under nuclear-magnetism effect for a long time with Margarita powder in glycerol in the present invention, by the tip shape rounding on ramee surface, polish, eliminate skin urtication sense, also retains its original antibacterial, characteristic of moisture absorbing and sweat releasing simultaneously, carrying out blending with pearl fiber, the Margarita antibacterial yarn made has extraordinary moisture absorbing and sweat releasing performance and health care.
Glycerol is without the sweet clear and bright thick liquid of color and taste.Odorless.There is warm sweet taste.It is commonly called as glycerol.Relative density 1.26362.Fusing point 17.8 DEG C.Boiling point 290.0 DEG C (decomposition).Index of refraction 1.4746.Flash-point (opening cup) 176 DEG C.Acute toxicity: LD50:31500mg/kg (rat oral).Glycerol is the framework ingredient of triglyceride molecule.When human body takes in edible fat, triglyceride therein decomposes through internal metabolism, forms glycerol and is stored in adipose cell.Therefore, the end product of Triglyceride Metabolism in Patients is glycerol and fatty acid.Can be used as solvent, lubricant, medicament and sweeting agent.The substantial amounts of use of glycerol is in textile industry, cosmetics and food industry, general it is considered that glycerol is harmless.
In the preparation process of blend fibre without add and crude oil, use glycerol both can reach the effect with crude oil, also without add chemical agent to and crude oil clean, directly rinse with water, reduce cost, decrease pollution.
In the present invention by the water content control of ramee within 2%; the purity of glycerol is higher than 99%; can hydrone stronger for the polarity in glycerol be controlled at the least number; simultaneously by the FREQUENCY CONTROL of ultrasound wave at 500-700w; frequency is the lowest; so farthest the internal structure of former ramee can be protected, not destroy the performances such as its antibacterial, moisture absorbing and sweat releasing.
Ramee will be carried out the size controlling of the Margarita powder of ultrasonic grinding at 50-200 micron, mainly have following purpose: one is if the particle diameter of Margarita powder is relatively big, relatively strong to the destructiveness of ramee, can affect its intensity, easily cause fracture in spinning process;Two is that particle diameter is slightly smaller, and the Margarita powder between 500-5000 nanometer can enter the macrovoid in ramee, thus destroys the internal structure of ramee, destroys its antibacterial, moisture absorbing and sweat releasing performance;Three be particle diameter below 500 nanometers, the poor effect of ultrasonic grinding, the ramee after grinding still has prodding and itching feeling;Four is that the Margarita powder using 50-200 micron is ground, and has a small amount of particle diameter to be ground out at the nanometer Margarita powder of below 100nm, inside particle diameter the least entrance ramee, affects little on the internal structure of ramee.
Nidus Vespae, bee colony life and the place raised up seed, be made up of Nidus Vespae.Each Nidus Vespae space in Nidus Vespae is parallel to each other suspension, and perpendicular to the ground, and Nidus Vespae spacing is 7~10 millimeters, referred to as honeybee road.Every Nidus Vespae is linked together by thousands of lairs and forms, and is that the Cera Flava secreted by the worker bee wax gland of self is built.Large and small hexagonal lair, is respectively and cultivates drone and worker bee, and bottom surface is 3 lozenges.The lair of queen breeding, referred to as Nidus Vespae, shape is like sagging Semen arachidis hypogaeae, and being that bee colony is interim before swarmming builds, how on Nidus Vespae bottom and corner.Between drone cell and worker cell, and the junction of Nidus Vespae and frame, have irregular transitional type lair, be used for storing Mel and reinforcing Nidus Vespae.
Research shows, Nidus Vespae preparation has the effect promoting Immune Function, Nidus Vespae immersion both had deactivation to hbs antigen, also staphylococcus aureus, bacillus pyocyaneus, escherichia coli, dysentery bacterium, Bacillus typhi and proteus vulgaris etc. was had the strongest restraint;The funguses such as Aspergillus fumigatus, Aspergillus flavus, eggplant sickle bacterium, leukonid also there is inhibitory action.The chemical composition of Nidus Vespae is the most complicated, mainly contains Cera Flava, resin, oils and fats, pigment, tannin, saccharide, organic acid, fatty acid, glycoside, enzyme and insect hormone etc..
Broussonetia papyrifera another name Chu Tao etc., for deciduous tree, high 10-20m;Bark lead;The close raw pubescence of sprig.Tree crown opens, avette to the most avette;Bark smooths, light grey or taupe, is difficult to split, and Herb contains milk.For strong positive seeds, adaptability extra-heavy, strong stress resistance.Broussonetia papyrifera juice has effect of inducing diuresis to remove edema removing toxic substances, Broussonetia papyrifera juice is modified pearl fiber, the fiber made can be made to possess more preferable anti-microbial property in the present invention.
