CN113802376B - Cotton feeling agent for chemical fiber fabric and preparation method thereof - Google Patents
Cotton feeling agent for chemical fiber fabric and preparation method thereof Download PDFInfo
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- CN113802376B CN113802376B CN202111224771.5A CN202111224771A CN113802376B CN 113802376 B CN113802376 B CN 113802376B CN 202111224771 A CN202111224771 A CN 202111224771A CN 113802376 B CN113802376 B CN 113802376B
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- 239000004744 fabric Substances 0.000 title claims abstract description 76
- 239000000126 substance Substances 0.000 title claims abstract description 58
- 239000000835 fiber Substances 0.000 title claims abstract description 52
- 229920000742 Cotton Polymers 0.000 title claims abstract description 49
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 39
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- 238000004519 manufacturing process Methods 0.000 title description 2
- -1 alcohol ether carboxylate Chemical class 0.000 claims abstract description 44
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 40
- 229920000570 polyether Polymers 0.000 claims abstract description 40
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 35
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 35
- 239000004814 polyurethane Substances 0.000 claims abstract description 35
- 229920002635 polyurethane Polymers 0.000 claims abstract description 35
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims abstract description 25
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000004094 surface-active agent Substances 0.000 claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 23
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000002994 raw material Substances 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 9
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 claims description 6
- 125000004368 propenyl group Chemical group C(=CC)* 0.000 claims description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 7
- 230000000694 effects Effects 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 230000007547 defect Effects 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- 229920006052 Chinlon® Polymers 0.000 description 1
- 229920002334 Spandex Polymers 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- 229920002978 Vinylon Polymers 0.000 description 1
- HGINCPLSRVDWNT-UHFFFAOYSA-N acrylaldehyde Natural products C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 150000002193 fatty amides Chemical class 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 238000012163 sequencing technique Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000004759 spandex Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- KJIOQYGWTQBHNH-UHFFFAOYSA-N undecanol Chemical compound CCCCCCCCCCCO KJIOQYGWTQBHNH-UHFFFAOYSA-N 0.000 description 1
Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/11—Compounds containing epoxy groups or precursors thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The application discloses a cotton feeling agent for chemical fiber fabrics, which is prepared from 5-30 parts of surfactant containing ethylene oxide and propylene oxide, 10-40 parts of high molecular weight polyether organosilicon, 5-30 parts of isomeric alcohol polyoxyethylene ether, 20-60 parts of water, 5-20 parts of polyurethane, 5-10 parts of alcohol ether carboxylate and 5-10 parts of fatty amide quaternary ammonium salt. The cotton feeling agent of the application is used for after-finishing chemical fiber fabrics, so that the hydrophilicity of the fiber fabric products is improved, the film layers are fine, and the good hand feeling is ensured, so that the fabric products not only have the advantages of cotton fabrics, but also have the advantages of chemical fibers. The application also provides a preparation method of the cotton feeling agent for the chemical fiber fabric.
Description
Technical Field
The application relates to the technical field of textile after-finishing, in particular to a cotton feeling agent for chemical fiber fabrics and a preparation method thereof.
Background
The chemical fiber is fiber prepared from natural or artificial polymer, such as terylene, chinlon, acrylon, polyvinyl chloride, vinylon, spandex, etc. Fabrics prepared from chemical fibers generally have a relatively easy availability of smoothness, but are poor in cotton feel and skin feel, and are not hydrophilic, extremely poor in hygroscopicity, and strong in greasy feel. With the improvement of the living standard of people, the consumption requirements of the chemical fiber textile are also changed. The hydrophilicity and fineness are also important for chemical fiber textiles, and the air permeability is also very high, which is very similar to the characteristics of cotton fabrics. On the other hand, the chemical fiber has high strength, bright color, good water-tightness, high stiffness and smoothness and good rebound resilience, and chemical fiber clothes are durable and do not fade after washing and airing for many times, which is not possessed by pure cotton fabrics.
Therefore, if the defects of the chemical fiber are overcome and the advantages of the chemical fiber are highlighted, the chemical fiber fabric has a wider market, and the chemical fiber fabric can be produced in a large scale and industrialized mode, so that the dependence of the planted cellulose fiber on the land and weather is avoided. In order to achieve the effect that the chemical fiber fabric has cotton fabric, the application provides a cotton feeling agent for the chemical fiber fabric to solve the defects.
