CN105794827A - Insecticidal composition containing spirotetramat - Google Patents
Insecticidal composition containing spirotetramat Download PDFInfo
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- CN105794827A CN105794827A CN201610363016.8A CN201610363016A CN105794827A CN 105794827 A CN105794827 A CN 105794827A CN 201610363016 A CN201610363016 A CN 201610363016A CN 105794827 A CN105794827 A CN 105794827A
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- Prior art keywords
- ethyl ester
- spiral shell
- worm ethyl
- shell worm
- pyridine quinazoline
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
- A01N47/06—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom containing —O—CO—O— groups; Thio analogues thereof
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses an insecticidal composition containing spirotetramat. The insecticidal composition is composed of spirotetramat, pyridine quinazoline, an auxiliary, a solvent or a carrier, spirotetramat and pyridine quinazoline are active ingredients are 50:1-1:50 in mass ratio, and total mass percentage content of the active ingredients is 1-80%. The insecticidal composition has remarkable synergistic effect, is conducive to overcoming and delaying pests to generate medicine resistance, high in environment compatibility and effective and safe on aleyrodid, aphid, thrips and coccid which can cause serious damage.
Description
Technical field
The present invention relates to a kind of Pesticidal combination, particularly relate to a kind of Pesticidal combination containing spiral shell worm ethyl ester and preventing and treating thereof
The application of crop pests, belongs to agricultural insecticide technical field.
Background technology
Along with China's pattern of farming and the change of mode of agriculture, vegetable and fruit tree area increase substantially, Pesticide use
Measuring increasing, application times frequent all the more, insect is increasingly faster to the resistance rate of climb of medicament, further results in recent years
The mini pests such as aleyrodid, aphid, thrips, wood louse occur increasingly severe, cause huge loss to agricultural production；The opposing party
Face, owing to these insects have, the bodily form is little, breeding is fast, hide the features such as harm, tags and stomach poison function is main chemical agent
Cannot effectively prevent and treat, such as pleocidin etc., though and anabasine medicament has a stronger systemic action, but through life-time service for many years
Creating obvious Drug resistance, field practical application effect is poor.
Spiral shell worm ethyl ester, pesticide adopted name: spirotetramat, is the tetronic acid class chemical combination of Bayer A.G's exploitation
Thing, has two-way Uptake and translocation performance, can move up and down in whole plant, arrives blade face and bark, can effectively prevent and treat
The insects such as scale insect, thrips, aleyrodid, aphid, wood louse.
Pyridine quinazoline, pesticide adopted name: pyrifluquinazon, is newly developed the planting of Nihon Nihyaku Co., Ltd
Thing source insecticides, this compound is remarkably productive to aleyrodid, aphid, thrips, scale insect, the especially activity to Bemisia tabaci adults
High, and virus propagation on melon crop can be suppressed.
Relevant report is there is no with the compounding of pyridine quinazoline and application currently, with respect to spiral shell worm ethyl ester.
Summary of the invention
It is an object of the invention to: a kind of Synergistic insecticidal compositions being suitable for and agriculturally using is provided, and contributes to subtracting
Lack dosage, delay insect produce resistance and reduce use cost.
The technical scheme is that a kind of Pesticidal combination containing spiral shell worm ethyl ester, it is characterized in that active ingredient is spiral shell
Worm ethyl ester and pyridine quinazoline, both mass ratioes are 50:1～1:50, and preferred mass is than for 10:1-1:10.Compositions is permissible
Use known method be processed into cream, aqueous emulsion, microemulsion, suspending agent, dry suspending agent, microcapsule suspending agent, wettable powder,
Granule, soluble granule or water dispersible granules, in preparation, active ingredient gross mass percentage composition is 1%--80%.
Compared with prior art, what the present invention produced has the beneficial effect that (1) compositions potentiation is obvious, preventive effect and list
Agent is compared and is significantly improved；(2), after drug effect improves, reduce field dosage and use cost, decrease pesticide residues and environment
Pollute；(3) compositions is made up of the effective ingredient of different mechanism of action, and action site increases, and is conducive to overcoming and delaying insect
Produce resistance.
Detailed description of the invention
For making the purpose of the present invention clearer, below in conjunction with embodiment, the present invention will be further described.
The embodiment of the present invention following bioassay test embodiment and example of formulations further illustrate answering of compositions
With and good effect, but the present invention is only limitted to absolutely not these examples.The following stated is only the preferable embodiment of the present invention, Jin Jinyong
In describing the present invention, it is impossible to be interpreted as limitation of the scope of the invention.It should be pointed out that, it is all in the spirit and principles in the present invention
Within any amendment, equivalent and the improvement etc. made, should be included within the scope of the present invention.
