CN108442103A - Super hydrophilic yarn smooth agent and preparation method thereof - Google Patents
Super hydrophilic yarn smooth agent and preparation method thereof Download PDFInfo
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- CN108442103A CN108442103A CN201810314806.6A CN201810314806A CN108442103A CN 108442103 A CN108442103 A CN 108442103A CN 201810314806 A CN201810314806 A CN 201810314806A CN 108442103 A CN108442103 A CN 108442103A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
- D06M13/148—Polyalcohols, e.g. glycerol or glucose
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/165—Ethers
- D06M13/17—Polyoxyalkyleneglycol ethers
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
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Abstract
The present invention relates to a kind of super hydrophilic yarn smooth agents and preparation method thereof, include each component of following parts by weight:10 ~ 30 parts of liquid wax, 1 ~ 5 part of hydrophilic agent, 1 10 parts of aliphatic surfactant, 15 parts of acid, 15 parts of bleeding agent, 5 10 parts of anti skinning agent, 0.5 2 parts of antifoaming agent, 0.5 2 parts of Ph conditioning agents, 50 60 parts of water.It is an advantage of the invention that:On the basis of liquid wax class yarn smooth agent, by incorporating hydrophilic agent, and it is aided with other components, forms good hydrophilic property, the outstanding super hydrophilic yarn smooth agent of flatness.
Description
Technical field
The present invention relates to a kind of super hydrophilic yarn smooth agents and preparation method thereof.
Background technology
Smooth agent be it is a kind of there is excellent soft, smooth, bright, feel textile auxiliary, be weaving of new generation high-grade
The soft finishing agent of product.The softness of fabric brilliance, the effect of smooth effect can be assigned, the finished product of various fibers is can be suitably used for;With
In smooth agent on yarn, the feel that has not only needed, it is also necessary to yarn smooth degree can be increased, reduce and rub between yarn and machine
Power facilitates spinning, reduces the broken yarn etc. of yarn, simultaneously as after spinning process, it is also necessary to the processing of next step is carried out,
Using to auxiliary agent be largely water-soluble, so also need to smooth agent processing yarn after so that yarn have excellent parent
It is aqueous, convenient for the post-processing of spinning;And most of yarn smooth agent is liquid wax class on the market at present, wax class is not hydrophilic, place
Reason is after yam surface, although having excellent flatness, not good hydrophily;A part of yarn smooth agent is hydrophilic
Fatty acyl amide, there is preferable hydrophily, but the film forming on yarn is bad, and flatness is bad, is susceptible to yarn
Situations such as broken yarn.
Smooth agent can assign the softness of fabric brilliance, smooth effect, be suitable for the manufactured goods of various fibers, be of new generation high
The optimal selection of shelves textile soft finishing agent;With excellent soft, smooth, uniform feel, with consumer spending water
Flat raising is promoted with cognition, and requirement of the people to clothes is also higher and higher, and a clothes are made fabric from yarn weaving,
So that the performance of embryo cloth reaches best, most basic is the quality for controlling yarn, such as to prevent Yarn break, solves yarn strength
Decline problem improves the hydrophily of yarn, reduces the friction coefficient etc. of yarn.
Popular most of yarn smooth agent is liquid wax class or hydrophilic fatty acyl amide currently on the market, this two
Major class yarn smooth agent suffers from respective merits and demerits;The newest yarn smooth agent for useful two class occur is compounded, and is adjusted
Both whole suitable ratio, then can have the advantages that, but have the shortcomings that stability is poor.
Invention content
To overcome the deficiencies of existing technologies, the present invention provides super fluffy silicon soft oil of one kind and preparation method thereof, of the invention
Technical solution is:
Super hydrophilic yarn smooth agent, includes each component of following parts by weight:10 ~ 30 parts of liquid wax, 1 ~ 5 part of hydrophilic agent, aliphatic table
Activating agent 1-10 parts of face, 1-5 parts sour, 1-5 parts of bleeding agent, 5-10 parts of anti skinning agent, 0.5-2 parts of antifoaming agent, Ph conditioning agents 0.5-2
Part, 50-60 parts of water.
20 parts of the liquid wax, 3 parts of hydrophilic agent, 5 parts of aliphatic surfactant, 3 parts of acid, 3 parts of bleeding agent, anti-skinning
8 parts of agent, 1 part of antifoaming agent, 1 part of Ph conditioning agents, 55 parts of water.