Disclosure of Invention
The application aims to provide the cotton feeling agent for the chemical fiber fabric, which is used for after-finishing the chemical fiber fabric, so that the hydrophilicity of the chemical fiber fabric is greatly improved, the fineness is strong, the hand feeling is good, the cotton feeling agent not only has the advantages of the cotton fabric, but also has the advantages of the chemical fiber.
The application further aims at providing a preparation method of the cotton feeling agent for chemical fiber fabrics.
In order to achieve the aim, the application provides a cotton feeling agent for chemical fiber fabrics, which is prepared from the raw materials of a surfactant containing ethylene oxide and propylene oxide, isomeric alcohol polyoxyethylene ether, high molecular weight polyether organosilicon and water.
Compared with the prior art, the cotton feeling agent for chemical fiber fabrics is prepared from the raw materials of the cotton feeling agent containing ethylene oxide and propylene oxide, the isomeric alcohol polyoxyethylene ether, the macromolecular polyether organic silicon and water. In the technical scheme, as the smoothness of the chemical fiber fabric is very smooth, if the small molecular weight polyether organosilicon is adopted, the increase of the smoothness is further promoted, so that the effect of the cotton fabric cannot be achieved. Meanwhile, the surfactant containing ethylene oxide and propylene oxide is introduced to enable the fabric to have hydrophilic performance, and the isomeric alcohol polyoxyethylene ether can promote the surfactant containing ethylene oxide and propylene oxide to further permeate the fabric so as to improve the hydrophilic performance of the fabric. The cotton feeling agent obtained by compounding the surfactant containing ethylene oxide and propylene oxide, the isomeric alcohol polyoxyethylene ether and the macromolecular polyether organosilicon is used for after-finishing the chemical fiber fabric, so that the hydrophilicity of the chemical fiber fabric is improved, the hand feeling is excellent, and the hand feeling effect of the cotton fabric is achieved.
Preferably, the preparation raw material also comprises alcohol ether carboxylate, on the premise of no alcohol ether carboxylate, spots can appear on the fabric obtained by treating the chemical fiber fabric with the cotton feeling agent for multiple times, and the occurrence of the conditions can be avoided after the alcohol ether carboxylate is added, so that spots formed on the surface of the fabric by the polyether organosilicon with high molecular weight can be avoided by the alcohol ether carboxylate, and the yield is improved.
Preferably, the preparation raw materials further comprise polyurethane, and the polyurethane is introduced into the high molecular weight polyether organosilicon system, so that a compact film layer is formed on the surface of the chemical fiber fabric, and the film layer is fine and smooth.
Preferably, the preparation raw materials also comprise fatty amide quaternary ammonium salt, and the addition of the fatty amide quaternary ammonium salt can effectively ensure the softness of the fabric.
Preferably, the preparation raw materials comprise 5-30 parts of surfactant containing ethylene oxide and propylene oxide, 10-40 parts of high molecular weight polyether organosilicon, 5-30 parts of isomeric alcohol polyoxyethylene ether, 20-60 parts of water, 5-20 parts of polyurethane, 5-10 parts of alcohol ether carboxylate and 5-10 parts of fatty amide quaternary ammonium salt. Wherein the content of the surfactant containing ethylene oxide and propylene oxide can be, but is not limited to, 5 parts, 10 parts, 15 parts, 20 parts, 25 parts, 30 parts; the content of the high molecular weight polyether silicone may be, but is not limited to, 5 parts, 10 parts, 15 parts, 20 parts, 25 parts, 30 parts; the water content may be, but is not limited to, 20 parts, 25 parts, 30 parts, 35 parts, 40 parts, 45 parts, 50 parts, 55 parts, 60 parts; the content of polyurethane may be, but is not limited to, 5 parts, 10 parts, 15 parts, 20 parts; the content of the alcohol ether carboxylate may be, but is not limited to, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts; the content of the fatty amide quaternary ammonium salt may be, but is not limited to, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts.