In the examples below, unless otherwise indicated, all percentage ratios are mass percent.
Former medicine used in embodiment, the 96% spiral shell former medicine of worm ethyl ester provides for Bayer Bitterfeld GmbH crop science company,
The 98.4% former medicine of pyridine quinazoline provides for Nihon Nihyaku Co., Ltd；Complex preparation used in example of formulations all uses
Above-mentioned former medicine is by listed formula or conventional method preparation, and single dose is commercial products.
Bioassay test embodiment 1: the virulence of Bemisia tabaci adults is surveyed by spiral shell worm ethyl ester, pyridine quinazoline and different ratio
Fixed test
Test uses blade infusion process: reagent agent is made into certain density mother solution, then is diluted to 5 gradients with clear water
Concentration is stand-by, if clear water is comparison.With card punch Fructus Cucumidis sativi without beating the circular blade taking a diameter of 2cm on worm Seedling, blade is existed
Impregnating 10s in variable concentrations medicinal liquid, blot unnecessary medicinal liquid with filter paper after taking-up, each process sets 4 repetitions.Move into band afterwards
Have in the dactylethrae of 15g/L agar, then pipette in 20 adults enter with pest sucking device, be placed in growth cabinet (T=25-28 DEG C,
RH=60-80%) raise.After processing, 48h investigates Bemisia tabaci adults death condition, records dead borer population.
Mode of application uses abundant co-toxicity coefficient (CTC) method waiting nineteen sixty to propose of Sun Yun.The calculating of co-toxicity coefficient is public
Formula is as follows:
Actual measurement toxicity index (ATI)=(standard agent LC50/ reagent agent LC50)×100
In theoretical toxicity index (TTI)=A medicament ATI × mixture in the percentage composition+B medicament ATI × mixture of A the hundred of B
Divide content
Co-toxicity coefficient (CTC)=(mixture ATI/ mixture TTI) × 100
When CTC≤80, then compositions shows as antagonism, and as 80 ＜ CTC ＜ 120, then compositions shows as being added and makees
With, when CTC >=120, then compositions shows as potentiation.
Result of the test refers to table 1.
The toxicity test of Bemisia tabaci adults is tested (48h) by table 1 spiral shell worm ethyl ester, pyridine quinazoline and different ratio
From table 1 result of the test, spiral shell worm ethyl ester and pyridine quinazoline press 50:1,10:1,5:1,1:1,1:5,1:10 and
The ratio of 1:50 carries out mixture, and it is all higher than 120 to the co-toxicity coefficient (CTC) of Bemisia tabaci adults, shows as potentiation, works as spiral shell
When worm ethyl ester and pyridine quinazoline carry out mixture in the ratio of 10:1-1:10, Bemisia tabaci adults is shown as notable potentiation,
CTC value is more than 160, and wherein when spiral shell worm ethyl ester carries out mixture with pyridine quinazoline with 1:1, potentiation is the most notable, co-toxicity coefficient
Reach 197.86.
Bioassay test embodiment 2: the toxicity test of black peach aphid is tested by spiral shell worm ethyl ester, pyridine quinazoline and different ratio
Test uses blade infusion process: with brush pen reject less black peach aphid on Chinese cabbage leaf individual with have wing to become aphid, make every
Retain 50 head growths on leaf and grow basically identical aptery one-tenth aphid, the leaf with black peach aphid is put in the medicinal liquid prepared and impregnate
10s, blots unnecessary medicinal liquid with filter paper after taking-up, encases petiole base immersion moisturizing with absorbent paper, puts into disposable plastic bosom
In and seal with gauze and rubber band, prevent aphid from runing away.In temperature 25-28 DEG C, relative temperature 60-80%, photoperiod L:D
The growth cabinet of=14:10h is raised.Dead borer population is checked after 72h.
Result of the test refers to table 2.
Black peach aphid is become the toxicity test of aphid to test (72h) by table 2 spiral shell worm ethyl ester, pyridine quinazoline and different ratio
From table 2 result of the test, spiral shell worm ethyl ester and pyridine quinazoline press 50:1,10:1,5:1,1:1,1:5,1:10 and
The ratio of 1:50 carries out mixture, black peach aphid becomes the co-toxicity coefficient of aphid be all higher than 120, shows as potentiation；When spiral shell worm ethyl ester with
When pyridine quinazoline carries out mixture in the ratio of 10:1-1:10, black peach aphid becomes aphid show as notable potentiation, wherein works as spiral shell
When worm ethyl ester and pyridine quinazoline carry out mixture with 1:1, black peach aphid becoming aphid potentiation the most notable, co-toxicity coefficient reaches
253.43。
Example of formulations:
The preparation processing method used in following example of formulations is the most known to those skilled in the art, according to actual need
Want to be varied from.
