CN105755829A - Hydrophilic softener for towel fabric - Google Patents
Hydrophilic softener for towel fabric Download PDFInfo
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- CN105755829A CN105755829A CN201410815486.4A CN201410815486A CN105755829A CN 105755829 A CN105755829 A CN 105755829A CN 201410815486 A CN201410815486 A CN 201410815486A CN 105755829 A CN105755829 A CN 105755829A
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- softening agent
- towel cloth
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- ammonium salt
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Abstract
The invention relates to a fabric softener, in particular to a hydrophilic softener for towel fabric and belongs to the field of textile softeners.The softener comprises the components according to percent by weight: 10-20% of modified amino siloxane, 5-10% of polyether polyester, 1-8% of quaternary ammonium salt, 5-10% of nonionic emulsifying agent, 0.1-0.5% of an organic acid, and 51.5-78.9% of deionized water.The softener is prepared: according to the above-mentioned ratio, adding the modified amino siloxane and the nonionic emulsifying agent into a variable speed mixer first, mixing well, adding the polyether polyester and the quaternary ammonium salt and stirring, and finally adding citric acid and deionized water according to a ratio for emulsification; stirring well, and packaging.The hydrophilic softener is good in quality stability, can impart fluffy and thick handle to the towel fabric without affecting hydrophilicity and color of the towel fabric and is also functional in inhibiting bacteria and removing odor.
Description
Technical field
The present invention relates to fabric softener, be specifically related to a kind of towel cloth hydrophilic softening agent, belong to yarn fabric softening agent field.
Background technology
Fabric softener develops into today, the history of existing over half a century, towel cloth is applied and also has very long history, the feel and sense of touch of improving towel cloth are played a significant role by it, raising day by day along with expanding economy and living standard, it is excellent that people do not require nothing more than towel cloth feel sense of touch, advocates towel cloth by practicality to functional development, increases some antibacterial and function of odor removal.
Current towel cloth softening agent be generally the fat race amide-type softening agent of hydrophilic fat and a small amount of amino-modified silicone oil with the use of, simply there is the single function improving feel, and quality stability, hydrophilic and feel have much room for improvement.
Summary of the invention
It is an object of the invention to provide a kind of towel cloth hydrophilic softening agent, softening agent provided by the invention overcomes defect that above-mentioned prior art exists and to provide one to have quality stability good, the feel that towel cloth is fluffy, abundant can not only be given, and do not affect hydrophilic and the color and luster of towel cloth, also there is the towel hydrophilic softening agent of the function of antibacterial and taste removal simultaneously.
A kind of towel cloth hydrophilic softening agent, is made up of by mass percentage following components: modified amido siloxanes 10%～20%, polyether polyester 5%～10%, quaternary ammonium salt are 1%～8%, nonionic emulsifier is 5%～10%, organic acid be 0.1～0.5% and deionized water be 51.5%～78.9%.
Preferably, described softening agent component is by mass percentage: modified amido siloxanes 15%, polyether polyester are 10%, quaternary ammonium salt is 5%, nonionic emulsifier is 8%, organic acid be 0.3% and deionized water be 61.7%.
Described modified amido siloxanes is ammonia value is the polyether modified amino siloxanes of 0.16mmol/g, and purchased from Shanghai Fluoropolymer Medical Products Co., Ltd., product grade is SF9288；
Described polyether polyester is water solublity or water-dispersion type polyether polyester, and as Shanghai fluorine dimerization Products Co., Ltd provides, product grade is STM；
Described quaternary ammonium salt is imidazoline quaternary ammonium salt, heptadecyl-beta-aminoethyl imidazoline quaternary ammonium salt；
Described nonionic surfactant is isomeric alcohol polyethenoxy ether (molecular weight is 378～554) or fatty alcohol-polyoxyethylene ether (molecular weight is 362～846)；
Wherein fatty alcohol-polyoxyethylene ether is the fatty alcohol-polyoxyethylene ether of AEO-5:AEO-9=3:7, AEO-5:AEO-15=2:3 or AEO-5:AEO-9=1:1；Wherein isomeric alcohol polyethenoxy ether is the isomeric alcohol polyethenoxy ether of XP50:XP90=4:6.
Described organic acid is one or more in acetic acid, citric acid, hydroxyacetic acid and p-phthalic acid.
The preparation method of a kind of towel cloth hydrophilic softening agent, carries out as steps described below:
According to above-mentioned raw materials proportioning, variable-ratio blender is initially charged modified amido siloxanes and nonionic emulsifier stirs, then add polyether polyester and quaternary ammonium salt stirring, be finally slowly added to citric acid and deionized water, emulsion reaction by proportioning；Stir subpackage.
