CN105838261B - A kind of polishing grinding material and preparation method thereof - Google Patents
A kind of polishing grinding material and preparation method thereof Download PDFInfo
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- CN105838261B CN105838261B CN201610256613.0A CN201610256613A CN105838261B CN 105838261 B CN105838261 B CN 105838261B CN 201610256613 A CN201610256613 A CN 201610256613A CN 105838261 B CN105838261 B CN 105838261B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09G—POLISHING COMPOSITIONS; SKI WAXES
- C09G1/00—Polishing compositions
- C09G1/02—Polishing compositions containing abrasives or grinding agents
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/14—Anti-slip materials; Abrasives
- C09K3/1454—Abrasive powders, suspensions and pastes for polishing
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Abstract
The present invention relates to a kind of polishing grinding material, including the material in terms of parts by weight as follows:100 parts of bonding agent, 5 15 parts of additive, 100 200 parts of aggregate, 15 parts of accelerating agent, 15 parts of initiator.The invention also discloses the aggregate processing method and the preparation method of polishing grinding material.Polishing grinding material shrinkage of the invention is small, voidage is few, and grinding and polishing effect are good, is processed stone material and ceramic surface quality is high.It can be widely applied in corase grinding, fine grinding and the fine grinding of stone material and ceramics, have a good application prospect.
Description
Technical field
The present invention relates to a kind of rubbing down material, and in particular to a kind of polishing grinding material for being applied to stone material and ceramic grinding
And preparation method thereof.
Background technology
Stone material and Ceramic manufacturing industry need to carry out grinding processing to product surface using grinding-material, are wanted with meeting to use
Ask.Unsaturated polyester resin is one of currently used rubbing down material bonding agent.But it releases moisture when curing, and makes product volume
Shrink greatly, the porosity is high, and appearance property is bad, and service life is short, also poor by the stone material and ceramic surface quality of its processing.
The content of the invention
The purpose of the present invention is for deficiency of the prior art, there is provided a kind of polishing grinding material, the polishing grinding material
Material has the features such as porosity is low, service life length, the grinding of progress stone material and ceramics and polishing effect are good, and the accuracy of manufacture is high,
Have a good application prospect.
To achieve the above object, the invention discloses following technical solution:
A kind of polishing grinding material, including the material in terms of parts by weight as follows:
100 parts of bonding agent, 5-15 parts of additive, 100-200 parts of aggregate, 1-5 parts of accelerating agent, 1-5 parts of initiator;
Wherein, the bonding agent includes the material in terms of following parts by weight:
191#1 part of unsaturated polyester (UP) resin;0.05~0.10 part of triallyl cyanurate;Dibutyl phthalate
0.05~0.10 part and 0.005~0.01 part of naphthalenesulfonate formaldehyde condensation compound.
Further, the material that the additive is included in terms of following parts by weight, which is uniformly mixed, to be formed:
21 parts of portland cement, 9 parts of aluminate cement, 70 parts of building gypsum plaster.
Further, the material that the aggregate is included in terms of following parts by weight is made:
100 parts of coal gas slugging, 15~25 parts of Ludox, 15~25 parts of boric acid, 10~20 parts of aluminium powder.
The invention also discloses a kind of aggregate processing method as described above, include the following steps:
--- --- dry --- adding 15~25 parts of boric acid --- exists 15~25 parts of 100 parts+Ludox of coal gas slugging for mixing
200 DEG C~400 DEG C heating in vacuum --- add aluminium powder 10~20 parts --- ground and mixed is uniform --- to be heated to 1000 in high temperature furnace
DEG C --- self- propagating is burnt till --- with hammer high speed disintegrator crush --- is classified to needed for granularity simultaneously mix in proportion in advance
It is spare.
Wherein, the granularity is respectively 120 mesh, 200 mesh, 325 mesh, 600 mesh and 1000 mesh.