Example of formulations 1:51% spiral shell worm ethyl ester pyridine quinazoline water dispersible granules
Weigh the spiral shell former medicine of worm ethyl ester, the former medicine of pyridine quinazoline and corresponding additive in mass ratio, use wet granulation size-reduced,
It is mixed, pelletize, prepares water dispersible granules of the present invention after screening.
In the present embodiment, the mass ratio of spiral shell worm ethyl ester and pyridine quinazoline can change between 50:1～1:50, Liang Zhezong
Weight/mass percentage composition be still 51%, form new embodiment.
Example of formulations 2:51% spiral shell worm ethyl ester pyridine quinazoline wettable powder
Weigh the spiral shell former medicine of worm ethyl ester, the former medicine of pyridine quinazoline and corresponding additive in mass ratio, through filler, former medicine, auxiliary agent
Mixture, the operation such as levigate, mixing i.e. prepare wettable powder of the present invention.
In the present embodiment the mass ratio of spiral shell worm ethyl ester and pyridine quinazoline can 50:1～1:50 (example 50:1,10:1,1:
1,1:10,1:50) between change, both total weight/mass percentage composition are still 51%, form new embodiment.
Example of formulations 3:22% spiral shell worm ethyl ester pyridine quinazoline cream
Weigh the spiral shell former medicine of worm ethyl ester, the former medicine of pyridine quinazoline and emulsifying agent, solvent in mass ratio, by spiral shell worm ethyl ester, pyridine
The former medicine of quinazoline, major part dimethylbenzene put into modulation kettle, start agitator and mix, under agitation make former medicine be dissolved in solvent
In；After former medicine all dissolves (if need when temperature is higher cooling), add agriculture breast 600#, agriculture breast 2000# and remaining
Solvent continues mixing, and temperature in the kettle is down to room temperature by mixing later, i.e. prepares cream preparation of the present invention.
In the present embodiment the mass ratio of spiral shell worm ethyl ester and pyridine quinazoline can 50:1～1:50 (example 50:1,10:1,1:
1,1:10,1:50) between change, both total weight/mass percentage composition are still 22%, form new example of formulations.
Example of formulations 4:11% spiral shell worm ethyl ester pyridine quinazoline aqueous emulsion
By recipe requirements, the mixing such as the spiral shell former medicine of worm ethyl ester, the former medicine of pyridine quinazoline, cosolvent, emulsifying agent, antifreezing agent are stirred
Mix dissolving and make oil phase, under 60-90r/min stirring and high shear forces, deionized water is directly added in oil phase, stir about
30min, obtains aqueous emulsion product of the present invention.
In this example of formulations the mass ratio of spiral shell worm ethyl ester and pyridine quinazoline can 50:1～1:50 (example 50:1,10:
1,1:1,1:10,1:50) between change, both total weight/mass percentage composition are still 11%, form new embodiment.
Example of formulations 5:12% spiral shell worm ethyl ester pyridine quinazoline microemulsion
By recipe requirements, the spiral shell former medicine of worm ethyl ester, the former medicine of pyridine quinazoline, cosolvent, emulsifying agent mix and blend are dissolved system
Become oil phase, under 60-90r/min stirring action, deionized water is directly added in oil phase, stir 15-30min, obtain transparent liquid
Body.Microemulsion of the present invention is i.e. obtained after analyzing each qualified.
In the present embodiment the mass ratio of spiral shell worm ethyl ester and pyridine quinazoline can 50:1～1:50 (example 50:1,10:1,1:
1,1:10,1:50) between change, both total weight/mass percentage composition are still 12%, form new embodiment.
Example of formulations 6:24% spiral shell worm ethyl ester pyridine quinazoline suspending agent
According to formula, in the dispersion tank having high speed agitator, former medicine and calcium lignosulfonate are dispersed in water, slightly
Pulverize former medicine；This mixture dosing pump through coarse pulverization is continually fed in grater, carries out finely pulverized；With medium
Last blending tank sent into by the material separate, discharged, and the methocel solution that additionally modulates is added blending tank, and pulverizes
Material mix equably, obtain final suspending agent.
In the present embodiment the mass ratio of spiral shell worm ethyl ester and pyridine quinazoline can 50:1～1:50 (example 50:1,10:1,1:
1,1:10,1:50) between change, both total weight/mass percentage composition are still 24%, form new embodiment.
