CN1036727C - Antibiotic health fabric and its prepn method and application - Google Patents
Antibiotic health fabric and its prepn method and application Download PDFInfo
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- CN1036727C CN1036727C CN95104287A CN95104287A CN1036727C CN 1036727 C CN1036727 C CN 1036727C CN 95104287 A CN95104287 A CN 95104287A CN 95104287 A CN95104287 A CN 95104287A CN 1036727 C CN1036727 C CN 1036727C
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- fabric
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- antibiotic health
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- slaine
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Abstract
The present invention relates to an antibacterial health care fabric and a preparation method thereof and an application thereof. The fabric is prepared by treating a fabric with the mixed solution of metal salts, complexon or natural organic acids and the sodium salts thereof, and a polyoxy nonionic surfactant for one time, and then drying the fabric for one time. The present invention is suitable for all fabrics, has highly effective bacteriostatic action and bactericidal action on gram-negative bacteria, gram-positive bacteria, fungi and various bacteria, and has the advantages of no harm to human bodies, strong antibacterial action, high wash resistance, simple technology and easy use; the present invention can be widely used in families, and can be used for clothes, bedding articles, decorative articles, tourist articles, etc. for people.
Description
The present invention relates to fabric is carried out the technical field of antimicrobial chemical arrangement.
Antibiotic health fabric and goods thereof can prevent PE cross infection and transmission of disease effectively, guarantee the human body safety and Health, have very big social benefit.At present, the antibacterial treatment of fabric also exist low, the washability of stability to some extent and antibiotic property poor, defective such as complex treatment process, suitable fabric types are limited.Measure as the fungistatic effect that the antibacterial socks to a kind of sanitary finish agent infuse of Chinese Disinfection magazine 94 years the 11st volume the 4th phase the 243rd page of report carry out, its bacteriostasis rate only is 99% after washing 40 times.And for example a kind of through 2,4,4 '-three chloro-2 '-fabric of dihydroxy diphenyl ether and fatty alcohol-polyoxyethylene ether antibiotic finish, its antibiotic health care effect stability is poor, storage period half a year only, easily oxidation and form separating layer, and adhesive force on the fabric a little less than, washability is also poor.A kind of antibacterial deodourizing fabric of slaine and sulfhydryl compound production that utilizes is disclosed for another example at present because sulfhydryl compound and slaine affinity are poor, can not form stable formulation solution, huge strong reaction takes place produce precipitation, so make two kinds of preparations, and will be through twice dipping and twice oven dry, production technology is comparatively complicated, only is suitable for suitability for industrialized production, is difficult for being accepted by numerous families.
The objective of the invention is to that a kind of antibacterial ability is strong, washability is strong, production technology is simple for people provide, can not only carry out suitability for industrialized production, and use easy and simple to handlely, be easy to antibiotic health fabric that enters into family and its production and application.
Purpose of the present invention can reach by following measure:
Antibiotic health fabric of the present invention, be connected to slaine group and complexones or natural organic acids and sodium salt thereof on its fabric respectively, also permeate the polyoxy class non-ionic surface active agent that emulsifying agent and bleeding agent effect have been arranged on the fabric, the amount of slaine accounts for 0.05～12% (weight %) of fabric weight, the amount of complexones or natural organic acids and sodium salt thereof accounts for 0.05～10% (weight %) of fabric weight, and the amount of polyoxy class non-ionic surface active agent accounts for 0.003～2% (weight %) of fabric weight.
Know-why of the present invention is after slaine and polyoxy class non-ionic surface active agent and complexones are applied on the fabric, it is uniform that slaine forms in solution, stable, trickle metal ion, by the hydroxyl in coordinate bond and Van der Waals force and its fabric fibre, amido, the combination of cyano group isoreactivity group, on fabric, complexones also can combine with above-mentioned metal ion on the fabric fibre by carboxyl and form antibiotic sediment, running on the fabric behind the bacterium, metal group will react with the organized enzyme of bacterium, with bacterial enzyme albumen-SH base combines, make its loss of activity, thereby influenced growth and the breeding of bacterium, reached antibacterial and effect sterilization.Because carboxyl and metal ion and polyoxy class non-ionic surface active agent affinity are good, can mix mutually and once prepare a kind of antiseptic, above-mentioned surfactant has emulsification preferably also to have osmosis to fiber to its mixed liquor, thereby make antibacterial firmly and equably attached on the fabric fibre, the adhesion of complex compound that complexones and metal ion generated and the hydroxyl on the fabric, amido, cyano group is very strong, and fabric can obtain more durable antibacterial action after making.Antibiotic preparation of the present invention is colourless, tasteless, transparent, does not change fabric color and physical property.