In order to protect organic acid in Nidus Vespae in the present invention, fatty acid, glycoside, the various larger molecular organics such as enzyme, freezing 8-10h under the condition of ultralow temperature of-40 to-30 DEG C, Organic substance is completely enclosed, then pulverize, then pulverize further under the low-temperature protection of glycerol, so glycerol can be wrapped in when Nidus Vespae macromole outer is trapped among grinding and protect, it is subsequently adding in deionized water and continues to be ground to nanoscale, can be distributed in Margarita powder calcium carbonate microcellular structure after refinement, after wearing next to the skin, under the temperature conditions of human body 30-40 DEG C, effective ingredient in Nidus Vespae is along with Margarita powder is after human sweat is dissolved, not only can play good antibacterial and bacteriostasis, but also light fragrant can be given out.
Petiolus Trachycarpi oil is also referred to as saturated oils and fats, because it contains the saturated fat of 50%.Oils and fats is saturated fat, monounsaturated fatty acid, three kinds of composition mixing compositions of polyunsaturated fat.Human body is to palmitic digestion and absorbance more than 97%, and the same with other all vegetable edible oils, Petiolus Trachycarpi oil itself does not contains cholesterol.
The method have the advantages that 1, the Margarita antibacterial yarn of the present invention adds Nidus Vespae powder and Broussonetia papyrifera juice in traditional pearl fiber, so that the fabric made possesses more preferable antibacterial and bacteriostasis, and sends light fragrance;2, to the course of processing of Nidus Vespae powder uses low temperature+glycerol duplicate protection in the present invention, it is ensured that the effective ingredient that human body is useful is not run off by Nidus Vespae;3, ramee is carried out supersound process, by the tip shape rounding on ramee surface, polish, eliminate skin urtication sense, also retains its original antibacterial, characteristic of moisture absorbing and sweat releasing simultaneously.
In addition to objects, features and advantages described above, the present invention also has other objects, features and advantages.The present invention is further detailed explanation below.
Detailed description of the invention
Hereinafter embodiments of the invention are described in detail, but the multitude of different ways that the present invention can limit according to claim and cover is implemented.
The preparation method of a kind of Margarita antibacterial yarn with moisture absorption sweat discharging functions, comprises the following steps:
A, ramee is put in glycerol after simple cleaning, drying;
B, to add particle diameter in glycerol be the Margarita powder of 50-200 micron, then solution is carried out ultrasonic Treatment, and treatment conditions are 600Hz, and the time is 5.5h, obtains modified ramie;
C, pretreatment: modified pearl fiber is added in the glycerol in step b, and stands 25 hours, carry out pretreatment;
D, mixed cotton: pretreated raw material is sent into cotton blender machine, mix modified pearl fiber and modified ramie;
E, shredding scutching cotton: respectively the modified pearl fiber after mixed cotton and modified ramie are sent into opener, carry out shredding scutching cotton;
F, comb and parallel cotton fibers prior to spinning: modified pearl fiber and the modified ramie through shredding scutching cotton is carried out comb and parallel cotton fibers prior to spinning, be completely decomposed into single fiber by fibre bundle, removes the impurity of residual;
G, drafting: the carded sliver is processed further ripe bar through mixing in doubling step, to improve cotton sliver quality;
H, rove: ripe bar is processed into same number and the rove of the different twist, uses for spinning process;
I, spun yarn: rove is spun into the spun yarn having certain special number, meeting quality standard or customer requirement;
J, winder: scribbled is carried out winder by the requirement of client;
The described Margarita antibacterial yarn with moisture absorption sweat discharging functions, including the composition of following main by weight percentage ratio:
Modified pearl fiber 65%
Modified ramie 35%;
The water content of the ramee after drying in described step a is less than 2%, and the purity of described glycerol is higher than 99%;
The preparation method of described modified pearl fiber, comprises the following steps:
A, the Mel in Apis Nidus Vespae is taken out completely after, under the condition of ultralow temperature of-35 DEG C, carry out machinery after freezing 9h repeatedly pulverize, cross 80 mesh sieves, obtain Nidus Vespae powder;
B, under the cryogenic conditions of-10 DEG C, Nidus Vespae powder is added in glycerol, carries out wet grinding, the particle diameter of Nidus Vespae powder is ground to 50-100 micron, obtain Nidus Vespae powder glycerol suspension;
C, at normal temperatures, adds Nidus Vespae powder glycerol suspension in deionized water, adds Petiolus Trachycarpi oil, add Margarita powder and Broussonetia papyrifera juice that particle diameter is 50-100 micron, after stirring, carry out wet grinding, make slurry, make diameter of particle reach less than 1 micron;
D, by pulp dilution to 20% concentration, filter;
E, will filter after slurry press formula ratio addition viscose rayon spinning slurry, blended, filtration, spray webbing, drawing-off, be shaped into modified pearl fiber.