Example of formulations 7:33% spiral shell worm ethyl ester pyridine quinazoline suspending agent
According to formula, in the dispersion tank having high speed agitator, former medicine and calcium lignosulfonate are dispersed in water, slightly
Pulverize former medicine；This mixture dosing pump through coarse pulverization is continually fed in grater, carries out finely pulverized；With medium
Last blending tank sent into by the material separate, discharged, and the methocel solution that additionally modulates is added blending tank, and pulverizes
Material mix equably, obtain final suspending agent.
In the present embodiment the mass ratio of spiral shell worm ethyl ester and pyridine quinazoline can 50:1～1:50 (example 50:1,10:1,1:
1,1:10,1:50) between change, both total weight/mass percentage composition are still 24%, form new embodiment.
Example of formulations 8:60% spiral shell worm ethyl ester pyridine quinazoline dry suspending agent
Weigh the spiral shell former medicine of worm ethyl ester, the former medicine of pyridine quinazoline and corresponding additive, filler etc. in mass ratio and be mixed into homogeneous
Powder, is passed through sand mill and prepares the water slurry of certain solid content through sand milling, and mean diameter is 2 μm-5 μm, is then hanged by water
Supernatant liquid is by being spray-dried granulating, thus prepares final dry suspending agent.
In the present embodiment the mass ratio of spiral shell worm ethyl ester and pyridine quinazoline can 50:1～1:50 (example 50:1,10:1,1:
1,1:10,1:50) between change, both total weight/mass percentage composition are still 60%, form new embodiment.
Example of formulations 9:20% spiral shell worm ethyl ester pyridine quinazoline microcapsule suspending agent
Weigh the spiral shell former medicine of worm ethyl ester, the former medicine of pyridine quinazoline and corresponding additive etc. in mass ratio, mixing, compounding kettle stirs,
Solidify encystation after making oil phase, more clipped dispersion mixed with water, prepare microcapsule suspending agent product.
In the present embodiment the mass ratio of spiral shell worm ethyl ester and pyridine quinazoline can 50:1～1:50 (example 50:1,10:1,1:
1,1:10,1:50) between change, both total weight/mass percentage composition are still 20%, form new embodiment.
Example of formulations 10:2% spiral shell worm ethyl ester pyridine quinazoline granule
Weigh the spiral shell former medicine of worm ethyl ester, the former medicine of pyridine quinazoline and corresponding additive etc. in mass ratio, size-reduced, mix, mediate,
After extruding, dry filter, prepare granule product.
In the present embodiment the mass ratio of spiral shell worm ethyl ester and pyridine quinazoline can 50:1～1:50 (example 50:1,10:1,1:
1,1:10,1:50) between change, both total weight/mass percentage composition are still 2%, form new embodiment.
Example of formulations 11:80% spiral shell worm ethyl ester pyridine quinazoline soluble granule
Weigh the spiral shell former medicine of worm ethyl ester, the former medicine of pyridine quinazoline and corresponding additive etc. in mass ratio, size-reduced, mix, mediate,
After extruding, dry filter, prepare soluble granule product.
In the present embodiment the mass ratio of spiral shell worm ethyl ester and pyridine quinazoline can 50:1～1:50 (example 50:1,10:1,1:
1,1:10,1:50) between change, both total weight/mass percentage composition are still 80%, form new embodiment.
Field control effectiveness test embodiment:
For further illustrating the advantage of the technology of the present invention formula scheme, present invention field control effectiveness test in detail below is implemented
Example is illustrated.
1, the field control effectiveness test to Fructus Lycopersici esculenti Bemisia tabaci Nymph
Testing and carry out in solution village, Boye County, Baoding city tomato in plastic greenhouse in October, 2015, experimental field Bemisia tabaci occurs
Seriously.Test process, using dosage and preventive effect refer to table 3, prepare related agents (granule is for spreading fertilizer over the fields) by experimental concentration, often
Process sets 4 repetitions, plot area 20m2, Gong56Ge community, random district group arranges.15 days, 30 days investigation cigarettes before medicine, after medicine
If aleyrodid borer population.
Table 3 spiral shell worm ethyl ester, pyridine quinazoline and the complex composition prevention effect to Fructus Lycopersici esculenti Bemisia tabaci Nymph
2, the field control effectiveness test to Brassica campestris L black peach aphid
Testing and carry out at Wu Fan village, Wuxue City Mei Chuan town, Hubei Province Rice-rape fields in April, 2015, experimental field black peach aphid is heavier.Examination
Test process, using dosage and preventive effect and refer to table 4, prepare related agents (granule is for spreading fertilizer over the fields) by experimental concentration, often process and set 4
Secondary repetition, plot area 20m2, Gong56Ge community, random district group arranges.1 day, 3 days, 5 days investigation black peach aphid numbers before medicine, after medicine.