In the present invention, the metal in the slaine preferably selects for use a kind of in sodium, copper, calcium, silver, zinc, the aluminium or several to use with, and the anion in its slaine then can be selected a kind of in sulfate radical, salt acid group, nitrate radical, carbonate, the carboxylate radical or several for use.
Complexones among the present invention is preferably selected a kind of in ethylenediamine tetra-acetic acid, disodium ethylene diamine tetraacetate, bicine N-, the ethoxy diethylamine triacetic acid or several for use, also can be the salt of above complexones.Natural organic acids can select a kind of in tartaric acid, citric acid, gluconic acid, the acetate or several, also can select these organic acid sodium salts for use.
Indication polyoxy class non-ionic surface active agent of the present invention is a kind of in polyoxyethylene nonylphenol ether, fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, aliphatic acid polyethenoxy ether, polyoxyethylene fatty amine, polyoxyethylene polyoxypropylene glycerin ether, the fatty alcohol ethylene oxide condensate or several preferably.
Process for making such fabric of the present invention is: will account for the slaine of 0.05～12% (weight %) of fabric weight and the polyoxy class non-ionic surface active agent that accounts for complexones or the natural organic acids and the sodium salt thereof of fabric weight 0.05～10% (weight %) and account for fabric weight 0.003～2% (weight %) and be mixed with mixed aqueous solution and be mixed and made into antibiotic health care solution, in this antibiotic health care liquid, metal salt concentrations is between 5 grams per liters～60 grams per liters, the concentration of complexones or natural organic acids and sodium salt thereof is between 5 grams per liters～50 grams per liters, the concentration of polyoxy class non-ionic surface active agent is between 0.3 grams per liter～10 grams per liters, this antiseptic solution is applied on the fabric, and then oven dry or air dry make product, and bake out temperature preferably is controlled at 60-160 ℃.
If three kinds of components are mixed with earlier the aqueous solution respectively, when being liquid, component itself just can be made into the aqueous solution, during mixing, all can by any order mixing, but preferably polyoxy class nonionic surfactant water-soluble liquid is added in the aqueous metal salt, add complexones at last or contain organic acid and the aqueous solution of sodium salt, mix and make antibiotic health care liquid, its pH value is 3-8, is preferably 5-7.
Among the present invention, applying method can be to pad or flood, and also can be spraying.
Fabric of the present invention can be natural fabric, animal fiber, chemical fibre separately or the fabric that forms of blending, also can be felt or bondedfibre fabric.
Use antibiotic health fabric of the present invention, can be made into people's clothing (as interior outerwear trousers, Work Clothes etc.), cloth for shoes, shoe-pad, cap, decoration and bedding, medical (as bandage, gauze etc.) and food (as food bag, dining table cloth etc.) fabric, air filting material, women sanitary articles (as sanitary napkin, brassiere etc.), handkerchief, gloves, towel, socks, diaper, tourism supplies textile articles such as (as health sleeping bags).
The present invention also routinely consumption add textile industry some additives commonly used, auxiliary agent etc., as spices, fire retardant, uvioresistant photo etching, softener, adhesive etc.
Compared with prior art, the present invention is many, the applied range of antibiotic health fabric kind not only, can be used in the various textile articles, and antibacterial ability and washability is strong, and technology is simple.
