CN110578251A - fabric antibacterial softener and preparation method thereof - Google Patents
fabric antibacterial softener and preparation method thereof Download PDFInfo
- Publication number
- CN110578251A CN110578251A CN201910856839.8A CN201910856839A CN110578251A CN 110578251 A CN110578251 A CN 110578251A CN 201910856839 A CN201910856839 A CN 201910856839A CN 110578251 A CN110578251 A CN 110578251A
- Authority
- CN
- China
- Prior art keywords
- parts
- deionized water
- esterquat
- eugenol
- hydroxybenzoate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/165—Ethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
the invention discloses a fabric antibacterial softener and a preparation method thereof, wherein the fabric antibacterial softener comprises the following components in parts by weight: 10-15 parts of amino silicone oil, 10-15 parts of esterquat, 1-3 parts of propyl p-hydroxybenzoate, 1-3 parts of carboxymethyl chitosan silver, 2-5 parts of eugenol and 200 parts of deionized water, heating the deionized water to 40 ℃, adding the amino silicone oil and the esterquat, stirring for 15min at constant temperature, then adding the propyl p-hydroxybenzoate, the carboxymethyl chitosan silver and the eugenol, stirring for 20min, and fully mixing to obtain the softener. According to the invention, the cationic surfactant adopts esterquat and esterquat which have excellent smoothness, antistatic property, yellowing resistance, biodegradability and environmental protection, so that the product has excellent softness and better antistatic property, and has excellent sterilization effect.
Description
Technical Field
the invention relates to the related technical field of fabric softeners, in particular to a fabric antibacterial softener and a preparation method thereof.
Background
With the continuous improvement of living standard of people, the fabric softener has higher requirements on hand feeling and texture of various textile materials and also has more specialized requirements on fabric maintenance treatment agents, the fabric is easy to form static after being washed and dried for many times, the comfort of clothes of people is influenced, the fabric softener refers to common liquid for fabric care, the fabric softener adopts a cationic surfactant as a main raw material, the fiber surface can be soft, smooth and antistatic after washing, and meanwhile, the fabric softener is not easy to be stained with ash, and the common fabric softener comprises a clothes softener (moth-proof type) and a clothes softener (antistatic type).
Most of the existing fabric softeners only have the functions of softening clothes and removing static electricity, cannot have the functions of sterilizing and inhibiting bacteria for microorganisms such as bacteria on the clothes, cannot improve the yellowing resistance of the fabric, and have single functionality.
disclosure of Invention
the invention aims to provide a fabric antibacterial softener and a preparation method thereof, and aims to solve the problems that most of the existing fabric softeners in the background art only have the functions of softening clothes and removing static electricity, cannot have the functions of sterilizing and inhibiting bacteria for microorganisms such as bacteria on the clothes, cannot improve the yellowing resistance of the fabric, have single functionality, and are complex in preparation method and inconvenient to popularize and apply.
in order to achieve the purpose, the invention provides the following technical scheme: a fabric antibacterial softener and a preparation method thereof are disclosed, which comprises the following components in parts by weight:
10-15 parts of amino silicone oil, 10-15 parts of esterquat, 1-3 parts of propyl p-hydroxybenzoate, 1-3 parts of carboxymethyl chitosan silver, 2-5 parts of eugenol and 150 parts of deionized water.
Preferably, the composition consists of the following components in parts by weight:
10 parts of amino silicone oil, 10 parts of esterquat, 1 part of propyl p-hydroxybenzoate, 1 part of carboxymethyl chitosan silver, 2 parts of eugenol and 150 parts of deionized water.
Preferably, the composition consists of the following components in parts by weight:
12 parts of amino silicone oil, 12 parts of esterquat, 2 parts of propyl p-hydroxybenzoate, 2 parts of carboxymethyl chitosan silver, 3 parts of eugenol and 170 parts of deionized water
Preferably, the composition consists of the following components in parts by weight:
14 parts of amino silicone oil, 14 parts of esterquat, 2.5 parts of propyl p-hydroxybenzoate, 2.5 parts of carboxymethyl chitosan silver, 4 parts of eugenol and 180 parts of deionized water.
