CN103636659A - Pesticide composition containing 1-(6-chloro-3-methylpyridyl)-8-nitro-7-methyl-1,2,3,4,5,6,7-hexahydroimidazo[1,2-a]pyridine and dinotefuran - Google Patents
Pesticide composition containing 1-(6-chloro-3-methylpyridyl)-8-nitro-7-methyl-1,2,3,4,5,6,7-hexahydroimidazo[1,2-a]pyridine and dinotefuran Download PDFInfo
- Publication number
- CN103636659A CN103636659A CN201310586878.3A CN201310586878A CN103636659A CN 103636659 A CN103636659 A CN 103636659A CN 201310586878 A CN201310586878 A CN 201310586878A CN 103636659 A CN103636659 A CN 103636659A
- Authority
- CN
- China
- Prior art keywords
- pyridine
- mti
- agent
- composition
- composition pesticide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a pesticide composition containing 1-(6-chloro-3-methylpyridyl)-8-nitro-7-methyl-1,2,3,4,5,6,7-hexahydroimidazo[1,2-a]pyridine and dinotefuran. The active components of the composition contain 1-(6-chloro-3-methylpyridyl)-8-nitro-7-methyl-1,2,3,4,5,6,7-hexahydroimidazo[1,2-a]pyridine and dinotefuran with a weight ratio of 1:40-15:1. The composition has a substantial better synergistic effect than single components, so the pesticide use cost is reduced, and the pesticide resistance is enlarged and delayed. The composition is a high-efficiency broad-spectrum pesticide provided for the production of rice, fruit trees, vegetables and the like.
Description
Technical field
The present invention relates to a kind of composition pesticide, especially relate to composition pesticide and application thereof that a class contains the pyridine of piperazine worm and MTI-446.
Background technology
The pyridine of piperazine worm, chemical name is 1-(the chloro-3-picolyl of 6-)-8-nitro-7-methyl isophthalic acid, 2,3,5,6,7-, six hydrogen imidazoles [1,2-a] pyridines.
Piperazine Chong Dingshiyou Kesheng Group Co., Ltd., Jiangsu Prov. and East China University of Science's cooperative development novel pesticide.The pyridine of piperazine worm is domestic new initiative patented product, and this compound has been obtained internal and international patent of invention, and in the Ministry of Agriculture, first obtains 95% former medicine and the registration of 10% suspending agent in Bing You Kesheng Group Co., Ltd., Jiangsu Prov..
Piperazine worm pyridine structure is unique, it is the cis-structure different from most insecticide, thereby its from have differently with existing nicotinic insecticide, to environment, people, animal, pest natural enemy and other beneficial organism safety, especially changed the situation of nicotinic insecticide to the high poison of honeybee.First exploitation at home, insect, to its non-resistant, belongs to the insecticide of friendly environment.
MTI-446 chemical name: (EZ)-(RS)-1-methyl-2-nitro-3-(tetrahydrochysene-3-furfuryl) guanidine.MTI-446 is a brand-new insecticides, there is the features such as efficient, low toxicity, low-residual, main the sucking pest of Homoptera (plant hopper, aphid, trialeurodes vaporariorum, leafhopper) is shown to excellent control efficiency is transmitted by spinal nerves and the systemic insecticide of the stomach poison function of tagging, can be absorbed by plants fast wide dispersion, nAChR is had to excitation.The current domestic formulations such as water-soluble granule of having registered.
Summary of the invention
The object of this invention is to provide a kind of synergistic function that has, to the existing certain lasting effect of insect, again have better quick-acting, the composition pesticide that contains the pyridine of piperazine worm and MTI-446 that is difficult for developing immunity to drugs.
Object of the present invention can reach by following measures:
A composition pesticide that contains the pyridine of piperazine worm and MTI-446, by the pyridine of piperazine worm and MTI-446, the ratio by weight 1:40～15:1 forms the active component of said composition.
Preferably, in described composition pesticide, the weight ratio of the pyridine of piperazine worm and MTI-446 is 1:10～5:1.
More preferably, in described composition pesticide, the weight ratio of the pyridine of piperazine worm and MTI-446 is 1:2.
