CN105755829B - A kind of towel cloth hydrophilic softening agent - Google Patents

A kind of towel cloth hydrophilic softening agent Download PDF

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Publication number
CN105755829B
CN105755829B CN201410815486.4A CN201410815486A CN105755829B CN 105755829 B CN105755829 B CN 105755829B CN 201410815486 A CN201410815486 A CN 201410815486A CN 105755829 B CN105755829 B CN 105755829B
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softening agent
towel cloth
quaternary ammonium
ammonium salt
aeo
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CN105755829A (en
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杨坡
张豪华
张玉
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Jiangxi Fluoropolymer New Material Technology Co ltd
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Shanghai Fluorine Chemical Products Ltd By Share Ltd
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Abstract

The present invention relates to fabric softeners, and in particular to a kind of towel cloth hydrophilic softening agent belongs to textile fabric softening agent field.The softening agent component is by mass percentage:Modified amido siloxanes 10%~20%, polyether polyester 5%~10%, quaternary ammonium salt are 1%~8%, nonionic emulsifier is 5%~10%, organic acid is 0.1~0.5% and deionized water is 51.5%~78.9%.It is matched according to above-mentioned raw materials, modified amido siloxanes is first added in variable-ratio mixer and nonionic emulsifier stirs evenly, then added polyether polyester and quaternary ammonium salt stirring, be finally slowly added to citric acid and deionized water, emulsion reaction according to the ratio;Stir evenly packing.Hydrophilic softening agent quality stability of the present invention is good, can not only assign the feel that towel cloth is fluffy, thick and solid, and does not influence the hydrophily and color and luster of towel cloth, while also having the function of antibacterial and taste removal.

