CN106675817A - Compound low-foam laundry detergent and preparation method thereof - Google Patents

Compound low-foam laundry detergent and preparation method thereof Download PDF

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Publication number
CN106675817A
CN106675817A CN201611213515.5A CN201611213515A CN106675817A CN 106675817 A CN106675817 A CN 106675817A CN 201611213515 A CN201611213515 A CN 201611213515A CN 106675817 A CN106675817 A CN 106675817A
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China
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type low
compositional type
low foam
laundry liquid
liquid according
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Pending
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CN201611213515.5A
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Chinese (zh)
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叶宗瑞
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Individual
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0026—Low foaming or foam regulating compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/34—Organic compounds containing sulfur
    • C11D3/3481—Organic compounds containing sulfur containing sulfur in a heterocyclic ring, e.g. sultones or sulfolanes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/008—Polymeric surface-active agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C11D1/24—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds containing ester or ether groups directly attached to the nucleus
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention belongs to the field of daily chemical products and specifically relates to a compound low-foam laundry detergent and a preparation method thereof. The compound low-foam laundry detergent provided by the invention comprises the following components by weight percent: 10-15% of anionic surfactant, 4-8% of non-ionic surface active agent, 3-6% of foaming agent, 6-14% of de-foaming agent, 3-6% of bamboo leaf extract, 1.5-3% of essence, 0.3-1.5% of thickening agent, 0.2-0.5% of preservative and 46-72% of water. According to the invention, the component compound is reasonable and scientific and all the components have a synergistic effect, so that the product has higher detergency and low-foam easy-cleaning effect. Furthermore, the formula of the laundry detergent is optimized according to the invention and the detergency and low-foam easy-cleaning effect of the laundry detergent formed after the optimization are maximized.