The active component of composition pesticide of the present invention and auxiliary element can be mixed with the preparation that is applicable to agricultural use, be that composition pesticide active ingredient of the present invention can be added the preparation that auxiliary element is mixed with any formulation that is applicable to agricultural use according to method known in those skilled in the art, formulation comprises water dispersible granules, wetting powder, suspending agent, soluble powder or dispersibles oil-suspending agent preferably.
In the present composition, operable auxiliary element is selected from one or more in surfactant, dispersant, binding agent, wetting agent, stabilizing agent, disintegrant, antifreezing agent, thickener, pH adjusting agent or bleeding agent, and other is of value to, and active component is stablized in storing and using and the known substance of drug effect performance, these are all various compositions conventional in pesticidal preparations or that allow to use, be not particularly limited, concrete composition and consumption are determined by simple experiment according to formulation.
One or more in lauryl sodium sulfate, neopelex, sldium lauryl sulfate, octylphenol polyethylene oxyethylene group ether sulfate, alkylnaphthalene sulfonate, alkyl fourth disulfonate of the surfactant that is applicable to the present composition.
Dispersant is selected from sodium lignin sulfonate, calcium lignosulfonate, lauryl alcohol polyethylene glycol oxide base ether sodium sulfate, Fluhyzon formaldehyde condensation products iodate, potassium oleate, enuatrol, alkyl polyoxyethylene ether iodate, alkylphenol-polyethenoxy base ether formaldehyde condensation products, alkylphenol-polyethenoxy base ether Nonyl pheno base ether, polyoxyethylene polyoxypropylene base ether block copolymers, pull open powder, poly-second carboxylic esters sodium salt, one or more in alkylpolyoxyethylene phosphate or Fluhyzon formaldehyde condensation products sulphate.
Binding agent selects one or more in Macrogol 200～4000, ethylene glycol, propane diols, glycerine.
Stabilizing agent is selected from one or more in catechol, butyl glycidyl ether, phenyl glycidyl ether, cresyl glycidyl ether, polyethylene glycol diglycidyl ether, chloropropylene oxide, sodium sorbate, epoxidised soybean oil, linseed oil, quinhydrones, eugenol, citric acid, hydroxy benzoate or nipasol.
Disintegrant is selected from one or more in potash, sodium carbonate, sodium bicarbonate, carbonic hydroammonium, ammonium nitrate, urea etc.
Bleeding agent comprises one or more of sulfonic acid succinic acid dialkyl, disecoctylmaleate sodium sulfonate, eucalyptus oil, azone, thiophene ketone.
Thickener comprises one or more in sodium carboxymethylcellulose, sodium carboxymethyl starch, polyvinylpyrrolidone, polyvinyl alcohol.
The water that is applicable to composition pesticide of the present invention comprises running water, natural water, deionized water, distilled water etc.
Composition pesticide of the present invention can be used for the control of the multiple sucking pest of the crops such as paddy rice, fruit tree, vegetables, as rice hoppers.
Benefit of the present invention is, compares have remarkable synergistic effect with single dose, and its co-toxicity coefficient is at least 120, thereby reduces drug cost, and can expand and delay pesticide resistance, for the production of paddy rice, fruit tree, vegetables etc. provides efficiently, the insecticide of wide spectrum.
Embodiment
In order to make object of the present invention, technical scheme and advantage clearer, the present invention describes with following specific embodiment, but the present invention is limited to absolutely not these examples.The following stated is only the good embodiment of the present invention, only for explaining the present invention, can not therefore be interpreted as the restriction to the scope of the claims of the present invention.It should be pointed out that all any modifications of making within the spirit and principles in the present invention, be equal to replacement and improvement etc., within all should being included in protection scope of the present invention.Therefore, the protection domain of patent of the present invention should be as the criterion with appended claims.
One, preparation processing formulation Example
Embodiment 1 40% piperazine worm pyridine MTI-446 wetting powder
Common process is made, piperazine worm pyridine 15%, and MTI-446 25%, lauryl sodium sulfate 2%, sodium lignin sulfonate 3%, sodium methylene bis-naphthalene sulfonate 2%, kaolin is mended to 100%.
