CN105766923B - A kind of desinsection, acaricidal composition - Google Patents
A kind of desinsection, acaricidal composition Download PDFInfo
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- CN105766923B CN105766923B CN201410820164.9A CN201410820164A CN105766923B CN 105766923 B CN105766923 B CN 105766923B CN 201410820164 A CN201410820164 A CN 201410820164A CN 105766923 B CN105766923 B CN 105766923B
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Abstract
The invention belongs to field of pesticides, it is related to a kind of desinsection, acaricidal composition.Composition is two kinds of component A, component B active components, and the weight fraction ratio between two component of component A and component B is 1:100-100:1；The active component A structure is as follows, and composition of the invention has many advantages, such as that synergy is obvious, delaying drug resistance, can be used for preventing and treating various pests.
Description
Technical field
The invention belongs to field of pesticides, it is related to a kind of desinsection, acaricidal composition.
Background technique
Insecticide has apparent effect in terms of prevention and treatment agriculture and forestry injurious insect or urban health insect.
Chinese invention patent CN101875633 discloses a kind of pyrazolyl acrylonitrile compound and its control insect pest and mite
Harmful purposes, wherein compound 5 (hereinafter referred to as compound A) can be used for preventing and treating various pests, harmful mite, especially have to harmful mite prominent
Control efficiency out.
Insecticide containing single active ingredient, is used continuously in control of insect, is easy that pest is made to develop drug resistance.It is logical
The insecticide for crossing two kinds of active components is compounded into mixed component by a certain percentage, and preventive effect often can be improved, and expands prevention spectrum, subtracts
The dosage of few effective component, save the cost.
Although disclosing compound A in the prior art and other Mixture Use of Insecticides can produce additional advantage and effect,
But specific disclosure is had no containing compound A and the technical solution of new type disinsection, the binary insecticide composition of mite agent.
Summary of the invention
It is an object of that present invention to provide a kind of desinsections, acaricidal composition.
To achieve the above object, the technical solution adopted by the present invention are as follows:
A kind of desinsection, acaricidal composition, composition are two kinds of component A, component B active components, two component of component A and component B
Between weight fraction ratio be 1:100-100:1；Component A is selected from following structural formula compound represented A, and component B is selected from fluorine pyridine
Worm amine nitrile (Sulfoxaflor), Pyrifluquinazon, Cyclaniliprole, Flupyradifurone,
Pyflubumide、Heptafluthrin、Momfluorothrin、Flometoquin、Afidopyropen、
Triflumezopyrim, Fluhexafon, Tetraniliprole, Fluensulfone, Imicyafos or Tioxazafen；
The component A structure is as follows:
The desinsection, acaricidal composition are preferably that component A is compound A, and component B is Tioxazafen；Two kinds of active components
Weight fraction ratio be 1:100-100:1；
The desinsection, acaricidal composition be preferably component A be compound A, component B be Pyrifluquinazon,
Sulfoxaflor、Afidopyropen、Flupyradifurone、Heptafluthrin、Cyclaniliprole、
Momfluorothrin or Pyflubumide；The weight fraction ratio of two kinds of active components is 1:20-20:1；
The desinsection, acaricidal composition are preferably that component A is compound A, and component B is Flometoquin；Two kinds of active components
Weight fraction ratio be 1:20-2:1.
Composition of the invention can be provided in finished product preparation form.Therefore, the invention also includes a kind of dosage forms
Desinsection, mite preparation compositions.Using composition as active component, missible oil, suspending agent, water-dispersible granules, water are made as needed
Emulsion, soluble liquid, wettable powder, oil-suspending agent etc..The cumulative amount of the active component of composition exists in preparation
Between 0.5%~95%, preferably cumulative amount is between 1%-85%.The content of active component depends in composition of the invention
Amount of application when being used alone, also depends on mixed ratio and synergistic effect degree.The optimum range of active component content according to
The preparation type of composition and it is different.
The preparation of composition finished product preparation of the invention can be prepared by common processing method, i.e., by active material and liquid
After carrier (solvent) or solid carrier mixing, one or more of surfactants such as emulsifier is added, dispersing agent, wetting agent, glues
Mixture, stabilizer and defoaming agent etc..Contain at least one carrier and at least one surfactant in usual composition.Various
In the case of, it should be ensured that present composition active component is uniformly distributed.
Missible oil usually contains 10~50% active component, and 2~20% emulsifiers, 0~20% other additives are for example
Stabilizer, bleeding agent etc. and solvent (also containing cosolvent when necessary).
Suspending agent usually needs to be sanded, to obtain stable non-deposited flowable product.Usually contain 5 in suspending agent~
75% active component, 5~15% dispersing agents, 4~10% antifreezing agents, 0~10% other additives for example defoaming agent, preservative,
Stabilizer, bleeding agent and thickener and liquid-carrier surplus.
Water-dispersible granules are usually made 10~100 international standard sieve mesh (1.676~0.152mm) particle, can pass through
It squeezes, prepared by dipping or Spray granulation method.Usual water-dispersible granules contain 0.5~75% active component and 5~20%
Surfactant such as stabilizer, wetting dispersing agent, disintegrating agent and adhesive and inert carrier surplus.
Wettable powder usually contains 10~85% active component, other than solid inert carrier, usually contain 3~
10% dispersing agent, can also containing 0~10% stabilizer and (or) other additives, such as bleeding agent or sticker.