Description

A kind of Compositional type low foam laundry liquid and preparation method thereof
Technical field
The invention belongs to cosmetics of everyday use field, and in particular to a kind of Compositional type low foam laundry liquid and preparation method thereof.
Background technology
It is well known that containing a large amount of filler Matrii Sulfas Exsiccatus without any cleaning function in detergent, in resource and energy side Face causes greatly waste, and dust pollution can be also caused aborning, is unfavorable for environmental protection, and liquid detergent is with resourceful water Replace Matrii Sulfas Exsiccatus, adopt surfactant biodegradable in the environment significantly solve for main component detergent for The pollution that environment is caused, on the original basis liquid detergent more focus on the safety for using, such as antibacterial, soft so, gently do not hinder The addition of the concepts such as handss, rises product price.The many hardly possible rinsed cleans of liquid detergent foam are a ratios of presently commercially available liquid detergent Larger shortcoming, this be because traditional liquid detergent surface-active contents are high, builder addition causes not only to waste more than foam less Water resource increases laundry cost, is unfavorable for energy-saving and emission-reduction and environmental protection.
Chinese patent CN103013723B discloses a kind of Liquid laundry composition of Low-foam and easily rinsing, the invention liquid detergent group Containing defoamer, fatty acid soaps, nonionic surfactant, anion surfactant, chelating agen, thickening agent etc. in compound, Using modified silicon oil as defoamer.The addition of organosilicon can quick froth breaking, but liquid detergent easily drift property can not be improved, add The liquid detergent of organosilicon formula still suffers from foam through repeatedly rinsing, and stability of the organosilicon in liquid detergent is also industry An interior generally acknowledged difficult problem.
The content of the invention
It is an object of the invention to provide a kind of Compositional type low foam laundry liquid and preparation method thereof, to solve prior art in The problems referred to above of presence.
Compositional type low foam laundry liquid of the present invention, including following components and its mass percent：
Anion surfactant 10~15%, nonionic surfactant 4~8%, foaming agent 3~6%, defoamer 6 ~14%, Folium Bambosae extract 3~6%, essence 1.5~3%, thickening agent 0.3~1.5%, preservative 0.2~0.5% and water 46 ~72%.
Preferably, the Compositional type low foam laundry liquid is made up of following components and its mass percent：
Anion surfactant 12.5%, nonionic surfactant 6%, foaming agent 4.5%, defoamer 10%, bamboo Leaf extract 4.5%, essence 2.25%, thickening agent 0.9%, preservative 0.35% and water 59%.
Preferably, described anion surfactant is dodecylbenzene sodium sulfonate.
Preferably, described nonionic surfactant by polypropylene glycol ethylene oxide adduct and sucrose fatty acid ester In mass ratio 2:3 compositions.
Preferably, the ethylene oxide adduct of described polypropylene glycol is to be in mass ratio with oxirane by polypropylene glycol 1:3~10 additions gained.
Preferably, described foaming agent is sodium lauryl sulphate.
Preferably, described defoamer is polydimethylsiloxane.
Preferably, described thickening agent is polyacrylate.
Further preferably, described preservative is Methylisothiazolinone.
Simultaneously present invention also offers a kind of preparation method of Compositional type low foam laundry liquid, comprises the following steps：In configuration Anion surfactant, nonionic surfactant, foaming agent, thickening agent and defoamer are added in the water of the amount of component 1/3, is stirred Mix to being completely dissolved, stirring is lower to add preservative, Folium Bambosae extract and essence, adds remaining water, stirs, adjust pH to 7.5~8.5, obtain final product.
Dodecylbenzene sodium sulfonate CAS：25155-30-0；Sucrose fatty acid ester CAS：37318-31-3；Dodecane Base sodium sulfate CAS：151-21-3；Polydimethylsiloxane CAS：9016-00-6；Polyacrylate CAS：107-10- 8；Methylisothiazolinone CAS：2682-20-4.
The present invention has selected anionic surfactant sodium dodecylbenzene sulfonate, nonionic surfactant polypropylene glycol Ethylene oxide adduct and sucrose fatty acid ester etc. as liquid detergent main component, dodecylbenzene sodium sulfonate is a kind of property The excellent anion surfactant of energy, has good degreasing power and has the surface tension for reducing water well and moistening, oozes The performance of saturating and emulsifying, stable chemical nature, all without decomposition in acid or alkaline medium and under heating condition；Poly- the third two The ethylene oxide adduct of alcohol belongs to polyether nonionic surfactant, the spy for having good resistance to hard water ability and low foaming characteristic Point；Be readily biodegradable due to sucrose ester, can for absorption of human body, it is harmless, do not stimulate skin the characteristics of, by both Green nonionic surfactant is compounded with dodecylbenzene sodium sulfonate anion surfactant, imparts liquid detergent excellent The characteristics of good dirt-removing power and environmental protection.
The characteristics of polydimethylsiloxane has froth breaking rapid and suppresses the foam time long, does not affect the basic of bubbling system Property, and diffusibility, good penetrability, stable chemical nature.
Thickening agent can improve thing system viscosity, make thing system keep uniform stable suspended state or milkiness state.Add Folium Bambosae extract further increases the antibiotic and sterilizing ability of liquid detergent.
Compared with prior art, the beneficial effect of Compositional type low foam laundry liquid of the present invention is：Each component compounding of the present invention is closed Reason, science, each component synergism so that product has functions that dirt-removing power is strong and Low-foam and easily is rinsed, further this The bright formula to liquid detergent is carried out preferably, preferably after composition make the dirt-removing power and Low-foam and easily of liquid detergent rinse effect maximum Change.
Specific embodiment
Below by specific embodiment the present invention is described in further details with comparative example, these embodiments are only used for example The purpose of card, is in no way intended to limit protection scope of the present invention.