Beneficial effect
Compared with prior art, the modified amido siloxanes composition in a kind of towel hydrophilic softening agent of the present invention, containing water absorption polyether group, there is good feel and hydrophilic, and fabric color impact is little；Polyether polyester composition in this softening agent, tool excellent hydrophilic and soft feel；Quaternary ammonium salt composition in this softening agent, has good antibacterial taste removal, has fluffy feel simultaneously.One towel hydrophilic softening agent of the present invention is that one realizes the polyfunctional desirable softening agent of towel.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in detail, it should be understood that these embodiments are merely to illustrate the present invention rather than the range of application of the restriction present invention.
Embodiment 1
One towel cloth hydrophilic softening agent of the present invention, component and mass percent are as follows: ammonia value is that the polyether modified amino siloxanes of 0.16mmol/g is (purchased from Shanghai Fluoropolymer Medical Products Co., Ltd., SF9288) 15%, water soluble polyether polyester is (purchased from Shanghai Fluoropolymer Medical Products Co., Ltd., STM) it is 10%, imidazoline quaternary ammonium salt is 5%, nonionic emulsifier fatty alcohol-polyoxyethylene ether (AEO-5:AEO-9=3:7) is (purchased from circle of China chemistry, the trade mark is ABLUNOLAEO-3, ABLUNOLAEO-9) it is 8%, acetic acid be 0.3% and deionized water be 61.7%.Variable-ratio blender is initially charged, by proportioning, polyether modified amino siloxanes that ammonia value is 0.16mmol/g and nonionic emulsifier fatty alcohol-polyoxyethylene ether stirs, then water soluble polyether polyester and imidazoline quaternary ammonium salt stirring is added again by proportioning, acetic acid and deionized water, emulsion reaction finally it is slowly added to by proportioning.Stir subpackage.
Embodiment 2
One towel cloth hydrophilic softening agent of the present invention, component and mass percent are as follows: ammonia value is that the polyether modified amino siloxanes of 0.16mmol/g is (purchased from Shanghai Fluoropolymer Medical Products Co., Ltd., SF9288) 10%, water soluble polyether polyester is (purchased from Shanghai Fluoropolymer Medical Products Co., Ltd., STM) it is 8%, imidazoline quaternary ammonium salt is 1%, nonionic emulsifier isomeric alcohol polyethenoxy ether (XP50:XP90=4:6) (is provided by DOW Chemical, the trade mark is LutensolXP50, LutensolXP90) it is 5%, citric acid be 0.1% and deionized water be 75.9%.Variable-ratio blender is initially charged, by proportioning, polyether modified amino siloxanes that ammonia value is 0.16mmol/g and nonionic emulsifier fatty alcohol-polyoxyethylene ether stirs, then water soluble polyether polyester and imidazoline quaternary ammonium salt stirring is added again by proportioning, citric acid and deionized water, emulsion reaction finally it is slowly added to by proportioning.Stir subpackage.
Embodiment 3
One towel cloth hydrophilic softening agent of the present invention, component and mass percent are as follows: ammonia value is that the polyether modified amino siloxanes of 0.16mmol/g is (purchased from Shanghai Fluoropolymer Medical Products Co., Ltd., SF9288) 20%, water soluble polyether polyester (purchased from Shanghai Fluoropolymer Medical Products Co., Ltd., STM) be 10%, imidazoline quaternary ammonium salt be 8%, nonionic emulsifier fatty alcohol-polyoxyethylene ether (AEO-5:AEO-15=2:3) (purchased from circle of China chemistry) be 10%, hydroxyacetic acid be 0.5% and deionized water be 51.5%.Variable-ratio blender is initially charged, by proportioning, polyether modified amino siloxanes that ammonia value is 0.16mmol/g and nonionic emulsifier fatty alcohol-polyoxyethylene ether stirs, then water-dispersion type polyether polyester and imidazoline quaternary ammonium salt stirring is added again by proportioning, hydroxyacetic acid and deionized water, emulsion reaction finally it is slowly added to by proportioning.Stir subpackage.
Embodiment 4
One towel cloth hydrophilic softening agent of the present invention, component and mass percent are as follows: ammonia value is that the polyether modified amino siloxanes of 0.16mmol/g is (purchased from Shanghai Fluoropolymer Medical Products Co., Ltd., SF9288) 12%, water soluble polyether polyester (purchased from Shanghai Fluoropolymer Medical Products Co., Ltd., STM) be 10%, imidazoline quaternary ammonium salt be 3%, nonionic emulsifier fatty alcohol-polyoxyethylene ether (AEO-5:AEO-9=1:1) (purchased from circle of China chemistry) be 6%, acetic acid be 0.2% and deionized water be 68.8%.Variable-ratio blender is initially charged, by proportioning, polyether modified amino siloxanes that ammonia value is 0.16mmol/g and nonionic emulsifier fatty alcohol-polyoxyethylene ether stirs, then water soluble polyether polyester and imidazoline quaternary ammonium salt stirring is added again by proportioning, acetic acid and deionized water, emulsion reaction finally it is slowly added to by proportioning.Stir subpackage.