The mixing that the various n-alkanes that the liquid wax is C10 to C18 form;The hydrophily agent is fatty acid amide, parent
Water class silicone oil, glycerine, one kind in fatty ester or according to arbitrary proportion composition mixture;The aliphatic surfactant is
One of AEO-3, AEO-7, AEO-9, peregal O-25, paregal O -20 or the mixture formed according to arbitrary proportion;The acid
For one kind in lactic acid, formic acid, glacial acetic acid or citric acid.
The bleeding agent is one kind in polycarboxylic acid salt, polyethenoxy ether class or silicon-containing surfactant class;It is described anti-
Crust forming agent is one kind in polyethylene glycol 200, polyethylene glycol 400 or Macrogol 600;The antifoaming agent defoams for organic silicon
One kind in agent, high-carbon alcohol defoaming agent or polyethers antifoaming agent;The Ph conditioning agents are citrate, borate or phosphoric acid
One kind in salt.
A method of super hydrophilic yarn smooth agent is prepared, is included the following steps:
(1)Liquid wax, hydrophilic agent, aliphatic surfactant are uniformly mixed according to proportioning, 40-60 DEG C is warming up to, stirs evenly,
Under the conditions of 40-60 DEG C of heat preservation, it is slowly added into water, is added on one side
It stirs on one side, adds subsequent 40-60 DEG C of continuation of insurance temperature, stir 2-5h;
(2)After bleeding agent, anti skinning agent and Ph conditioning agents is added, 40-60 DEG C is kept the temperature, stirs 1-2h,
Then antifoaming agent and acid is added, stirs 10-30min.
It is an advantage of the invention that:On the basis of liquid wax class yarn smooth agent, by incorporating hydrophilic agent, and it is aided with other groups
Point, form good hydrophilic property, the outstanding super hydrophilic yarn smooth agent of flatness.
Specific implementation mode
The invention will now be further described with reference to specific embodiments, the advantages and features of the present invention will be with description and more
It is clear.But examples are merely exemplary for these, and it is not intended to limit the scope of the present invention in any way.Those skilled in the art answer
It should be appreciated that can be repaiied without departing from the spirit and scope of the invention to the details and form of technical solution of the present invention
Change or replace, but these modifications and replacement are each fallen in protection scope of the present invention.
Embodiment 1:Super hydrophilic yarn smooth agent, includes each component of following parts by weight:10 parts of liquid wax, 1 part of hydrophilic agent, fat
1 part of fat race surfactant, 1 part of acid, 1 part of bleeding agent, 5 parts of anti skinning agent, 0.5 part of antifoaming agent, 0.5 part of Ph conditioning agents, water 50
Part.
The mixing that the various n-alkanes that the liquid wax is C10 to C18 form;The hydrophily agent is fatty acid amide, parent
One kind in water class silicone oil, glycerine, fatty ester;The aliphatic surfactant is AEO-3, AEO-7, AEO-9, paregal O-
25, one kind in paregal O -20;The acid is lactic acid.
The bleeding agent is polycarboxylic acid salt;The anti skinning agent is polyethylene glycol 200;The antifoaming agent is organic silicon
Antifoaming agent;The Ph conditioning agents are citrate.
A method of super hydrophilic yarn smooth agent is prepared, is included the following steps:
(1)Liquid wax, hydrophilic agent, aliphatic surfactant are uniformly mixed according to proportioning, 40 DEG C is warming up to, stirs evenly, is protected
Under the conditions of 40 DEG C of temperature, it is slowly added into water, is stirred while being added,
Subsequent 40 DEG C of continuation of insurance temperature is added, 2h is stirred;
(2)After bleeding agent, anti skinning agent and Ph conditioning agents is added, 40 DEG C are kept the temperature, stirs 1h,
Then antifoaming agent and acid is added, stirs 10min.
Embodiment 2:Super hydrophilic yarn smooth agent, includes each component of following parts by weight:20 parts of the liquid wax, it is hydrophilic
3 parts of agent, 5 parts of aliphatic surfactant, 3 parts of acid, 3 parts of bleeding agent, 8 parts of anti skinning agent, 1 part of antifoaming agent, 1 part of Ph conditioning agents,
55 parts of water.
The mixing that the various n-alkanes that the liquid wax is C10 to C18 form;The hydrophily agent is fatty acid amide, parent
According to arbitrary proportion composition mixture in water class silicone oil, glycerine, fatty ester;The aliphatic surfactant is AEO-3, AEO-
7, the mixture that AEO-9, peregal O-25, paregal O -20 are formed according to arbitrary proportion;The acid is glacial acetic acid or citric acid
In one kind.
The bleeding agent is polyethenoxy ether class;The anti skinning agent is polyethylene glycol 400;The antifoaming agent is higher alcohols
Class antifoaming agent;The Ph conditioning agents are borate.