Aqueous emulsion is to mix raw medicine, organic solvent, surfactant to form oily phase；Water, antifreezing agent are mixed,
At homogeneous aqueous phase.Oily phase, usual effective component is added in water phase with high-shear emulsion machine high speed shear oil phase, while slowly
1~60%, surfactant 5~20%, antifreezing agent 2~10%, water surplus.
Microemulsion is to mix raw medicine, organic solvent, surfactant, water, at homogeneous aqueous phase.Usually have
Imitate ingredient 1~50%, surfactant 10~40%, antifreezing agent 2~10%, water surplus.
Soluble liquid is to mix active component, organic solvent, surfactant, at transparent and homogeneous liquid.
Usual effective component 1~50%, surfactant 6~20%, organic solvent surplus.
Water dispersible oil suspending agent is that active component, surfactant, oil based vehicle are added in sand mill and are sanded, until grain
Diameter is qualified, usual effective component 2~60%, surfactant 6~20%, oil based vehicle surplus.
Aqueous dispersion liquid and emulsion are (as being diluted with water missible oil of the invention, wettable powder or concentrate obtain
Composition) it is also within the scope of the invention.Above-mentioned emulsion can be water-in-oil type or oil-in-water type, can have thick
Paste-like consistency.
The preparation of composition finished product preparation of the invention can (liquid be solid using well known to those skilled in the art
Body) carrier and various auxiliary agents.For example including but be not limited to following each substances.
Suitable liquid-carrier or solvent can be water, various aromatic hydrocarbons, aliphatic hydrocarbon, ketone, ethers etc., such as toluene, diformazan
Benzene, acetone, cyclohexanone, acetonitrile, benzene, hexamethylene, isopropanol, ethylene glycol, sorbierite, methanol, ethyl alcohol, butanol, dimethyl formyl
Amine, dimethyl sulfoxide, N- methyl-pyrrolidon, tributyl phosphate, methyl iso-butyl ketone (MIBK), naphthalane, machine oil, petroleum ether, oleic acid first
One or more of ester, methylated soya oil or the molten fiber of methyl etc..The mixture of different liquids is often applicable.
Suitable solid carrier includes natural or synthesis clay and silicate, and the solid carrier suitable for pulvis includes
The White Carbon black that naturally occurs, rock dust, chalk, quartz, clay, montmorillonite, sodium sulphate, white carbon black, silica, diatom
Soil, float stone, gypsum, talcum, bentonite, kaolin, attapulgite, precipitated calcium carbonate, clay and the minerals of synthesis ground
(such as microdispersed silicic acid or aluminium oxide).Suitable particulate vector include broken and classification natural rock such as calcite,
Marble, float stone, sepiolite and dolomite and the synthesis particle made of the powder of organic matter and inorganic matter.
Suitable co-solvents are methanol, phenol, isoamyl alcohol, dimethyl sulfoxide, tributyl phosphate, ethyl acetate, butanone, diformazan
One in base formamide, dimethyl sulfoxide, N- methyl-pyrrolidon, methyl oleate, methyl iso-butyl ketone (MIBK), the molten fiber of methyl etc.
Kind is several.
Suitable emulsifier can be ethoxylated castor oil, polyoxyethylene (n20) phenethyl phenolic group oleic acid ester, alkyl virtue
Base polyoxyethylene poly-oxygen propylene aether, alkylaryl formaldehyde resin polyoxyethylene ether, triphenyl vinyl phenol polyoxyethylene (n20) ether phosphorus
It is acidified triethanolamine salt, castor oil polyoxyethylene ether, alkyl vinyl aryl phenyl ether (YUS-SC3), diphenyl phenolic group polyoxy second
Alkene (n18) ether formaldehyde condensation products, the different thionic acid calcium of oleic acid, agriculture breast AEO-3, agriculture breast 0201B, agriculture breast 0203B, agriculture breast T-20, agriculture breast
T-85, agriculture breast S-80, agriculture breast 507#, agriculture breast 100#, agriculture breast 36#, agriculture breast 500#, agriculture breast 600#, Nongru-700 #, agriculture breast 1601#,
Agriculture breast OX-2681, agriculture breast OX-8686, agriculture breast 2201#, agriculture breast NP-7, agriculture breast OX-635, agriculture breast OX-653, agriculture breast YUS-
D935, agriculture breast YUS-CP120, agriculture breast YUS-A41B, agriculture breast YUS-D3020, agriculture breast NP-10, agriculture breast NP-15 etc..