In the present embodiment, the part by weight of the pyridine of piperazine worm and MTI-446 can change between 1:40～15:1, and both weight percentages can change between 5～80%, and the proportioning of used additives is also adjusted accordingly thereupon, forms new embodiment.
Embodiment 2 35% piperazine worm pyridine MTI-446 dispersible oil-suspending agent
Common process is made, wherein piperazine worm pyridine 10%, and MTI-446 25%, phenethyl phenol polyethenoxy polyoxypropylene ether carboxylate 5%, aluminium-magnesium silicate 0.5%, propanediol polyoxypropylene APEO 7%, ethylene glycol 3%, histosol 2%, methyl oleate is mended to 100%.
In the present embodiment, the part by weight of the pyridine of piperazine worm and MTI-446 can change between 1:40～15:1, and both weight percentages can change between 5～60%, and the proportioning of used additives is also adjusted accordingly thereupon, forms new embodiment.
Embodiment 3 60% piperazine worm pyridine MTI-446 water dispersible granules
Common process is made, piperazine worm pyridine 25%, MTI-446 35%, dispersant Fluhyzon formaldehyde condensation products iodate 4%, alkylphenol-polyethenoxy base ether formaldehyde condensation products 5%, wetting agent neopelex 2%, binding agent cetomacrogol 1000 5%, disintegrant ammonium nitrate 10%.
In the present embodiment, the part by weight of the pyridine of piperazine worm and MTI-446 can change between 1:40～15:1, and both weight percentages can change between 5～80%, and the proportioning of used additives is also adjusted accordingly thereupon, form new embodiment.
Two, biological activity determination and test of pesticide effectiveness example
Indoor biological activity determination test
Rice hoppers [Nilaparvata lugens (stal)]: catch adult from field, Yancheng, Jiangsu Province.
The good rice paddy seed of germination is rinsed with clear water, float not plump paddy.24h at normal temperatures soaks seed.Hand-launder seed-grain several times, then use the warm water washing 1～2 time of 45～50 ℃, put into plastic casing, cover wet towel, be placed in vernalization in the constant incubator of 30 ℃.While putting into, plastic basin bottom tilts slightly, makes water not submergence seed-grain as far as possible.After 24h, the rice paddy seed showing money or valuables one carries unintentionally is spread out in dish for cultivating equably, with seed-grain, does not stack and be advisable.Put Stainless-steel space grids, be placed in (illumination 2000～3000lx, 16h, 28 ℃ of temperature) water-retaining cultivation in illumination box.Just can be for laying eggs and raising when rice bud grows up to 1.5cm.
To have the dish for cultivating of rice bud to put into dependent insect cage, fixing, the dependent insect cage back side be to light source.Separately a glass door that is connected to the dependent insect cage of the adult of adopting back from field is opened, made its Men Yumen relative.Vibrate gently cage, adult is rushed in the cage of new rice bud.Lay eggs 24 or 48h after use the same method adult removed again.The rice bud that adult has been laid eggs, 27～29 ℃ of room temperatures, is cultivated in the insectary of illumination 12h, keeps rice bud not cut off the water supply.After 6～8d, ovum hatching.When rice bud is eaten extremely by rice fulgorid before, must change rice bud.While changing seedling, first cage is inverted gently, is made withered rice bud in the above, then put new rice bud into cage.After 2d, insect is automatically transferred on rice bud, then takes withered rice bud away.
2.2 instrument and equipment
2.2.1 electronic balance (sensibility reciprocal 0.1mg);
2.2.2 clap net;
2.2.3 dependent insect cage (34 * 34 * 34cm
3);
2.2.4 dish for cultivating (28.5 * 28.5 * 0.6cm
3);
2.2.5 the fixing rack (26cm * 26cm) of rice bud;
2.2.6 micro intravenous drip device;
2.2.7 burn bosom;
2.2.8 pipette;
2.2.9 constant incubator;
2.2.10 illumination box etc.
