CN101669492A - Synergic agricultural pesticide composition - Google Patents
Synergic agricultural pesticide composition Download PDFInfo
- Publication number
- CN101669492A CN101669492A CN 200910206538 CN200910206538A CN101669492A CN 101669492 A CN101669492 A CN 101669492A CN 200910206538 CN200910206538 CN 200910206538 CN 200910206538 A CN200910206538 A CN 200910206538A CN 101669492 A CN101669492 A CN 101669492A
- Authority
- CN
- China
- Prior art keywords
- pyridine
- composition
- piperazine worm
- emamectin
- benzoate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 55
- 239000000575 pesticide Substances 0.000 title claims abstract description 13
- 230000002195 synergetic effect Effects 0.000 title claims abstract description 11
- CXEGAUYXQAKHKJ-NSBHKLITSA-N emamectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](NC)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 CXEGAUYXQAKHKJ-NSBHKLITSA-N 0.000 claims abstract description 36
- 238000009472 formulation Methods 0.000 claims abstract description 19
- 239000000839 emulsion Substances 0.000 claims abstract description 8
- 239000004530 micro-emulsion Substances 0.000 claims abstract description 8
- 239000004562 water dispersible granule Substances 0.000 claims abstract description 7
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 140
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 claims description 139
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims description 70
- 239000005660 Abamectin Substances 0.000 claims description 38
- RRZXIRBKKLTSOM-XPNPUAGNSA-N avermectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 RRZXIRBKKLTSOM-XPNPUAGNSA-N 0.000 claims description 33
- 239000000375 suspending agent Substances 0.000 claims description 13
- 239000000843 powder Substances 0.000 claims description 8
- 238000009736 wetting Methods 0.000 claims description 7
- 241001124076 Aphididae Species 0.000 claims description 5
- 241001498622 Cixius wagneri Species 0.000 claims description 5
- 230000000361 pesticidal effect Effects 0.000 claims description 5
- 239000004563 wettable powder Substances 0.000 abstract description 2
- 239000000470 constituent Substances 0.000 abstract 7
- 241001466042 Fulgoromorpha Species 0.000 abstract 1
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- 239000003814 drug Substances 0.000 description 32
- 238000012360 testing method Methods 0.000 description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
- 239000003795 chemical substances by application Substances 0.000 description 15
- 239000002270 dispersing agent Substances 0.000 description 13
- -1 hydrogen imidazoles Chemical class 0.000 description 12
- 241000209094 Oryza Species 0.000 description 11
- 235000007164 Oryza sativa Nutrition 0.000 description 11
- 238000012545 processing Methods 0.000 description 11
- 235000009566 rice Nutrition 0.000 description 11
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- 239000002904 solvent Substances 0.000 description 9
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 8
- 241000238631 Hexapoda Species 0.000 description 8
- 241001556089 Nilaparvata lugens Species 0.000 description 8
- 241000125167 Rhopalosiphum padi Species 0.000 description 7
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- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 239000003153 chemical reaction reagent Substances 0.000 description 6
- 239000002131 composite material Substances 0.000 description 6
- 229950008167 abamectin Drugs 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 239000002562 thickening agent Substances 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 229940077388 benzenesulfonate Drugs 0.000 description 4
- 239000006184 cosolvent Substances 0.000 description 4
- 230000000749 insecticidal effect Effects 0.000 description 4
- 239000002917 insecticide Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 239000012071 phase Substances 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 239000005906 Imidacloprid Substances 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000008485 antagonism Effects 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 239000000306 component Substances 0.000 description 3