Described modified pearl fiber, including the composition of following main by weight percentage ratio:
Viscose rayon 90%
Margarita powder 6%
Broussonetia papyrifera juice 0.06%
Nidus Vespae powder 0.9%
Glycerol 3%
Petiolus Trachycarpi oil 0.04%.
In each specific embodiment, two kinds of fibre fractionation percentage by weights of Margarita antibacterial yarn please see table:
In each specific embodiment, each weight percentages of components of modified pearl fiber please see table:
The Margarita antibacterial yarn with moisture absorption sweat discharging functions of the present invention is made into fabric, detects, and contrast with the tradition fabric that is made into of pearl fiber yarn, draw following data:
The preparation method of described traditional sample is:
The first step: prepared by slurry:
By the Margarita primary powder body that 50kg particle diameter is less than 6 microns, 30kg particle diameter is Radix Notoginseng primary powder body and the 120kg pure water mix and blend of less than 10 microns, adds 2kg long-chain fatty acid, grind 2h, add 1kg silane, grind 2h, test its particle diameter, pulp or add mill 1h, make slurry;
Second step: by pulp dilution to 20% concentration, filters;
3rd step: the slurry Margarita 5% by weight percentage after filtering, Radix Notoginseng 3%, injects viscose rayon spinning slurry 92%, mixes, filters, spray webbing, drafting forming, desulfurization are washed the drying that oils, made finished fiber;
4th step;Pearl fiber is obtained pearl fiber yarn through blowing, comb and parallel cotton fibers prior to spinning, drafting, rove, spun yarn, winder.
Table one: water suction, water vapour permeability testing result
Detection project and detection foundation:
Poisture-penetrability: GB/T12704.1-2009 (test temperature 38 DEG C, relative humidity 90%R.H., test period 1h) moisture absorption method;
Water absorption: GB/T21655.1-20088.1
Textile water absorption test-drop method (AATCC79-2010)
Table two: the impact of human body is tested by fabric:
The test condition that affects of human body is by described fabric: be 19-21 DEG C in temperature, humidity is under the indoor conditions of 48-52%R.H., randomly select man and the Ms in 20-40 year to test, first adapt to environment 10 minutes, then put on test fabric 30 minutes, test in the middle part of the forearm of human body before wearing the clothes and after wearing the clothes.
Table three: after fabric washs 20 times, anti-microbial property is tested:
From detecting data above, the Margarita antibacterial yarn of prepared by the present invention have moisture absorption sweat discharging functions possesses more preferable moisture absorbing and sweat releasing performance compared to tradition pearl fiber yarn, more efficiently improves human body skin microcirculation, more preferable antibacterial bacteriostatic performance.
Comparative example 1:
Being removed by Broussonetia papyrifera juice in embodiment 1, other condition is constant, the anti-microbial property of the fabric that the Margarita antibacterial yarn of test preparation is made into:
Table four: after fabric washs 20 times, anti-microbial property is tested:
From test data, it is added without Broussonetia papyrifera juice, the antibacterial bacteriostatic performance of Margarita antibacterial yarn is affected the biggest.
Comparative example 2:
Being removed by Nidus Vespae powder in embodiment 1, other condition is constant, and the fabric that is made into of Margarita antibacterial yarn of test preparation is on the impact of human body and anti-microbial property:
Table five: the impact of human body is tested by fabric:
Table seven: after fabric washs 20 times, anti-microbial property is tested:
From test data, it is added without Nidus Vespae powder, the biggest on skin microcirculation lifting effect and the impact of antibacterial bacteriostatic performance of human body on Margarita antibacterial yarn.
From embodiment 1, comparative example 1 and 2, the present invention adds Broussonetia papyrifera juice and Nidus Vespae powder is not only simple superposition to the antibacterial and bacteriostasis of antibacterial, add Broussonetia papyrifera juice and Nidus Vespae powder more a lot of than the antibacterial and bacteriostasis being individually added into Broussonetia papyrifera juice or Nidus Vespae powder.
The foregoing is only the preferred embodiments of the present invention, be not limited to the present invention, for a person skilled in the art, the present invention can have various modifications and variations.All within the spirit and principles in the present invention, any modification, equivalent substitution and improvement etc. made, should be included within the scope of the present invention.