Description

A kind of towel cloth hydrophilic softening agent
Technical field
The present invention relates to fabric softeners, and in particular to a kind of towel cloth hydrophilic softening agent belongs to textile fabric softness Agent field.
Background technology
Fabric softener develops to today, has the history of over half a century, very long using also having on towel cloth History, it to improve towel cloth feel and sense of touch play a significant role, with the development of economy with living standard It increasingly improves, it is excellent that people do not require nothing more than towel cloth feel sense of touch, advocates towel cloth from practicability to function sexual development, increases Add some antibacterial and function of odor removal.
Towel cloth is generally fat race amides softening agent and on a small quantity amino modified of hydrophilic fat with softening agent at present Silicone oil is used cooperatively, and only has the function of single improvement feel, and quality stability, hydrophily and feel need to be carried It is high.
Invention content
The purpose of the present invention is to provide a kind of towel cloth hydrophilic softening agent, softening agent provided by the invention overcomes The problems of the above-mentioned prior art and provide it is a kind of have quality stability good, it is fluffy, thick and solid that towel cloth can not only be assigned Feel, and do not influence the hydrophily and color and luster of towel cloth, while also having the function of that antibacterial and taste removal towel is close Water softening agent.
A kind of towel cloth hydrophilic softening agent is made of by mass percentage following components:Modified amido siloxanes 10%~20%, polyether polyester 5%~10%, quaternary ammonium salt are 1%~8%, nonionic emulsifier is 5%~10%, organic acid It is 51.5%~78.9% for 0.1~0.5% and deionized water.
Preferably, the softening agent component is by mass percentage:Modified amido siloxanes 15%, polyether polyester are 10%, quaternary ammonium salt 5%, nonionic emulsifier 8%, organic acid are 0.3% and deionized water is 61.7%.
The modified amido siloxanes is the polyether modified amino siloxanes that ammonia value is 0.16mmol/g, poly- purchased from Shanghai fluorine Chemical products Co., Ltd, product grade SF9288;
The polyether polyester is water-soluble or water-dispersion type polyether polyester, as Products Co., Ltd of Shanghai Fluoropolymer Medical Products Co., Ltd. carries It supplies, product grade STM;
The quaternary ammonium salt is imidazoline quaternary ammonium salt, heptadecyl-beta-aminoethyl imidazoline quaternary ammonium salt;
The nonionic surfactant is isomeric alcohol polyethenoxy ether (molecular weight is 378~554) or fatty alcohol polyoxy Vinethene (molecular weight is 362~846);
Wherein fatty alcohol polyoxyethylene ether is AEO-5:AEO-9=3:7,AEO-5:AEO-15=2:3 or AEO-5:AEO-9 =1:1 fatty alcohol polyoxyethylene ether;Wherein isomeric alcohol polyethenoxy ether is XP50:XP90=4:6 isomery alcohol polyoxyethylene Ether.
The organic acid is one or more of acetic acid, citric acid, hydroxyacetic acid and terephthalic acid (TPA).
A kind of preparation method of towel cloth hydrophilic softening agent, carries out as steps described below:
It is matched according to above-mentioned raw materials, modified amido siloxanes is first added in variable-ratio mixer and nonionic emulsifier stirs It mixes uniformly, then adds polyether polyester and quaternary ammonium salt stirring, be finally slowly added to citric acid and deionized water according to the ratio, breast Change reaction;Stir evenly packing.
Advantageous effect
Compared with prior art, the modified amido siloxanes composition in a kind of towel hydrophilic softening agent of the present invention, contains Water imbibition polyether group has good feel and hydrophily, and is influenced on fabric color small;Polyethers in the softening agent is poly- Ester composition has excellent hydrophily and soft feel;Quaternary ammonium salt composition in the softening agent has good antibacterial taste removal Property, while there is fluffy feel.A kind of towel of the present invention is a kind of ideal for realizing towel multifunctionality with hydrophilic softening agent Softening agent.
Specific implementation mode
With reference to specific embodiment, the present invention is described in detail, it should be understood that these embodiments are merely to illustrate this hair It is bright, rather than limit the application range of the present invention.
Embodiment 1
A kind of towel cloth hydrophilic softening agent of the present invention, component and mass percent are as follows:Ammonia value is 0.16mmol/g Polyether modified amino siloxanes (be purchased from Shanghai Fluoropolymer Medical Products Co., Ltd., SF9288) 15%, water soluble polyether polyester (being purchased from Shanghai Fluoropolymer Medical Products Co., Ltd., STM) is 10%, imidazoline quaternary ammonium salt 5%, nonionic emulsifier fatty alcohol Polyoxyethylene ether (AEO-5:AEO-9=3:7) (purchased from magnificent boundary's chemistry, the trade mark is ABLUNOL AEO-3, ABLUNOL AEO-9) For 8%, acetic acid be 0.3% and deionized water is 61.7%.It is 0.16mmol/ that ammonia value is first added in variable-ratio mixer according to the ratio The polyether modified amino siloxanes and nonionic emulsifier fatty alcohol polyoxyethylene ether of g stirs evenly, and is then added according to the ratio again Water soluble polyether polyester and imidazoline quaternary ammonium salt stirring, are finally slowly added to acetic acid and deionized water, emulsion reaction according to the ratio.It stirs Mix uniform packing.
Embodiment 2