The fineness and dosage composition of the aggregate of difference grinding type are as follows:
The granularity mass ratio of aggregate when being roughly ground for product is:4 parts of 120 mesh, 2 parts of 200 mesh, the 1 of 325 mesh
Part;
The granularity mass ratio of aggregate during for product fine grinding is:4 parts of 200 mesh, 2 parts of 325 mesh, the 1 of 600 mesh
Part;
The granularity mass ratio of aggregate when being refined for product is:4 parts of 325 mesh, 2 parts of 600 mesh, the 1 of 1000 mesh
Part;
The aggregate of variant granularity is mixed according to the above ratio before rubbing down product forming ingredient, different grindings is obtained and uses
The aggregate on way.
The invention also discloses a kind of preparation method of polishing grinding material as described above, include the following steps:
(1) 5-15 parts of 100-200 parts of aggregate and additive are subjected to abundant batch mixing in proportion, obtain mixed dry material;
(2) 1-5 parts of 100 parts of bonding agent and accelerating agent are subjected to abundant batch mixing in proportion, obtain mixed glue solution;
(3) mixed dry material that step (1) obtains is added in the mixed glue solution that step (2) obtains, carries out abundant batch mixing, obtain
To mixture;
(4) in the mixture for obtaining 1-5 parts of addition steps (3) of initiator, it is sufficiently mixed, is finally mixed
Material;
(5) the final mixture that step (4) obtains is poured into mould, is vibrated, when cold curing 12~24 is small after
Form removal obtains the polishing grinding material product.
A kind of polishing grinding material disclosed by the invention and preparation method thereof, has the advantages that:
Polishing grinding material shrinkage of the invention is small, voidage is few, and grinding and polishing effect are good, is processed stone material and pottery
Porcelain surface quality is high.It can be widely applied in corase grinding, fine grinding and the fine grinding of stone material and ceramics, have a good application prospect.
Embodiment
With reference to embodiment, the invention will be further described.
A kind of polishing grinding material, including the material in terms of parts by weight as follows:
100 parts of bonding agent, 5-15 parts of additive, 100-200 parts of aggregate, 1-5 parts of accelerating agent, 1-5 parts of initiator;
Wherein, the bonding agent includes the material in terms of following parts by weight:
191#1 part of unsaturated polyester (UP) resin;0.05~0.10 part of triallyl cyanurate;Dibutyl phthalate
0.05~0.10 part and 0.005~0.01 part of naphthalenesulfonate formaldehyde condensation compound.
In the present invention, the additive is uniformly mixed including the material in terms of following parts by weight and forms:
21 parts of portland cement, 9 parts of aluminate cement, 70 parts of building gypsum plaster.
In the present invention, the material that the aggregate is included in terms of following parts by weight is made:
100 parts of coal gas slugging, 15~25 parts of Ludox, 15~25 parts of boric acid, 10~20 parts of aluminium powder.
The invention also discloses a kind of aggregate processing method as described above, include the following steps:
--- --- dry --- adding 15~25 parts of boric acid --- exists 15~25 parts of 100 parts+Ludox of coal gas slugging for mixing
200 DEG C~400 DEG C heating in vacuum --- add aluminium powder 10~20 parts --- ground and mixed is uniform --- to be heated to 1000 in high temperature furnace
DEG C --- self- propagating is burnt till --- with hammer high speed disintegrator crush --- is classified to needed for granularity simultaneously mix in proportion in advance
It is spare.
Wherein, the granularity is respectively 120 mesh, 200 mesh, 325 mesh, 600 mesh and 1000 mesh.
The fineness and dosage composition of the aggregate of difference grinding type are as follows:
The granularity mass ratio of aggregate when being roughly ground for product is:4 parts of 120 mesh, 2 parts of 200 mesh, the 1 of 325 mesh
Part;
The granularity mass ratio of aggregate during for product fine grinding is:4 parts of 200 mesh, 2 parts of 325 mesh, the 1 of 600 mesh
Part;
The granularity mass ratio of aggregate when being refined for product is:4 parts of 325 mesh, 2 parts of 600 mesh, the 1 of 1000 mesh
Part;
The aggregate of variant granularity is mixed according to the above ratio before rubbing down product forming ingredient, different grindings is obtained and uses
The aggregate on way.Aggregate during rubbing down product forming ingredient is to be mixed in advance by varigrained particulate material.According to it
Purposes is different, and the product of corase grinding is made into aggregate in proportion by thicker particulate material, and fine grinding is then matched somebody with somebody in proportion by thinner particle
Into its aggregate.During product molding is the mixing particle diameter aggregate mixed in proportion.