Preferably, the composition consists of the following components in parts by weight:
15 parts of amino silicone oil, 15 parts of esterquat, 3 parts of propyl p-hydroxybenzoate, 3 parts of carboxymethyl chitosan silver, 5 parts of eugenol and 200 parts of deionized water.
A preparation method of a fabric antibacterial softener comprises the following preparation steps:
Preparing materials: taking appropriate amount of amino silicone oil, ester quaternary ammonium salt, propyl p-hydroxybenzoate, carboxymethyl chitosan silver, eugenol and deionized water for later use;
Mixing: adding deionized water into a container, heating to 40 ℃, keeping constant temperature, then gradually adding amino silicone oil, esterquat, propyl hydroxybenzoate, carboxymethyl chitosan silver and eugenol into the deionized water by stirring, and uniformly stirring to fully mix the materials to prepare the softener.
Preferably, in the mixing process, firstly, the amino silicone oil and the esterquat are added into deionized water and stirred for 15min, then, the propyl hydroxybenzoate, the carboxymethyl chitosan silver and the eugenol are added, and the materials in the container are mixed and stirred to be fully and uniformly mixed.
The invention provides a fabric antibacterial softener and a preparation method thereof, and the fabric antibacterial softener has the following beneficial effects:
According to the invention, the cationic surfactant adopts esterquat and esterquat which have excellent smoothness, antistatic property, yellowing resistance, biodegradability and environmental protection, so that the product has excellent softness and antistatic property, and the product has excellent bactericidal effect, and the preparation method is simple and is easy to popularize and apply.
Detailed Description
the technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention.
Example 1:
10 parts of amino silicone oil, 10 parts of esterquat, 1 part of propyl p-hydroxybenzoate, 1 part of carboxymethyl chitosan silver, 2 parts of eugenol and 150 parts of deionized water.
The preparation method comprises the following steps: adding deionized water into a container, heating to 40 ℃, adding amino silicone oil and esterquat, stirring for 15min at constant temperature, adding propyl p-hydroxybenzoate, carboxymethyl chitosan silver and eugenol, stirring for 20min, and mixing completely to obtain the softener.
Example 2:
12 parts of amino silicone oil, 12 parts of esterquat, 2 parts of propyl p-hydroxybenzoate, 2 parts of carboxymethyl chitosan silver, 3 parts of eugenol and 170 parts of deionized water.
The preparation method comprises the following steps: adding deionized water into a container, heating to 40 ℃, adding amino silicone oil and esterquat, stirring for 15min at constant temperature, adding propyl p-hydroxybenzoate, carboxymethyl chitosan silver and eugenol, stirring for 20min, and mixing completely to obtain the softener.
Example 3:
14 parts of amino silicone oil, 14 parts of esterquat, 2.5 parts of propyl p-hydroxybenzoate, 2.5 parts of carboxymethyl chitosan silver, 2.5 parts of eugenol and 180 parts of deionized water.
The preparation method comprises the following steps: adding deionized water into a container, heating to 40 ℃, adding amino silicone oil and esterquat, stirring for 15min at constant temperature, adding propyl p-hydroxybenzoate, carboxymethyl chitosan silver and eugenol, stirring for 20min, and mixing completely to obtain the softener.
Example 4:
15 parts of amino silicone oil, 15 parts of esterquat, 3 parts of propyl p-hydroxybenzoate, 3 parts of carboxymethyl chitosan silver, 5 parts of eugenol and 200 parts of deionized water.
The preparation method comprises the following steps: adding deionized water into a container, heating to 40 deg.C, adding amino silicone oil and esterquat, stirring at constant temperature for 15min, adding propyl p-hydroxybenzoate, carboxymethyl chitosan silver and eugenol, stirring for 20min, and mixing to obtain softener
Comparative example 1:
Selecting common antibacterial softener on the market.