3 experimental scheme
3.1 examination material is prepared
Select the 2nd generation nymph in 3 age of indoor feeding.
3.2 medicament
(1) piperazine worm pyridine: 95% former medicine;
(3) MTI-446 (dinotefuan): 95% former medicine;
Above medicament provides by Kesheng Group Co., Ltd., Jiangsu Prov..
3.3 test procedure
3.3.1 liquid preparation
First with ethanol, dissolve former medicine, according to the result of preliminary experiment, two appropriate former medicines are made into 5 different proportionings, then it is stand-by with ethanol, each processing to be diluted to respectively to 5 series concentration gradients.(ratio of active ingredient is respectively 1:8 to 5 piperazine worms pyridine proportionings different from MTI-446,1:4,1:2,1:1,2:1; ).
3.3.2 chemicals treatment
The drop method that adopts NY/T1154.1-2006 to recommend is measured.By micro intravenous drip device solvent clean, regulate dropper to stand-by state.With writing brush, choose the examination worm CO of neat and consistent
2slight anesthesia is placed in 9cm culture dish, then with micro intravenous drip device by medicament by a drop in the polypide belly of examination worm, every some drops physic liquor 0.1 μ L, with drop 0.1 μ L not containing medicament but the contrast that is treated to that contains ethanol.Examination worm after drop is transferred to respectively in the culturing room that (28 ± 2) ℃, relative moisture are 75% and is normally cultivated.Every processing 4 times repeats, and often repeats to try 20 of worms, 80 of every processing examination worms.
4 investigation
After processing, 24h investigation examination worm death condition (judgement is gently to sting without autonomic response with pin for examination worm death standard), records total borer population and dead borer population.
5 data statistics and analysis
5.1 computational methods
According to survey data, calculate the corrected mortality that each is processed.And adopt the abundant method of Sun Yun to calculate the co-toxicity coefficient (CTC value) of mixture with reference to NY/T1154.7-2006.If contrast lethality < 5%, does not proofread and correct; Contrast lethality, between 5%～20%, is proofreaied and correct by formula 2; Contrast lethality > 20%, test need be reformed.
5.2 data statistic analysis
The logarithm value of drug concentration (mg/L) of take is independent variable x, and the probit value of corrected mortality of take is dependent variable y, sets up respectively virulence regression equation formula, adopts DPS software to calculate the LC of single dose and each proportioning mixture
50and 95% confidence limit, LC
90and 95% confidence limit, mixture co-toxicity coefficient, relatively synergy situation.
The co-toxicity coefficient of mixture (CTC value) calculates by following formula:
ATI＝(S/M)×100
In formula: AT is mixture actual measurement toxicity index; S is the LC of standard insecticide
50, unit is milligrams per liter (mg/l); M is the LC50 of mixture, and unit is milligrams per liter (mg/l);
TTI＝TIA?x?PA+TIB?x?PB
In formula: TTI is the theoretical toxicity index of mixture; TIA is that A medicament toxicity index: PA is the percentage composition of A medicament in mixture, and unit is percentage; TIB is B medicament toxicity index; PB is the percentage composition of B medicament in mixture, and unit is percentage.
CTC＝(ATI/TTI)×100
In formula: CTC is co-toxicity coefficient; ATI is mixture actual measurement toxicity index; TTI is the theoretical toxicity index of mixture.
6 interpretations of result and discussion
According to the NY/T11547.7-2006 insecticide synergy criteria for classifying: co-toxicity coefficient (CTC) >=120 shows as synergistic effect; CTC≤80 show as antagonism; 80 < CTC < 120 show as summation action.As can be seen from Table 1: the pyridine of piperazine worm and MTI-446 are when with each ratio proportioning, and its co-toxicity coefficient is all greater than 120, shows as synergistic effect.Co-toxicity coefficient when wherein the pyridine of piperazine worm and MTI-446 are composite with 1:2 ratio is the highest, reaches 178.50, and synergistic effect is the most remarkable.Experimental result illustrates described in this that composition for preventing and controlling rice hoppers has reasonability and feasibility.