The invention also discloses a kind of preparation method of polishing grinding material as described above, include the following steps:
(1) 5-15 parts of 100-200 parts of aggregate and additive are subjected to abundant batch mixing in proportion, obtain mixed dry material;
(2) 1-5 parts of 100 parts of bonding agent and accelerating agent are subjected to abundant batch mixing in proportion, obtain mixed glue solution;
(3) mixed dry material that step (1) obtains is added in the mixed glue solution that step (2) obtains, carries out abundant batch mixing, obtain
To mixture;
(4) in the mixture for obtaining 1-5 parts of addition steps (3) of initiator, it is sufficiently mixed, is finally mixed
Material;
(5) the final mixture that step (4) obtains is poured into mould, is vibrated, when cold curing 12~24 is small after
Form removal obtains the polishing grinding material product.
Embodiment 1
A kind of polishing grinding material, including the material in terms of parts by weight as follows:
100 parts of bonding agent, 5 parts of additive, 100 parts of aggregate, 1 part of accelerating agent, 1 part of initiator;
Wherein, the bonding agent includes the material in terms of following parts by weight:
191#1 part of unsaturated polyester (UP) resin;0.05 part of triallyl cyanurate;0.05 part of dibutyl phthalate and
0.005 part of naphthalenesulfonate formaldehyde condensation compound.
In the present invention, the additive is uniformly mixed including the material in terms of following parts by weight and forms:
21 parts of portland cement, 9 parts of aluminate cement, 70 parts of building gypsum plaster.
In the present invention, the material that the aggregate is included in terms of following parts by weight is made:
100 parts of coal gas slugging, 15 parts of Ludox, 15 parts of boric acid, 10 parts of aluminium powder.
The invention also discloses a kind of aggregate processing method as described above, include the following steps:
--- --- dry --- adding 15 parts of boric acid --- is in 200 DEG C of vacuum for mixing for 15 parts of 100 parts+Ludox of coal gas slugging
--- adding 10 parts of aluminium powder, --- ground and mixed is uniform --- to be heated to 1000 DEG C --- self- propagating is burnt till --- in high temperature furnace for heating
Being crushed with hammer high speed disintegrator --- granularity needed for being classified to simultaneously mixes spare in proportion in advance.
Wherein, the granularity is respectively 120 mesh, 200 mesh, 325 mesh, 600 mesh and 1000 mesh.
The fineness and dosage composition of the aggregate of difference grinding type are as follows:
The granularity mass ratio of aggregate when being roughly ground for product is:4 parts of 120 mesh, 2 parts of 200 mesh, the 1 of 325 mesh
Part;
The granularity mass ratio of aggregate during for product fine grinding is:4 parts of 200 mesh, 2 parts of 325 mesh, the 1 of 600 mesh
Part;
The granularity mass ratio of aggregate when being refined for product is:4 parts of 325 mesh, 2 parts of 600 mesh, the 1 of 1000 mesh
Part;
The aggregate of variant granularity is mixed according to the above ratio before rubbing down product forming ingredient, different grindings is obtained and uses
The aggregate on way.Aggregate during rubbing down product forming ingredient is to be mixed in advance by varigrained particulate material.According to it
Purposes is different, and the product of corase grinding is made into aggregate in proportion by thicker particulate material, and fine grinding is then matched somebody with somebody in proportion by thinner particle
Into its aggregate.During product molding is the mixing particle diameter aggregate mixed in proportion.
The invention also discloses a kind of preparation method of polishing grinding material as described above, include the following steps:
(1) 5 parts of 100-200 parts of aggregate and additive are subjected to abundant batch mixing in proportion, obtain mixed dry material;
(2) 1 part of 100 parts of bonding agent and accelerating agent are subjected to abundant batch mixing in proportion, obtain mixed glue solution;
(3) mixed dry material that step (1) obtains is added in the mixed glue solution that step (2) obtains, carries out abundant batch mixing, obtain
To mixture;
(4) in the mixture for obtaining 1 part of addition step (3) of initiator, it is sufficiently mixed, obtains final mixture;
(5) the final mixture that step (4) obtains is poured into mould, is vibrated, when cold curing 12 is small after form removal
Obtain the polishing grinding material product.