- 239000007884 disintegrant Substances 0.000 description 3
- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 description 3
- 229940056881 imidacloprid Drugs 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 239000002574 poison Substances 0.000 description 3
- 231100000614 poison Toxicity 0.000 description 3
- 230000002829 reductive effect Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- FYGHSUNMUKGBRK-UHFFFAOYSA-N 1,2,3-trimethylbenzene Chemical compound CC1=CC=CC(C)=C1C FYGHSUNMUKGBRK-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- QWCKQJZIFLGMSD-GSVOUGTGSA-N D-alpha-aminobutyric acid Chemical compound CC[C@@H](N)C(O)=O QWCKQJZIFLGMSD-GSVOUGTGSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- DFPAKSUCGFBDDF-UHFFFAOYSA-N Nicotinamide Chemical compound NC(=O)C1=CC=CN=C1 DFPAKSUCGFBDDF-UHFFFAOYSA-N 0.000 description 2
- 241000819999 Nymphes Species 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 239000007859 condensation product Substances 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 2
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 2
- 229940043264 dodecyl sulfate Drugs 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000009313 farming Methods 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 238000005286 illumination Methods 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- 231100000225 lethality Toxicity 0.000 description 2
- 231100000053 low toxicity Toxicity 0.000 description 2
- 230000010534 mechanism of action Effects 0.000 description 2
- 239000012452 mother liquor Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 210000002784 stomach Anatomy 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- MTXSIJUGVMTTMU-JTQLQIEISA-N (S)-anabasine Chemical compound N1CCCC[C@H]1C1=CC=CN=C1 MTXSIJUGVMTTMU-JTQLQIEISA-N 0.000 description 1
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 description 1
- VNHBYKHXBCYPBJ-UHFFFAOYSA-N 5-ethynylimidazo[1,2-a]pyridine Chemical compound C#CC1=CC=CC2=NC=CN12 VNHBYKHXBCYPBJ-UHFFFAOYSA-N 0.000 description 1
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 102000002322 Egg Proteins Human genes 0.000 description 1
- 108010000912 Egg Proteins Proteins 0.000 description 1
- 241000258937 Hemiptera Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 206010033799 Paralysis Diseases 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 229930014345 anabasine Natural products 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 229940088710 antibiotic agent Drugs 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 230000000853 biopesticidal effect Effects 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 150000004657 carbamic acid derivatives Chemical class 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
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- 235000014113 dietary fatty acids Nutrition 0.000 description 1
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- 238000011049 filling Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 238000003958 fumigation Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
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- 239000001257 hydrogen Substances 0.000 description 1
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- 230000002401 inhibitory effect Effects 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
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- 229960003966 nicotinamide Drugs 0.000 description 1
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- 239000011570 nicotinamide Substances 0.000 description 1
- 238000012946 outsourcing Methods 0.000 description 1
- 210000004681 ovum Anatomy 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 125000004193 piperazinyl group Chemical group 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000002728 pyrethroid Substances 0.000 description 1
- 150000004040 pyrrolidinones Chemical class 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
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- 239000003381 stabilizer Substances 0.000 description 1
- 238000007619 statistical method Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