Suitable dispersing agent can for sodium lignin sulfonate, calcium lignosulfonate, alkyl naphthalene sulfonic acid condensation polymer sodium salt, poly-
Carboxylate dispersants GY-D800, polycarboxylate salt dispersant GY-D04, polycarboxylate salt dispersant GY-D02, naphthalene sulfonate formaldehyde contracting
Close object, naphtholsulfonic acid formaldehyde condensation products sodium salt, condensation compound of methyl naphthalene sulfonic acid and formaldehyde, alkyl-diethylene glycol ether-sodium sulfonate, N- first
Base-oleoyl-sodium taurocholate, methanonaphthalene sodium sulfonate, oleic acid methylaminoethyl sodium sulfonate, epoxidized polyether, divides detergent LS
Powder SP-28F, dispersing agent SP-SC3, profit dispersing agent D909S, alkyl aryl polyoxyethylene ether, dodecyl polyoxyethylene are reached
Ether phosphate, polyaryl phenol polyethenoxy ether, to tertbutyl ether, piperonyl butoxide, alkamide taurine salt, alkyl naphthalene sulfonic acid
Salt formaldehyde condensation products (NNO), ethylene oxide-propylene oxide block copolymer APES formaldehyde condensation product, N- first
Base-fatty acyl group-sodium taurocholate, APES formaldehyde condensation product, pull open powder, dibutyl naphthalenesulfonic acid formaldehyde condensation
Object, alkylphenol polyoxyethylene ether formaldehyde condensate sulfate, alkylphenol-polyethenoxy based phosphates, dispersing agent YUS-
NV1203, dispersing agent YUS-NV1420, dispersing agent YUS-WG4, dispersing agent YUS-TG285, dispersing agent YUS-WP1, dispersing agent
YUS-110, dispersing agent YUS-EP60P, dispersing agent YUS-CH1100, etc..
Suitable wetting agent can be sodium sulphate, Morwet EFW, wetting agent SP-SC3266, wetting agent YUS-LXC, profit
Humectant YUS-204, isopropyl naphthalene sulfonate, alkylol polyoxyethylene base ether sodium sulfate, the contracting of alkylphenol-polyethenoxy base ether formaldehyde
Close object sulfate, sldium lauryl sulfate, neopelex, lauryl sodium sulfate, calcium dodecyl benzene sulfonate, alkyl
Sodium naphthalene sulfonate fatty alcohol polyoxyethylene ether, alkylphenol-polyethenoxy base ether etc..
Suitable thickener can be (such as carbonyl methylol alcohol, polyvinyl alcohol, the polyvinyl acetate) or natural water of synthesis
Soluble polymer (such as xanthan gum, gelatin, gum arabic, polyvinylpyrrolidone, aluminium-magnesium silicate, polyvinyl alcohol, poly- second two
Alcohol, phenolic resin, shellac, methylcellulose, soluble starch, carboxymethyl cellulose and sodium alginate etc.), with powder, particle
Or latex form is added in preparation.
Suitable defoaming agent is GPE, silicone, the fatty alcohol of C8~10, phosphoric acid ester, the saturated fat acids of C10~20
(such as capric acid) and amide.
Suitable adhesive can be polyvinyl alcohol, polyvinyl acetate, xanthan gum, gelatin, carboxymethyl cellulose and sea
Mosanom etc..
Desinsection of the present invention, acaricidal composition for aerosol can be made when preventing and treating city pest need that throwing is added wherein
Agent is penetrated, bait formulation composition can also be made, in addition to containing active component, also contains one or more foods suitable for insect's food-taking
Material, optional attractant and optional wetting agent.
The invention also includes the present compositions to be prepared into desinsection, mite preparation control agriculture and forestry injurious insect or urban health insect
Purposes.It is particularly adapted to prevent and treat a variety of important agricultural insect pests.
It prevents and treats in one embodiment, pest of the combination for anti-Orthoptera of curing the disease.Specific kind of nonexhaustive is lifted
Example includes but is not limited to Asiatic migrotory locust, reading room management, Ban Tui locust section, Chinese rice grasshopper, Patanga japonica (l.Bol.), single thorn mole cricket, east mole cricket
Mqb, Gryllotalpa unispina, African mole cricket, Taiwan mole cricket；
It prevents and treats in another embodiment, pest of the combination for anti-Thysanoptera of curing the disease.Specific kind of nonexhaustive
Citing includes but is not limited to rice thrips, onion thrips, greenhouse thrips, haplothrips aculeatus, Testa Tritici thrips, end Taeniothrips spp, onion thrips, flower
Thrips, golden thistle horse, Sugarcane Thrips, yellow thrips；
It prevents and treats in another embodiment, pest of the combination for anti-Homoptera of curing the disease.Specific kind of nonexhaustive
Citing include but is not limited to Trialeurodes vaporariorum Westwood, rice green leafhopper, Erythroneura subrufa, green leaf hopper, chlorita biguttula, Siberian elm leaf cicada, smaller green leaf hopper,
India chlorita biguttula, spot clothing plant hopper, brown paddy plant hopper, white backed planthopper, small brown rice planthopper, pear sucker, diaphorina citri, Aleurocanthus spiniferus, the flat angle of sugarcane
Plant hopper, cotten aphid, green bugs, grain aphid, soybean aphid, Aphis medicaginis, black peach aphid, kaoliang aphid, radish aphid, sugar cane cottony aphid, apple are continuous
Aphid, icerya purchasi, Pseudaulacaspis pentagona, unaspis shield kuwana, san jose scale, wax insect, ceroplastes rubens, Didesmococcus koreanus Borchs, cotton pearl a red-spotted lizard, sugarcane mealybug, length
White a red-spotted lizard, white peach scale, apricot ball heavily fortified point a red-spotted lizard, Ceroplastes japonicus Green, persimmon suede a red-spotted lizard, chaff piece a red-spotted lizard, chaff scale, brown round a red-spotted lizard, heap wax powder a red-spotted lizard；
It prevents and treats in another embodiment, pest of the combination for anti-Semiptera of curing the disease.Specific kind of nonexhaustive