Embodiment 2
A kind of polishing grinding material, including the material in terms of parts by weight as follows:
100 parts of bonding agent, 15 parts of additive, 200 parts of aggregate, 5 parts of accelerating agent, 5 parts of initiator;
Wherein, the bonding agent includes the material in terms of following parts by weight:
191#1 part of unsaturated polyester (UP) resin;0.10 part of triallyl cyanurate;0.10 part of dibutyl phthalate and
0.01 part of naphthalenesulfonate formaldehyde condensation compound.
In the present invention, the additive is uniformly mixed including the material in terms of following parts by weight and forms:
21 parts of portland cement, 9 parts of aluminate cement, 70 parts of building gypsum plaster.
In the present invention, the material that the aggregate is included in terms of following parts by weight is made:
100 parts of coal gas slugging, 25 parts of Ludox, 25 parts of boric acid, 20 parts of aluminium powder.
The invention also discloses a kind of aggregate processing method as described above, include the following steps:
--- --- dry --- adding 25 parts of boric acid --- is in 400 DEG C of vacuum for mixing for 25 parts of 100 parts+Ludox of coal gas slugging
--- adding 20 parts of aluminium powder, --- ground and mixed is uniform --- to be heated to 1000 DEG C --- self- propagating is burnt till --- in high temperature furnace for heating
Being crushed with hammer high speed disintegrator --- granularity needed for being classified to simultaneously mixes spare in proportion in advance.
Wherein, the granularity is respectively 120 mesh, 200 mesh, 325 mesh, 600 mesh and 1000 mesh.
The fineness and dosage composition of the aggregate of difference grinding type are as follows:
The granularity mass ratio of aggregate when being roughly ground for product is:4 parts of 120 mesh, 2 parts of 200 mesh, the 1 of 325 mesh
Part;
The granularity mass ratio of aggregate during for product fine grinding is:4 parts of 200 mesh, 2 parts of 325 mesh, the 1 of 600 mesh
Part;
The granularity mass ratio of aggregate when being refined for product is:4 parts of 325 mesh, 2 parts of 600 mesh, the 1 of 1000 mesh
Part;
The aggregate of variant granularity is mixed according to the above ratio before rubbing down product forming ingredient, different grindings is obtained and uses
The aggregate on way.Aggregate during rubbing down product forming ingredient is to be mixed in advance by varigrained particulate material.According to it
Purposes is different, and the product of corase grinding is made into aggregate in proportion by thicker particulate material, and fine grinding is then matched somebody with somebody in proportion by thinner particle
Into its aggregate.During product molding is the mixing particle diameter aggregate mixed in proportion.
The invention also discloses a kind of preparation method of polishing grinding material as described above, include the following steps:
(1) 15 parts of 100-200 parts of aggregate and additive are subjected to abundant batch mixing in proportion, obtain mixed dry material;
(2) 5 parts of 100 parts of bonding agent and accelerating agent are subjected to abundant batch mixing in proportion, obtain mixed glue solution;
(3) mixed dry material that step (1) obtains is added in the mixed glue solution that step (2) obtains, carries out abundant batch mixing, obtain
To mixture;
(4) in the mixture for obtaining 5 parts of addition steps (3) of initiator, it is sufficiently mixed, obtains final mixture;
(5) the final mixture that step (4) obtains is poured into mould, is vibrated, when cold curing 24 is small after form removal
Obtain the polishing grinding material product.
Embodiment 3
A kind of polishing grinding material, including the material in terms of parts by weight as follows:
100 parts of bonding agent, 10 parts of additive, 150 parts of aggregate, 3 parts of accelerating agent, 3 parts of initiator;
Wherein, the bonding agent includes the material in terms of following parts by weight:
191#1 part of unsaturated polyester (UP) resin;0.08 part of triallyl cyanurate;0.08 part of dibutyl phthalate and
0.008 part of naphthalenesulfonate formaldehyde condensation compound.