Comparative example
Towel softening agent conventional in the market, component and mass percent are as follows: amino modified siloxanes 5%, hydrophilic aliphatic amide-type softening agent are 10%, emulsifying agent 3%, acetic acid be 0.2% and deionized water be 82.8%.
Test example
To above-described embodiment 1～4 and the product consumption made by comparative example be 10g/L for white cotton untwisted yarn towel, after 150 degrees Celsius dry, carry out following performance test:
(1) feel
Feel is evaluated by digital palpation for examination of trauma by 5 seasoned professionals.1 grade shows that feel is worst, and 5 grades show that feel is best.
(2) hydrophilic
Measure according to AATCC79-2000 " water absorption of textile measures ".
(3) whiteness
Adopt SBDY-1 digital display whiteness instrument detection whiteness.Numerical value shows that more greatly whiteness is more good.
(4) biocidal property
Bacteriostasis rate is measured according to GB/T20944-2007 " evaluation of antibacterial textile performance ".
The towel cloth hydrophilic softening agent the performance test results of the present invention is shown in table 1 below
The hydrophilic application performance of towel cloth of table 1 present invention
| Sequence number | Grey cloth | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Comparative example |
| Feel/level | 1 | 4 | 3 | 4 | 3 | 2 |
| Hydrophilic/s | <1 | <1 | 1 | 1 | <1 | 2 |
| Whiteness/% | 85 | 84 | 84.2 | 83.5 | 84 | 82.7 |
| Bacteriostasis rate/% | 0 | 70 | 20 | 80 | 50 | 0 |
As can be seen from the above table, one towel cloth hydrophilic softening agent of the present invention has good feel, simultaneously on the hydrophilic of fabric and whiteness substantially without impact, also has certain anti-microbial property, is a kind of desirably multifunctional towel softening agent.
The quality stability using the towel cloth hydrophilic softening agent prepared in embodiment 1～4 is fabulous, the towel cloth after process, has fluffy, an abundant feel, and the hydrophilic not affected and color and luster, also there is antibacterial and taste removal function simultaneously.
Below the preferred embodiment of the invention has been illustrated, but the invention is not limited to described embodiment, those of ordinary skill in the art are under the premise without prejudice to the invention spirit, also can make all equivalent modification or replacement, these equivalent modification or replacement to be all contained in the application claim limited range.
Claims (9)
1. a towel cloth hydrophilic softening agent, is made up of by mass percentage following components: modified amido siloxanes 10%～20%, polyether polyester 5%～10%, quaternary ammonium salt 1%～8%, nonionic emulsifier 5%～10%, organic acid 0.1～0.5% and deionized water 51.5%～78.9%.
2. a kind of towel cloth hydrophilic softening agent according to claim 1, it is characterized in that, its component is by mass percentage: modified amido siloxanes 15%, polyether polyester 10%, quaternary ammonium salt 5%, nonionic emulsifier 8%, organic acid 0.3% and deionized water 61.7%.
3. a kind of towel cloth hydrophilic softening agent according to claim 1, it is characterised in that described modified amido silane is polyether modified amino siloxanes, and ammonia value is 0.16mmol/g.
4. a kind of towel cloth hydrophilic softening agent according to claim 1, it is characterised in that described polyether polyester is water soluble polyether polyester.
5. a kind of towel cloth hydrophilic softening agent according to claim 1, it is characterised in that described quaternary ammonium salt is imidazoline quaternary ammonium salt.
6. a kind of towel cloth hydrophilic softening agent according to claim 1, it is characterised in that described nonionic emulsifier is isomeric alcohol polyethenoxy ether or fatty alcohol-polyoxyethylene ether.
7. a kind of towel cloth hydrophilic softening agent according to claim 6, it is characterised in that wherein fatty alcohol-polyoxyethylene ether is the fatty alcohol-polyoxyethylene ether of AEO-5:AEO-9=3:7, AEO-5:AEO-15=2:3 or AEO-5:AEO-9=1:1；Wherein isomeric alcohol polyethenoxy ether is the isomeric alcohol polyethenoxy ether of XP50:XP90=4:6.
