CN105994326A - Insecticide composition containing spirotetramat - Google Patents
Insecticide composition containing spirotetramat Download PDFInfo
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- CN105994326A CN105994326A CN201610356670.6A CN201610356670A CN105994326A CN 105994326 A CN105994326 A CN 105994326A CN 201610356670 A CN201610356670 A CN 201610356670A CN 105994326 A CN105994326 A CN 105994326A
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- Prior art keywords
- spiral shell
- ethyl ester
- bistrifluron
- worm ethyl
- shell worm
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
- A01N47/06—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom containing —O—CO—O— groups; Thio analogues thereof
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses insecticide composition containing spirotetramat. The insecticide composition comprises spirotetramat and bistrifluron as effective components, as well as assistants, solvents and a carrier, wherein the mass ratio of the effective components, that is, spirotetramat to bistrifluron, is (50:1)-(1:50); the total mass percentage of the effective components is 1-80%. The insecticide composition has remarkable synergism, is helpful in overcoming and retarding drug resistance of insects, is relatively good in environment compatibility, is efficient for whiteflies which can do great harm, and is safe.
Description
Technical field
The present invention relates to a kind of Pesticidal combination, particularly relate to a kind of Pesticidal combination containing spiral shell worm ethyl ester and
The application of its preventing and treating crop pests, belongs to agricultural insecticide technical field.
Background technology
Along with China's pattern of farming and the change of mode of agriculture, vegetable and fruit tree area increase substantially, agriculture
Medicine usage amount is increasing, application times is frequent all the more, and insect is increasingly faster to the resistance rate of climb of medicament,
Further result in the pierce-suck type such as aleyrodid, wood louse, thrips or rasping-sucking mouthparts insect in recent years and occur more and more tighter
Weight, causes huge loss to agricultural production;On the other hand, due to these insects, to have the bodily form little, numerous
Grow the features such as fast, hiding harm, tag and the chemical agent that stomach poison function is master cannot effectively be prevented and treated, as many
Bacteriocidin etc., though and anabasine medicament has stronger systemic action, but create through life-time service for many years
Significantly Drug resistance, field practical application effect is poor.
Spiral shell worm ethyl ester, pesticide adopted name: spirotetramat, is the tetronic acid class of Bayer A.G's exploitation
Compound, has two-way Uptake and translocation performance, can move up and down in whole plant, arrive blade face with
Bark, can effectively prevent and treat the insects such as scale insect, thrips, aleyrodid, aphid, wood louse.
Bistrifluron, pesticide adopted name: bistrifluron, is that Dong Bao chemical company of Korea S is from more than 2000
The high activity chitin synthesis inhibitor filtered out in benzoyl urea derivative, can significantly inhibit the growth of insecticide
Growth effect, makes insecticide normally not cast off a skin and dead, than other chitin synthesis inhibitor high 25-of activity
50 times.Can be used for the Pest control such as Homoptera, Lepidoptera, coleoptera, to aleyrodid and diamondback moth specially good effect.
Relevant report is there is no with the compounding of bistrifluron and application currently, with respect to spiral shell worm ethyl ester.
Summary of the invention
It is an object of the invention to: a kind of Synergistic insecticidal compositions being suitable for and agriculturally using is provided, and has
Help reduce dosage, delay insect produce resistance and reduce use cost.
The technical scheme is that a kind of Pesticidal combination containing spiral shell worm ethyl ester, it is characterized in that effectively becoming
Part is spiral shell worm ethyl ester and bistrifluron, and both mass ratioes are 50:1~1:50, and preferred mass ratio is 10:
1-1:10.Compositions can use known method be processed into cream, aqueous emulsion, microemulsion, suspending agent,
Dry suspending agent, microcapsule suspending agent, wettable powder, granule, soluble granule or water dispersible granules, preparation
Middle active ingredient gross mass percentage composition is 1%--80%.
Compared with prior art, what the present invention produced has the beneficial effect that (1) compositions potentiation is obvious,
Preventive effect significantly improves compared with single dose;(2), after drug effect improves, field dosage and use cost are reduced,
Decrease pesticide residues and environmental pollution;(3) compositions is made up of the effective ingredient of different mechanism of action, makees
Increase with site, be conducive to overcoming and delay insect to produce resistance.