Preferably, the molecular weight of the high molecular weight polyether silicone is 10000-20000, which can be, but is not limited to 10000, 12000, 14000, 16000, 18000, 20000. More preferably, the molecular weight of the high molecular weight polyether silicone is preferably 12000 to 16000.
Preferably, the high molecular weight polyether organosilicon is selected from polyurethane modified polyether organosilicon or propenyl polyoxyethylene ether modified organosilicon, preferably polyurethane modified polyether organosilicon is adopted, and the use of polyurethane modified polyether organosilicon can improve the hygroscopicity of the fabric.
Preferably, the isomeric alcohol polyoxyethylene ether is at least one selected from isomeric decaalcohol polyoxyethylene ether, isomeric undecanol polyoxyethylene ether and isomeric tridecanol polyoxyethylene ether.
Preferably, the preparation raw materials comprise surfactant containing ethylene oxide and propylene oxide, high molecular weight polyether organosilicon, isomeric alcohol polyoxyethylene ether, water, polyurethane, alcohol ether carboxylate and fatty amide quaternary ammonium salt, wherein the high molecular weight polyether organosilicon is selected from polyurethane modified polyether organosilicon, and the molecular weight of the high molecular weight polyether organosilicon is 10000-20000.
Correspondingly, the application also provides a preparation method of the cotton feeling agent for the chemical fiber fabric, which comprises the following steps:
uniformly mixing the isomeric alcohol polyoxyethylene ether and the high molecular weight polyether organosilicon, and then adding the surfactant containing ethylene oxide and propylene oxide and water for continuous uniform mixing.
Preferably, when the cotton feel agent for chemical fiber fabrics comprises a surfactant containing ethylene oxide and propylene oxide, high molecular weight polyether organosilicon, isomeric alcohol polyoxyethylene ether, water, polyurethane, alcohol ether carboxylate and fatty amide quaternary ammonium salt. The preparation method comprises the following steps:
uniformly mixing the isomeric alcohol polyoxyethylene ether and the high molecular weight polyether organosilicon, adding the surfactant containing ethylene oxide and propylene oxide, polyurethane, alcohol ether carboxylate, fatty amide quaternary ammonium salt and water, and uniformly stirring.
Detailed Description
The following examples are intended to illustrate the present application, but not to limit the scope of the claims.
The sources of materials in the technical scheme are as follows:
alcohol ether carboxylate source China national institute of chemical industry, fatty amide quaternary ammonium salt source Wuhanana white pharmaceutical chemical Co., ltd, surfactant source Saxoma chemical R61 containing ethylene oxide and propylene oxide, propenyl polyoxyethylene ether modified organosilicon source Zhejiang Heng, polyurethane modified polyether organosilicon source Qingyuan macro auxiliary agent Co., ltd SR-209, and isomeric alcohol polyoxyethylene ether source Pasteur.
Example 1
The cotton feeling agent for chemical fiber fabric is prepared with surfactant containing ethylene oxide and propylene oxide 10 weight portions, polyurethane modified polyether organosilicon with molecular weight of 12000 20 weight portions, isomeric tridecanol polyoxyethylene ether 10 weight portions, water 50 weight portions, polyurethane 5 weight portions, alcohol ether carboxylate 5 weight portions and fatty amide quaternary ammonium salt 5 weight portions.
The preparation method of the cotton feeling agent for the chemical fiber fabric comprises the following steps:
uniformly mixing the isomeric alcohol polyoxyethylene ether and the high molecular weight polyether organosilicon, adding the surfactant containing ethylene oxide and propylene oxide, polyurethane, alcohol ether carboxylate, fatty amide quaternary ammonium salt and water, and uniformly stirring.
Example 2
The cotton feeling agent for chemical fiber fabric is prepared with the materials including surfactant containing ethylene oxide and propylene oxide 5 weight portions, propylene-based polyoxyethylene ether modified organosilicon with molecular weight of 14000 30 weight portions, isomeric decaol polyoxyethylene ether 20 weight portions, water 40 weight portions, polyurethane 5 weight portions, alcohol ether carboxylate 10 weight portions and fatty amide quaternary ammonium salt 5 weight portions.
The method for preparing the cotton feel agent for chemical fabrics is the same as that of example 1 and is not described in detail herein.
