CN105732120B - A kind of preparation method of photocuring ceramics renovation agent - Google Patents
A kind of preparation method of photocuring ceramics renovation agent Download PDFInfo
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- CN105732120B CN105732120B CN201610110065.0A CN201610110065A CN105732120B CN 105732120 B CN105732120 B CN 105732120B CN 201610110065 A CN201610110065 A CN 201610110065A CN 105732120 B CN105732120 B CN 105732120B
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- renovation agent
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5025—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with ceramic materials
- C04B41/5035—Silica
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Devices For Post-Treatments, Processing, Supply, Discharge, And Other Processes (AREA)
Abstract
The invention discloses a kind of preparation method of photocuring ceramics renovation agent, comprise the following steps：The first step, two kinds of light-cured resins are well mixed and form hybrid resin A；Second step, distilled water and ethanol are well mixed and form mixture B；3rd step, it is material C from ball-shaped silicon micro powder；4th step, it is material D from silica；5th step, it is material E from silane coupler；6th step, mixed material, forms mixture F in proportion；7th step, mixture F is stirred, redisperse forms homogeneous dispersion G；8th step, homogeneous dispersion G is stirred, until material liquid occurs and is layered admittedly；9th step, the ethanol and distilled water being heated in material volatilize completely；Tenth step, heat and stir, until transparence is presented in material, composite completes.The preparation method of the photocuring ceramics renovation agent of the present invention, obtain a kind of quick renovation agent for repairing the ceramic surface slight flaws such as firing defects such as pin hole, pinhole, contracting glaze.
Description
Technical field
The present invention relates to a kind of preparation method of photocuring ceramics renovation agent, belong to field of ceramic preparation technology.
Background technology
Ceramics are to be made using natural clay and various natural minerals as primary raw material by crushing to be kneaded, be molded and calcine
Material various products；People were referred to as the article fired in special kiln high temperature being fabricated to clay and made pottery in the past
Porcelain, ceramics are the general names of pottery and porcelain；Because ceramic is to fire to form at a high temperature of 1300 DEG C or so, glaze planar defect
Generation be difficult to avoid that using simple, easy-operating later stage renovation technique is repaired to these flaws, can improve factory
Yield rate, and can reduces factory and defect ware is smashed, buries the expense of processing, undoubtedly both increased the benefit for one, and energy-conserving and environment-protective
New technology.
The content of the invention
(1) technical problems to be solved
To solve the above problems, the present invention proposes a kind of preparation method of photocuring ceramics renovation agent, obtain a kind of fast
Speed repairs the renovation agent of the firing defects such as ceramic surface slight flaws such as pin hole, pinhole, contracting glaze.
(2) technical scheme
The preparation method of the photocuring ceramics renovation agent of the present invention, comprises the following steps：
The first step, by two kinds of light-cured resins of sartomer cn996 and sartomr sr454 with 3:1 ratio, electricity consumption
Dynamic agitator is well mixed, and forms hybrid resin A；
Second step, by distilled water and ethanol with 2:1 ratio, is well mixed with electric mixer, forms mixture B；
3rd step, the ball-shaped silicon micro powder for being 600nm from particle diameter are material C；
4th step, the silica for being 40nm from particle diameter are material D；
5th step, it is material E from silane coupler 6030；
6th step, according to A:B:C:D:E=100g:300g:240g:60g:8.4g scalemic thereof material, form mixture
F；
7th step, first mixture F is stirred with electric mixer, then scattered 30 minutes, the shape with ultrasonic wave separating apparatus
Into homogeneous dispersion G；
8th step, homogeneous dispersion G is stirred with 200 turns per minute of speed with electric mixer, until liquid occurs in material
Gu layering；
9th step, the material for solid-liquid layering occurred is heated, temperature is constant at 80 DEG C, continues to use electric mixer
Continue to stir with 100 turns per minute of speed, until the ethanol and distilled water in material volatilize completely；
Tenth step, heated material is to 120 DEG C and keeps constant, continues electric mixer and is stirred with 100 turns per minute of speed
Mix, until each component crosslinking is completed in material, show transparence, composite completes.
11st step, 0.5g light triggers are added under the conditions of lucifuge, heating-up temperature is transferred to 60 DEG C, electric stirring composite wood
Material is until uniformly；
12nd step, the ceramic colour table provided by factory, adds various pigments in the composite, and electric stirring is uniform,
The addition of each pigment is constantly adjusted, until the color of composite is consistent with colour table.
Further, the light trigger is camphorquinone.
(3) beneficial effect
Compared with prior art, the preparation method of photocuring ceramics renovation agent of the invention, reparation speed is fast, of the invention
Repair materials realize the instantaneous hardening of material using visible-light curing technology, only ten seconds used times time of material solidification, entirely repair
The multiple process used time is no more than 3 minutes；Color inhibition, basic material of the invention from the high resin of ageing-resistant degree, charges and
Auxiliary agent, the color inhibition phase of dummy was up to more than 10 years；Repair materials visually close to the texture of ceramics, are easy to be formed well
Repairing effect.