Detailed description of the invention
For making the purpose of the present invention clearer, below in conjunction with embodiment, the present invention will be further described.
The embodiment of the present invention following bioassay test embodiment and example of formulations further illustrate compositions
Application and good effect, but the present invention is only limitted to absolutely not these examples.It is preferable that the following stated is only the present invention
Embodiment, be used only for describe the present invention, it is impossible to be interpreted as limitation of the scope of the invention.Should be understood that
, all any amendment, equivalent and improvement etc. made within the spirit and principles in the present invention, all
Within protection scope of the present invention should being included in.
In the examples below, unless otherwise indicated, all percentage ratios are mass percent.
Former medicine used in embodiment, the 96% spiral shell former medicine of worm ethyl ester provides for Bayer Bitterfeld GmbH crop science company,
The 95% former medicine of bistrifluron provides for sea, Qingdao rel Pharmaceutical limited company;Used in example of formulations
Complex preparation all use above-mentioned former medicine to prepare by listed formula or conventional method, single dose is commercial products.
Bioassay test embodiment 1: spiral shell worm ethyl ester, bistrifluron and the different ratio virulence to Bemisia tabaci
Determination test
Test uses blade infusion process: reagent agent is made into certain density mother solution, then is diluted to 5 with clear water
Individual gradient concentration is stand-by, if clear water is comparison.Take a diameter of 2cm Fructus Cucumidis sativi without beating on worm Seedling with card punch
Circular blade, impregnates blade 10s in variable concentrations medicinal liquid, blots unnecessary medicinal liquid with filter paper after taking-up,
Each process sets 4 repetitions.Move into afterwards in the dactylethrae with 15g/L agar, then pipette with pest sucking device
In 20 adults enter, it is placed in growth cabinet (T=25-28 DEG C, RH=60-80%) and raises.In process
Rear 48h investigates Bemisia tabaci adults death condition, records dead borer population.
Mode of application uses abundant co-toxicity coefficient (CTC) method waiting nineteen sixty to propose of Sun Yun.Co-toxicity coefficient
Computing formula is as follows:
Actual measurement toxicity index (ATI)=(standard agent LC50/ reagent agent LC50)×100
Percentage composition+B medicament the ATI of A in theoretical toxicity index (TTI)=A medicament ATI × mixture × mixed
The percentage composition of B in agent
Co-toxicity coefficient (CTC)=(mixture ATI/ mixture TTI) × 100
When CTC≤80, then compositions shows as antagonism, as 80 < CTC < 120, then and compositions performance
For summation action, when CTC >=120, then compositions shows as potentiation.
Result of the test refers to table 1.
The toxicity test of Bemisia tabaci adults is tested (48h) by table 1 spiral shell worm ethyl ester, bistrifluron and different ratio
From table 1 result of the test, spiral shell worm ethyl ester and bistrifluron press 50:1,10:1,5:1,1:
1, the ratio of 1:5,1:10 and 1:50 carries out mixture, its co-toxicity coefficient (CTC) to Bemisia tabaci adults
It is all higher than 120, shows as potentiation, when spiral shell worm ethyl ester is entered in the ratio of 10:1-1:10 with bistrifluron
During row mixture, Bemisia tabaci adults showing as notable potentiation, CTC value is more than 200, wherein when spiral shell worm second
When ester and bistrifluron carry out mixture with 1:1, potentiation is the most notable, and co-toxicity coefficient has reached 238.70.
Bioassay test embodiment 2: spiral shell worm ethyl ester, bistrifluron and the different ratio poison to tobacco powder nit
Power determination test
Test uses blade infusion process: beats with card punch and takes without worm circle cucumber leaves, by face of blade down
It is placed in bottom and has in the dactylethrae of 15g/L agar culture medium, in each dactylethrae, then access 15-20 head
Bemisia tabaci adults, seals mouth of pipe gauze, and downward-sloping about 30 ° of the mouth of pipe is placed under illumination.Lay eggs 24h
After from dactylethrae by blade take out, reject unnecessary tobacco powder nit under anatomical lens, retain 20 ovum;Will band
There is the circular blade leaching medicine of ovum grain, naturally dry, then blade is transferred to the cultivation with 15g/L agar
On ware (face of blade is down), it is placed in illumination box (T=25-28 DEG C, RH=60-80%);After 10d
Check blade under the microscope, if borer population hatched in record;Often process and be repeated 4 times.