Citing includes but is not limited to pear lace bug, banana lace bug, thin corner piece stinkbug, Orius minutus, slender rice bug, big Leptocorisa spp, paddy fly, rice
Brown stinkbug, scotinophora lurida, green rice bug, green plant bug, alfalfa plant bug, black striped plant bug, wheat root fleahopper, adelphocoris taeniophorus, tarnished plant bug, lichee
Stinkbug；
It prevents and treats in another embodiment, pest of the combination for anti-Lepidoptera of curing the disease.Specific kind of nonexhaustive
Citing include but is not limited to rain moth, casemaking clothes moth, oriental moth, brown slug moth, thosea siensis, gelechiid, pink bollworm, oriental tobacco budworm, brachmia triannuella,
Diamondback moth, eating-core bean worm, small heart-eating peach worm, hemp Grapholita spp, oriental fruit months, pear fruit borer, carpocapsa pononella, apple
Spilonota lechriaspis, apple tabaniformis, macula lutea leaf roller, apple ermine moth, brown belt length leaf roller, intends small yellow leaf curl at applied perfume
The brown leaf roller of moth, stain, the small hairstreak of lichee, striped rice borer, bean-pod borer, corn borer, yellow rice borer, goldrimmed moth, Oeobia undalis, cnaphalocrocis
Snout moth's larva, chilotraea infuscatellus, duckweed ash snout moth's larva, duckweed snout moth's larva, snout moth's larva, Notarchaderogata, Sweet Potato snout moth's larva, some paddy snout moth's larvas, dichocrocis punctiferalis, sunflower moth, yellow snout moth's larva,
Chilo infuscatellus, white snout moth's larva, leukorrhea snout moth's larva, loxostege sticticalis, armyworm, prodenia litura, three-spotted plusia, hole wing noctuid, Chenopodiaceae noctuid, jute noctuid, ramie
Numb noctuid, fruit piercing moth, Chlumetia transversa Walker, lopper worm, beet armyworm, elegant noctuid, loquat yellow caterpillar, the red Jia of ramie
Butterfly, a ramie Huang a kind of butterfly harmful to crop plants, rice green caterpillar, anomis flava, pink rice borer, bollworm, cotton leafroller, soybean leaf roll snout moth's larva, peach pyralid moth, ancient cooking vessel point
Spark, earias fabia, earias insulana, black cutworm, big cutworm, yellow cutworm, white edge cutworm, alert line it is old
Tiger steals poison moth, gypsymoth, palaearctic sweet potato, greenish brown hawk moth, straight grain rice hesperiidae, pelopidas mathias, Papilio xuthus, Common Mormon, vegetable powder
Butterfly, biobelt night butterfly, Rice Leaf night butterfly, amyloid plaque snout moth, Euproctis pseudoconspersa, looper, tea bagworm, big psychid, tea bagworm, Parametrites theae, tea branch
Sickle moth, wild silkworm, euproctis similis, tent caterpillar, Atrijuglans hetaohei, persimmon fruit moth, phyllocnistis citrella stainton, Erionota thorax (Linne)；
It prevents and treats in another embodiment, pest of the combination for anti-coleoptera of curing the disease.Specific kind of nonexhaustive
Citing includes but is not limited to beans blister beetle, Venus ground beetle, wrinkle sheath ground beetle, wheat head ground beetle, pleonomus canaliculatus, Agriotes subrittatus Motschulsky, wide back gold
Needle worm, brown line wireworm, khapra beetle, attagenus piceus, the small buprestid beetle of citrus, flat headed apple borer, golden edge buprestid beetle, citrus blistering
Worm, citrus slip skinworm, potato bug, potato ladybug, Chenopodiaceae ladybug, yellow meal worm, dark mealworm, red flour beetle, miscellaneous quasi- paddy
It is robber, grain peat, saw-toothed grain beetle, Cryptolestes pusillus, black wrinkle gill cockchafer, clouding gill cockchafer, Anomala exoleta, verdigris different beetle, dark
Dark fund tortoise, holotrichia oblita, mulberry borer, longicorn beetle, nadezhdiella cantori, pink neck longicorn, red neck longicorn, sugarcane prionid,
Paralglenes fortunei, hemo longicorn beetle, brown longicorn beetle, the green longicorn of light shield, big daikon leaf beetle, daicon leaf beetle, rice root is chrysomelid, grain fish-scale is chrysomelid, sesame slices
First, pernicious chrysomelid, tangerine leaf mining first, trifoliate orange leaf mining first, aulacophora femoralis, phyllotreta striolata, beet flea beetle, paddy flea beetle, Callosobruchus chinensis, pea
As, broad bean weevil, sitophilus zea-mais, rice weevil, root nodule weevil, the beautiful line weevil of tea, tea seed weevil, beet weevil, Rape stem weevil, pear curculio,
Apricot tiger, peach tiger, black suede scarab beetle, mesh quasi- ground first, Mongolia quasi- ground first, Lissorhoptrus oryzophilus Kuschel, Oulema oryzae, corn dicladispa armigera, sweet potato
Small green nail, prominent back glycosides tortoise, light back glycosides tortoise, yellow leaf worm, banana root weevil, the double black-tape curculionids of banana；
It prevents and treats in another embodiment, pest of the combination for anti-Diptera of curing the disease.Specific kind of nonexhaustive
Citing include but is not limited to wheat midge, contarinia tritici, pachydiplosis oryzae, rice midge, ricestem-fly, hydrellia griseola, rice ephydrid,
Citrus fruit fly, dacus dorsalis, bactrocera tsuneonis, melonfly, wheat leaf ash latent fly, Americal rice leaf miner, Soybean stem borer, straw
It is fly, Hylemyia Platura Meigen, onion fly, radish fly, sorghum shoot fly, millet stem fly, Chinese milk vetch Liriomyza, duckweed midge, kmangold fly, beet root maggot, small
Radish fly；
It prevents and treats in another embodiment, pest of the combination for anti-Acarina of curing the disease.Specific kind of nonexhaustive
Citing includes but is not limited to grain spider mite, penthaleus major duges, cotton Tetranychus cinnabarinus, vegetables tetranychid, tetranychus viennensis, the full pawl of citrus
Mite, phyllocoptruta oleivora, apple tetranychus, Tetranychus urticae, goitre mite, flour mite, privet mite, Bryobia praetiosa, citrus tumor mite.