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- 229920001285 xanthan gum Polymers 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
Reagent agent (active ingredient weight ratio) | ??LC 50??(mg/l) | ??ATI | ??TTI | Co-toxicity coefficient CTC |
The pyridine of piperazine worm | ??2.67 | ??100.00 | ||
Avermectin | ??4.59 | ??58.17 | ||
Piperazine worm pyridine: Avermectin (100: 1) | ??2.22 | ??120.27 | ??99.59 | ??120.77 |
Piperazine worm pyridine: Avermectin (50: 1) | ??2.01 | ??132.84 | ??99.18 | ??133.93 |
Piperazine worm pyridine: Avermectin (30: 1) | ??1.79 | ??149.16 | ??98.65 | ??151.20 |
Piperazine worm pyridine: Avermectin (20: 1) | ??1.32 | ??202.27 | ??98.01 | ??206.38 |
Piperazine worm pyridine: Avermectin (10: 1) | ??2.1 | ??157.99 | ??96.20 | ??164.23 |
Piperazine worm pyridine: Avermectin (1: 1) | ??3.75 | ??113.62 | ??79.08 | ??143.66 |
Piperazine worm pyridine: Avermectin (1: 5) | ??8.19 | ??89.30 | ??65.14 | ??137.08 |
Piperazine worm pyridine: Avermectin (1: 10) | ??11.87 | ??68.99 | ??61.97 | ??111.33 |
Reagent agent (active ingredient weight ratio) | ??LC 50??(mg/l) | ??ATI | ??TTI | Co-toxicity coefficient CTC |
The pyridine of piperazine worm | ??4.03 | ??100.00 | ||
Emamectin-benzoate | ??2.18 | ??184.86 | ||
Piperazine worm pyridine: emamectin-benzoate (100: 1) | ??3.21 | ??125.55 | ??100.84 | ??124.50 |
Piperazine worm pyridine: emamectin-benzoate (50: 1) | ??3.01 | ??133.89 | ??101.66 | ??131.70 |
Piperazine worm pyridine: emamectin-benzoate (30: 1) | ??2.79 | ??144.44 | ??102.74 | ??140.60 |
Piperazine worm pyridine: emamectin-benzoate (20: 1) | ??1.22 | ??330.33 | ??104.04 | ??317.50 |
Piperazine worm pyridine: emamectin-benzoate (10: 1) | ??1.62 | ??248.77 | ??107.71 | ??230.95 |
Piperazine worm pyridine: emamectin-benzoate (1: 1) | ??1.85 | ??217.84 | ??142.43 | ??152.94 |
Piperazine worm pyridine: emamectin-benzoate (1: 5) | ??1.92 | ??209.90 | ??170.72 | ??122.95 |
Piperazine worm pyridine: emamectin-benzoate (1: 10) | ??2.01 | ??200.50 | ??177.15 | ??113.18 |
Claims (6)
Priority Applications (1)
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CN 200910206538 CN101669492B (en) | 2009-10-16 | 2009-10-16 | Synergic agricultural pesticide composition |
Applications Claiming Priority (1)
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CN 200910206538 CN101669492B (en) | 2009-10-16 | 2009-10-16 | Synergic agricultural pesticide composition |
Publications (2)
Publication Number | Publication Date |
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CN101669492A true CN101669492A (en) | 2010-03-17 |
CN101669492B CN101669492B (en) | 2012-12-12 |
Family
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Family Applications (1)
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CN 200910206538 Active CN101669492B (en) | 2009-10-16 | 2009-10-16 | Synergic agricultural pesticide composition |
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101856033A (en) * | 2010-06-29 | 2010-10-13 | 江苏克胜集团股份有限公司 | Novel nicotine pesticide combination containing 1-[(6-Chloropyridin-3-yl)methyl]-7- methyl-8-nitro-5-propoxy-1,2,3,5,6,7-hexahydroimidazo [1,2-Alpha] pyridine |
CN101861875A (en) * | 2010-06-29 | 2010-10-20 | 江苏克胜集团股份有限公司 | Synergistic pesticide compound containing mepiquat chloride and organophosphorus pesticide |
CN102042966A (en) * | 2010-11-12 | 2011-05-04 | 哈尔滨工业大学 | Quick analysis method for reaction process of emamectin benzoate |
WO2013127228A1 (en) * | 2012-02-28 | 2013-09-06 | 深圳诺普信农化股份有限公司 | Insecticidal composition and application thereof |
CN103636659A (en) * | 2013-11-21 | 2014-03-19 | 张晓强 | Pesticide composition containing 1-(6-chloro-3-methylpyridyl)-8-nitro-7-methyl-1,2,3,4,5,6,7-hexahydroimidazo[1,2-a]pyridine and dinotefuran |
CN103766358A (en) * | 2013-12-28 | 2014-05-07 | 上海艳紫化工科技有限公司 | Pest control pesticide suspension agent |
CN107821409A (en) * | 2017-10-25 | 2018-03-23 | 江苏克胜集团股份有限公司 | A kind of Pesticidal combination containing paichongding and antibiotic insecticide |
CN107873714A (en) * | 2017-10-25 | 2018-04-06 | 江苏克胜作物科技有限公司 | A kind of processing method of paichongding nanometer micro-emulsion pesticide |
Family Cites Families (2)
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