In the present invention, the additive is uniformly mixed including the material in terms of following parts by weight and forms:
21 parts of portland cement, 9 parts of aluminate cement, 70 parts of building gypsum plaster.
In the present invention, the material that the aggregate is included in terms of following parts by weight is made:
100 parts of coal gas slugging, 20 parts of Ludox, 20 parts of boric acid, 15 parts of aluminium powder.
The invention also discloses a kind of aggregate processing method as described above, include the following steps:
--- --- dry --- adding 20 parts of boric acid --- is in 300 DEG C of vacuum for mixing for 20 parts of 100 parts+Ludox of coal gas slugging
--- adding 15 parts of aluminium powder, --- ground and mixed is uniform --- to be heated to 1000 DEG C --- self- propagating is burnt till --- in high temperature furnace for heating
Being crushed with hammer high speed disintegrator --- granularity needed for being classified to simultaneously mixes spare in proportion in advance.
Wherein, the granularity is respectively 120 mesh, 200 mesh, 325 mesh, 600 mesh and 1000 mesh.
The fineness and dosage composition of the aggregate of difference grinding type are as follows:
The granularity mass ratio of aggregate when being roughly ground for product is:4 parts of 120 mesh, 2 parts of 200 mesh, the 1 of 325 mesh
Part;
The granularity mass ratio of aggregate during for product fine grinding is:4 parts of 200 mesh, 2 parts of 325 mesh, the 1 of 600 mesh
Part;
The granularity mass ratio of aggregate when being refined for product is:4 parts of 325 mesh, 2 parts of 600 mesh, the 1 of 1000 mesh
Part;
The aggregate of variant granularity is mixed according to the above ratio before rubbing down product forming ingredient, different grindings is obtained and uses
The aggregate on way.Aggregate during rubbing down product forming ingredient is to be mixed in advance by varigrained particulate material.According to it
Purposes is different, and the product of corase grinding is made into aggregate in proportion by thicker particulate material, and fine grinding is then matched somebody with somebody in proportion by thinner particle
Into its aggregate.During product molding is the mixing particle diameter aggregate mixed in proportion.
The invention also discloses a kind of preparation method of polishing grinding material as described above, include the following steps:
(1) 10 parts of 150 parts of aggregate and additive are subjected to abundant batch mixing in proportion, obtain mixed dry material;
(2) 3 parts of 100 parts of bonding agent and accelerating agent are subjected to abundant batch mixing in proportion, obtain mixed glue solution;
(3) mixed dry material that step (1) obtains is added in the mixed glue solution that step (2) obtains, carries out abundant batch mixing, obtain
To mixture;
(4) in the mixture for obtaining 3 parts of addition steps (3) of initiator, it is sufficiently mixed, obtains final mixture;
(5) the final mixture that step (4) obtains is poured into mould, is vibrated, when cold curing 18 is small after form removal
Obtain the polishing grinding material product.
The above is only the preferred embodiment of the present invention, rather than its limitations;It should be pointed out that although with reference to above-mentioned each
The present invention is described in detail in embodiment, it will be understood by those of ordinary skill in the art that, it still can be to above-mentioned each
Technical solution described in embodiment is modified, or carries out equivalent substitution to which part or all technical characteristic;And this
A little modifications and replacement, do not make the essence of corresponding technical solution depart from the scope of various embodiments of the present invention technical solution.