This product can resist effectively and suppress because human body sweat, the spread of germs of excreta and public article and breeding, eliminate consequent peculiar smell, through Henan Province health and epidemic prevention station, how tame unit testings such as Henan medical college and application result prove, fabric behind the anti-bacteria health finishing of the present invention, has tangible anti-inflammation, deodorization, antipruritic, convergence, effects such as mildew-resistant, to Gram-negative bacteria (gonococcus that contains venereal disease), gram-positive bacteria, various bacteriums such as fungi all have inhibition and bactericidal action efficiently, can prevent bacterial cross-infection effectively and prevent and treat gonorrhoea, pneumonia, typhoid fever, meningitis, infectious diseases such as conjunctivitis; Skin diseases such as the ringworm of the foot, jock itch, eczema, furuncle carbuncle; Gynaecological disease such as vaginitis, Uterine Cervix inflammation is to preventing that bad smell of perspiration, pin are smelly, skin itching has positive effect, and various germs, the acarid in woollen blanket, the carpet had good inhibitory or killing effect.According to the detection of Henan Province health and epidemic prevention station, this product is non-stimulated to skin, no allergic reaction.Harmless, single-use skin test reaction integral mean is " zero ".
Because the strong adhesion of antibiotic health care liquid of the present invention on fabric, good stability, thereby good anti-bacterial effect, washing resistance is strong, detect through units such as Henan Province health and epidemic prevention stations, to staphylococcus aureus, Escherichia coli, Candida albicans, the antibacterial action of withered black sporeformer is efficiently responsive, its test result is to golden yellow grape ball, Escherichia coli, Candida albicans, withered black sporeformer inhibition zone diameter is respectively 36mm, 26mm, 36mm, 18mm, its inhibition zone diameter is respectively 22mm after 150 washings, 13mm, 25mm, 14mm, after 210 washings, bacteriostasis rate is 100%.
The present invention also has a big advantage, only need exactly once to be applied to fabric on after being made into aqueous solution slaine, polyoxy class non-ionic surface active agent, complexones three, oven dry once gets final product, than apply for twice, the production technology of twice oven dry is simple, cost also reduces.Both be suitable for suitability for industrialized production, and be suitable for family again and use, and, dried to dry and get final product as clothes being immersed in the antibiotic health care liquid after 3-5 minute; Also bottled or canned antibiotic health care liquid can be painted on the fabric (as fabrics such as sock, sofa, mattresses) that to wash or to dry.
Describe the present invention in detail below in conjunction with embodiment.
Embodiment one:
Textile article: knitted underwear
In copper sulphate: ethylenediamine tetra-acetic acid: polyoxyethylene nonylphenol ether: water=13: 20: 1.5: 965.5 ratio preparation antibiotic health care liquid, preferably these three kinds of compositions are added low amounts of water respectively and make the aqueous solution, add edta solution in the copper sulfate solution earlier in the stirring, again the polyoxyethylene nonylphenol ether aqueous solution is added in the above-mentioned mixed liquor, be diluted with water to aforementioned proportion at last, be mixed with pH value and be 5～7 antibiotic health care liquid, with this antibiotic health care liquid dipping knitted underwear, during dipping with the whole moistening degree of being of fabric, use centrifuge dewatering again, under 90-110 ℃ of temperature, dry at last, press 100 ℃ of typings with vapour.
Embodiment two:
Textile article: woollen sweater
In sodium nitrate: bicine N-: alkylphenol polyoxyethylene: water=12: 10: 1: 977 ratio preparation antibiotic health care liquid, preferably these three kinds of compositions are added suitable quantity of water respectively and make the aqueous solution, the alkylphenol polyoxyethylene aqueous solution is joined in the sodium nitrate aqueous solution, again the bicine N-aqueous solution is added in the above-mentioned mixed liquor, be diluted with water to aforementioned proportion at last, make antibiotic health care liquid, woollen sweater was flooded 10-20 minute in antibiotic health care liquid, centrifuge dries the back with 60-90 ℃ of temperature preliminary drying, presses typing in 1-2 minute with 100 ℃ of vapour at last.
Embodiment three:
Textile article: 20 * 20 60 * 58 38 " bleach textile cloth
In silver nitrate: disodium ethylene diamine tetraacetate: natrium citricum: fatty alcohol-polyoxyethylene ether: water=8: 12: 8: 5: 967 ratio preparation antibiotic health care liquid, preferably preceding four kinds of compositions are added suitable quantity of water respectively and make the aqueous solution, in any order with after four kinds of aqueous solution and thin up to above-mentioned ratio, make antibiotic health care liquid, pad the textile cloth of bleaching, dehydration, 90-110 ℃ of hot-air seasoning then with this antibiotic health care liquid, drying cylinder pressure is 2kg/cm, the stenter speed of a motor vehicle be 40-50 rice/minute.