Result of the test refers to table 2.
The toxicity test of tobacco powder nit is tested (10d) by table 2 spiral shell worm ethyl ester, bistrifluron and different ratio
From table 2 result of the test, spiral shell worm ethyl ester and bistrifluron press 50:1,10:1,5:1,1:
1, the ratio of 1:5,1:10 and 1:50 carries out mixture, and the co-toxicity coefficient of tobacco powder nit is all higher than 120,
Show as potentiation;When spiral shell worm ethyl ester carries out mixture with bistrifluron in the ratio of 10:1-1:10,
Tobacco powder nit is shown as notable potentiation, wherein mixes with 1:1 with bistrifluron when spiral shell worm ethyl ester
Timing, the most notable to tobacco powder nit potentiation, co-toxicity coefficient has reached 312.54.
Example of formulations:
The preparation processing method used in following example of formulations is the most known to those skilled in the art, according to
It is actually needed and can be varied from.
Example of formulations 1:51% spiral shell worm ethyl ester bistrifluron water dispersible granules
Weigh the spiral shell former medicine of worm ethyl ester, the former medicine of bistrifluron and corresponding additive in mass ratio, use wet granulation
Size-reduced, be mixed, pelletize, prepare water dispersible granules of the present invention after screening.
In the present embodiment, the mass ratio of spiral shell worm ethyl ester and bistrifluron can change between 50:1~1:50,
Both total weight/mass percentage composition are still 51%, form new embodiment.
Example of formulations 2:51% spiral shell worm ethyl ester bistrifluron wettable powder
Weigh the spiral shell former medicine of worm ethyl ester, the former medicine of bistrifluron and corresponding additive in mass ratio, through filler, former
The operations such as medicine, the mixture of auxiliary agent, levigate, mixing i.e. prepare wettable powder of the present invention.
In the present embodiment the mass ratio of spiral shell worm ethyl ester and bistrifluron can 50:1~1:50 (example 50:
1,10:1,1:1,1:10,1:50) between change, both total weight/mass percentage composition are still 51%,
Form new embodiment.
Example of formulations 3:22% spiral shell worm ethyl ester bistrifluron cream
Weigh the spiral shell former medicine of worm ethyl ester, the former medicine of bistrifluron and emulsifying agent, solvent in mass ratio, by spiral shell worm second
The former medicine of ester, bistrifluron, major part dimethylbenzene put into modulation kettle, start agitator and mix, are stirring
Mix down and make former medicine be dissolved in solvent;After former medicine all dissolves (if needing cooling when temperature is higher), then
Add agriculture breast 600#, agriculture breast 2000# and remaining solvent continues mixing, after mixing, temperature in the kettle is dropped
To room temperature, i.e. prepare cream preparation of the present invention.
In the present embodiment the mass ratio of spiral shell worm ethyl ester and bistrifluron can 50:1~1:50 (example 50:
1,10:1,1:1,1:10,1:50) between change, both total weight/mass percentage composition are still 22%,
Form new example of formulations.
Example of formulations 4:11% spiral shell worm ethyl ester bistrifluron aqueous emulsion
By recipe requirements, by the spiral shell former medicine of worm ethyl ester, the former medicine of bistrifluron, cosolvent, emulsifying agent, antifreeze
The mix and blends such as agent dissolve makes oil phase, under 60-90r/min stirring and high shear forces, by deionized water
It is directly added in oil phase, stir about 30min, obtains aqueous emulsion product of the present invention.
In this example of formulations, spiral shell worm ethyl ester can be in 50:1~1:50 (example with the mass ratio of bistrifluron
50:1,10:1,1:1,1:10,1:50) between change, both total weight/mass percentage composition are still 11%,
Form new embodiment.