Folium Bambosae extract is purchased from the favorable to the people pharmaceutcal corporation, Ltd of Suichang of Zhejiang Province.
Embodiment 1-3, comparative example 1-2
The Compositional type low foam laundry liquid component and mass percent of embodiment 1-3 and comparative example 1-2 is as shown in table 1.
The liquid detergent component of table 1 and mass percent
Embodiment 1-3 is by polypropylene glycol and oxirane with the ethylene oxide adduct of polypropylene glycol in comparative example 1-2 In mass ratio it is 1:6 additions gained.
Comparative example 1 is with the difference of embodiment 2：Nonionic surfactant by polypropylene glycol ethylene oxide adduct and Sucrose fatty acid ester in mass ratio 1:1 composition.
Comparative example 2 is with the difference of embodiment 2：Folium Bambosae extract is not added, anion surfactant and non-is increased The consumption of ionic surface active agent.
The preparation method of the Compositional type low foam laundry liquid of embodiment 2：Anionic surface is added in the water of the configuration amount of component 1/3 Activating agent, nonionic surfactant, foaming agent, thickening agent and defoamer, stir to being completely dissolved, and stirring is lower to add anti-corrosion Agent, Folium Bambosae extract and essence, add remaining water, stir, and adjust pH to 7.5~8.5, obtain final product.
The preparation method of the Compositional type low foam laundry liquid of embodiment 1, embodiment 3 and comparative example 1-2 and the preparation of embodiment 2 Method is similar to.
Properties of product evaluation test
For checking, the present invention prepares rinsing and the detergency ability of liquid detergent, the liquid detergent of embodiment preparation is respectively adopted with And standard liquid detergent carries out foam height experiment and decontamination test experiments, the standard liquid detergent is standard used in GB test Liquid detergent, purchase is from Chinese daily chemical industry academy.
(1) foam height experiment
Method of testing：
1. washing machine is cleaned up with tap water, be not added with detergent by standardization program and clean up towel, dried standby With every towel about 45g；
2. washing hard water is prepared with anhydrous calcium chloride and magnesium chloride, the water hardness is 250mg/kg (Ca2+:Mg2+=3:2), Water temperature is adjusted to 30 ± 2 DEG C；
3. the hard water 1L in 2 is added in basin, 4.0g standards liquid detergent or liquid detergent to be measured is sunk to, is put into after stirring and dissolving Towel in 1 one, towel soaks；
4. by the positive and negative each stranding of towel 10 times, wring out, measure 600mL cleaning mixture, the liquid detergent is standard liquid detergent, implements The Compositional type low foam laundry liquid that example 1-3 and comparative example 1-3 are prepared, with Ross-Miles foam meters GB/T 13173- are pressed 2008 regulations determine foam height (record start foam height)；
5. outwell remaining cleaning mixture in basin and clean the hard water 2L added in washbowl in 2, respectively wash by rubbing with the hands towel is positive and negative 10 times, measure 600mL rinsing liquids and determine initial foam height；
6. repeat 5 steps 3 time, and the foam height data of cleaning mixture and rinsing liquid are tested with Roche foam meter.
Foam height (mm) data of cleaning mixture and rinsing liquid are tested with Roche foam meter, as a result as shown in table 2.
Table 2 tests foam height data with Roche foam meter
As shown in Table 2, compare with comparative example 1-2 with standard liquid detergent, liquid detergent prepared by the present invention is in identical rinsing time Several lower defoaming effects more preferably, illustrate to add by the ethylene oxide adduct and sucrose fatty acid ester in mass ratio 2 of polypropylene glycol:3 Compared with 1:More preferably, the addition of Folium Bambosae extract does not only reduce the froth breaking of liquid detergent to the nonionic surfactant effect of 1 composition Performance makes on the contrary antifoam performance increase, and illustrates that Folium Bambosae extract is further carried with the other components synergism in liquid detergent The high performance of liquid detergent；In addition compared with embodiment 1,3, the foam height produced under identical rinsing times is more for embodiment 2 It is low, it follows that the proportioning raw materials that embodiment 2 is selected are the proportioning raw materials of optimization.
(2) detergency test experiment
1st, experimental subject：The Compositional type low foam laundry liquid that standard liquid detergent, embodiment 1-3 and comparative example 1-2 are prepared.
2nd, method of testing：With reference to GB/T13174-2008 standards《Dress material is with detergent detergency and circulates scourability Determine》Specified in method tested, detergency ratio is as shown in table 3.
The liquid detergent detergency test result of table 3
Test index Embodiment 1 Embodiment 2 Embodiment 3 Standard liquid detergent Comparative example 1 Comparative example 2
Carbon black R (ratio) 1.153 1.202 1.184 1.00 1.110 1.112
Albumen R (ratio) 1.235 1.267 1.244 1.00 1.165 1.179
Sebum R (ratio) 1.275 1.325 1.288 1.00 1.214 1.225
From table 3 it can be seen that the Compositional type low foam laundry liquid prepared in embodiment of the present invention 1-3, its dirt-removing power is higher than Standard liquid detergent and comparative example 1-2, illustrate the ethylene oxide adduct of nonionic surfactant in the present invention by polypropylene glycol With sucrose fatty acid ester in mass ratio 2:3 compared with 1:More preferably, the addition of Folium Bambosae extract improves the soil release performance of liquid detergent to 1 effect Energy；And the Compositional type low foam laundry liquid of embodiment 2 is compared with embodiment 1 and the clean effect of embodiment 3 more preferably, is that the present invention is preferable to carry out Example.
The above is only the preferred embodiment of the present invention, it is noted that it is right that above-mentioned preferred implementation is not construed as The restriction of the present invention, protection scope of the present invention should be defined by claim limited range.For the art For those of ordinary skill, without departing from the spirit and scope of the present invention, some improvements and modifications can also be made, these change Enter and retouch also to should be regarded as protection scope of the present invention.