A kind of towel cloth hydrophilic softening agent of the present invention, component and mass percent are as follows:Ammonia value is 0.16mmol/g Polyether modified amino siloxanes (be purchased from Shanghai Fluoropolymer Medical Products Co., Ltd., SF9288) 10%, water soluble polyether polyester (being purchased from Shanghai Fluoropolymer Medical Products Co., Ltd., STM) is 8%, imidazoline quaternary ammonium salt 1%, nonionic emulsifier isomery alcohol Polyoxyethylene ether (XP50:XP90=4:6) it (is provided by DOW Chemical, the trade mark is Lutensol XP50, Lutensol XP90) For 5%, citric acid be 0.1% and deionized water is 75.9%.Ammonia value is first added in variable-ratio mixer according to the ratio is The polyether modified amino siloxanes and nonionic emulsifier fatty alcohol polyoxyethylene ether of 0.16mmol/g stirs evenly, and then presses again Water soluble polyether polyester and imidazoline quaternary ammonium salt stirring is added in proportioning, is finally slowly added to citric acid and deionization according to the ratio Water, emulsion reaction.Stir evenly packing.
Embodiment 3
A kind of towel cloth hydrophilic softening agent of the present invention, component and mass percent are as follows:Ammonia value is 0.16mmol/g Polyether modified amino siloxanes (be purchased from Shanghai Fluoropolymer Medical Products Co., Ltd., SF9288) 20%, water soluble polyether polyester (being purchased from Shanghai Fluoropolymer Medical Products Co., Ltd., STM) is 10%, imidazoline quaternary ammonium salt 8%, nonionic emulsifier fatty alcohol Polyoxyethylene ether (AEO-5:AEO-15=2:3) be 10% (purchased from magnificent boundary's chemistry), hydroxyacetic acid is 0.5% and deionized water is 51.5%.The polyether modified amino siloxanes and nonionic that ammonia value is 0.16mmol/g is first added in variable-ratio mixer according to the ratio Emulsifier fatty alcohol polyoxyethylene ether stirs evenly, and water-dispersion type polyether polyester and imidazoline quaternary ammonium salt is then added according to the ratio again Stirring, is finally slowly added to hydroxyacetic acid and deionized water, emulsion reaction according to the ratio.Stir evenly packing.
Embodiment 4
A kind of towel cloth hydrophilic softening agent of the present invention, component and mass percent are as follows:Ammonia value is 0.16mmol/g Polyether modified amino siloxanes (be purchased from Shanghai Fluoropolymer Medical Products Co., Ltd., SF9288) 12%, water soluble polyether polyester (being purchased from Shanghai Fluoropolymer Medical Products Co., Ltd., STM) is 10%, imidazoline quaternary ammonium salt 3%, nonionic emulsifier fatty alcohol Polyoxyethylene ether (AEO-5:AEO-9=1:1) be 6% (purchased from magnificent boundary's chemistry), acetic acid is 0.2% and deionized water is 68.8%.The polyether modified amino siloxanes and nonionic that ammonia value is 0.16mmol/g is first added in variable-ratio mixer according to the ratio Emulsifier fatty alcohol polyoxyethylene ether stirs evenly, and water soluble polyether polyester then is added according to the ratio again and imidazoline quaternary ammonium salt stirs It mixes, is finally slowly added to acetic acid and deionized water, emulsion reaction according to the ratio.Stir evenly packing.
Comparative example
Common towel softening agent, component and mass percent are as follows currently on the market:Amino modified siloxanes 5%, parent Aqueous aliphatic amide type softening agent is 10%, emulsifier 3%, acetic acid are 0.2% and deionized water is 82.8%.
Test example
It is that 10g/L is used for white cotton untwisted yarn towel to the product dosage made by above-described embodiment 1~4 and comparative example, Following performance test is carried out after 150 degrees Celsius of drying:
(1) feel
By 5 seasoned professionals feel is evaluated with digital palpation for examination of trauma.1 grade shows that feel is worst, and 5 grades show feel most It is good.
(2) hydrophily
According to AATCC 79-2000《The water imbibition of textile measures》It measures.
(3) whiteness
Whiteness is detected using SBDY-1 digital display whiteness instrument.Numerical value shows that more greatly whiteness is better.
(4) biocidal property
According to GB/T 20944-2007《The evaluation of antibacterial textile performance》Measure bacteriostasis rate.
The towel cloth of the present invention see the table below 1 with hydrophilic softening agent the performance test results
The hydrophilic application performance of towel cloth of 1 present invention of table
Serial number Fabric Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Comparative example
Feel/grade 1 4 3 4 3 2
Hydrophily/s <1 <1 1 1 <1 2
Whiteness/% 85 84 84.2 83.5 84 82.7
Bacteriostasis rate/% 0 70 20 80 50 0
As can be seen from the above table, a kind of towel cloth of the present invention has preferable feel with hydrophilic softening agent, while to knitting The hydrophily and whiteness of object also have certain anti-microbial property substantially without influence, are that a kind of ideal multifunctional towel is soft Agent.
Quality stability with towel cloth hydrophilic softening agent obtained in Examples 1 to 4 is fabulous, treated towel Fabric has fluffy, thick and solid feel, and the hydrophily and color and luster not influenced, while also having the function of antibacterial and taste removal.
The preferred embodiment of the invention is illustrated above, but the invention be not limited to it is described Embodiment, those skilled in the art can also make various be equal under the premise of without prejudice to the invention spirit Modification or replacement, these equivalent modifications or replacement are all contained in the application claim limited range.