A method of super hydrophilic yarn smooth agent is prepared, is included the following steps:
(1)Liquid wax, hydrophilic agent, aliphatic surfactant are uniformly mixed according to proportioning, 50 DEG C is warming up to, stirs evenly, is protected
Under the conditions of 50 DEG C of temperature, it is slowly added into water, is stirred while being added, added subsequent 50 DEG C of continuation of insurance temperature, stir 3h;
(2)After bleeding agent, anti skinning agent and Ph conditioning agents is added, 50 DEG C are kept the temperature, stirs 1.5h,
Then antifoaming agent and acid is added, stirs 20min.
Embodiment 3:Super hydrophilic yarn smooth agent, includes each component of following parts by weight:30 parts of liquid wax, 5 parts of hydrophilic agent, fat
10 parts of fat race surfactant, 5 parts of acid, 5 parts of bleeding agent, 10 parts of anti skinning agent, 2 parts of antifoaming agent, 2 parts of Ph conditioning agents, 60 parts of water.
The mixing that the various n-alkanes that the liquid wax is C10 to C18 form;The hydrophily agent is fatty acid amide;Institute
It is AEO-3 to state aliphatic surfactant;The acid is formic acid.
The bleeding agent is one kind in silicon-containing surfactant class;The anti skinning agent is Macrogol 600;It is described to disappear
Infusion is one kind in polyethers antifoaming agent;The Ph conditioning agents are phosphate.
A method of super hydrophilic yarn smooth agent is prepared, is included the following steps:
(1)Liquid wax, hydrophilic agent, aliphatic surfactant are uniformly mixed according to proportioning, 60 DEG C is warming up to, stirs evenly, is protected
Under the conditions of 60 DEG C of temperature, it is slowly added into water, is added on one side
It stirs on one side, adds subsequent 60 DEG C of continuation of insurance temperature, stir 5h;
(2)After bleeding agent, anti skinning agent and Ph conditioning agents is added, 60 DEG C are kept the temperature, stirs 2h,
Then antifoaming agent and acid is added, stirs 10-30min.
Properties of product are tested
1:Feel is tested
Same money cotton is handled respectively using the smooth agent in control group and embodiment 1-3, and 10 professionals is selected to touch
Test is touched, 1 point worst for feel, and 5 points best for feel, and results are averaged according to marking.
1 feel test result of table
Control group 1 | Control group 2 | Control group 3 | Embodiment 1 | Embodiment 2 | Embodiment 3 | |
Score | 2.5 | 2.8 | 3.1 | 3.6 | 4.2 | 4.5 |
Note:Control group is the yarn smooth agent of routine on the market.
Conclusion:By 1 feel test result of table it is found that for compared to the control group, using smooth obtained by embodiment 1-3
After agent handles cotton, the flexible smooth degree of yarn is more preferable, naturally sliding sense.
2:Stability Determination
Measure resistance to hard water, alkaline-resisting, electrolyte-resistant, the acid-resistant stability of control group and the smooth agent in embodiment 1-3.
2 stability test result of table
Note:Control group is conventional yarn smooth agent on the market.
Conclusion:By 2 stability test result of table it is found that being better than using the smooth agent stability obtained by embodiment 1-3
Control group smooth agent, hence it is evident that reduce risk when use, bring convenience to users.
3:Hydrophily measures
The hydrophily of the smooth agent in control group and embodiment 1-3 is measured using sedimentation.
3 hydrophily test result of table
Control group 1 | Control group 2 | Control group 3 | Embodiment 1 | Embodiment 2 | Embodiment 3 | |
Sedimentation time | 18.42s | 25.33s | 10.78s | 1.02s | 1.45s | 1.62s |
Note:Control group is conventional yarn smooth agent on the market.
Conclusion:By 3 hydrophily test result of table it is found that using the sedimentation time as basis for estimation, the time is shorter, hydrophily
Can be better, it is significantly better than control group smooth agent using the smooth agent hydrophily obtained by embodiment 1-3.
Claims (5)
1. super hydrophilic yarn smooth agent, which is characterized in that include each component of following parts by weight:10 ~ 30 parts of liquid wax, hydrophilic agent 1 ~
5 parts, 1-10 parts of aliphatic surfactant is 1-5 parts sour, 1-5 parts of bleeding agent, 5-10 parts of anti skinning agent, 0.5-2 parts of antifoaming agent,
0.5-2 parts of Ph conditioning agents, 50-60 parts of water.