Claims (10)

1. a kind of Compositional type low foam laundry liquid, it is characterised in that including following components and its mass percent：
Anion surfactant 10~15%, nonionic surfactant 4~8%, foaming agent 3~6%, defoamer 6~ 14%th, Folium Bambosae extract 3~6%, essence 1.5~3%, thickening agent 0.3~1.5%, preservative 0.2~0.5% and water 46~ 72%.
2. Compositional type low foam laundry liquid according to claim 1, it is characterised in that by following components and its mass percent Composition：
Anion surfactant 12.5%, nonionic surfactant 6%, foaming agent 4.5%, defoamer 10%, Folium Bambusae are carried Take thing 4.5%, essence 2.25%, thickening agent 0.9%, preservative 0.35% and water 59%.
3. Compositional type low foam laundry liquid according to claim 1 and 2, it is characterised in that described anion surface active Agent is dodecylbenzene sodium sulfonate.
4. Compositional type low foam laundry liquid according to claim 1 and 2, it is characterised in that described non-ionic surface active Agent by polypropylene glycol ethylene oxide adduct and sucrose fatty acid ester in mass ratio 2:3 compositions.
5. Compositional type low foam laundry liquid according to claim 4, it is characterised in that the oxirane of described polypropylene glycol It by polypropylene glycol and oxirane is 1 that addition product is in mass ratio:3~10 additions gained.
6. Compositional type low foam laundry liquid according to claim 1 and 2, it is characterised in that described foaming agent is dodecane Base sodium sulfate.
7. Compositional type low foam laundry liquid according to claim 1 and 2, it is characterised in that described defoamer is poly- diformazan Radical siloxane.
8. Compositional type low foam laundry liquid according to claim 1 and 2, it is characterised in that described thickening agent is polypropylene Acid esters.
9. Compositional type low foam laundry liquid according to claim 1 and 2, it is characterised in that described preservative is that methyl is different Thiazolinone.
10. the preparation method of the Compositional type low foam laundry liquid according to any one of claim 1-9, it is characterised in that include Following steps：Anion surfactant, nonionic surfactant, foaming agent, increasing are added in the water of the configuration amount of component 1/3 Thick dose and defoamer, stir to being completely dissolved, and stirring is lower to add preservative, Folium Bambosae extract and essence, adds remaining water, stirs Mix uniform, adjust pH to 7.5~8.5, obtain final product.
CN201611213515.5A 2016-12-23 2016-12-23 Compound low-foam laundry detergent and preparation method thereof Pending CN106675817A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111356367A (en) * 2017-10-03 2020-06-30 索理思科技公司 Compositions and methods for inhibiting microbial attachment to surfaces
CN111743478A (en) * 2020-06-15 2020-10-09 天津市艳胜工贸有限公司 KBS plant extraction wet tissue
RU2799595C2 (en) * 2017-10-03 2023-07-07 Соленис Текнолоджиз, Л.П. Composition and method intended to suppress microbial adhesion on surfaces

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103013723A (en) * 2012-12-21 2013-04-03 纳爱斯集团有限公司 Low-foam laundry detergent composite facilitating rinsing
CN104250585A (en) * 2013-06-28 2014-12-31 青岛康泰鑫环保科技有限公司 High efficiency and low foam liquid laundry detergent
CN104830561A (en) * 2015-03-16 2015-08-12 周小燕 Super-concentrated low-foam high-efficient laundry detergent
CN105462705A (en) * 2014-09-10 2016-04-06 天津市天亨洗涤剂有限公司 Laundry detergent

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103013723A (en) * 2012-12-21 2013-04-03 纳爱斯集团有限公司 Low-foam laundry detergent composite facilitating rinsing
CN104250585A (en) * 2013-06-28 2014-12-31 青岛康泰鑫环保科技有限公司 High efficiency and low foam liquid laundry detergent
CN105462705A (en) * 2014-09-10 2016-04-06 天津市天亨洗涤剂有限公司 Laundry detergent
CN104830561A (en) * 2015-03-16 2015-08-12 周小燕 Super-concentrated low-foam high-efficient laundry detergent

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111356367A (en) * 2017-10-03 2020-06-30 索理思科技公司 Compositions and methods for inhibiting microbial attachment to surfaces
EP3691451A4 (en) * 2017-10-03 2021-07-07 Solenis Technologies, L.P. Composition and method for inhibiting microbial adhesion on surfaces
CN111356367B (en) * 2017-10-03 2022-05-03 索理思科技公司 Compositions and methods for inhibiting microbial attachment to surfaces
RU2799595C2 (en) * 2017-10-03 2023-07-07 Соленис Текнолоджиз, Л.П. Composition and method intended to suppress microbial adhesion on surfaces
CN111743478A (en) * 2020-06-15 2020-10-09 天津市艳胜工贸有限公司 KBS plant extraction wet tissue

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Application publication date: 20170517