Claims (2)
1. a kind of polishing grinding material, it is characterised in that including the material in terms of parts by weight as follows:
100 parts of bonding agent, 5-15 parts of additive, 100-200 parts of aggregate, 1-5 parts of accelerating agent, 1-5 parts of initiator;
Wherein, the bonding agent includes the material in terms of following parts by weight:
191#1 part of unsaturated polyester (UP) resin;0.05~0.10 part of triallyl cyanurate;Dibutyl phthalate 0.05~
0.10 part and 0.005~0.01 part of naphthalenesulfonate formaldehyde condensation compound;
The material that the additive is included in terms of following parts by weight, which is uniformly mixed, to be formed:
21 parts of portland cement, 9 parts of aluminate cement, 70 parts of building gypsum plaster;
The material that the aggregate is included in terms of following parts by weight is made:
100 parts of coal gas slugging, 15~25 parts of Ludox, 15~25 parts of boric acid, 10~20 parts of aluminium powder;
The aggregate processing method, includes the following steps:
--- --- dry --- adding 15~25 parts of boric acid --- is at 200 DEG C for mixing for 15~25 parts of 100 parts+Ludox of coal gas slugging
--- adding 10~20 parts of aluminium powder, --- ground and mixed is uniform --- 1000 DEG C are heated in high temperature furnace --- for~400 DEG C of heating in vacuum
Granularity needed for being classified to that self- propagating is burnt till --- being crushed with hammer high speed disintegrator --- simultaneously mixes spare in proportion in advance;
The granularity is respectively 120 mesh, 200 mesh, 325 mesh, 600 mesh and 1000 mesh;
The fineness and dosage composition of the aggregate of difference grinding type are as follows:
The granularity mass ratio of aggregate when being roughly ground for product is:4 parts of 120 mesh, 2 parts of 200 mesh, 1 part of 325 mesh;
The granularity mass ratio of aggregate during for product fine grinding is:4 parts of 200 mesh, 2 parts of 325 mesh, 1 part of 600 mesh;
The granularity mass ratio of aggregate when being refined for product is:4 parts of 325 mesh, 2 parts of 600 mesh, 1 part of 1000 mesh;
The aggregate of variant granularity is mixed according to the above ratio before rubbing down product forming ingredient, different grinding purposes is obtained and uses
Mixing particle diameter aggregate.
2. a kind of preparation method of polishing grinding material as claimed in claim 1, it is characterised in that include the following steps:
(1) 5-15 parts of 100-200 parts of aggregate and additive are subjected to abundant batch mixing in proportion, obtain mixed dry material;
(2) 1-5 parts of 100 parts of bonding agent and accelerating agent are subjected to abundant batch mixing in proportion, obtain mixed glue solution;
(3) mixed dry material that step (1) obtains is added in the mixed glue solution that step (2) obtains, carries out abundant batch mixing, mixed
Close material;
(4) in the mixture for obtaining 1-5 parts of addition steps (3) of initiator, it is sufficiently mixed, obtains final mixture;
(5) the final mixture that step (4) obtains is poured into mould, is vibrated, when cold curing 12~24 is small after form removal
Obtain the polishing grinding material product.
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101767318A (en) * | 2010-02-11 | 2010-07-07 | 北京国瑞升科技有限公司 | Granulation polishing film, preparing method thereof and application thereof |
CN102372496A (en) * | 2011-08-18 | 2012-03-14 | 陕西延长石油(集团)有限责任公司研究院 | Material formula for preparing gasification furnace slag ceramisite and production method of ceramisite |
CN102515685A (en) * | 2011-12-27 | 2012-06-27 | 长安大学 | Coal gangue building thermal insulation exterior wall brick and production method thereof |
CN105417987A (en) * | 2015-11-10 | 2016-03-23 | 宝鸡汇德三废开发利用有限公司 | High-modulus asphalt concrete material doped with coal gasification slag and preparation method thereof |
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2016
- 2016-04-22 CN CN201610256613.0A patent/CN105838261B/en not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101767318A (en) * | 2010-02-11 | 2010-07-07 | 北京国瑞升科技有限公司 | Granulation polishing film, preparing method thereof and application thereof |
CN102372496A (en) * | 2011-08-18 | 2012-03-14 | 陕西延长石油(集团)有限责任公司研究院 | Material formula for preparing gasification furnace slag ceramisite and production method of ceramisite |
CN102515685A (en) * | 2011-12-27 | 2012-06-27 | 长安大学 | Coal gangue building thermal insulation exterior wall brick and production method thereof |
CN105417987A (en) * | 2015-11-10 | 2016-03-23 | 宝鸡汇德三废开发利用有限公司 | High-modulus asphalt concrete material doped with coal gasification slag and preparation method thereof |
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