Field natural conditions are different from indoor conditions, therefore, between field population and indoor population, also there are differences.Under the natural conditions of field, can this result of the test be applied needs further checking.
The toxicity test result of the different proportioning compositions of the worm pyridine of table 1 piperazine and MTI-446 to rice fulgorid
| Proportioning (%) | LC50(mg/L) | ATI | TTI | Co-toxicity coefficient CTC |
| The pyridine of piperazine worm | 5.12 | 100.00 | ? | ? |
| MTI-446 | 6.43 | 95.32 | ? | ? |
| Piperazine worm pyridine 4+ MTI-446 32 | 5.48 | 92.56 | 67.14 | 122.43 |
| Piperazine worm pyridine 6+ MTI-446 24 | 4.36 | 95.63 | 73.86 | 163.70 |
| Piperazine worm pyridine 8+ MTI-446 16 | 2.97 | 109.89 | 77.22 | 178.60 |
| Piperazine worm pyridine 16+ MTI-446 16 | 1.42 | 128.17 | 83.31 | 170.10 |
| Piperazine worm pyridine 16+ MTI-446 8 | 1.96 | 138.10 | 90.25 | 166.06 |
Field medicine effect test
1, material and method
1.1 reagent agent
1.1.110% Pai Chongding SC Kesheng Group Co., Ltd., Jiangsu Prov. produces, and 20 MTI-446 soluble granula middle peasants live business (Tianjin) agricultural chemicals Co., Ltd.
1.1.235% piperazine worm pyridine MTI-446 dispersibles oil-suspending agent (embodiment 2 gained)
1.2 Treatment Design
1.2.20% MTI-446 SG30g/667m
2; 10% piperazine worm pyridine SC40g/667m
2;
1.2.235% piperazine worm pyridine MTI-446 OF20g/667m
2;
1.2.3 blank (CK)
1.3 using method
Establish altogether 3 processing, each is processed and repeats 3 times, community area 60m
2.Local rice field four generations brown planthopper nymph in 1 age peak period dispenser on August 17th, 2012, every 667m
2press above-mentioned design dosage to water 45kg.Aim at manually evenly complete stool spraying of rice seedling, maintenance water layer in field in week during dispenser and after medicine.
This experimental field rice varieties is for raising spoke round-grained rice No. 7.During dispenser, average 4756 of field brown planthopper hundred cave worm amount, wherein 1 age nymph account for more than 90%.
1.4 investigation method
1.4.1 security survey
After dispenser, irregularly community rice seedling growing state is respectively processed in observation, records rice shoot to the reaction of medicament or symptom of chemical damage, analyzes the safety of medicament to rice seedling.
1.4.2 preventive effect effect research
Before dispenser, investigation insect population radix, respectively looks into the residual worm amount in field for after medicine 1,3,7,10,15 day one time.The sampling of 3 of every communities, every some company looks into 6 caves, and 18 caves are looked in every community.With insect population survival rate, calculate control efficiency, computing formula is as follows:
Proofread and correct preventive effect (%)=(check plot insect population survival rate-applying area insect population survival rate) insect population survival rate * 100, ÷ check plot
2, the safety of medicament to rice seedling
Execute observation post administration, each community rice seedling growth is normal, does not occur any poisoning situation.
3, results and analysis
10% piperazine worm pyridine SC, 20% MTI-446 SG, 35% piperazine worm pyridine MTI-446 OF, Brown Planthopper is had to good control efficiency, 10% piperazine worm pyridine SC, better in quick-acting, slightly poor in lasting effect, 35% piperazine worm pyridine MTI-446 OF is all showing aspect quick-acting and lasting effect control well, to rice seedling safety.20% MTI-446 SG better quick-acting aspect lasting effect is slightly poor.
Experimental data represents, the correction preventive effect of 35% piperazine worm pyridine MTI-446 OF is better than 10% piperazine worm pyridine SC and 20% MTI-446 SG, illustrates that the pyridine of piperazine worm and MTI-446 are composite to have an obvious synergistic effect.
Several preparations of table 2 are to Brown Planthopper control efficiency
Note: B, 20% MTI-446 SG30g/667m
2; C, 10% piperazine worm pyridine SC40g/667m
2; D, 35% piperazine worm pyridine MTI-446 OF20g/667m
2.