When for preventing and treating agricultural pest, can be applied to fruit tree for example apple, pears, citrus, peach, hawthorn, apricot, plum, jujube,
Walnut, persimmon, longan, banana, loquat, mango, lichee etc., cereal such as wheat, rice, corn, sorghum, millet etc., cotton, oil plant
Crop such as soybean, peanut, sunflower, castor-oil plant, sesame etc., sugar crop such as beet, sugarcane etc., crudefiber crop such as jute, ramie
Deng, green manure crop such as clover, duckweed, Chinese milk vetch etc., vegetables for example wild cabbage, cauliflower, Chinese cabbage, cucumber, potato, rape, eggplant,
Kidney bean, semen viciae fabae, mung bean, watermelon, sweet potato, tomato, capsicum, green onion, leek, garlic, ginger and flowers, tea, tobacco, mulberry tree etc..
When for preventing and treating city pest, family, public place, office space, factory, gardens, golf can be applied to
Court, and trees, the dykes and dams etc. of termite damage occur.
The invention also includes a kind of methods for controlling insect pest, the present composition can be imposed on effective dose and need to control
Pest or its growth medium on.The more suitable effective dose generally selected is 10 grams to 500 grams of per hectare, preferably effectively
Dosage is 15 grams to 100 grams of per hectare.
The present invention has the advantage that
1. composition of the invention shows apparent synergistic effect within a certain ratio range, the compound pair is improved
The control efficiency of pest.Specially compound A and Pyrifluquinazon, Heptafluthrin, Flupyradifurone,
Afidopyropen, Sulfoxaflor, Pyflubumide, Cyclaniliprole, Momfluorothrin are in 1:20-20:1
In range, compound A and Flometoquin are within the scope of 20:1-1:2, and compound A and Tioxazafen are in 1:100-100:1
Certain synergistic effect is shown to Tetranychus cinnabarinus in range.
2. the present composition reduces the dosage of compound in the application, to reduce use cost, environment is reduced
Pollution.
3. the problem of mechanism of action of each effective component is different in the present composition, and cross resistance is not present, anti-with it
The generation of pest resistance to insecticide can be delayed by controlling pest, and improve the control efficiency of antagonism population, to meet agricultural and city
The demand that health field pest control aspect increasingly improves insecticide effect and kind is constantly updated.
Specific embodiment
Following specific embodiments are for present invention be described in more detail, but the present invention is by no means limited to these examples.It is real
Each component percentage composition or proportion in example is applied to be by weight.Active component in each formula is calculated with effective content, while group
Close the available usual manner preparation of each substance in object.
Formulation Example
The preparation of embodiment 1,21%Momfluorothrin compound A missible oil
By recipe requirements, it is separately added into 1 part of Momfluorothrin, 20 parts of compound A, 8 parts of agriculture breast OX-2681,1 part of agriculture
Newborn 1601#, 5 parts of agriculture breast 600#, 10 parts of dimethylformamides, 5 parts of methanol, dimethylbenzene complement in 100% addition mixing kettle, stir
It mixes uniformly mixed, is dissolved by heating when necessary with hot bath, 21%Momfluorothrin compound A missible oil can be obtained.
Can also by B described in Momfluorothrin alternative costs specification be selected from Sulfoxaflor,
Pyrifluquinazon、Cyclaniliprole、Flupyradifurone、Pyflubumide、Heptafluthrin、
Flometoquin、Afidopyropen、Triflumezopyrim、Fluhexafon、Tetraniliprole、
One of Fluensulfone, Imicyafos, Tioxazafen form 21% new active component B compound A missible oil.
The preparation of embodiment 2,42%Sulfoxaflor compound A wettable powder
By recipe requirements, by 40 parts of Sulfoxaflor, 2 parts of compound A, 2 parts of lauryl sodium sulfate, 3 parts of methanonaphthalenes
Sodium sulfonate, 4 parts of naphtholsulfonic acid formaldehyde condensation products sodium salts, 4 parts of condensation compound of methyl naphthalene sulfonic acid and formaldehyde, 5 parts of White Carbon blacks, precipitated calcium carbonates
It complements to 100% to be sufficiently mixed, arrives 42%Sulfoxaflor compound A wettable powder after ultra-fine pulverizer disintegrating
Agent.
Can also by B described in Sulfoxaflor alternative costs specification be selected from Pyrifluquinazon,
Cyclaniliprole、Flupyradifurone、Pyflubumide、Heptafluthrin、Momfluorothrin、
Flometoquin、Afidopyropen、Triflumezopyrim、Fluhexafon、Tetraniliprole、
It is wettable to form 42% new active component B compound A by one of Fluensulfone, Imicyafos, Tioxazafen
Property pulvis.
