CN105820274A - 一种阳离子表面活性引发剂及其制备方法 - Google Patents
一种阳离子表面活性引发剂及其制备方法 Download PDFInfo
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- CN105820274A CN105820274A CN201510420376.2A CN201510420376A CN105820274A CN 105820274 A CN105820274 A CN 105820274A CN 201510420376 A CN201510420376 A CN 201510420376A CN 105820274 A CN105820274 A CN 105820274A
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- 239000000178 monomer Substances 0.000 claims abstract description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 150000003254 radicals Chemical class 0.000 claims abstract description 16
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims abstract description 11
- 229920001400 block copolymer Polymers 0.000 claims abstract description 9
- 238000006479 redox reaction Methods 0.000 claims abstract description 7
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- 230000000977 initiatory effect Effects 0.000 claims abstract description 6
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- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 21
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- 238000006243 chemical reaction Methods 0.000 claims description 16
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 claims description 13
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 claims description 13
- 239000003093 cationic surfactant Substances 0.000 claims description 12
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 9
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- MCTWTZJPVLRJOU-UHFFFAOYSA-N 1-methyl-1H-imidazole Chemical compound CN1C=CN=C1 MCTWTZJPVLRJOU-UHFFFAOYSA-N 0.000 claims description 4
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- 239000012141 concentrate Substances 0.000 claims description 3
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- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- RAXXELZNTBOGNW-UHFFFAOYSA-O Imidazolium Chemical compound C1=C[NH+]=CN1 RAXXELZNTBOGNW-UHFFFAOYSA-O 0.000 claims 1
- 239000008346 aqueous phase Substances 0.000 claims 1
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 1
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- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
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- 238000010586 diagram Methods 0.000 description 1
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- 239000001257 hydrogen Substances 0.000 description 1
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- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 229920005553 polystyrene-acrylate Polymers 0.000 description 1
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- 239000012966 redox initiator Substances 0.000 description 1
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106519156A (zh) * | 2016-10-22 | 2017-03-22 | 宁波大学 | 一种阳离子型聚氯乙烯膜材料的绿色制备方法 |
CN109134774A (zh) * | 2018-04-18 | 2019-01-04 | 宁波大学 | 一种活性黑染料kn-b的高分子化方法 |
CN109134773A (zh) * | 2018-04-18 | 2019-01-04 | 宁波大学 | 一种荧光素染料的高分子化方法 |
CN109957047A (zh) * | 2019-02-27 | 2019-07-02 | 宁波大学 | 一种多羟基十二酰肼引发剂及其使用方法 |
CN109970934A (zh) * | 2019-02-27 | 2019-07-05 | 宁波大学 | 一种十二酰肼双阳离子引发剂及其制备与使用方法 |
CN109970886A (zh) * | 2019-02-27 | 2019-07-05 | 宁波大学 | 一种异辛酰肼磺酸钠引发剂及其制备方法 |
CN111320551A (zh) * | 2019-01-15 | 2020-06-23 | 山东大学 | 一种仲酰胺双胺季铵盐两性型沥青乳化剂及其制备方法 |
CN114890906A (zh) * | 2022-06-23 | 2022-08-12 | 麦加芯彩新材料科技(上海)股份有限公司 | 一种阳离子双子叔铵盐低温破乳剂及其制备方法与应用 |
Citations (5)
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US6358914B1 (en) * | 1999-06-17 | 2002-03-19 | Gladys S. Gabriel | Surfactant compositions with enhanced soil release properties containing a cationic gemini surfactant |
CN102503844A (zh) * | 2011-11-11 | 2012-06-20 | 江西科技师范学院 | 一种具有双子表面活性的原子转移自由基聚合引发剂及其合成方法 |
CN102850479A (zh) * | 2012-08-22 | 2013-01-02 | 华中科技大学 | 一种阳离子型苯丙微乳液的制备方法 |
CN103289671A (zh) * | 2013-05-28 | 2013-09-11 | 四川安东油气工程技术服务有限公司 | 缓蚀剂及其制备方法 |
CN103406065A (zh) * | 2013-08-20 | 2013-11-27 | 齐齐哈尔大学 | 新型酰胺键联接咪唑盐基双子表面活性剂及其制备方法 |
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2015
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US6358914B1 (en) * | 1999-06-17 | 2002-03-19 | Gladys S. Gabriel | Surfactant compositions with enhanced soil release properties containing a cationic gemini surfactant |
CN102503844A (zh) * | 2011-11-11 | 2012-06-20 | 江西科技师范学院 | 一种具有双子表面活性的原子转移自由基聚合引发剂及其合成方法 |
CN102850479A (zh) * | 2012-08-22 | 2013-01-02 | 华中科技大学 | 一种阳离子型苯丙微乳液的制备方法 |
CN103289671A (zh) * | 2013-05-28 | 2013-09-11 | 四川安东油气工程技术服务有限公司 | 缓蚀剂及其制备方法 |
CN103406065A (zh) * | 2013-08-20 | 2013-11-27 | 齐齐哈尔大学 | 新型酰胺键联接咪唑盐基双子表面活性剂及其制备方法 |
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Title |
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程传杰 等: "具有Gemini表面活性ATRP引发剂的合成", 《合成化学》 * |
程传杰 等: "具有阳离子表面活性ATRP引发剂的合成", 《合成化学》 * |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106519156A (zh) * | 2016-10-22 | 2017-03-22 | 宁波大学 | 一种阳离子型聚氯乙烯膜材料的绿色制备方法 |
CN106519156B (zh) * | 2016-10-22 | 2018-08-07 | 宁波大学 | 一种阳离子型聚氯乙烯膜材料的绿色制备方法 |
CN109134774A (zh) * | 2018-04-18 | 2019-01-04 | 宁波大学 | 一种活性黑染料kn-b的高分子化方法 |
CN109134773A (zh) * | 2018-04-18 | 2019-01-04 | 宁波大学 | 一种荧光素染料的高分子化方法 |
CN111320551A (zh) * | 2019-01-15 | 2020-06-23 | 山东大学 | 一种仲酰胺双胺季铵盐两性型沥青乳化剂及其制备方法 |
CN109970886A (zh) * | 2019-02-27 | 2019-07-05 | 宁波大学 | 一种异辛酰肼磺酸钠引发剂及其制备方法 |
CN109970934A (zh) * | 2019-02-27 | 2019-07-05 | 宁波大学 | 一种十二酰肼双阳离子引发剂及其制备与使用方法 |
CN109957047A (zh) * | 2019-02-27 | 2019-07-02 | 宁波大学 | 一种多羟基十二酰肼引发剂及其使用方法 |
CN109970886B (zh) * | 2019-02-27 | 2021-10-08 | 宁波大学 | 一种异辛酰肼磺酸钠引发剂及其制备方法 |
CN109957047B (zh) * | 2019-02-27 | 2021-11-16 | 宁波大学 | 一种多羟基十二酰肼引发剂及其使用方法 |
CN109970934B (zh) * | 2019-02-27 | 2021-11-30 | 宁波大学 | 一种十二酰肼双阳离子引发剂及其制备与使用方法 |
CN114890906A (zh) * | 2022-06-23 | 2022-08-12 | 麦加芯彩新材料科技(上海)股份有限公司 | 一种阳离子双子叔铵盐低温破乳剂及其制备方法与应用 |
CN114890906B (zh) * | 2022-06-23 | 2024-05-14 | 麦加芯彩新材料科技(上海)股份有限公司 | 一种阳离子双子叔铵盐低温破乳剂及其制备方法与应用 |
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