Example 3
The cotton feeling agent for chemical fiber fabric is prepared with the materials including surfactant containing ethylene oxide and propylene oxide 20 weight portions, polyurethane modified polyether organosilicon with molecular weight of 16000 20 weight portions, isomeric deca alcohol polyoxyethylene ether 20 weight portions, water 40 weight portions, polyurethane 10 weight portions, alcohol ether carboxylate 5 weight portions and fatty amide quaternary ammonium salt 10 weight portions.
The method for preparing the cotton feel agent for chemical fabrics is the same as that of example 1 and is not described in detail herein.
Example 4
This example is essentially the same as example 1, except that the polyurethane is absent from this example 4.
The method for preparing the cotton feel agent for chemical fabrics is the same as that of example 1 and is not described in detail herein.
Example 5
This example is substantially the same as example 1 except that the quaternary ammonium salt of fatty amide is not contained in this example 5.
The method for preparing the cotton feel agent for chemical fabrics is the same as that of example 1 and is not described in detail herein.
Example 6
This example is essentially the same as example 1 except that in this example 6 the high molecular weight polyether silicone is a propylene-based polyoxyethylene ether modified silicone having a molecular weight of 12000, whereas in example 1 the high molecular weight polyether silicone is a polyurethane modified polyether silicone having a molecular weight of 12000.
Comparative example 1
The cotton feeling agent for chemical fiber fabric is prepared with surfactant containing ethylene oxide and propylene oxide 10 weight portions, polyurethane modified polyether organosilicon with molecular weight of 8000 20 weight portions, isomeric tridecanol polyoxyethylene ether 10 weight portions, water 50 weight portions, polyurethane 5 weight portions, alcohol ether carboxylate 5 weight portions and fatty amide quaternary ammonium salt 5 weight portions.
The method for preparing the cotton feel agent for chemical fabrics is the same as that of example 1 and is not described in detail herein.
Comparative example 2
The cotton feeling agent for chemical fiber fabric is prepared from 20 parts of polyurethane modified polyether organosilicon with molecular weight of 12000, 10 parts of isomeric tridecanol polyoxyethylene ether, 60 parts of water, 5 parts of polyurethane, 5 parts of alcohol ether carboxylate and 5 parts of fatty amide quaternary ammonium salt.
The method for preparing the cotton feel agent for chemical fabrics is the same as that of example 1 and is not described in detail herein.
The cotton feel agents obtained in examples 1 to 6 and comparative examples 1 to 2 were prepared into aqueous solutions to perform after-treatment on nylon fiber fabrics, and comparative example 3 was set as a blank (i.e., the cotton feel agent was replaced with water), after-treatment was not performed, and then performance test was performed, and the test results are shown in table 1.
Hydrophilicity: the hydrophilicity was determined by a static drip method using a standard dropper (25 drops/mL) to drip 1 drop of water from 4cm from the fabric, and by the time the water drop was completely absorbed. The shorter the time, the better the hydrophilicity.
Feel test: the hand feeling of the fabrics is evaluated by a professional team consisting of 5 personnel with industry literacy by using a physical hand feeling evaluation method. After the hand feeling of a plurality of people is evaluated, the fabrics with the best hand feeling and the worst hand feeling are selected by adopting a sequencing method, the fabrics with the best hand feeling are set to be 5 minutes, the fabrics with the worst hand feeling are set to be 1 minute, the hand feeling of the rest fabrics is obtained by a comparison method, the fabrics are classified into 1-5 grades, the larger the numerical value is, the softer the hand feeling is, and the better the hand feeling is.
Table 1 test results
From the test results of examples 1 to 6 and comparative examples 1 to 3, the hand feeling of the blank is 1, and the cotton feeling agent prepared by the preparation method of the application performs after-treatment on the chemical fiber fabric, so that the hydrophilicity of the chemical fiber fabric is greatly improved, the hand feeling becomes better, the hand feeling effect of the cotton fabric is also achieved, and meanwhile, the hydrophilicity is not basically reduced after 5 times of washing, which indicates that the binding capacity with the chemical fiber fabric is stronger, and the better washing resistance can be realized. Therefore, the fabric after finishing the chemical fiber fabric by adopting the cotton feeling agent not only has the advantages of cotton fabric, but also has the advantages of chemical fiber.