2. super hydrophilic yarn smooth agent according to claim 1, which is characterized in that 20 parts of the liquid wax, hydrophilic agent 3
Part, 5 parts of aliphatic surfactant, 3 parts of acid, 3 parts of bleeding agent, 8 parts of anti skinning agent, 1 part of antifoaming agent, 1 part of Ph conditioning agents, water 55
Part.
3. super hydrophilic yarn smooth agent according to claim 1 or 2, which is characterized in that the liquid wax is C10 to C18's
The mixing of various n-alkane compositions;The hydrophily agent is one kind in fatty acid amide, hydrophilic class silicone oil, glycerine, fatty ester
Or according to arbitrary proportion composition mixture;The aliphatic surfactant be AEO-3, AEO-7, AEO-9, peregal O-25,
One of paregal O -20 or the mixture formed according to arbitrary proportion;The acid is in lactic acid, formic acid, glacial acetic acid or citric acid
It is a kind of.
4. super hydrophilic yarn smooth agent according to claim 1 or 2, which is characterized in that the bleeding agent is polycarboxylate
One kind in class, polyethenoxy ether class or silicon-containing surfactant class;The anti skinning agent is polyethylene glycol 200, polyethylene glycol
400 or Macrogol 600 in one kind;The antifoaming agent is that organic silicon antifoaming agent, high-carbon alcohol defoaming agent or polyethers disappear
One kind in infusion;The Ph conditioning agents are one kind in citrate, borate or phosphate.
5. a kind of method preparing the super hydrophilic yarn smooth agent of Claims 1-4 any one, which is characterized in that including following
Step:
(1)Liquid wax, hydrophilic agent, aliphatic surfactant are uniformly mixed according to proportioning, 40-60 DEG C is warming up to, stirs evenly,
Under the conditions of 40-60 DEG C of heat preservation, it is slowly added into water, is added on one side
It stirs on one side, adds subsequent 40-60 DEG C of continuation of insurance temperature, stir 2-5h;
After bleeding agent, anti skinning agent and Ph conditioning agents is added, 40-60 DEG C is kept the temperature, stirs 1-2h,
Then antifoaming agent and acid is added, stirs 10-30min.
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CN201810314806.6A CN108442103A (en) | 2018-04-10 | 2018-04-10 | Super hydrophilic yarn smooth agent and preparation method thereof |
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CN201810314806.6A CN108442103A (en) | 2018-04-10 | 2018-04-10 | Super hydrophilic yarn smooth agent and preparation method thereof |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113445318A (en) * | 2021-07-28 | 2021-09-28 | 沂水祥腾化工有限公司 | Yarn smoothing agent for spinning and preparation method thereof |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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JPH04136270A (en) * | 1990-09-25 | 1992-05-11 | Yushiro Chem Ind Co Ltd | Yarn treatment-finishing oil |
CN102619090A (en) * | 2011-01-27 | 2012-08-01 | 上海雅运纺织助剂有限公司 | Smoothening softener composition for cotton and its blended yarns, and preparation method thereof |
CN103614906A (en) * | 2013-10-31 | 2014-03-05 | 安徽东锦化纤科技有限公司 | Regenerated terylene short fiber compound oil agent |
CN105625026A (en) * | 2014-10-26 | 2016-06-01 | 上海肯多拉蜡业有限公司 | Energy-saving yarn smoothing agent and preparation method thereof |
CN107354740A (en) * | 2017-08-17 | 2017-11-17 | 苏州卡佩罗尔高分子材料有限公司 | A kind of weaving smooth agent |
-
2018
- 2018-04-10 CN CN201810314806.6A patent/CN108442103A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH04136270A (en) * | 1990-09-25 | 1992-05-11 | Yushiro Chem Ind Co Ltd | Yarn treatment-finishing oil |
CN102619090A (en) * | 2011-01-27 | 2012-08-01 | 上海雅运纺织助剂有限公司 | Smoothening softener composition for cotton and its blended yarns, and preparation method thereof |
CN103614906A (en) * | 2013-10-31 | 2014-03-05 | 安徽东锦化纤科技有限公司 | Regenerated terylene short fiber compound oil agent |
CN105625026A (en) * | 2014-10-26 | 2016-06-01 | 上海肯多拉蜡业有限公司 | Energy-saving yarn smoothing agent and preparation method thereof |
CN107354740A (en) * | 2017-08-17 | 2017-11-17 | 苏州卡佩罗尔高分子材料有限公司 | A kind of weaving smooth agent |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113445318A (en) * | 2021-07-28 | 2021-09-28 | 沂水祥腾化工有限公司 | Yarn smoothing agent for spinning and preparation method thereof |
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Application publication date: 20180824 |