5 pieces of fabric with the same size were treated with the softeners of examples 1, 2, 3, 4 and comparative example 1, respectively, and the test results are shown in the following table:
the examples show an improvement in the percentage of the original fabric properties
| Examples | Stiffness of the sheet | recovery angle of fold | Shear stiffness | Flexural rigidity | antibacterial property | Yellowing resistance |
| Example 1 | 2 | 1.22 | 190 | 0.367 | 92 | 82 |
| Example 2 | 3 | 1.03 | 195 | 0.348 | 95 | 88 |
| example 3 | 4 | 1.14 | 192 | 0.363 | 93 | 93 |
| Example 4 | 3 | 1.08 | 189 | 0.353 | 92 | 87 |
| Comparative example 1 | 1 | 0.67 | 178 | 0.213 | 75 | 45 |
According to the experimental result, the antibacterial effect of the softener prepared by the invention is better than that of the common antibacterial softener on the market.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.
Claims (7)
1. The fabric antibacterial softener and the preparation method thereof are characterized by comprising the following components in parts by weight:
10-15 parts of amino silicone oil, 10-15 parts of esterquat, 1-3 parts of propyl p-hydroxybenzoate, 1-3 parts of carboxymethyl chitosan silver, 2-5 parts of eugenol and 150 parts of deionized water.
2. The fabric antibacterial softener and the preparation method thereof according to claim 1 are characterized by comprising the following components in parts by weight:
10 parts of amino silicone oil, 10 parts of esterquat, 1 part of propyl p-hydroxybenzoate, 1 part of carboxymethyl chitosan silver, 2 parts of eugenol and 150 parts of deionized water.
3. the fabric antibacterial softener and the preparation method thereof according to claim 1 are characterized by comprising the following components in parts by weight:
12 parts of amino silicone oil, 12 parts of esterquat, 2 parts of propyl p-hydroxybenzoate, 2 parts of carboxymethyl chitosan silver, 3 parts of eugenol and 170 parts of deionized water.
4. the fabric antibacterial softener and the preparation method thereof according to claim 1 are characterized by comprising the following components in parts by weight:
14 parts of amino silicone oil, 14 parts of esterquat, 2.5 parts of propyl p-hydroxybenzoate, 2.5 parts of carboxymethyl chitosan silver, 4 parts of eugenol and 180 parts of deionized water.
5. the fabric antibacterial softener of claim 1, which is characterized by comprising 15 parts of amino silicone oil, 15 parts of ester quaternary ammonium salt, 3 parts of propyl p-hydroxybenzoate, 3 parts of carboxymethyl chitosan silver, 5 parts of eugenol and 200 parts of deionized water.
6. The preparation method of the fabric antibacterial softener according to any one of claims 1 to 5, which is characterized by comprising the following preparation steps:
Preparing materials: taking appropriate amount of amino silicone oil, ester quaternary ammonium salt, propyl p-hydroxybenzoate, carboxymethyl chitosan silver, eugenol and deionized water for later use;
Mixing: adding deionized water into a container, heating to 40 ℃, keeping constant temperature, then gradually adding amino silicone oil, esterquat, propyl hydroxybenzoate, carboxymethyl chitosan silver and eugenol into the deionized water by stirring, and uniformly stirring to fully mix the materials to prepare the softener.