As is clear from a comparison of example 1 with comparative example 1, when the molecular weight of the high molecular weight polyether silicone in the technical scheme is low, for example, when the molecular weight is 8000, the increase in the fabric slip is further promoted, resulting in a decrease in the hand feeling.
As is clear from a comparison of example 1 with comparative example 2, the hydrophilicity was poor when the surfactant containing ethylene oxide and propylene oxide was absent in the technical scheme.
As can be seen from a comparison of example 1 and example 6, the addition of the polyurethane modified polyether silicone can improve the hydrophilic performance of the fabric compared with the propenyl polyoxyethylene ether modified silicone, so that the fabric has better hygroscopicity.
The present application is not limited to the above-mentioned embodiments, but is not limited to the above-mentioned embodiments, and any person skilled in the art can make some changes or modifications to the equivalent embodiments without departing from the scope of the technical solution of the present application, but any simple modification, equivalent changes and modifications to the above-mentioned embodiments according to the technical substance of the present application are still within the scope of the technical solution of the present application.
Claims (6)
1. The cotton feeling agent for the chemical fiber fabric is characterized by comprising the following raw materials: 5-30 parts of surfactant containing ethylene oxide and propylene oxide, 10-40 parts of high molecular weight polyether organosilicon, 5-30 parts of isomeric alcohol polyoxyethylene ether, 20-60 parts of water, 5-20 parts of polyurethane, 5-10 parts of alcohol ether carboxylate and 5-10 parts of fatty amide quaternary ammonium salt, wherein the molecular weight of the high molecular weight polyether organosilicon is 10000-20000, and the high molecular weight polyether organosilicon is selected from polyurethane modified polyether organosilicon or propenyl polyoxyethylene ether modified organosilicon.
2. The cotton feeling agent for chemical fiber fabric according to claim 1, wherein the composition of the raw materials for preparation is as follows: 10 parts of surfactant containing ethylene oxide and propylene oxide, 20 parts of polyurethane modified polyether organosilicon with molecular weight of 12000, 10 parts of isomeric tridecanol polyoxyethylene ether, 50 parts of water, 5 parts of polyurethane, 5 parts of alcohol ether carboxylate and 5 parts of fatty amide quaternary ammonium salt.
3. The cotton feeling agent for chemical fiber fabric according to claim 1, wherein the composition of the raw materials for preparation is as follows: 5 parts of surfactant containing ethylene oxide and propylene oxide, 30 parts of propenyl polyoxyethylene ether modified organosilicon with the molecular weight of 14000, 20 parts of isomeric decaol polyoxyethylene ether, 40 parts of water, 5 parts of polyurethane, 10 parts of alcohol ether carboxylate and 5 parts of fatty amide quaternary ammonium salt.
4. The cotton feeling agent for chemical fiber fabric according to claim 1, wherein the composition of the raw materials for preparation is as follows: 20 parts of surfactant containing ethylene oxide and propylene oxide, 20 parts of polyurethane modified polyether organosilicon with molecular weight of 16000, 20 parts of isomeric decaol polyoxyethylene ether, 40 parts of water, 10 parts of polyurethane, 5 parts of alcohol ether carboxylate and 10 parts of fatty amide quaternary ammonium salt.
5. The cotton feeling agent for chemical fiber fabric according to claim 1, wherein the composition of the raw materials for preparation is as follows: 10 parts of surfactant containing ethylene oxide and propylene oxide, 20 parts of propenyl polyoxyethylene ether modified organosilicon with the molecular weight of 12000, 10 parts of isomeric tridecanol polyoxyethylene ether, 50 parts of water, 5 parts of polyurethane, 5 parts of alcohol ether carboxylate and 5 parts of fatty amide quaternary ammonium salt.
6. A method for preparing the cotton feel agent for chemical fiber fabrics according to any one of claims 1 to 5, comprising the steps of:
uniformly mixing the isomeric alcohol polyoxyethylene ether and the high molecular weight polyether organosilicon, adding the surfactant containing ethylene oxide and propylene oxide, polyurethane, alcohol ether carboxylate, fatty amide quaternary ammonium salt and water, and uniformly stirring.
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