Table 4 spiral shell worm ethyl ester, pyridine quinazoline and the complex composition prevention effect to Brassica campestris L black peach aphid
3, the field control effectiveness test to Flos Chrysanthemi palm thrips
Testing and carry out in flower and plant base, Baoan District, Shenzhen City, Guangdong Province in July, 2015, experimental field thrips occurs heavier.Examination
Test process, using dosage and preventive effect and refer to table 5, prepare related agents (granule is for spreading fertilizer over the fields) by experimental concentration, often process and set 4
Secondary repetition, plot area 20m2, Gong56Ge community, random district group arranges.Within 1 day, 3 days, 5 days before medicine, after medicine, investigate thrips and live
Borer population.
Table 5 spiral shell worm ethyl ester, pyridine quinazoline and the complex composition prevention effect to Flos Chrysanthemi palm thrips
4, the field control effectiveness test to honey Fructus Citri grandis scale insect
Testing and carry out in Mi You base, Pinghe County, Zhangzhou City of Fujian Province in April, 2015, experimental field on honey Fructus Citri grandis, brown circle Jie sends out
Raw lighter.Test process, using dosage and preventive effect refer to table 6, prepare related agents by experimental concentration, often process and set 4 weights
Multiple, every repeat spraying 1 strain honey Fructus Citri grandis, random district group arranges.15,30 days investigation shell borer populations before medicine, after medicine.
Table 6 spiral shell worm ethyl ester, pyridine quinazoline and the complex composition prevention effect to honey Fructus Citri grandis scale insect
Claims (5)
1. the Pesticidal combination containing spiral shell worm ethyl ester, is characterized in that active ingredient is spiral shell worm ethyl ester and pyridine quinazoline, two
The mass ratio of person is 50:1-1:50.
Pesticidal combination containing spiral shell worm ethyl ester the most according to claim 1, it is characterized in that active ingredient spiral shell worm ethyl ester and
The mass ratio of pyridine quinazoline is 10:1-1:10.
Pesticidal combination containing spiral shell worm ethyl ester the most according to claim 1 and 2, is characterized in that active ingredient in compositions
Gross mass percentage composition is 1%-80%.
Pesticidal combination containing spiral shell worm ethyl ester the most according to claim 3, it is characterized in that the dosage form of compositions be cream,
Aqueous emulsion, microemulsion, suspending agent, dry suspending agent, microcapsule suspending agent, wettable powder, granule, soluble granule or water-dispersible grain
Agent.
5. the Pesticidal combination containing spiral shell worm ethyl ester described in claim 1 is used for preventing and treating the evils such as aleyrodid, aphid, thrips, scale insect
The purposes of worm.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107736381A (en) * | 2017-11-24 | 2018-02-27 | 江苏省农业科学院 | A kind of microorganism for being used to prevent and treat sucking insect and chemical insecticide compounded combination |
| CN107751206A (en) * | 2016-08-16 | 2018-03-06 | 江苏龙灯化学有限公司 | A kind of Pesticidal combination and its method for controlling agricultural pest |
| CN109197884A (en) * | 2018-08-31 | 2019-01-15 | 南通江山农药化工股份有限公司 | Spiral shell worm ethyl ester insecticide, purposes and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006106798A1 (en) * | 2005-03-30 | 2006-10-12 | Nihon Nohyaku Co., Ltd. | Pest control agent and method of using the same |
| CN105794804A (en) * | 2014-12-30 | 2016-07-27 | 江苏龙灯化学有限公司 | Insecticidal composition and agricultural insect control method |
-
2016
- 2016-05-26 CN CN201610363016.8A patent/CN105794827A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006106798A1 (en) * | 2005-03-30 | 2006-10-12 | Nihon Nohyaku Co., Ltd. | Pest control agent and method of using the same |
| CN105794804A (en) * | 2014-12-30 | 2016-07-27 | 江苏龙灯化学有限公司 | Insecticidal composition and agricultural insect control method |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107751206A (en) * | 2016-08-16 | 2018-03-06 | 江苏龙灯化学有限公司 | A kind of Pesticidal combination and its method for controlling agricultural pest |
| CN107736381A (en) * | 2017-11-24 | 2018-02-27 | 江苏省农业科学院 | A kind of microorganism for being used to prevent and treat sucking insect and chemical insecticide compounded combination |
| CN109197884A (en) * | 2018-08-31 | 2019-01-15 | 南通江山农药化工股份有限公司 | Spiral shell worm ethyl ester insecticide, purposes and preparation method thereof |
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