A kind of composition pesticide that contains the pyridine of piperazine worm and MTI-446 of the present invention is described by concrete example, those skilled in the art can use for reference content of the present invention, the links such as appropriate change raw material, process conditions realize corresponding other object, its relevant change does not all depart from content of the present invention, within all similar replacements and change will become apparent to those skilled in the art that and be all deemed to be included in scope of the present invention.
Claims (8)
1. a composition pesticide that contains the pyridine of piperazine worm and MTI-446, by the pyridine of piperazine worm and MTI-446, the ratio by weight 1:40～15:1 forms the active component that it is characterized in that said composition.
2. composition pesticide according to claim 1, the weight ratio that it is characterized in that the two is 1:10～5:1.
3. composition pesticide according to claim 1, the weight ratio that it is characterized in that the two is 1:2.
4. according to the arbitrary described composition pesticide of claims 1 to 3, it is characterized in that the active component of said composition and auxiliary element are mixed with the preparation that is applicable to agricultural use.
5. composition pesticide according to claim 4, the preparation that it is characterized in that described applicable agricultural use is water dispersible granules, wetting powder, suspending agent, soluble powder or dispersibles oil-suspending agent.
6. composition pesticide according to claim 4, is characterized in that described auxiliary element is selected from one or more in surfactant, dispersant, binding agent, wetting agent, stabilizing agent, disintegrant, antifreezing agent, thickener, pH adjusting agent or bleeding agent.
7. the arbitrary described composition pesticide of claims 1 to 3 is in the application of the sucking pest of control paddy rice, fruit tree or vegetable crop.
8. application according to claim 7, is characterized in that described sucking pest is rice hoppers.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310586878.3A CN103636659A (en) | 2013-11-21 | 2013-11-21 | Pesticide composition containing 1-(6-chloro-3-methylpyridyl)-8-nitro-7-methyl-1,2,3,4,5,6,7-hexahydroimidazo[1,2-a]pyridine and dinotefuran |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310586878.3A CN103636659A (en) | 2013-11-21 | 2013-11-21 | Pesticide composition containing 1-(6-chloro-3-methylpyridyl)-8-nitro-7-methyl-1,2,3,4,5,6,7-hexahydroimidazo[1,2-a]pyridine and dinotefuran |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103636659A true CN103636659A (en) | 2014-03-19 |
Family
ID=50242076
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310586878.3A Pending CN103636659A (en) | 2013-11-21 | 2013-11-21 | Pesticide composition containing 1-(6-chloro-3-methylpyridyl)-8-nitro-7-methyl-1,2,3,4,5,6,7-hexahydroimidazo[1,2-a]pyridine and dinotefuran |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103636659A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104365650A (en) * | 2014-10-27 | 2015-02-25 | 池州弘利农业科技开发有限公司 | Synergistic insecticidal composition containing chloropyridine and dinotefuran |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1631887A (en) * | 2004-11-23 | 2005-06-29 | 华东理工大学 | Nitryl methylene derivatives and uses thereof |
| CN101069509A (en) * | 2007-06-21 | 2007-11-14 | 江苏克胜集团股份有限公司 | IPP suspension preparation and preparing method |
| CN101658178A (en) * | 2009-07-22 | 2010-03-03 | 深圳诺普信农化股份有限公司 | Synergistic insecticidal composition |
| CN101669492A (en) * | 2009-10-16 | 2010-03-17 | 深圳诺普信农化股份有限公司 | Synergic agricultural pesticide composition |
| CN101856033A (en) * | 2010-06-29 | 2010-10-13 | 江苏克胜集团股份有限公司 | Novel nicotine pesticide combination containing 1-[(6-Chloropyridin-3-yl)methyl]-7- methyl-8-nitro-5-propoxy-1,2,3,5,6,7-hexahydroimidazo [1,2-Alpha] pyridine |