Example of formulations 5:12% spiral shell worm ethyl ester bistrifluron microemulsion
By recipe requirements, the spiral shell former medicine of worm ethyl ester, the former medicine of bistrifluron, cosolvent, emulsifying agent mixing are stirred
Mix dissolving and make oil phase, under 60-90r/min stirring action, deionized water is directly added in oil phase, stirs
Mix 15-30min, obtain transparency liquid.Microemulsion of the present invention is i.e. obtained after analyzing each qualified.
In the present embodiment the mass ratio of spiral shell worm ethyl ester and bistrifluron can 50:1~1:50 (example 50:
1,10:1,1:1,1:10,1:50) between change, both total weight/mass percentage composition are still 12%,
Form new embodiment.
Example of formulations 6:24% spiral shell worm ethyl ester bistrifluron suspending agent
According to formula, in the dispersion tank having high speed agitator, former medicine and calcium lignosulfonate are scattered in
In water, the former medicine of coarse pulverization;This mixture dosing pump through coarse pulverization is continually fed in grater,
Carry out finely pulverized;Last blending tank sent into by the material separate with medium, discharged, the first additionally modulated
Base cellulose solution adds blending tank, mixes equably with the material pulverized, obtains final suspending agent.
In the present embodiment the mass ratio of spiral shell worm ethyl ester and bistrifluron can 50:1~1:50 (example 50:
1,10:1,1:1,1:10,1:50) between change, both total weight/mass percentage composition are still 24%,
Form new embodiment.
Example of formulations 7:33% spiral shell worm ethyl ester bistrifluron water dispersible granules
Extruder grain method is used to prepare: to weigh the spiral shell former medicine of worm ethyl ester, the former medicine of bistrifluron and phase in mass ratio
Answer auxiliary agent, filler etc. after comminution by gas stream, obtain water dispersible granules by extruder grain legal system.
In the present embodiment the mass ratio of spiral shell worm ethyl ester and bistrifluron can 50:1~1:50 (example 50:
1,10:1,1:1,1:10,1:50) between change, both total weight/mass percentage composition are still 33%,
Form new embodiment.
Example of formulations 8:60% spiral shell worm ethyl ester bistrifluron dry suspending agent
Weigh the spiral shell former medicine of worm ethyl ester, the former medicine of bistrifluron and corresponding additive, filler etc. in mass ratio to be mixed into
Homogeneous powder, is passed through sand mill and prepares the water slurry of certain solid content through sand milling, and mean diameter is 2 μm
-5 μm, then by water slurry by being spray-dried granulating, thus prepare final dry suspending agent.
In the present embodiment the mass ratio of spiral shell worm ethyl ester and bistrifluron can 50:1~1:50 (example 50:
1,10:1,1:1,1:10,1:50) between change, both total weight/mass percentage composition are still 60%,
Form new embodiment.
Example of formulations 9:20% spiral shell worm ethyl ester bistrifluron microcapsule suspending agent
Weigh the spiral shell former medicine of worm ethyl ester, the former medicine of bistrifluron and corresponding additive etc. in mass ratio, mixing, allotment
Still stirs, and solidifies encystation after making oil phase, more clipped dispersion mixed with water, prepares microcapsule suspending agent and produces
Product.
In the present embodiment the mass ratio of spiral shell worm ethyl ester and bistrifluron can 50:1~1:50 (example 50:
1,10:1,1:1,1:10,1:50) between change, both total weight/mass percentage composition are still 20%,
Form new embodiment.
Example of formulations 10:2% spiral shell worm ethyl ester bistrifluron granule
Weigh the spiral shell former medicine of worm ethyl ester, the former medicine of bistrifluron and corresponding additive etc. in mass ratio, size-reduced, mixed
Even, mediate, extrude, after dry filter, prepare granule product.
In the present embodiment the mass ratio of spiral shell worm ethyl ester and bistrifluron can 50:1~1:50 (example 50:
1,10:1,1:1,1:10,1:50) between change, both total weight/mass percentage composition are still 2%, shape
The embodiment of Cheng Xin.
Example of formulations 11:80% spiral shell worm ethyl ester bistrifluron soluble granule
Weigh the spiral shell former medicine of worm ethyl ester, the former medicine of bistrifluron and corresponding additive etc. in mass ratio, size-reduced, mixed
Even, mediate, extrude, after dry filter, prepare soluble granule product.