The preparation of embodiment 3,40%Afidopyropen compound A wettable powder
By recipe requirements, 20 parts of Afidopyropen, 20 parts of compound A, 2 parts of neopelexes, 2 parts are pulled open
Powder, 4 parts of dibutyl naphthalenesulfonic acid formaldehyde condensation producs, 4 parts of sodium lignin sulfonates, 5 parts of White Carbon blacks, diatomite complement to 100% sufficiently
Mixing, after ultra-fine pulverizer disintegrating, can be obtained 40%Afidopyropen compound A wettable powder.
Can also by B described in Afidopyropen alternative costs specification be selected from Sulfoxaflor,
Pyrifluquinazon、Cyclaniliprole、Flupyradifurone、Pyflubumide、Heptafluthrin、
Momfluorothrin、Flometoquin、Triflumezopyrim、Fluhexafon、Tetraniliprole、
It is wettable to form 40% new active component B compound A by one of Fluensulfone, Imicyafos, Tioxazafen
Property pulvis.
The preparation of embodiment 4,11%Sulfoxaflor compound A aqueous emulsion
By recipe requirements, by 10 parts of Sulfoxaflor, 1 part of compound A, 5 parts of triphenyl vinyl phenol polyoxyethylene (n20) ether
Phosphorylation triethanolamine salt, 6 parts of agriculture breast OX-2681,2 parts of agriculture breast 1601#, 8 parts of dimethylformamides, 15 parts of dimethylbenzene are added mixed
It closes in kettle, is stirred, makes to be dissolved into homogeneous oil phase, under high velocity agitation, excess water (complementing to 100%) is added to oil
The 11%Sulfoxaflor compound A aqueous emulsion of favorable dispersibility can be obtained in phase.
Can also by B described in Sulfoxaflor alternative costs specification be selected from Pyrifluquinazon,
Cyclaniliprole、Flupyradifurone、Pyflubumide、Heptafluthrin、Momfluorothrin、
Flometoquin、Afidopyropen、Triflumezopyrim、Fluhexafon、Tetraniliprole、
One of Fluensulfone, Imicyafos, Tioxazafen form 11% new active component B compound A missible oil.
The preparation of embodiment 5,20%Heptafluthrin compound A aqueous emulsion
By recipe requirements, by 10 parts of Heptafluthrin, 10 parts of compound A, 6 parts of agriculture breast 2201#, 4 parts of agriculture breast OX-
8686,2 parts of agriculture breast 1601#, 1 part of Nongru-700 #, 8 parts of N- methyl-pyrrolidons, 3 parts of tributyl phosphates, 8 parts of dimethylbenzene are added
It in mixing kettle, is stirred, makes to be dissolved into homogeneous oil phase, under high velocity agitation, excess water (complementing to 100%) is added to oil
The 20%Heptafluthrin compound A aqueous emulsion of favorable dispersibility can be obtained in phase.
Can also by B described in Heptafluthrin alternative costs specification be selected from Sulfoxaflor,
Pyrifluquinazon、Cyclaniliprole、Flupyradifurone、Pyflubumide、Momfluorothrin、
Flometoquin、Afidopyropen、Triflumezopyrim、Fluhexafon、Tetraniliprole、
One of Fluensulfone, Imicyafos, Tioxazafen form 20% new active component B compound A water and milk
Agent.
Embodiment 6,60%Heptafluthrin compound A water-dispersible granules
By recipe requirements, by 30 parts of Heptafluthrin, 30 parts of compound A, 7 parts of dispersing agent YUS-WG4,4 parts of alkylnaphthalenes
The sodium salt of sulfonic acid condensation polymer, 1.5 parts of lauryl sodium sulfate, 8 parts of sodium sulphate, 6 parts of soluble starches, bentonites complement to
100% is added together, and carries out co-grinding, then after adding water to mediate, is added in the pelletizer equipped with certain specification sieve and carries out
It is granulated.Then 60%Heptafluthrin compound A water dispersible can be obtained through drying, screening (pressing screen cloth scope) again
Granula.
Can also by B described in Heptafluthrin alternative costs specification be selected from Sulfoxaflor,
Pyrifluquinazon、Cyclaniliprole、Flupyradifurone、Pyflubumide、Momfluorothrin、
Flometoquin、Afidopyropen、Triflumezopyrim、Fluhexafon、Tetraniliprole、
One of Fluensulfone, Imicyafos, Tioxazafen form 60% new active component B compound A moisture
Dissipate property granula.
Embodiment 7,44%Sulfoxaflor compound A water-dispersible granules
By recipe requirements, by 4 parts of Sulfoxaflor, 40 parts of compound A, 5 parts of polycarboxylate salt dispersant GY-D800,5 parts
Sodium lignin sulfonate, 3 parts of dibutyl naphthalenesulfonic acid formaldehyde condensation producs, 3 parts of sodium carboxymethylcelluloses, attapulgites complement to 100%
It is added together, carries out co-grinding, then after adding water to mediate, be added in the pelletizer equipped with certain specification sieve and be granulated.
Then 44%Sulfoxaflor compound A water-dispersible granules can be obtained through drying, screening (pressing screen cloth scope) again.
