CN105764936B - 主催化剂颗粒及抗冲共聚物的聚合方法 - Google Patents

主催化剂颗粒及抗冲共聚物的聚合方法 Download PDF

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Publication number
CN105764936B
CN105764936B CN201480064998.XA CN201480064998A CN105764936B CN 105764936 B CN105764936 B CN 105764936B CN 201480064998 A CN201480064998 A CN 201480064998A CN 105764936 B CN105764936 B CN 105764936B
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microns
propylene
particles
substituted
procatalyst
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CN105764936A (zh
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J.W.范埃蒙
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WR Grace and Co Conn
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WR Grace and Co Conn
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/001—Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
    • C08F4/6493—Catalysts containing a specific non-metal or metal-free compound organic containing halogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/651—Pretreating with non-metals or metal-free compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/06—Catalyst characterized by its size

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Graft Or Block Polymers (AREA)
CN201480064998.XA 2013-11-27 2014-11-26 主催化剂颗粒及抗冲共聚物的聚合方法 Active CN105764936B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810337337.XA CN108503734B (zh) 2013-11-27 2014-11-26 主催化剂颗粒及抗冲共聚物的聚合方法

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201361909461P 2013-11-27 2013-11-27
US61/909461 2013-11-27
PCT/US2014/067703 WO2015081254A1 (en) 2013-11-27 2014-11-26 Procatalyst particles and polymerization process for impact copolymers

Related Child Applications (1)

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CN201810337337.XA Division CN108503734B (zh) 2013-11-27 2014-11-26 主催化剂颗粒及抗冲共聚物的聚合方法

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CN105764936A CN105764936A (zh) 2016-07-13
CN105764936B true CN105764936B (zh) 2018-05-11

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US (2) US10059784B2 (https=)
EP (1) EP3074435B1 (https=)
JP (2) JP6573885B2 (https=)
KR (1) KR102205993B1 (https=)
CN (2) CN105764936B (https=)
BR (1) BR112016012033B1 (https=)
ES (1) ES2901954T3 (https=)
PL (1) PL3074435T3 (https=)
RU (1) RU2709203C1 (https=)
SA (1) SA516371206B1 (https=)
WO (1) WO2015081254A1 (https=)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105764936B (zh) * 2013-11-27 2018-05-11 格雷斯公司 主催化剂颗粒及抗冲共聚物的聚合方法
KR102763007B1 (ko) 2016-08-30 2025-02-04 더블유.알. 그레이스 앤드 컴파니 -씨오엔엔. 저회분 함량의 폴리올레핀들 및 그 제조방법
WO2018167305A1 (en) * 2017-03-17 2018-09-20 Sabic Global Technologies B.V. Process for preparing a procatalyst for polymerization of olefins
WO2019094216A1 (en) * 2017-11-13 2019-05-16 W.R. Grace & Co.-Conn. Catalyst components for propylene polymerization
WO2019094347A1 (en) * 2017-11-13 2019-05-16 W.R. Grace & Co.-Conn. Catalyst components for propylene polymerization
KR20230091125A (ko) * 2020-10-23 2023-06-22 더블유.알. 그레이스 앤드 캄파니-콘. Voc 함량이 감소한 충격 저항성 폴리프로필렌 중합체 조성물
EP4359448A1 (en) 2021-06-25 2024-05-01 Braskem, S.A. Propylene preliminary polymerization

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6403518B2 (en) * 1995-06-07 2002-06-11 W. R. Grace & Co.-Conn. Supported catalyst composition derived from halogenated supports and support activators
CN1124294C (zh) * 1998-08-07 2003-10-15 博里利斯技术有限公司 包括镁,钛,卤素和电子给体的催化剂组分,它的制备和应用
CN1512915A (zh) * 2001-05-29 2004-07-14 ����̼����ѧƷ�����ϼ�����˾ 改进的烯烃聚合催化剂组合物及其制备方法
CN1856512A (zh) * 2003-09-23 2006-11-01 陶氏环球技术公司 含有二羧酸酯内部给体的自限制催化剂组合物和丙烯聚合方法
US20120157645A1 (en) * 2010-12-21 2012-06-21 Linfeng Chen Procatalyst Composition with Alkoxypropyl Ester Internal Electron Donor and Polymer From Same
US20130035227A1 (en) * 2008-12-31 2013-02-07 Dow Global Technologies Llc Procatalyst Composition with Substituted 1,2-Phenylene Aromatic Diester Internal Donor and Method
US20130225398A1 (en) * 2010-12-21 2013-08-29 Dow Global Technologies Llc Process for Producing Procatalyst Composition with Alkoxyalkyl Ester Internal Electron Donor and Product