Claims (7)

1. a kind of towel cloth hydrophilic softening agent is made of by mass percentage following components:Modified amido siloxanes 10% ~20%, water-soluble or water dispersible polyether polyester 5%~10%, quaternary ammonium salt 1%~8%, nonionic emulsifier 5%~ 10%, organic acid 0.1~0.5% and deionized water 51.5%~78.9%,
Wherein, the modified amido silane is polyether modified amino siloxanes, and ammonia value is 0.16mmol/g.
2. a kind of towel cloth hydrophilic softening agent according to claim 1, which is characterized in that its component presses quality percentage Than for:Polyether modified amino siloxanes 15%, water-soluble or water dispersible polyether polyester 10%, quaternary ammonium salt 5%, non-ionic emulsifier Agent 8%, organic acid 0.3% and deionized water 61.7%.
3. a kind of towel cloth hydrophilic softening agent according to claim 1, which is characterized in that the quaternary ammonium salt is imidazoline Quaternary ammonium salt.
4. a kind of towel cloth hydrophilic softening agent according to claim 1, which is characterized in that the nonionic emulsifier is Isomeric alcohol polyethenoxy ether or fatty alcohol polyoxyethylene ether.
5. a kind of towel cloth hydrophilic softening agent according to claim 4, which is characterized in that wherein aliphatic alcohol polyethenoxy Ether is AEO-5:AEO-9=3:7,AEO-5:AEO-15=2:3 or AEO-5:AEO-9=1:1 fatty alcohol polyoxyethylene ether;Its Middle isomeric alcohol polyethenoxy ether is XP50:XP90=4:6 isomeric alcohol polyethenoxy ether.
6. a kind of towel cloth hydrophilic softening agent according to claim 1, which is characterized in that the organic acid includes second The one or more of acid, citric acid, hydroxyacetic acid and terephthalic acid (TPA).
7. the preparation method of towel cloth hydrophilic softening agent described in claim 1, carries out as steps described below:According to above-mentioned Raw material proportioning is first added modified amido siloxanes in variable-ratio mixer and nonionic emulsifier stirs evenly, and then adds again Enter polyether polyester and quaternary ammonium salt stirring, is finally slowly added to citric acid and deionized water, emulsion reaction according to the ratio;It stirs evenly Packing.
CN201410815486.4A 2014-12-19 2014-12-19 A kind of towel cloth hydrophilic softening agent Active CN105755829B (en)

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Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106498751A (en) * 2016-10-13 2017-03-15 无锡市华诚印染剂厂 Hydrophilic fabricses softening agent
CN106758249A (en) * 2017-02-10 2017-05-31 苏州市统业化工有限公司 Fabric softener and preparation method thereof
CN108221390B (en) * 2017-12-13 2021-03-19 上海氟聚化学产品股份有限公司 Hydrophilic softening agent for silk fabrics and preparation method thereof
CN108103785B (en) * 2017-12-13 2020-07-03 上海氟聚化学产品股份有限公司 Cashmere fabric softener and preparation method thereof
CN107974823A (en) * 2018-01-22 2018-05-01 皮勇 The environment protection health washing methods of towel
CN109137529A (en) * 2018-07-18 2019-01-04 浙江宝娜斯袜业有限公司 A kind of silk stocking with hydrophilic softener
US11753699B2 (en) 2021-12-03 2023-09-12 Beijing University Of Technology Cost-effective method for recovering precious metals in circuit board components

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CN102965953A (en) * 2012-11-21 2013-03-13 桐乡市濮院毛针织技术服务中心 Formula and synthetic process of novel multifunctional soft additive
CN103696253A (en) * 2013-10-31 2014-04-02 山东鲁普科技有限公司 Soft finishing method of rope
CN103774420A (en) * 2014-01-24 2014-05-07 南通惠通纺织器材有限公司 Preparation method of a softener
CN104098776A (en) * 2014-06-13 2014-10-15 安徽科光新材料有限公司 Preparation method of polyether polyester modified silicone oil

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