Embodiment
The preparation method of the photocuring ceramics renovation agent of the present invention, comprises the following steps：
The first step, by two kinds of light-cured resins of sartomer cn996 and sartomr sr454 with 3:1 ratio, electricity consumption
Dynamic agitator is well mixed, and forms hybrid resin A；
Second step, by distilled water and ethanol with 2:1 ratio, is well mixed with electric mixer, forms mixture B；
3rd step, the ball-shaped silicon micro powder for being 600nm from particle diameter are material C；
4th step, the silica for being 40nm from particle diameter are material D；
5th step, it is material E from silane coupler 6030；
6th step, according to A:B:C:D:E=100g:300g:240g:60g:8.4g scalemic thereof material, form mixture
F；
7th step, first mixture F is stirred with electric mixer, then scattered 30 minutes, the shape with ultrasonic wave separating apparatus
Into homogeneous dispersion G；
8th step, homogeneous dispersion G is stirred with 200 turns per minute of speed with electric mixer, until liquid occurs in material
Gu layering；
9th step, the material for solid-liquid layering occurred is heated, temperature is constant at 80 DEG C, continues to use electric mixer
Continue to stir with 100 turns per minute of speed, until the ethanol and distilled water in material volatilize completely；
Tenth step, heated material is to 120 DEG C and keeps constant, continues electric mixer and is stirred with 100 turns per minute of speed
Mix, until each component crosslinking is completed in material, show transparence, composite completes.
11st step, 0.5g light triggers are added under the conditions of lucifuge, heating-up temperature is transferred to 60 DEG C, electric stirring composite wood
Material is until uniformly；
12nd step, the ceramic colour table provided by factory, adds various pigments in the composite, and electric stirring is uniform,
The addition of each pigment is constantly adjusted, until the color of composite is consistent with colour table.
The light trigger is camphorquinone.
The application method of the repair materials of the present invention is as follows：
The first step, with electric grinding machine polishing ceramic flaw part to be repaired, form coarse pit；
Second step, repair materials press-in Ao Keng And are allowed to smooth with knife is chosen；
3rd step, pastes overlay on repair materials；
4th step, irradiate dummy 10 seconds with portable photo solidification machine；
5th step, takes plastic foil off, and dummy is gently ground with fine sandpaper to flat smooth, repairs and completes.Reality recited above
It is only that the preferred embodiment of the present invention is described to apply example, and not the spirit and scope of the present invention are defined.
On the premise of not departing from design concept of the present invention, various modifications that ordinary people in the field makes to technical scheme and
Improve, protection scope of the present invention all should be dropped into, the claimed technology contents of the present invention, being all documented in right will
Ask in book.
Claims (2)
- A kind of 1. preparation method of photocuring ceramics renovation agent, it is characterised in that：Comprise the following steps：The first step, by two kinds of light-cured resins of sartomer cn996 and sartomr sr454 with 3:1 ratio, uses electric mixing Mix device to be well mixed, form hybrid resin A；Second step, by distilled water and ethanol with 2:1 ratio, is well mixed with electric mixer, forms mixture B；3rd step, the ball-shaped silicon micro powder for being 600nm from particle diameter are material C；4th step, the silica for being 40nm from particle diameter are material D；5th step, it is material E from silane coupler 6030；6th step, according to A:B:C:D:E=100g:300g:240g:60g:8.4g scalemic thereof material, form mixture F；7th step, first mixture F is stirred with electric mixer, then it is scattered 30 minutes with ultrasonic wave separating apparatus, formed even Matter dispersion G；8th step, homogeneous dispersion G is stirred with 200 turns per minute of speed with electric mixer, until material liquid occurs and divided admittedly Layer；9th step, the material for solid-liquid layering occurred is heated, temperature is constant at 80 DEG C, continues with electric mixer with every The speed of 100 turns of minute continues to stir, until the ethanol and distilled water in material volatilize completely；Tenth step, heated material is to 120 DEG C and keeps constant, continues electric mixer and is stirred with 100 turns per minute of speed, directly Into material, each component crosslinking is completed, and shows transparence, composite completes；11st step, 0.5g light triggers are added under the conditions of lucifuge, heating-up temperature is transferred to 60 DEG C, and electric stirring composite is straight To uniform；12nd step, the ceramic colour table provided by factory, adds various pigments, electric stirring is uniform, constantly in the composite The addition of each pigment is adjusted, until the color of composite is consistent with colour table.
- 2. the preparation method of photocuring ceramics renovation agent according to claim 1, it is characterised in that：The light trigger is Camphorquinone.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610110065.0A CN105732120B (en) | 2016-02-29 | 2016-02-29 | A kind of preparation method of photocuring ceramics renovation agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610110065.0A CN105732120B (en) | 2016-02-29 | 2016-02-29 | A kind of preparation method of photocuring ceramics renovation agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105732120A CN105732120A (en) | 2016-07-06 |
| CN105732120B true CN105732120B (en) | 2018-02-13 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610110065.0A Expired - Fee Related CN105732120B (en) | 2016-02-29 | 2016-02-29 | A kind of preparation method of photocuring ceramics renovation agent |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102552046A (en) * | 2012-01-13 | 2012-07-11 | 东华大学 | Composite dental restoration resin with silica microspheres as filler and preparation method thereof |
| CN104893631A (en) * | 2014-03-05 | 2015-09-09 | 余博 | Ceramic repairing material |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11267479A (en) * | 1998-03-20 | 1999-10-05 | Sumitomo Electric Ind Ltd | Porous silica glass membrane and its production |
-
2016
- 2016-02-29 CN CN201610110065.0A patent/CN105732120B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102552046A (en) * | 2012-01-13 | 2012-07-11 | 东华大学 | Composite dental restoration resin with silica microspheres as filler and preparation method thereof |
| CN104893631A (en) * | 2014-03-05 | 2015-09-09 | 余博 | Ceramic repairing material |
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| CN105732120A (en) | 2016-07-06 |
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