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4882380A (en) 1987-07-07 1989-11-21 Union Carbide Chemicals And Plastics Company Inc. Process for the production of impact polypropylene copolymers
JPH0693061A (ja) * 1992-09-16 1994-04-05 Sumitomo Chem Co Ltd ポリプロピレンブロック共重合体及びそのフィルム
FI981717A7 (fi) * 1998-08-07 2000-02-08 Borealis As Katalysaattorikomponentti, joka käsittää magnesiumia, titaania, halogeenia ja elektronidonorin, sen valmistus ja käyttö
US8788826B1 (en) 2008-06-06 2014-07-22 Marvell International Ltd. Method and apparatus for dynamically allocating a mobile network prefix to a mobile terminal
EP2315790B1 (en) * 2008-08-21 2018-04-25 W.R. Grace & CO. - CONN. High melt flow propylene impact copolymer and method
US8604118B2 (en) * 2008-12-26 2013-12-10 Dow Global Technologies Llc Antifoulant for impact copolymers and method
JP5731988B2 (ja) * 2008-12-31 2015-06-10 ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット プロピレン系ポリマー、物品およびその製造プロセス
JP5448702B2 (ja) * 2009-10-14 2014-03-19 日本ポリプロ株式会社 プロピレン系ブロック共重合体の製造方法
JP2014500384A (ja) * 2010-12-21 2014-01-09 ダウ グローバル テクノロジーズ エルエルシー アルコキシアルキルエステル内部電子供与体を有するプロ触媒組成物の製造方法および製品
MX2013007356A (es) * 2010-12-21 2014-01-23 Dow Global Technologies Llc Proceso para producir polimeros basados en propileno con alto indice de fluidez y productos preparados a partir de los mismos.
US9133286B2 (en) * 2011-08-30 2015-09-15 W. R. Grace & Co.-Conn Production of substituted phenylene dibenzoate internal electron donor and procatalyst with same
CN105764936B (zh) 2013-11-27 2018-05-11 格雷斯公司 主催化剂颗粒及抗冲共聚物的聚合方法

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6403518B2 (en) * 1995-06-07 2002-06-11 W. R. Grace & Co.-Conn. Supported catalyst composition derived from halogenated supports and support activators
CN1124294C (zh) * 1998-08-07 2003-10-15 博里利斯技术有限公司 包括镁,钛,卤素和电子给体的催化剂组分,它的制备和应用
CN1512915A (zh) * 2001-05-29 2004-07-14 ����̼����ѧƷ�����ϼ�����˾ 改进的烯烃聚合催化剂组合物及其制备方法
CN1856512A (zh) * 2003-09-23 2006-11-01 陶氏环球技术公司 含有二羧酸酯内部给体的自限制催化剂组合物和丙烯聚合方法
US20130035227A1 (en) * 2008-12-31 2013-02-07 Dow Global Technologies Llc Procatalyst Composition with Substituted 1,2-Phenylene Aromatic Diester Internal Donor and Method
US20120157645A1 (en) * 2010-12-21 2012-06-21 Linfeng Chen Procatalyst Composition with Alkoxypropyl Ester Internal Electron Donor and Polymer From Same
US20130225398A1 (en) * 2010-12-21 2013-08-29 Dow Global Technologies Llc Process for Producing Procatalyst Composition with Alkoxyalkyl Ester Internal Electron Donor and Product

Also Published As

Publication number Publication date
EP3074435B1 (en) 2021-11-10
JP6573885B2 (ja) 2019-09-11
SA516371206B1 (ar) 2019-07-31
EP3074435A4 (en) 2017-06-28
WO2015081254A1 (en) 2015-06-04
JP6869276B2 (ja) 2021-05-12
US10059784B2 (en) 2018-08-28
JP2019131811A (ja) 2019-08-08
BR112016012033B1 (pt) 2021-02-09
PL3074435T3 (pl) 2022-01-24
RU2016125244A (ru) 2018-01-09
KR20160091952A (ko) 2016-08-03
CN105764936A (zh) 2016-07-13
KR102205993B1 (ko) 2021-01-21
CN108503734A (zh) 2018-09-07
US20180305479A1 (en) 2018-10-25
RU2709203C1 (ru) 2019-12-17
EP3074435A1 (en) 2016-10-05
CN108503734B (zh) 2021-09-03
ES2901954T3 (es) 2022-03-24
JP2016538396A (ja) 2016-12-08
US20160297906A1 (en) 2016-10-13

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