-
2013
- 2013-11-21 CN CN201310586878.3A patent/CN103636659A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1631887A (en) * | 2004-11-23 | 2005-06-29 | 华东理工大学 | Nitryl methylene derivatives and uses thereof |
| CN101069509A (en) * | 2007-06-21 | 2007-11-14 | 江苏克胜集团股份有限公司 | IPP suspension preparation and preparing method |
| CN101658178A (en) * | 2009-07-22 | 2010-03-03 | 深圳诺普信农化股份有限公司 | Synergistic insecticidal composition |
| CN101669492A (en) * | 2009-10-16 | 2010-03-17 | 深圳诺普信农化股份有限公司 | Synergic agricultural pesticide composition |
| CN101856033A (en) * | 2010-06-29 | 2010-10-13 | 江苏克胜集团股份有限公司 | Novel nicotine pesticide combination containing 1-[(6-Chloropyridin-3-yl)methyl]-7- methyl-8-nitro-5-propoxy-1,2,3,5,6,7-hexahydroimidazo [1,2-Alpha] pyridine |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104365650A (en) * | 2014-10-27 | 2015-02-25 | 池州弘利农业科技开发有限公司 | Synergistic insecticidal composition containing chloropyridine and dinotefuran |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102487952B (en) | Insecticidal composition containing cycloxaprid and biological insecticide | |
| CN101554170A (en) | Chlorantraniliprole and emamectin benzoate insecticidal composition | |
| CN101880205B (en) | Paichongding water dispersible granule and preparation method thereof | |
| CN103271073B (en) | Insecticidal composition containing epoxy worm moiety and buprofezin | |
| CN104186516A (en) | Pyribenzoxim-containing paddy field herbicide composition | |
| CN107306976A (en) | A kind of Pesticidal combination containing matrine and bromine worm fluorobenzene bisamide and its application | |
| CN102362601A (en) | Insecticidal composition containing spinetoram and lythidathion | |
| CN101856033B (en) | Pesticide combination containing IPP and neonicotinoids | |
| Tuelher et al. | Toxicity of organic-coffee-approved products to the southern red mite Oligonychus ilicis and to its predator Iphiseiodes zuluagai | |
| CN101861875B (en) | Synergistic pesticide compound containing mepiquat chloride and organophosphorus pesticide | |
| CN111616154A (en) | Pesticide composition containing difenoconazole and matrine | |
| CN103168787A (en) | Insecticidal composition containing lufenuron and cyantraniliprole | |
| CN103598189A (en) | Pesticide composition containing 1-((6-chloro-3-pyridinyl)methyl)-1,2,3,5,6,7-hexahydro-7-methyl-8-nitro-5-propoxyimidazo(1,2-a)pyridine and pymetrozine | |
| CN103518731B (en) | Herbicide composition containing pyrasulfotole and clodinafop acid | |
| CN102217623B (en) | Pesticide composition containing chlorbenzuron and flubendiamide | |
| CN104542611A (en) | Bactericidal composition containing mandipropamid | |
| CN103636659A (en) | Pesticide composition containing 1-(6-chloro-3-methylpyridyl)-8-nitro-7-methyl-1,2,3,4,5,6,7-hexahydroimidazo[1,2-a]pyridine and dinotefuran | |
| CN101861869A (en) | Pesticide compound containing mepiquat chloride | |
| CN101692833B (en) | Pesticide composition of cidial and pymetrozine | |
| CN104222125B (en) | A kind of containing lufenuron with the composition pesticide of fluazinam | |
| CN103262848A (en) | Insecticidal composition containing cycloxaprid and biological insecticide | |
| CN103300047B (en) | Insecticidal composition containing cycolxylidin and tolfenpyrad | |
| CN106508944A (en) | Pesticidal composition containing 2-methylsulfonyl-5-(2,4-dichlorophenyl)-1,3,4-oxadiazole and prochloraz | |
| CN102440260A (en) | Insecticidal composition comprising sulfoxaflor and cyhalothrin | |
| CN102239875A (en) | Insecticidal composition containing 1-(3-fluoro-4-chlorphenyl)-2-methylthioethanone-O-(2-hydroxymethyl-3-methyl)aether and partial nicotine compounds |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20140319 |