Can make decoration and goods such as bedding, handkerchief, diaper, clothes and trousers with this kind antibiotic health fabric.
Embodiment four:
Fabric: 45 * 45 96 * 72 wash fine cloth
Antibiotic health care liquid proportioning is pressed zinc sulfate: natrium citricum: tartaric acid: peregal 0: water=55: 20: 25: 1: 899, all the other processing steps and process conditions were same as embodiment three.
Embodiment five:
Textile article: elastic force silk stocking
Antibiotic health care liquid proportioning is pressed calcium carbonate: sodium carbonate: bicine N-: the fatty alcohol ethylene oxide condensate: the polyoxyethylene polyoxypropylene glycerin ether: water=50: 50: 30: 5: 5: 860.
All the other processing steps and process conditions are same as embodiment two.
Embodiment six:
Fabric: wash/bonded non-woven fabrics
Antibiotic health care liquid Main Ingredients and Appearance proportioning is pressed silver nitrate: sodium tartrate: citric acid: fatty alcohol ethylene oxide condensate: water=12: 5: 13: 10: 960, but constant adds adhesive.Antibiotic health care liquid applies mode: be sprayed on the fabric 150-180 ℃ of bake out temperature 80-120 ℃, 2-5 minute, molten baking.
All the other processing steps and process conditions are same as embodiment three.
Embodiment seven:
Textile article: cotton towel quilt
Antibiotic health care liquid Main Ingredients and Appearance proportioning is pressed zinc acetate: copper sulphate: sodium tartrate: polyoxyethylene nonylphenol ether: water=5: 7: 20: 8: 960.With antibiotic health care liquid impregnate fabric goods, all the other processing steps and condition are same as embodiment two.
Embodiment eight:
Textile article: textile articles such as lining cloth, Lining inserts for leather shoes, sofa backrest, automobile cushion, fabric toy for children in the textile footwear.
Antibiotic health care liquid Main Ingredients and Appearance proportioning is pressed copper sulphate: ethoxy diethylamine triacetic acid: peregal 0: water=13: 30: 2.5: 954.5, and the concrete compound method of antibiotic health care liquid is same as embodiment one.
Apply mode: antibiotic health care liquid is poured in aerosol can or the bottle, be sprayed on the above-mentioned fabrics goods, dry and get final product.
Claims (9)
1, a kind of antibiotic health fabric, it is characterized in that being connected to respectively on the fabric slaine group and complexones and/or natural organic acids and sodium salt thereof, also permeate on the fabric polyoxy class non-ionic surface active agent is arranged, the amount of slaine accounts for 0.05～12% (weight %) of fabric weight, the amount of complexones and/or natural organic acids and sodium salt thereof accounts for 0.05～10% (weight %) of fabric weight, the amount of polyoxy class non-ionic surface active agent accounts for 0.003～2% (weight %) of fabric weight, mixture is applied on the fabric by the mode that applies, then oven dry or air dry.
2, fabric according to claim 1 is characterized in that metal ion in the slaine can be a kind of in sodium, copper, calcium, silver, zinc, the aluminium or several.
3, fabric according to claim 1 is characterized in that anion in the slaine can be a kind of in sulfate radical, salt acid group, nitrate radical, carbonate, the carboxylate radical or several.
4, fabric according to claim 1, it is characterized in that complexones can be a kind of in the following complexones or several: ethylenediamine tetra-acetic acid, disodium ethylene diamine tetraacetate, bicine N-, hydroxyl two basic diethylamine triacetic acids, natural organic acids can be in tartaric acid, citric acid, acetate, the gluconic acid a kind of or several.
5, fabric according to claim 1 is characterized in that polyoxy class nonionic table and activating agent can be a kind of in polyoxyethylene nonylphenol ether, fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, aliphatic acid polyethenoxy ether, polyoxyethylene fatty amine, polyoxyethylene polyoxypropylene glycerin ether, the fatty alcohol ethylene oxide condensate or several.
6, the preparation method of antibiotic health fabric according to claim 1, the polyoxy class non-ionic surface active agent that it is characterized in that accounting for the slaine of fabric weight 0.05～12% (weight %) and account for complexones and/or the natural organic acids and the sodium salt thereof of fabric weight 0.05～10% (weight %) and account for fabric weight 0.003～2% is mixed with mixed aqueous solution and makes antibiotic health care liquid, this antibiotic health care liquid is applied on the fabric, and then product is made in oven dry or air dry.