7. The method for preparing the antibacterial fabric softener according to claim 6, wherein the method comprises the following steps: in the mixing process, firstly, the amino silicone oil and the esterquat are added into deionized water and stirred for 15min, then, propyl hydroxybenzoate, carboxymethyl chitosan silver and eugenol are added, and the materials in the container are mixed and stirred to be fully and uniformly mixed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910856839.8A CN110578251A (en) | 2019-09-11 | 2019-09-11 | fabric antibacterial softener and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910856839.8A CN110578251A (en) | 2019-09-11 | 2019-09-11 | fabric antibacterial softener and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110578251A true CN110578251A (en) | 2019-12-17 |
Family
ID=68812789
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910856839.8A Pending CN110578251A (en) | 2019-09-11 | 2019-09-11 | fabric antibacterial softener and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110578251A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114517413A (en) * | 2022-03-07 | 2022-05-20 | 广州兰洁宝日用品科技有限公司 | Full-soluble soft tablet and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103031714A (en) * | 2012-12-30 | 2013-04-10 | 浙江喜得宝丝绸科技有限公司 | Silk afterfinishing compound softening agent and preparation method |
| CN103409991A (en) * | 2013-07-18 | 2013-11-27 | 吴江市利达上光制品有限公司 | Clothing antibacterial softener preparation method |
| CN104060471A (en) * | 2014-06-19 | 2014-09-24 | 宁波市川宁环保科技有限公司 | Softener composition and application of composition |
| CN106520403A (en) * | 2016-09-30 | 2017-03-22 | 广西汇智生产力促进中心有限公司 | Silver carboxymethyl chitosan anti-microbial brightening laundry detergent and preparation method thereof |
-
2019
- 2019-09-11 CN CN201910856839.8A patent/CN110578251A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103031714A (en) * | 2012-12-30 | 2013-04-10 | 浙江喜得宝丝绸科技有限公司 | Silk afterfinishing compound softening agent and preparation method |
| CN103409991A (en) * | 2013-07-18 | 2013-11-27 | 吴江市利达上光制品有限公司 | Clothing antibacterial softener preparation method |
| CN104060471A (en) * | 2014-06-19 | 2014-09-24 | 宁波市川宁环保科技有限公司 | Softener composition and application of composition |
| CN106520403A (en) * | 2016-09-30 | 2017-03-22 | 广西汇智生产力促进中心有限公司 | Silver carboxymethyl chitosan anti-microbial brightening laundry detergent and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114517413A (en) * | 2022-03-07 | 2022-05-20 | 广州兰洁宝日用品科技有限公司 | Full-soluble soft tablet and preparation method thereof |
| CN114517413B (en) * | 2022-03-07 | 2022-10-18 | 广州兰洁宝日用品科技有限公司 | Full-soluble soft tablet and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106835698B (en) | Softener composition | |
| CN106758249A (en) | Fabric softener and preparation method thereof | |
| CN104328655A (en) | Antibacterial softener | |
| CN105934506A (en) | Method for stabilizing softening composition | |
| CN104592527A (en) | Preparation method of modified silicone oil surfactant for textile | |
| CN103668960A (en) | Softening agent for processing clothing | |
| CN110578251A (en) | fabric antibacterial softener and preparation method thereof | |
| CN104060471A (en) | Softener composition and application of composition | |
| CN103668963B (en) | A kind of disinfectant fabric softener and preparation method thereof | |
| CN104762812A (en) | Clothes softening agent | |
| CN104818615A (en) | Dyed yarn fabric antibacterial finishing | |
| CN104074049A (en) | Anti-bacterial clothing softening agent | |
| CN103741488B (en) | A kind of quilt cover dressing liquid and preparation method thereof | |
| CN104711854A (en) | Finishing agent for blended fabric made of combed cotton and soybean protein fiber | |
| CN108103785B (en) | Cashmere fabric softener and preparation method thereof | |
| CN108221390B (en) | Hydrophilic softening agent for silk fabrics and preparation method thereof | |
| CN102115975A (en) | Dyeing and finishing technology for Hismer blended fabric | |
| CN103866560A (en) | Washing-free degerming wrinkle-eliminating fabric care agent | |
| CN103666854A (en) | Leather garment stain remover | |
| CN104233798A (en) | Refreshing and ventilating towel softener | |
| CN106118928A (en) | A kind of Antibacterial laundry detergent | |
| CN107829317B (en) | A kind of high-efficiency activated dyestuff loose colour remover and its padding process | |
| CN106520404A (en) | Carboxymethyl chitosan silver anti-microbial low-foam laundry detergent and preparation method thereof | |
| CN105985870A (en) | Quick-drying antimicrobial mildewproof multifunctional laundry detergent and preparation method thereof | |
| JP2006057199A (en) | Treatment agent composition for textile product |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20191217 |
|
| RJ01 | Rejection of invention patent application after publication |