Can also by B described in Sulfoxaflor alternative costs specification be selected from Pyrifluquinazon,
Cyclaniliprole、Flupyradifurone、Pyflubumide、Heptafluthrin、Momfluorothrin、
Flometoquin、Afidopyropen、Triflumezopyrim、Fluhexafon、Tetraniliprole、
One of Fluensulfone, Imicyafos, Tioxazafen form 44% new active component B compound A moisture
Dissipate property granula.
Embodiment 8,21%Sulfoxaflor compound A suspending agent
By recipe requirements, by 1 part of Sulfoxaflor, 20 parts of compound A, 4 parts of dispersing agent SP-28F, 2 parts of alkylnaphthalene sulphurs
Hydrochlorate formaldehyde condensation products, 0.1 part of xanthan gum, 0.3 part of white carbon black, 5 parts of ethylene glycol, are complemented to water 2 parts of agriculture breast 0201B
100%, be added sequentially to mix in blending tank, first pass through high shear carry out coarse crushing, homogenize, be then pumped into sand mill into
Row fine grinding detects the granularity that material is sanded with particles distribution instrument, and after partial size reaches standard requirements, filtering can be obtained 21%
Sulfoxaflor compound A suspending agent.
Can also by B described in Sulfoxaflor alternative costs specification be selected from Pyrifluquinazon,
Cyclaniliprole、Flupyradifurone、Pyflubumide、Heptafluthrin、Momfluorothrin、
Flometoquin、Afidopyropen、Triflumezopyrim、Fluhexafon、Tetraniliprole、
One of Fluensulfone, Imicyafos, Tioxazafen form 21% new active component B compound A and suspend
Agent.
Embodiment 9,30%Afidopyropen compound A suspending agent
By recipe requirements, by 15 parts of Afidopyropen, 15 parts of compound A, 4 parts of dispersing agent SP-SC3,1 part of Morwet
EFW, the sodium salt of 4 parts of alkyl naphthalene sulfonic acid condensation polymers, 1 part of agriculture breast 1601#, 0.1 part of xanthan gum, 0.2 part of white carbon black, 5 parts of ethylene glycol,
100% is complemented to water, is added sequentially to mix in blending tank, high shear is first passed through and carries out coarse crushing, homogenizes, be then pumped into
Fine grinding is carried out in sand mill, and the granularity that material is sanded is detected with particles distribution instrument, after partial size reaches standard requirements, filtering, i.e.,
30%Afidopyropen compound A suspending agent can be obtained.
Can also by B described in Afidopyropen alternative costs specification be selected from Sulfoxaflor,
Pyrifluquinazon、Cyclaniliprole、Flupyradifurone、Pyflubumide、Heptafluthrin、
Momfluorothrin、Flometoquin、Triflumezopyrim、Fluhexafon、Tetraniliprole、
One of Fluensulfone, Imicyafos, Tioxazafen form 30% new active component B compound A and suspend
Agent.
Embodiment 10,21%Flupyradifurone compound A microemulsion
By recipe requirements, by 1 part of Flupyradifurone, 20 parts of compound A, 4 parts of alkyl vinyl aryl phenyl ethers, 2 parts
Agriculture breast 100#, 6 parts of diphenyl phenolic group polyoxyethylene (n18) ether formaldehyde condensation products, 6 parts of agriculture breast OX-2681,10 parts of N- methyl-pyrrols
Alkanone, 5 parts of tributyl phosphates are added together, and make it dissolve into homogeneous oil phase, surplus complements to 100% with water, in high-speed stirred
Under, water phase is added to oily phase or oil is added to water phase, forms the 21%Flupyradifuroneization of favorable dispersibility
Close object A microemulsion.
Can also by B described in Flupyradifurone alternative costs specification be selected from Sulfoxaflor,
Pyrifluquinazon、Cyclaniliprole、Pyflubumide、Heptafluthrin、Momfluorothrin、
Flometoquin、Afidopyropen、Triflumezopyrim、Fluhexafon、Tetraniliprole、
One of Fluensulfone, Imicyafos, Tioxazafen form 21% new active component B compound A micro emulsion
Agent.
Embodiment 11,21%Sulfoxaflor compound A soluble concentrate
By recipe requirements, by 1 part of Sulfoxaflor, 20 parts of compound A, 5 parts of agriculture breast 0201B, 6 parts of agriculture breast OX-2681,2
Part agriculture breast 1601#, 3 parts of agriculture breast 500#, 4 parts of tributyl phosphates, 6 parts of methyl iso-butyl ketone (MIBK)s, 10 parts of acetonitriles, the molten fiber of methyl are supplied
It is uniformly mixed, is dissolved by heating when necessary with hot bath, 21%Sulfoxaflor compound A can be made can solution to 100%
Agent.
Can also by Pyrifluquinazon described in Sulfoxaflor alternative costs specification,
Cyclaniliprole、Flupyradifurone、Pyflubumide、Heptafluthrin、Momfluorothrin、
Flometoquin、Afidopyropen、Triflumezopyrim、Fluhexafon、Tetraniliprole、
It is solvable to form 21% new active component B compound A by one of Fluensulfone, Imicyafos, Tioxazafen
Liquor.