7, preparation method according to claim 6 is characterized in that applying method can be to pad or flood, and can also be spraying.
8, preparation method according to claim 6 is characterized in that described fabric can be by natural fabric, animal fiber, chemical fibre separately or the fabric that forms of blending, also can be felt or bondedfibre fabric.
9, antibiotic health fabric according to claim 1, it is characterized in that to be used to make people's clothing, shoes and hats, decoration and bedding, also can be used as medical and food with fabric, tourism supplies, air filting material, women sanitary articles, handkerchief, gloves, socks, diaper, shoe-pad, towel.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN95104287A CN1036727C (en) | 1995-04-28 | 1995-04-28 | Antibiotic health fabric and its prepn method and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN95104287A CN1036727C (en) | 1995-04-28 | 1995-04-28 | Antibiotic health fabric and its prepn method and application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1121126A CN1121126A (en) | 1996-04-24 |
| CN1036727C true CN1036727C (en) | 1997-12-17 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN95104287A Expired - Fee Related CN1036727C (en) | 1995-04-28 | 1995-04-28 | Antibiotic health fabric and its prepn method and application |
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| Country | Link |
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| CN (1) | CN1036727C (en) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1057807C (en) * | 1996-08-29 | 2000-10-25 | 舒军 | Prodn process of physically antiseptic non-woven fabric |
| TW402526B (en) * | 1997-08-07 | 2000-08-21 | Fukusen Industry Co Ltd | The disinfection and anti-bacterial process method and the apparature |
| CN100344822C (en) * | 2004-10-19 | 2007-10-24 | 东华大学 | Polycomponent fiber product composite nano antibacterial agent, its preparing method and use |
| CN101144247B (en) * | 2006-09-15 | 2011-05-11 | 高德康 | Special-purpose avian influenza resisting finishing agent for eiderdown and preparation method thereof |
| CN103538511B (en) * | 2013-09-25 | 2017-04-12 | 浙江吉利控股集团有限公司 | Antimicrobial car carpet and manufacturing method thereof |
| CN103835124B (en) * | 2014-02-28 | 2015-11-25 | 河南省科学院化学研究所有限公司 | Carry silver-colored COTTON FABRIC anti-biotic material and preparation method thereof |
| CN104387936A (en) * | 2014-12-19 | 2015-03-04 | 常熟市雷号医疗器械有限公司 | Medical leg bag |
| CN105019228A (en) * | 2015-07-10 | 2015-11-04 | 湖州高歌纺织有限公司 | Nano-silver antibacterial finishing method of polyester fabrics |
| CN105288713B (en) * | 2015-11-12 | 2018-04-20 | 深圳市康乐美科技有限公司 | Bacteria-inhibiting type sanitary napkin |
| CN106308229A (en) * | 2016-10-11 | 2017-01-11 | 青岛裕王智能科技床业有限公司 | Antiviral mattress |
| CN109771689A (en) * | 2019-03-12 | 2019-05-21 | 诗乐氏实业（深圳）有限公司 | A kind of functional sanitary towel and pad |
| CN112176725A (en) * | 2020-10-28 | 2021-01-05 | 上海威露美生物科技有限公司 | Carboxyl esterification complex antibacterial fiber, preparation method and application |
| CN111996797A (en) * | 2020-10-28 | 2020-11-27 | 上海威露美生物科技有限公司 | Amidation complex antibacterial fiber, preparation method and application |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62142559A (en) * | 1985-12-18 | 1987-06-25 | 株式会社祥光化学研究所 | Structure having deodorizing and antibacterial functions |
| JP4144564B2 (en) * | 2004-05-25 | 2008-09-03 | ヤマハ株式会社 | Electronic drum |
-
1995
- 1995-04-28 CN CN95104287A patent/CN1036727C/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62142559A (en) * | 1985-12-18 | 1987-06-25 | 株式会社祥光化学研究所 | Structure having deodorizing and antibacterial functions |
| JP4144564B2 (en) * | 2004-05-25 | 2008-09-03 | ヤマハ株式会社 | Electronic drum |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1121126A (en) | 1996-04-24 |
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