8. a kind of towel cloth hydrophilic softening agent according to claim 1, it is characterised in that described organic acid includes one or more of acetic acid, citric acid, hydroxyacetic acid and p-phthalic acid.
9. the preparation method of the towel cloth hydrophilic softening agent described in claim 1, carries out as steps described below:
According to above-mentioned raw materials proportioning, variable-ratio blender is initially charged modified amido siloxanes and nonionic emulsifier stirs, then add polyether polyester and quaternary ammonium salt stirring, be finally slowly added to citric acid and deionized water, emulsion reaction by proportioning；Stir subpackage.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410815486.4A CN105755829B (en) | 2014-12-19 | 2014-12-19 | A kind of towel cloth hydrophilic softening agent |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410815486.4A CN105755829B (en) | 2014-12-19 | 2014-12-19 | A kind of towel cloth hydrophilic softening agent |
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| CN105755829A true CN105755829A (en) | 2016-07-13 |
| CN105755829B CN105755829B (en) | 2018-10-26 |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106498751A (en) * | 2016-10-13 | 2017-03-15 | 无锡市华诚印染剂厂 | Hydrophilic fabricses softening agent |
| CN106758249A (en) * | 2017-02-10 | 2017-05-31 | 苏州市统业化工有限公司 | Fabric softener and preparation method thereof |
| CN107974823A (en) * | 2018-01-22 | 2018-05-01 | 皮勇 | The environment protection health washing methods of towel |
| CN108103785A (en) * | 2017-12-13 | 2018-06-01 | 上海氟聚化学产品股份有限公司 | A kind of fleece fabrics softening agent and preparation method thereof |
| CN108221390A (en) * | 2017-12-13 | 2018-06-29 | 上海氟聚化学产品股份有限公司 | A kind of silk fabric hydrophilic softening agent and preparation method thereof |
| CN109137529A (en) * | 2018-07-18 | 2019-01-04 | 浙江宝娜斯袜业有限公司 | A kind of silk stocking with hydrophilic softener |
| US11753699B2 (en) | 2021-12-03 | 2023-09-12 | Beijing University Of Technology | Cost-effective method for recovering precious metals in circuit board components |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106498751A (en) * | 2016-10-13 | 2017-03-15 | 无锡市华诚印染剂厂 | Hydrophilic fabricses softening agent |
| CN106758249A (en) * | 2017-02-10 | 2017-05-31 | 苏州市统业化工有限公司 | Fabric softener and preparation method thereof |
| CN108103785A (en) * | 2017-12-13 | 2018-06-01 | 上海氟聚化学产品股份有限公司 | A kind of fleece fabrics softening agent and preparation method thereof |
| CN108221390A (en) * | 2017-12-13 | 2018-06-29 | 上海氟聚化学产品股份有限公司 | A kind of silk fabric hydrophilic softening agent and preparation method thereof |
| CN108103785B (en) * | 2017-12-13 | 2020-07-03 | 上海氟聚化学产品股份有限公司 | Cashmere fabric softener and preparation method thereof |
| CN108221390B (en) * | 2017-12-13 | 2021-03-19 | 上海氟聚化学产品股份有限公司 | Hydrophilic softening agent for silk fabrics and preparation method thereof |
| CN107974823A (en) * | 2018-01-22 | 2018-05-01 | 皮勇 | The environment protection health washing methods of towel |
| CN109137529A (en) * | 2018-07-18 | 2019-01-04 | 浙江宝娜斯袜业有限公司 | A kind of silk stocking with hydrophilic softener |
| US11753699B2 (en) | 2021-12-03 | 2023-09-12 | Beijing University Of Technology | Cost-effective method for recovering precious metals in circuit board components |
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| CN105755829B (en) | 2018-10-26 |
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Address after: 201512 1, 5 building, 688 Qiushi Road, Jinshan Town, Jinshan District, Shanghai. Applicant after: SHANGHAI SHINCHEM CHEMICALS CO.,LTD. Address before: 201512 C, No. 688, Qiu Shi Road, Jinshan District, Shanghai, 1-1 Applicant before: SHANGHAI SHINCHEM CHEMICALS CO.,LTD. |
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Effective date of registration: 20230927 Address after: 330300 Xinghuo Industrial Park, Yunshan Economic Development Zone, Yongxiu County, Jiujiang City, Jiangxi Province Patentee after: Jiangxi Fluoropolymer New Material Technology Co.,Ltd. Address before: 201512 1, 5 building, 688 Qiushi Road, Jinshan Town, Jinshan District, Shanghai. Patentee before: SHANGHAI SHINCHEM CHEMICALS CO.,LTD. |