In the present embodiment the mass ratio of spiral shell worm ethyl ester and bistrifluron can 50:1~1:50 (example 50:
1,10:1,1:1,1:10,1:50) between change, both total weight/mass percentage composition are still 80%,
Form new embodiment.
Field control effectiveness test embodiment:
For further illustrating the advantage of the technology of the present invention formula scheme, the present invention examination of field efficacy in detail below
Test embodiment to be illustrated.
1, the field control effectiveness test to Fructus Lycopersici esculenti Bemisia tabaci Nymph
Test and carry out in Xin Kou town, Xiqing District, Tianjin tomato in plastic greenhouse in JIUYUE, 2015, experimental field Bemisia tabaci
Occur serious.Test process, using dosage and preventive effect refer to table 3, prepare related agents by experimental concentration,
Use nebulization (granule is for spreading fertilizer over the fields), often process and set 4 repetitions, plot area 20m2, totally 56 little
District, random district group arranges.15 days, 30 days investigation Bemisia tabaci Nymph numbers before medicine, after medicine.
Table 3 spiral shell worm ethyl ester, bistrifluron and the complex composition prevention effect to Fructus Lycopersici esculenti Bemisia tabaci
2, the field control effectiveness test to Flos Chrysanthemi Frankliniella occidentalis
Test and carry out in flower and plant base, Shilou County town, Fanyu District, Guangzhou, Guangdong in April, 2015, experimental field west
Flower thrips occurs serious, and medicament conventional to pleocidin, anabasine etc. creates serious resistance.Test
Process, using dosage and preventive effect refer to table 4, prepare related agents by experimental concentration, use nebulization (
Granule is for spreading fertilizer over the fields), often process and set 4 repetitions, often repeat 3 strains.Before medicine, after medicine 1 day, 3 days, 5
It investigates Frankliniella occidentalis number.
Table 4 spiral shell worm ethyl ester, bistrifluron and the complex composition prevention effect to Flos Chrysanthemi Frankliniella occidentalis
Claims (5)
1. the Pesticidal combination containing spiral shell worm ethyl ester, is characterized in that active ingredient is spiral shell worm ethyl ester and double trifluoro worm
Urea, both mass ratioes are 50:1-1:50.
Pesticidal combination containing spiral shell worm ethyl ester the most according to claim 1, is characterized in that active ingredient spiral shell worm
The mass ratio of ethyl ester and bistrifluron is 10:1-1:10.
Pesticidal combination containing spiral shell worm ethyl ester the most according to claim 1 and 2, is characterized in that in compositions
Active ingredient gross mass percentage composition is 1%-80%.
Pesticidal combination containing spiral shell worm ethyl ester the most according to claim 3, is characterized in that the dosage form of compositions
For cream, aqueous emulsion, microemulsion, suspending agent, dry suspending agent, microcapsule suspending agent, wettable powder,
Granule, soluble granule or water dispersible granules.
5. the Pesticidal combination containing spiral shell worm ethyl ester described in claim 1 is used for preventing and treating the evils such as aleyrodid, wood louse, thrips
The purposes of worm.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN109197884A (en) * | 2018-08-31 | 2019-01-15 | 南通江山农药化工股份有限公司 | Spiral shell worm ethyl ester insecticide, purposes and preparation method thereof |
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CN101489384A (en) * | 2006-07-11 | 2009-07-22 | 拜尔农作物科学股份公司 | Active ingredient combinations with insecticidal and acaricidal properties |
US20110224075A1 (en) * | 2008-03-28 | 2011-09-15 | Basf Se | Pesticidal Active Mixtures Comprising Aminothiazoline Compounds |
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CN1225626A (en) * | 1996-06-29 | 1999-08-11 | 东部韩农化学株式会社 | 2-chloro-3,5-bis (trifluoromethyl) phenyl benzoyl urea derivative and process for preparing same |
CN1452457A (en) * | 2000-09-05 | 2003-10-29 | 拜尔农作物科学股份公司 | Active ingredient combinations with insecticidal and acaricidal properties |
CN101489384A (en) * | 2006-07-11 | 2009-07-22 | 拜尔农作物科学股份公司 | Active ingredient combinations with insecticidal and acaricidal properties |
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Application publication date: 20161012 |