Embodiment 12,21%Afidopyropen compound A water dispersible oil suspending agent
By recipe requirements, by 1 part of Afidopyropen, 20 parts of compound A, 3 parts of agriculture breast S-80,5 parts of agriculture breast 0201B, 4 parts
Agriculture breast 500#, 3 parts of agriculture breast 1601#, 3 parts of white carbon blacks, 15 parts of methyl oleates, methylated soya oil complement to 100% and sequentially add
It is mixed into blending tank, first passes through high shear and carry out coarse crushing, homogenize, be then pumped into sand mill and carry out fine grinding, use granularity
The granularity of material is sanded in distribution instrument detection, and after partial size reaches standard requirements, 21%Afidopyropen is can be obtained in filtering
Compound A water dispersible oil suspending agent.
Can also by Sulfoxaflor described in Afidopyropen alternative costs specification,
Pyrifluquinazon、Cyclaniliprole、Flupyradifurone、Pyflubumide、Heptafluthrin、
Momfluorothrin、Flometoquin、Triflumezopyrim、Fluhexafon、Tetraniliprole、
One of Fluensulfone, Imicyafos, Tioxazafen form 21% new active component B compound A moisture
Dissipate property oil suspending agent.
Indoor biological activity assay
Synergism determination of composition of the embodiment 13 containing compound A to Tetranychus cinnabarinus
For examination object: Tetranychus cinnabarinus (Tetranychus cinnabarinus Boisduval), adult mite, indoor raising
Sensitive strain.
Test condition: temperature: 24~26 DEG C, humidity: RH 60%, illumination: L:D=14:10
Test method: pot-spraying method is used.The sizing potting Kidney bean seedling (2 true leaves) of hot-house culture, stays a piece of true leaf,
It is connected into mite 40-60 head on it.Test material is handled using Airbrush spray-on process medical fluid, is dried in the shade naturally.Blank control is first handled,
Then 4 repetitions of the every processing of aforesaid operations are repeated from low to high according to experimental design dosage.By treated, test worm is placed in
In observation ward, routine observation test worm response situation investigates number of dead and live insects after 72h, calculates the death rate.
Evaluation uses Bliss method, and this method is to evaluate one of the classical way of mixture effect.Bliss is proposed according to it
Independent joint action concept thinks, theoretical death rate P when Mixture Use of Insecticides can be calculated with following formula:
P=Pm+Pn(1-Pm)
PmFor the death rate (%) of the first active component target when concentration is m；PnIt is using concentration for the second active component
The death rate (%) of target when n.
If the actual of two kinds of active component targets after being mixed with a certain concentration is greater than theoretical death rate P,
Determine that two kinds of active components are used in mixed way in the case where setting concentration with synergistic effect, it is on the contrary then be antagonism.It the results are shown in Table 1.
10 kinds of medicaments such as table 1 compound A and Cyclaniliprole are used in mixed way the synergistic effect to Tetranychus cinnabarinus adult mite
Measurement
Claims (6)
1. a kind of desinsection, acaricidal composition, it is characterised in that: composition is component A, two kinds of active components of component B, component A and group
The weight fraction ratio being divided between two component of B is 1:50-50:1；
Active component A is selected from following structural formula compound represented A, and active component B is selected from Pyflubumide；
The active component A structure is as follows:
2. composition described in accordance with the claim 1, it is characterised in that: the composition can be configured to missible oil, suspending agent, water
Dispersive granule, aqueous emulsion, microemulsion, soluble concentrate, wettable powder or water dispersible oil suspending agent.
3. composition according to claim 2, it is characterised in that: the cumulative amount of active component exists in the composition
Between 0.5%-95%.
4. composition described in accordance with the claim 3, it is characterised in that: the cumulative amount of active component exists in the composition
Between 1%-85%.
5. a kind of application of desinsection described in accordance with the claim 1, acaricidal composition, it is characterised in that: the composition is for making
Standby desinsection, mite agent, for controlling agricultural pests or urban health insect.
6. the application of desinsection, acaricidal composition according to claim 5, it is characterised in that: with effective agent meter, will be prepared into
Desinsection, mite agent the composition impose on the medium for needing the pest that controls or its growth.
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| TW202011811A (en) * | 2018-06-08 | 2020-04-01 | 日商日本化藥股份有限公司 | Water-dispersible agrochemical composition |
| CN111789122A (en) * | 2019-04-09 | 2020-10-20 | 浙江省化工研究院有限公司 | Acaricidal composition containing oxapyrile-acarbonitrile and spirocyclic tetronic acid pesticide |
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| CN101367784A (en) * | 2008-09-28 | 2009-02-18 | 江苏省农药研究所股份有限公司 | Vinyl cyanide compounds, preparation and application thereof |
| CN101817784A (en) * | 1996-04-25 | 2010-09-01 | 日产化学工业株式会社 | Ethene derivatives and the pesticides that contains this derivative |
| CN101875633A (en) * | 2009-04-29 | 2010-11-03 | 中国中化股份有限公司 | Pyrazolyl acrylonitrile compound and application thereof |
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| CN101817784A (en) * | 1996-04-25 | 2010-09-01 | 日产化学工业株式会社 | Ethene derivatives and the pesticides that contains this derivative |
| CN101367784A (en) * | 2008-09-28 | 2009-02-18 | 江苏省农药研究所股份有限公司 | Vinyl cyanide compounds, preparation and application thereof |
| CN101875633A (en) * | 2009-04-29 | 2010-11-03 | 中国中化股份有限公司 | Pyrazolyl acrylonitrile compound and application thereof |
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